6 VLOL. [ony suns paspaiioonoren saa =] Suppapoun wang op oy susp SUMNOTO, z 1 pusos0q BHISIDeqy/POTIE] 992 wIO}ONG Dip fe amns SopeuOL,| (EH) [oped ammo 093), 1 ogy ured so 7 ped aonpas asagro.| zodea 1 o@ rer | wesis2100/ 18] (ay) 7 | F-2serams TI oN N t Kamp Tins 5 woIo// wea US ATO. Wi woREArGGQ yeote Baysueat> ||) fe r yuszoqop :N rT vos] O}) 1 "AVEOL| ans ~~ WNOLIDES ¢ waava Rave ‘SWSHIS ONDRIVAL “ON.NO. MARKING SCHEME , MARK sue | TOTAL | 2¢@)_[ Na7Mig AT 1 1 @ (28728 T T | fr: 2:8} (OG | Forces of attraction between muclous and electrons is stronger in| 1 T chlorine atom // nuclei attraction towards electron is stronger ia hlorine’atom (e ishighee] a @ © J S|©) Se. A 1. Correct number of electrons and shell with nucleus 1 2 2. Label the charge and symbol of atom (can infer from nucleus) wa 1 1 @ ~ | Sdiniccnductoxi/to produce microchips// fo make concrete? "| 1 T ‘cement / ceramic/ pottery/ enamels (©@ | Chemically inert /! argon atom achieves stable octet electron 1 arrangement @ | Volume of argon gas = 0.002 x 24 // 0.048 dm? // 48 cm? 1 2 TOTAL 2 (CONFIDENTIAL 3NO. MARKING SCHEME ‘3@___ | Tonic compound/substance that can conduct electricity ia molten stale or aqucous solution and underjoes chemical changes. KT, On ©@ [odide ion and hydroxide ion @ | w+ h+2 @@ | Colouriessy gas bubbles releases | 1. Hf iomislowerthan K* ion in the Electrochemical Series 2. Ht_ion'will be selectively discharged to form hydrogen ws ©@ | Oxygen @| 1. Noofmole=24/24000 = 0.001 mol 2. Noofmolecule = 0,001 x 6.02x 10= 6,02x 10” t TOTAL 10 CONFIDENTIAL 4NO. MARKING SCHEME MARK 2 SuB [TOTAL 4@@ | Copper(l) oxide r Te copper oxide] Gi) | Green 1 Gi) | Sodium carbonate / potassium carbonate/ ammonium carbonate 1 3 [a : formula] Ge) | NaxCOs + Cu (NOs)2- + CuCOs +2 NaNO; [based on answer in a(ii)] 1. Correct formulae of reactants and products i 2: Balanced equation 2 @ |. Blue precipitate T 2, Dissolves in excess ammonia solution 1 2 © | 1. Add 2.cm? dilute sulphuric acid followed by 2. cm? of iron 1 . (AD sulphate solution and shake 2. Concentrated sulphuric acid is added slowly/drop by drop 1 3. Brown ring is formed L 3 TOTAL 10 CONFIDENTIAL 5MARKINGSCHEME —~ 5a) “Volume of gas liberated 17 Mass of calcium carbonate oO @ @) @) ‘No of mole = 25 x.0.1 /1000 = 0.0025 mol ‘ 1, 0,0025 mol HNOs produce 0.00125 mol CO 2. Volume of CO2= 0.00125 x 24 = 0.03 dm? Rote : 1. fect from (6)()] 2. Point 2 must be correct with uait ‘Volume of gas! em? pad gaz] em? Time/ s Masals 1, Correct curves with label 2. ° Axis with label & units 1, Rate of reaction of Exp I is higher than Exp 1 1, Exp has higher temperature than Exp. I 2. Kinetic energy of partictes is higher. 3: Frequency of collision between f+ and CaCOs/ COs is higher 4, Frequency of effective collision is higher TOTAL rT aNO MARKING SCHEME” TOTAL 6@) “To allow the movement of fons ® ‘shown it the diagram (fom electrode L to electrode M through external circuit), fr: answers in words] _ oO® @ Tron(iit) fon / Feram({) fon Iron(HIh) sulphate {formula} : Altemative 1 1. Add sodium hydroxide/ammonia solution. 2. Brown precipitate is formed. Alteriative 2 1. Add potassium hexacyanoferrate(H) solution. 2. Dark blue precipitate is formed. Alternative 3 1. Add potassium thiocyanate solution. 2. Blood red colouration is formed. @ Bat 205 Br @ T Solution tunis green 2 ion undergoes reduction to form Ci** ion Girbon elearede porous pot Bromine waterj i MARKING SCHEME ‘SUB | TOTAL MARK | MARKS | (a) G) | P1. Empirical formula is Chemical) formula that shows the 7 i? simplest ratio of hydrogen and carbon atoms in beazene // | ‘Formula that shows the simplest ratio of hydrogen to | carbon atoms in Benzene is 1:1 2, Molecular formula is (chemical) formula that shows the actual number of hydrogen and carbon afoms in benzenci! | 1 4 shows the actual aumber of atoms which are ‘Ghydrogen and 6 carbon in benzene. @ | ethanol,C, HOH // water,H,0 // magnesium oxide, MgO 1 fa: any compound where its empirical formula and molecular formula is the same] oOo | ‘Hlement c H ~ ‘Number of molo | 80/12=667_| 201 =20 Simplest ratio of | ~6.67/667=1 | 2016.67=3 1 I moles 1 i ‘Empirical formula of the compound is CE, 1 ; . [ctbJn=30 [12430)]n=30 a=2 1 ‘ ‘Motecular formula of the compound is CH . 1 { Max 4 A @ | Cots + 712 02> 2002+ 320 1 Correct formula of reactants and products a if Balanced equation 1 i o@ Hydrocarbon | Homologous Nemo E alkane butane 5 “fom ppm bye = ae > coteene - ee ee ee i (@ [PLT produces more sootihan E. T ! P2.& P3. Calculation i E a | ACD} x 100 = 82.76 | AD) x 100 = 85.71 %ofcartoa | 58 56 i ‘% of carbon by mass ia J is higher than E 1H ; 1 4 | J TOTAL 20 CONFIDENTIAL 8NO EXPLANATION ‘SOB TOTAL 8@O coy Substance P g Name | Bronze Borosilicate glass Specific | Shiny surface | Withstand high Properties | Docs not corrode | temperature// casily/fnard and | Resistant to chémicals strong, ‘Movs thermal expansion i 4 PI P2, Diagram ‘copper Pare, copper Alloy P P3. Alloy P/bronze is harder than pure copper P4, Atomic size in pure copper is the same, atomic size in alloy Proronze is different. PS, Atoms in pure copper are orderly arranged while atoms in “alloy P/oronze are not orderly arrariged. 6. When fore is applied, layer of atoms in pure copper is ‘easier to slide than in alloy P/ bronze. Mm Pi. Sulphur dioxide bumnt/react with excess oxygen to produce sulphur trioxide. 2. Passed over vanadium(V) oxide catalyst at 450°C, 1 atm 3. Chemical equation : 2802+'O2 -> 2803 3. Step 2: Oleum is diluted with water to produce sulphuric acid, PA. Hz807 + HzO > 212504 PI. Moles of S = 48732=1.5 mol P2, 1 mol of S produce 1 mol SO ‘Thus, 1.5 mol of S produce 1.5 mol SO P3.Volume of S02 = 1.5 x 24 dm?=36 dm? TOTAL |RO, ‘EXPLANATION MARKS OO Pi.Correct suggestion for solution T Eg. Copper (i) sulphate solution / ‘Sodium chloride/ zine sulphate solution / sulphuric acid P2. Comect suggestion for solution V ‘Eg. Glucose solution/benzene/ ethanoYmethylbenzene 3, Solution T has fice moving ions. 4, Solution V is made up of neutral motccules// docs not have free moving ions @ I, Zinc is more electropositive than copper. 2. Zine atom releases electron to form zinc fon Za? 3, Half equation: Za-> Zn™* +2¢ P4. Electrons flow through extcmal cireut to the copper electrode IE Tis copper(I) sulphate solution PS. Copper(0) ion receives electron to form copper atom 6, Half equation: Cu" +2¢-> Cu OR -Tiasodinm chlocie solution {3 : PS. Hydrogen ion reccives electron to form hydrogen 6, Half equation: 24° + 2c -> He @ PI. Materials :2.0 mol dar? sodium hydroxide, distilled water 2, Apparatus : volumetric flask100 cm, pipette 25 em*, [note : Pi & P2 can be inferred from procedure] Mii = M2V2 P3. 20x Vi=0.5 x 100 ‘Vi=25 em? Procedure = 5. Pipette 25 cm? 2.0 mol day” of sodium hydroxide solution. ‘P6. Transfer the solution into a volumetric flask. P7. Add distilled water into the volumetric flask. P8. until reaches the calibration mark. 9. Close/ Put stopper on the volumetric flask. ‘P10.Shake the volumetric flask. 10 TOTAL, CONFIDENTIAL 10 6NO. EXPLANATION MARK 40 | PI. L:Mg/ Magnesium @@ | P2.R:Zn/ Zine [Note : 1. L:must be more eleetropositive than R 2. Both L and R must be more electropositive than Cu 3, The heat of displacement for Experiment lis higher than Experiment I 4, The distance between L / Cu is bigger/furtherin the Electrochemical Series / L is more electropositive than R @ Mg * CiSO,-> MgSO, + Cu PI. Conrect chemical formula of reactant and product P2, Balance chemtical equation. < ladp metal L but shoutd be more clectropositive than Cu} P3. Number of mole of CuSO4= 0.250 // 0.01 1000 4. 1 mol of Ci displaced release 3360003. heat PS. .:0.01 mol of Cu~> 336000 J_x 0.01 mol heat Tmot =33603 6. Changc'in temperature = 3360 rest =16°C PI. Apparatus: Polystyrene cup , thermometer, ‘measuring cylinder (suitable volume) 2. Materials : [suitable salt solutions to recipitatc/any insoluble salt] Eg. Lead(i) nitrate solution, sodium sulphate sotution Procedure: 3, Measure [25-200] cm of [0.1-2.0] mol dm fead(I1) nitrate solution. P4, Pour into a polystyrene cup. 5. Measure [25-200] cm? of {0.1-2.0] mol dan sodium sulphate solution. 6. Pour into a different polystyrene cup. 7. Mcasure the initial temperature of both solutions. 8. Pour sodium sulphate solution quickly into tead(1) nitrate solution [a: vice versa] P9, Stir the mixture. 50X42 ccf PS from P3] ® P10. Record the highést temperature'fr: Final temperature] | 10 TOTAL CONFIDENTIAL n 20 i i‘MARKING GUIDELINES SIJIL PENDIDIKAN MESM, 2014 ~~~ PAPER2—— ~~ Symbot uw ~ replace the whole sentence Oo. = \ replace the previous word 1 = cam be summarised from explanation __orbold =. . key-word aap = avoid double penalty wer =_ + Wrongeanect right 2 =" accept 5 = reject ef = error carry forwand ! - oF (CONEIDENTIAL 2 aSHJIL PENDIDIKAN MAKTAB RENDAH SAINS MARA 2014 SULIT ee CHEMISTRY -- PAPER 3 MARKING SCHEME