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SELECTED THERMODYNAMIC PROPERTIES OF GASES Comprisinc C-H-O-N System TABLES A.1 TO A.12 Ideal-gas values for standard reference state (T= 298,15K, P = latm) for ET) FD) ~ licers BT) ET) BAT) for CO, CO;, Hp, H, OH, Hy0, No, N, NO, NO», 03,0. Enthalpy of formation and Gibbs function of formation for compounds are calculated from the elements as HAT) = WAT) ~ YO vig) BAT) = 8D) — Yo vign(7) =hD- THT) YL vi[-THITY] SOURCE: Tables were generated from curvefit coefficients given in Kee, R. J., Rupley, F. M., and Miller, J. A., “The Chemkin Thermodynamic Data Base,” Sandia Report, SAND87-8215B, March 1991 TABLE A.13 Curvelt coeficients for (7) for the same gases as above, SOURCE: ibid oz 622 Appendix A Table A.1 _Corbon monosde (CO), MW = 28.010, enthalpy of formation @ 298K {kuhmol = 110,541 HO) TT) Tm) (usmotk) afar) (fmol) Ga/hmel-K) (AS /Ame) m0 DRT —25 Ting 186011282 pm Stas srs Sista jo ore Sto ig 137328 an Stoo meta 146382 so 29st Tiao 21272 issn ao oa07 Tos 218282 —tos4a70 soo 31.089 mom -m9 a0 31860 gris “lazer mo 32609 Soo “iste tom 255 asso 200238 hoo 3335 aren “wow 12003148 dws “2IT768 10034530 rage Lagan iano eure isos “238087 1500 35:78 hem -2aa6t4 Too 3sst son 252214 1700 gas “0711 1800 Taae 168 1300 deere “271516 200 ashi? 2es948 S00 deosi “254281 2200 aso 302576, 200 gars “3108s 200 asa “319057 2500 dees “ars 200 waa “3S 2100 dees —unsi9 Zao moor “3sts 2900 mms “asst 000 mse a6re84 00 mars Laser m0 Zon 3439 3300 mo “w1sn 300 zaam 3500 z202 00 moms “a1si92 30 gna hoe ant mass 0.796 20 nase “87 000 ios dean “a46291 a0 134806 pasaaa 453907 am asks ees 461677 a0 ray dsnoss “459320 400 ese der91s——areas7 “00 19988 28.768 588 “a0 sis dean “aon 40 157581 enais esses Toble A.1 7) 00 $900) 5.00) (continued) a (We) — 0%) CT) (esfhmolky (kina) shan) 38019 6342 146 589 380m 6s las =197783 38083 1.938 = 138987 Appendix A 62a ) Hr) (sfhaob) Geshe) 21219 S070 pros si4710, LT 22186 624 Appendix A Table A.2 Coron dioxide (CO2), MW = 44.011, enthalpy of formation @ 298K (iu/kmel} = -293, 546 ey ((r)— a9) (T) a7) a TK) Gfimol-k)——_(es/Amol) (ksfhot) (amok) (hol) ao 32387 Tyes4ss 199876 394,106, rs 31198 Sands 213736 394028 30037280 HhSdT 213966 394.433 4 41276 Ss36i7 225257394718, soo 4369 H3372 Daas 394983, 6 313 Kanes 243209 395.226, 70 49617 2s0.ss0 395,443 too 51.580, 257436 3856835 990 S336 263603 395,799 1000 $4360 269.268 395,939 58.333 214495 396056 56.205, 29.348 396,185, S984 23878 396,236 srn 2eg.127 396,301 S292 Drie 396382 58436 396389 9.316 sold 59.738 = 396.425 co. =396404 oass =3964410 717 396.384 60.966 396,346 8s 396.294 ists =396230 sia 396152 61701 = 396,061 619 =395957 61965 = 395840 e208 395,708 e298 =395,562 62301 3951403 62.406 95229 62510 =395041 sis 395,538 ay =398600, ans 398,388, on S394 3.081 393.879 63.131 393,602 63.261 393.3 63.369 4357s 393.008 ssa74 355253 392.683, es7s 356748 ~392346 63.669 338210 391,995, 63753 33962 391/609 63.825 solos ~391.247 63.881 ae24l7——2904851 TobleA2 (continued) B in) a 0%) HT) TK) _dusmotk) —asfaat) may ‘asio eine 266508 re) 9m 6h9n2 mimo ait267 5000 63.919, ren 412010 (r) (bajamot-) 368.763 365.081 366.372 Appendix A a spat) 290.40 3900014 = 39,572 625 626 Appendix A Table A3 Hydrogen (He), MW = 2.016, enthalpy of formation @ 298K (kimal) = 0 & Hee) BT) Tek) (hsphmot) (d/l) asia) asfamolK) —_ifkmod 2028522 2818 0 9.37 ° ae 28871 ° ° 130.393 ° 2s ° 130773 ° 9120 ° a6 o 29208 ° 145632 0 29375 ° 150979 ° 25461 ° Assia ° 281 ° 159.455 ° 29792 ° 162950, ° 30.160 ° 166.106 0 soars ° 169.003, ° 3107 ° 111.687 0 31316 ° 7492 ° 31983 ° 16348 © 32.356 ° 178761 ° 52788 ° 10.862 ° 33146 ° 182.860 ° sas ° 184768, ° 5.885 ° 186387 ° 34236 © 186384 ° 36575 ° 10.018, ° 38901 0 91.69 ° 33216 ° ess? ° 33319 ° itn ° sail ° 196.148, ° 6091 © 197388, ° 36361, ° 198926, ° ieeat 0 200258 ° 36871 ° noise ° aru ° 202.796 ° 3138 ° 204017 0 37366 ° 208206, 0 sr781 59.968 ° 206.365 ° 31989 103.157 ° 207496 ° 38.190 107 566 o 208.00, ° 38.85 111385 ° 209679 ° sare 18248, ° 210733, ° 33759 119,109, ° 211768 o 38939 122908 ° 274 o 38.116 136897 ° 21378 ° e201 ‘boat ° 218730 ° 59.64 134755 0 216% © 39.636 138.710 0 216.609 ° 59.808 1.682 ° ° 39981 146672 ° ° 40.156 150,679 ° ° 4034 14.208 6 ° Appendix A 627 Table A3 continued) a Ha) m7) (1) em TOK) _(ksfhrwokK) (AS /hmol) (cSfhanol) —(As/kmol-K) (kl Jhmot) 430040516 ssc46 ° aioe ° ‘$900 40.702 162,806 0 Di3si ° 5000 40.895 166.886 0 mors ° 628 Appendix A Table Ad Hydrogen atom (H], MW = 1.008, enthalpy of formation @ 298K ki/kmel) 17,977 3 (T) = Ha) HD (7) Hn) T(K)_(hafkinolK) (43h) (s/he) (43/kmol-K) (kJ/mol) 20020786 2,000 207.99) ae 20786 ° 203.276, 30020786 8 203.85 000786 247 198,155 500 20.786 4196 192968 coo o.786 om 187.687 00 20.786 335 12.244 20.786 10331 sit 20.786 12510 137569 20.786 14389 139.159 20786 16.667 141.740 20.786 18746 143589 20786 20804 145213 20786 22303 14675314261 20.786 24982 148187136596, 20786 149528 130,300, 20786 130789124777 20786 1sL977 118830 20786 133101112889 20786 134167 106.869 20786 1ssi81—— 100.860 20786 136.148 9483 20786 isto 83.798 20786 15798682739 20786: 2st 158.805 6872 20786 287 159620 70,593 20.786 29.087 160405 4.508 20.786 229301 161.161 58.405 20.786 2958 161890 52298 20.786 297 12.395 46182 20.786 2997 168.276 a0 58 20.786 230,95 163936 33938 20.786 230,350 29 20.786 230576 21/650 20.786 230,348, 15302 20786 230812 9350 20.786 231,067 394 20.786 21212 2967 2076 231348 9.132 20.786 Bias 15299 20.786 aise 21470 20.786 231708 2h 20.786 2313805 3520 20786 aia =39998 20.786 231.981 46,79 20.786 2323056 52361 20.786 22,13 =58,545 Table As Te) “400 +4900 5.000 (continued) (u/amot) 20786 20.786 20786 er) — has) (sana) 975 95.654 97933 (esha) 4) wr) (es/hinohk) 173.368 172793 mans Appendix A a) ashi) 68730 ~70316 =77103 629 Appendix A Table AS Hydroxyl (OH), MW 38,985 7.007, enthooy of formation @ 298K (ki/kmol) 5 Rem) ser) Tew) _(s/hmolK)—_—__/) (kifkmot) —(hs/kmol-K) (kha aw 0 ~28 sence «7G «3808 et Bases Iho soo 29928 3987183789 34250 3028718 wo 182393282 so 29570 son 198983 sm 295827 35909 204368 im 29415 377020895, ssa 38599212893, 500 30.208, 3310 216428, 100 304682 sam 219638 100 3.186 3R039 222583 12031662 mise) 25317 130 Satie ses 227868 14003240 ssa 230265 32983 Mas 232524 ja was 4662 33082 09236698, saois 36959 28.628 baa dea 0476 34935 seers 2422485 34915 sesss 283942 38178 Beale 45572 352s 362% 141 35656 36133 248.654 33872 38986 250.114 36078 35836251528, 36263, 35682252890 3639 a3sm 254212, 36.04 35360 55498, 36739 1 256337 36903 35016 257.945 so basis 29.118 1166 Baeis 260.260, s12385, seasé 260371 31358, Mas 22434 w1308 30s 263.500 108, SSA 264538 37701 33610268342 1098 aaa 266522 57882 33M6 267480 57968 sass 268.417 s80s2 ses 269388 3a135 sas 270209 34217 sane nhao7 38300 SiR) 271967 38382 313s 272.800, 3866 31305273636, Toble AS 1K) 800 $900 5.00 (continued) (smolk) Appendix A 631 (O)— 5am) (7) aa) (uyamot) (ijkl) (Ad /kmol-K) (Iho) 157836 BLO) —2TaaM | 26.956 it 395 yom sz 2x61 Ies.268 30822 arson 293360 Appendix A Table AS Wotor 20), MW. = ~241,845-entholy of vaporization (ki/kmol) 18.016, enthalpy of formation @ 298K (ki/kmel) 14,010 Oho) RT) Tek) @asfaewok) —_(ks/kmol) Gesfanat)—(ka/AmolK) Cfo) 32258 —oase 1756022279 33448 Saaigss 188715, 33.468 Suinss isso. Mast 242858 198.686 33397 =13.522 206467 36288,

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