MARKING SCHEME CHEMISTRY PAPER 2

SPM TRIAL 2016

SKEMA KIMIA KERTAS 2
PEPERIKSAAN PERCUBAAN SPM 2016

No of Mark Scheme Total

Questions Mark
1 (a) W 1
(b)(i) V 1
(ii) - Atomic size of V is bigger than U. 1
- The force of attraction of nucleus to valence electron in atom V is weaker 1
compare to atom U
- Atom U can easily release one valens electron to achieve stable octet 1
electron arrangements. Max
Saiz atom V levih besar dari atom U 2
- Daya tarikan antara nucleus dan elektron valens dalam atom V lemah
berbanding atom U.
- Atom U senang menderma satu elektron valens untuk mencapai susunan
oktet yang stabil
(c) Y 1
Covalent bond/Ikatan kovelan 1
(d) Z, X, U, Y, W, V 1
- The number of proton increases across period 1
- The force of attraction between nucleus to valence electron/ electron on 1
outer shells becomes stronger
- Bilangan proton bertambah merentasi satu kala
- Daya tarikan nucleus terhadap elektron valens semakain kuat .
TOTAL 9

Number of Mark scheme Total

Question mark

2 (a) Chemical formula that shows the simplest ratio of atom of elements in the
compound 1
formula kimia yang menunjukkan nisbah paling mudah atom unsur-unsur dalam
sebatian
(b)(i) Able to calculate the mass of copper and oxygen with unit
- mass of copper 1
jisim kuprum : 37.76 35.20 = 2.56g
- mass of oxygen 1
jisim oksigen : 38.40 37.76 = 0.64g
(b)(ii) Cu : O
 2.56/64 : 0.64/16 1
0.04 : 0.04
1 : 1
(b)(iii) CuO 1
(c) Remove all the air from the apparatus before the oxide of
copper is heated 1
Singkirkan semua udara dari radas sebelum oksida kuprum dipanaskan

The flow of hydrogen gas is continued throughout the cooling of the

product
gas hidrogen dialirkan secara berterusan sepanjang eksperimen.

Any one answer correct

(d) CuO + H2 H2O + Cu 1

(e) Cannot. Magnesium is more reactive than hydrogen // Magensium is higher
position than hydrogen in reactivity series. 1+1
Tidak boleh. Magnesium lebih reaktif daripada hidrogen.// Magnesium berada di
atas hidrogen dalam Siri Kereaktifan logam.
TOTAL 9

Number of Mark scheme Total

Question Marks

3 (a)(i) The food taste better/more delicious 1

Rasa makanan lebih baik/ rasa lebih sedap
(a)(ii) food colouring/colouring agents 1
Pewarna makanan/ Agen pewarna
(a)(iii) Dyes 1
Dye
(a)(iv) Benzyl ethanoate 1
Benzyl etanoate
(b) (i) Type of medicine: Analgesics 1
Jenis ubat : analgesic
Example : Codeine 1
Contoh : Kodein
(b)(ii) Streptomycin is used to treat diseases caused by bacteria 1
If the patients have not finish the doctors prescription, the bacteria will multiply
and
It will immune the disease. 1

Streptomycin digunakan untuk sakit yang disebabkan oleh bakteria. Jika pesakit
tidak menghabiskan ubat yang telah dipreskripsikan oleh doktor, bakteria akan
membahagi lagi dan bakteria akan immun dengan penyakit tersebut.
(c) (i) Aspartame/ sorbitol/ stevia 1
Apartam/sorbitol/stevia
 (c) (ii) Government should spend lot of budget to cure the patient/ 1
Productivity reduce due to commitment of worker with hospital/ leave/
If the patients got amputated, their ability to move/ work are very limit
Any suitable answer

Kerajaan akan membelanjakan bajet untuk merawat pesakit/

Produktiviti akan berkurang kerana komitmen pekerja untuk ke hospital/ cuti
Jika pesakit dipotong kaki, mereka sangat terhad untuk bergerak/ bekerja
Mana-mana jawapan yang sesuai

TOTAL 10

Number of Mark scheme Total

Question mark
4 (a)
1

(b)(i) Hydrogenation/ reduction 1

Penghidrogenan/ penurunan
(ii) Catalyst nickel/ platinum and temperature 180-200oC 1
Mangkin nikel/ platinum dan suhu 180-200oC
(c)
C4H9OH C4H8 + H2O

1. correct formula of reactant 1

2. correct formula of products 1

(d) Acidified potassium dichromate(VI) solution/ acidified potassium 1

manganate(VII) solution
Larutan kalium dikromat(VI) berasid/ larutan kalium manganat(VII) berasid
 (e)(i) C4H9OH + C3H7COOH C3H7COOC4H9 + H2O
1. correct formula of reactant 1
2. correct formula of products 1

(ii) Butyl butanoate 1

Butil butanoat
TOTAL 10

Number of Mark scheme Total

Question mark
5 (a) (i) Carbon dioxide, CO2 1
Karbon dioksida, CO2
(ii) Yellow 1
kuning
(b) (i) PbCO3 + 2HNO3 Pb(NO3)2 + CO2 + H2O 2
(ii) Solid P dissolve and formed colourless / colourless bubbles gas released 1
Pepejal P larut dan larutan tidak berwarna terhasil /
(iii) lead (II) iodide 1
plumbum (II) iodida
(iv) Pb2+ + 2l- Pbl2 1
(c) Add 2cm3 of dilute sulphuric acid and 2cm3 Iron (II) sulphate solution into 1
solution S.
Masukkan 2cm3asid sufurik cair dan 2 cm3 larutan ferum (II) sulphate ke dalam
larutan S.

A few drops of concentratred suphuric acid is added slowly the side of the text
tube to mixture.
1
Beberapa titis asid sufurik pekat dimasukkan secara perlahan melalui tepi tabung
uji ke dalam campuran itu.

Brown ring is formed. 1

Gelang perang terbentuk.

TOTAL 10

Number of Mark scheme Total

Question mark
6. (a)(i) The reaction that involves oxidation and reduction that occur 1
simultaneously
Tindak balas yang melibatkan pengoksidaan dan penurunan berlaku pada masa
yang sama

(a) (ii) Colourless solution of potassium bromide change to brown 1

Larutan kalium bromida yang tidak berwarna berubah kepada perang

(a) (iii) 1. Correct formula of reactant and product 1

 2. Balanced 2I- I2 + 2e 1

1. Formula bahan tindak balas dan produk yang betul

2. Seimbang 2I- I2 + 2e

(b) Add starch solution into the solution 1

A dark blue colour is formed. 1
Tambahkan larutan kanji kepada larutan.
Warna biru gelap terhasil
(c) 1. Chlorine water 1
2. Chlorine accept / receive electron 1
1. Air klorin
2. Klorin menerima elektron
(d) 0 to -1 1
0 kepada -1
(e) 1. Functional apparatus 1
2. Label 1

1. Alat berfungsi
2. Label

Bromine water
Air bromin

Iron(II)sulphate Sulphuric acid

Ferum(II)sulfat Asid sulfurik
TOTAL 11

Number of Mark scheme Total

Question Mark
7 (a)(i) 2.8.1 1
(ii) R- metal/logam 1
S and T- non metal/ bukan logam 1
(b)(i) RS 1
 2

Solid state: ion cannot move freely 1

Pepejal: ion tidak boleh bergerak bebas
Solution:ion can move freely 1
Larutan; ion boleh bergerak bebas
(ii) 1. High melting & boiling point/ 1
Takat didih dan takat lebur yang tinggi
2. Need a lot heat energy 1
Perlukan banyak tenaga haba
3. to overcome electrostatic forces between ion
untuk mengatasi daya tarikan elektrostatik antara ion. 1
4. Soluble in water
Larut dalam air 1
5. Ion are disociate in water for freely moving ions
Ion-ion terurai di dalam air membentuk ion bebas bergerak.
1

(c) 1. T atom has four valence electron/2.4/proton no 6 1

Atom T mempunyai 4 elektron valens/2.4/ nombor proton 6
2. Q atom has seven valence elektron 7/ 2.8.7/ proton no. 17 1
Atom Q mempunyai 7 elektron valens/2.8.7/no proton 17.
3. T atom contributes four electron for sharing 1
Setiap atom T menyumbang 4 elektron untuk dikongsikan
4. Each S atom contributes one electron for sharing 1
Setiap atom S menyumbang satu elektron untuk dikongsikan
5. to achieve a stable octet electron arrangement 1
Untuk mencapai susunan elektron oktet
6. One T atom shares four pairs of electrons with four S atoms
1
Satu atom T berkongsi 4 pasang elektron dengan 4 atom S.

2
 1
MAX
7

7.TS4
TOTAL 20

Number of Mark scheme Total

Question mark

8 (a) (i) The minimum energy required by a reactant before a chemical reaction can 1
take place.
Tenaga minimum yang diperlukan oleh satu bahan tindak balas sebelum suatu
tindak balas kimia boleh berlaku.
(b)
Energy
Tenaga

xkJ O2 + 2H2O

2H2O2

-Correct shape 4
-Label energy axis
-Label reactant and product
-Label xkJ

(c) (i) The volume of gas produced per unit time (per second) 1
 Isi padu gas dihasilkan per unit masa (per saat)
(ii) 1
Experiment I Eksperimen I = 3
// 0.5 cm s -1 1
1

Experiment II Eksperimen II = //0.83 cm3 s-1

Experiment III Eksperimen III = //2.0 cm3 s-1

(d) Experiment I and Experiment II
Eksperimen I dan Eksperimen II

Rate of reaction of Experiment II is greater than Experiment I. 1

Kadar tindak balas Eksperimen II adalah lebih tinggi daripada Eksperimen I.
The concentration of H+ ions is higher in Experiment II.
Kepekatan ion H+ adalah lebih tinggi dalam Eksperimen II.
1
Frequency of collision between H+ ions and calcium carbonate is higher.
Frekuensi perlanggaran antara ion H+ dan kalsium karbonat adalah lebih tinggi. 1
Frequency of effective collision is higher.
Frekuensi perlanggaran berkesan adalah lebih tinggi.
1
Experiment II and III
Eksperimen II dan III

Rate of reaction of Experiment III is greater than Experiment II. 1

Kadar tindak balas Eksperimen III adalah lebih tinggi daripada Eksperimen II.

The size of calcium carbonate in Experiment III is smaller has bigger total 1
surface area.
Saiz kalsium karbonat dalam Eksperimen III adalah lebih kecil mempunyai
jumlah luas permukaan yang besar.

Frequency of collision between H+ ions and clacium carbonate is higher. 1

+
Frekuensi perlanggaran antara ion H dan kalsium karbonat adalah lebih tinggi

Frequency of effective collision is higher.

Frekuensi perlanggaran berkesan adalah lebih tinggi. 1

(e) The volume of gas of experiment III is double compare to Experiment II . 1

Isipadu gas bagi Eksperiment III adalah dua kali ganda berbanding
Eksperiment II.
Volume of carbon dioxide (cm3) 2
Isipadau karbon dioksida (cm3)
Experiment III
Reaction 1 Reaction II
Tindakbalas 1 Tindakbalas II
Exothermic Endothermic
Eksotermik Endotermik
Total energy content of the Total energy content
products is lower than the of the products is
total energy content of higher than the total
reactants energy content of
reactants
Jumlah kandungan tenaga Experiment II
hasil tindakbalas lebih rendah Jumlah kandungan
berbanding jumlah tenaga hasil
tindakbalas bahan tindak tindakbalas lebih
balas tinggi berbanding Time/s
jumlah tindakbalas Masa/s
bahan tindak balas TOTAL 20
H is negative H is positive
H ialah negatif H ialah positif
Formation of chemical bonds Breaking of
Pembentukan ikatan kimia chemical bonds
Pemutusan ikatan
kimia
Energy absorbed to break the Energy absorbed to
bond < energy break the bond >
release energy release

Tenaga yang diserap untuk Tenaga yang diserap

memecahkan ikatan< tenaga untuk memecahkan
yang dilepaskan ikatan> tenaga yang
dilepaskan
Number of Question
Mark scheme
Total mark
9.
(a)

1
1

(b)
Suitablesalts:copper(II)sulphate/copper(II)nitrate/copper(II)chloride
Garamyangsesuai:kuprum(II)sulfat/kuprum(II)nitrat/kuprum(II)klorida

R:copper(II)carbonate
R:kuprum(II)karbonat

Procedureoftheexperiment
Prosedureksperimen
1. Using a measuring cylinder, (20.0 100.0)cm3 of (0.1 - 2.0 )mol dm-3 copper(II)
sulphate solution is measured
Dengan menggunakan silinder, sukat (20.0 100.0) cm3
(0.1-2.0 mol dm-3) laruran kuprum (II) sulfat.
Noted : ADP the name of salt suggested

2. Pour into a plastic cup.

Tuangkan ke dalam cawan plastic

3. The temperature of the solution is measured

Suhu awal larutan diukur

4. The zinc powder is poured into copper (II) sulphate solution.

Serbuk zink dituang ke dalam larutan kuprum (II) sulfat.

5. Then, the content of plastic cup is stirred

Campuran di dalam cawan plastic dikacau

6. Highest temperature is recorded.

Suhu tertinggi campuran dicatatkan

Results
Keputusan
Highesttemperature x
Suhutertinggi
Initialtemperature y
Suhuawal
Temperaturechange z
Perubahansuhu

Precautionarystepstogetbetterresults
Langkahberjagajagauntukmendapatkeputusanlebihbaik
1. The initial temperature must be taken immediately after the solution pour into plastic cup.
 Suhu awal larutan mesti diambil dengan kadar segera apabila larutan dituang ke dalam cawan
plastik.
2. The reactants must stirred continuously and slowly so that the temperature of the solution
is uniform.
Bahan tindak balas mesti dikacau secara berterusan dan perlahan-lahan supaya suhu larutan
adalah sama.
3. The thermometer reading must be observed continuously
Bacaan thermometer mesti diperhatikan secara berterusan
4. The mixture must be mixed quickly
Campuran dikacau dengan cepat

Any three answer

1
1 + 1+ 1

(c)
Value of heat of displacement is zero
Nilai haba penyesaran adalah kosong
Explanation
1. Silver is lower than copper in electrochemical series
Argentum terletak lebih bawah daripada kuprum dalam siri elektrokimia.
2. Silver do not have the ability to displace copper from its salt solution
Argentum tidak mempunyai keupayaan untuk menyesarkan kuprum daripada larutan garamnya.
3. No reaction occurred, no heat released
Tindak balas tidak berlaku, tiada haba yang dibebaskan
1

TOTAL
20
Number of Mark scheme Total
Question mark
10 (a) (i) Chemical substances that ionise in water to produce hydrogen ion, H+. 1
Bahan kimia yang mengion dalam air menghasilkan ion hidrogen, H+.
 (ii) Hydrochloric acid in water in 1
Eksperimen I reacts with magnesium
Asid hidroklorik
dalam air dalam I 1
bertindak balas
dengan
magnesium. 1
Hydrogen
chloride in 1
tetrachlorometha
ne in
Eksperimen II
does not react
with magnesium.
Hidrogen klorida
dalam
tetraklorometana
dalam Eksperimen
II tidak bertindak
balas dengan
magnesium.
Hydrochloric
acid ionises in
water to produce
hydrogen ions.
Asid hidroklorik
mengion dalam
air menghasilkan
ion hidrogen, H+.
Hydrogen
chloride in
tetrachlorometha
ne remains in the
form of
molecule. No
hydrogen ion
present.
Hidrogen klorida
dalam
tetraklorometana
kekal dalam
bentuk molekul.
Tiada ion
hidrogen hadir.
(b) (i) Standard solution is the solution with known concentration. 1
Larutan piawai ialah larutan yang mana kepekatannya diketahui dengan tepat.
(ii) Preparation of 250 cm3 of 1.0 mol dm-3 of sodium hydroxide solution.
Penyediaan 250 cm3 larutan natrium hidroksida 1.0 mol dm-3.
Materials : solid sodium hydroxide, distilled water 1
Bahan : pepejal natrium hidroksida, air suling
Apparatus : Electronic balance, beaker, 250 cm3 volumetric flask, filter 1
funnel, glass rod
Bahan : bikar, 250 cm3 kelalang volumetric, corong turas, rod kaca.
[Accept from labelled diagram / description]
Calculation/ pengiraan :
Number of moles of NaOH / jisim molar NaOH = 1 x 250 1
1000
=0.25 mol
1
RFM of NaOH = 23 + 16 + 1 =40
Mass of NaOH / jisim NaOH= 0.25 x 40 1
= 10 g
Procedure: 1
1. Weigh 10 g of solid sodium hydroxide .
Timbang 10 g natrium hidroksida. 1
2. Dissolve 10g sodium hodroxide in 100 cm3 of distilled water in a
beaker.
Larutkan 10g natrium hidroksida dalam 100 cm3 air suling di dalam
bikar. 1
3. Stir the solution using a glass rod.
Kacau larutan dengan rod kaca.
1
4. Pour the solution into 250 cm3 volumetric flask using a filter
funnel.
Masukkan larutan ke dalam kelalang volumetric 250 cm3 menggunakan
corong turas.
5. Rinse the beaker, filter funnel with distilled water and transfer the 1
solution into volumetric flask.
Bilas bikar dan corong turas menggunakan air suling dan pindahkan
larutan tersebut ke kelalang volumetrik.
6. Add distilled water drop by drop into the volumetric flask until 1
reaches the graduation mark.
Tambahkan air suling kepada kelalang volumetrik sehingga mancapai
tanda senggatan.
7. The volumetric flask is closed tightly and inverted a few times to 1
get homogeneous solution.
Kelalang volumetrik ditutup dengan penutup dan ditelangkupkan
beberapa kali untuk mendapatkan larutan yang homogen.
M1V1 = M2V2
1.0 (25) = M2 (100) 1
M2 = 0.25 mol dm-3 1
TOTAL 20

END OF SCHEME MARK

SKEMA TAMAT