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Code No.:) (Time Allowed: 3 Hours) (Maximum Marks: 70
Code No.:) (Time Allowed: 3 Hours) (Maximum Marks: 70
.
Series : SSO/1/C Code No. 56/1/1
- -
.
Roll No. Candidates must write the Code on
the title page of the answer-book.
- 11
- - -
- 26
,
- 15 - 10.15
10.15 10.30 -
-
Please check that this question paper contains 11 printed pages.
Code number given on the right hand side of the question paper should be written on the
title page of the answer-book by the candidate.
Please check that this question paper contains 26 questions.
Please write down the Serial Number of the question before attempting it.
15 minutes time has been allotted to read this question paper. The question paper will be
distributed at 10.15 a.m. From 10.15 a.m. to 10.30 a.m., the students will read the
question paper only and will not write any answer on the answer-book during this period.
()
CHEMISTRY (Theory)
: 3 ] [ : 70
Time allowed : 3 hours ] [ Maximum Marks : 70
:
(i)
(ii) - 1 5 - 1
(iii) - 6 10 - 2
(iv) - 11 22 - 3
(v) - 23 4
(vi) - 24 26 - 5
(vii)
56/1/1 1 [P.T.O.
General Instructions :
(i) All questions are compulsory.
(ii) Q. No. 1 to 5 are very short answer questions and carry 1 mark each.
(iii) Q. No. 6 to 10 are short answer questions and carry 2 marks each.
(iv) Q. No. 11 to 22 are also short answer questions and carry 3 marks each.
(vi) Q. No. 24 to 26 are long answer questions and carry 5 marks each.
1. : (z) ?
What is the no. of atoms per unit cell (z) in a body-centred cubic structure ?
2.
In reference to surface chemistry, define dialysis.
3. [Ni(NH3)6]Cl2 (IUPAC)
What is the IUPAC name of the complex [Ni(NH3)6]Cl2 ?
4.
3-
Draw the structure of 3-methylpentanal.
5. :
C6H5N2Cl + H3PO2 + H2O - - -
7. :
(i) (t)
(ii) (k)
Define the following terms :
(i) Half-life of a reaction (t)
8. :
(i) H2SO4
(ii) XeF2
(ii) XeF2
9. ?
:
(i)
(ii)
What is meant by disproportionation ? Give an example of a disproportionation
reaction in aqueous solution.
OR
Suggest reasons for the following features of transition metal chemistry :
(i) The transition metals and their compounds are usually paramagnetic.
(ii) The transition metals exhibit variable oxidation states.
56/1/1 3 [P.T.O.
10. :-
H+
CH3CH2OH CH2 = CH2 + H2O
443 K
Explain the mechanism of dehydration steps of ethanol :-
H+
CH3CH2OH CH2 = CH2 + H2O
443 K
11. :
(i)
(ii)
(iii) F-
Define the following :
(i) Schottky defect
(ii) Frenkel defect
(iii) F-centre
(i) Electrophoresis
(ii) Adsorption
15. :
(i)
(ii)
(iii)
(Pig) ?
Outline the principles of refining of metals by the following methods :
(i) Distillation
(iii) Electrolysis
OR
Write down the reactions taking place in different zones in the blast furnace during the
extraction of iron. How is pig iron different from cast iron ?
16. ? ?
What is lanthanoid contraction ? What are the consequences of lanthanoid contraction ?
56/1/1 5 [P.T.O.
17. :
(i) [Co(NH3)5(NO2)]2+
(i) [Co(NH3)5(NO2)]2+
(iii) [Pt(NH3)2Cl2]
18. (IUPAC) :
(i) CH3 CH CH2 CH3
|
OH
(ii)
CH3
|
(iii) CH3 C CH2 Cl
|
CH3
(ii)
CH3
|
(iii) CH3 C CH2 Cl
|
CH3
56/1/1 6
19. ?
(i) -2-
(ii)
(iii) p-
How are the following conversions carried out ?
(i) Propene to propane-2-ol
(ii) Benzyl chloride to Benzyl alcohol
(iii) Anisole to p-Bromoanisole
20. A B
Br2 KOH C C C6H7N
A, B C (IUPAC)
An aromatic compound A on treatment with aqueous ammonia and heating forms
compound B which on heating with Br2 and KOH forms a compound C of
molecular formula C6H7N. Write the structures and IUPAC names of compounds A, B
and C.
21. ?
How are vitamins classified ? Name the vitamin responsible for the coagulation of
blood.
22. :
(i) -S
(ii)
(iii)
Write the names and structures of the monomers of the following polymers :
(i) Buna-S
(ii) Neoprene
(iii) Teflon
56/1/1 7 [P.T.O.
23. -
-
(i)
(ii) ?
(iii) ?
Ramesh went to a departmental store to purchase groceries. On one of shelves he
noticed sugar-free tablets. He decided to buy them for his grandfather who was a
diabetic. There were three types of sugar-free tablets. Ramesh decided to buy
sucrolose which was good for his grandfathers health.
(i) Name another sugar free tablet which Ramesh did not buy.
(ii) Was it right to purchase such medicines without doctors prescription ?
(iii) What quality of Ramesh is reflected above ?
24. (a) :
(i) (^m)
(ii)
(iii)
(b) :
(i)
(ii)
(a) -
(b)
Ni(s) | Ni2+(aq) || Ag+(aq) | Ag(s)
25 C
?
E = 0.25 V, E + = 0.80 V.
Ni2+/Ni Ag /Ag
56/1/1 8
(a) Define the following terms :
25. (a) :
(i) Cu + HNO3()
(i) Cu + HNO3(dilute)
(b) (i) Why does R3P = O exist but R3N = O does not ? (R = alkyl group)
OR
(b) Describe the contact process for the manufacture of sulphuric acid with special
reference to the reaction conditions, catalysts used and the yield in the process.
26. (a) :
(i)
(ii) -
(b) ?
(i)
(ii) m-
(iii) 3-
(a) :
(i)
(ii)
56/1/1 10
(b) :
LiAlH4
(i) CH3 C CH3 ?
||
O
CHO
HNO3 / H2SO4
(ii) ?
273 283 K
PCl5
(iii) CH3 COOH ?
OR
(a) Describe the following actions :
(i) Acetylation (ii) Aldol condensation
(b) Write the main product in the following equations :
LiAlH4
(i) CH3 C CH3 ?
||
O
CHO
HNO3 / H2SO4
(ii) ?
273 283 K
PCl5
(iii) CH3 COOH ?
___________
56/1/1 11 [P.T.O.
56/1/1 12