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1). Injection is performed either in the gas cap (local) or . the oil (dispersed). The injected gas nearly always consists of hydrocarbons: R. COSSE 2798, SECONDARY AND ENHANCED OIL RECOVERY reservoir production gas. In the frequent case where there is no outside sour- ce of gas, the aim is to slow down the drop in pressure, but this comes tio- where Gas injection i “@ If there is a gas cap. is light (the solution GOR is high and the oil viscosity is low). V(c) If the permeability is high. These conditions imply good vertical. sweep of the oil. by the gas. cap, and recovery.is. good (particularly for reef-type reservoirs). The gas injected into an oil rescrvoir.can also. be recovered subscquently (production GOR), after breakthrough. 8.5.2 Economic Aspect Since the small increase in recovery.generally precludes the drilling of many wells, production wells. are.often. converted (subject to changes in per- forations for injection in a gas cap). For injection in the oil.zone.. the ten- dency is to adopt 4 nine-spot pattern. This requires fewer injection wells than water-flood, because the, injectivity is greater (M> 1). However, the gas i are often. high. ~ 8.5.3 Implementation 2 1a) Well cleaning, casing inspection: do not select a wetl producing water (it is useless to inject gas into water!). vb) Well injectivity test. 1-4) Closure of zones with preferential paths. LAG) Gas treatment to remove H,S, CO,, 0, and H,O: corrosion and risk of precipitates (hydrates) liable to plug the lines. //@) Compression: for reasons of flexibility, it is preferable to install seve- ral small compressors rather than one large one. Reciprocating compres- sors are generally used, driven by gas engines. Af) Monitoring: use of radioactive markers. 280 R. COSSE8. SECONDARY AND ENHANCED OIL RECOVERY 8.5.4 Comparison of Waterflood and Gas Injection Injection Displaced off = —> Fairly heavy Mobility 1 M<1 M>1 M>>1 Efficiency Good ‘Medium Poor Encroachmen| Stable + Stable + Unstable Imbibition Favorable Favorable - - Number of we injectors (1).. High Medium Low Investment (2)... + High + Medium tLow (1) The number of injectors depends on the mobility ratio M, and also on the injection pressure. (2) Additional investment due to injection compared with investment for primary re covery. Note that these comparative details are provided for information only, and may vary considerably from one reservoir to another. 8.6 GAS CYCLING IN RETROGRADE CONDENSATE GAS RESERVOIRS jection of the light components of the produced gas after treatment may have beneficial technico-economic effects, because it allows better reco- very of condensate, which is a highly valuable product. Cycling of dry gas tends to have a dual effec (a) Limit the average pressure drop and hence the drop in production of condensates due to the fact that the percentage of heavy products in R, COSSE 2818, SECONDARY AND ENHANCED OIL RECOVERY the effluent decreases with the pressure (P < retrograde dew-point pressure). {b) Revaporize the condensate deposited in the reservoir zones subjected to injection, ‘The injection wells are sufficiently far from the production wells to avoid any premature breakthrough of dry gas, Thanks to cycling, condensate recovery often exceeds 60%. Example: At North Brae (UK, North Sea), cycling is total, Production for 400 Mcfd of treated gas is 75,000 bpd of condensate (3.2 Mt/year), and the reinjection of 360 Mcfd (90% of the gas produced) will last for nine years: the reservoir will then produce by decompression of the gas and also of the natural gaso- line at a declining rate. Total condensate recovery is estimated to be twice as high as in primary recovery: (a) Cycling: 65% (9 years). (b) Cycling + decompression: 82%. (©) Primary recovery: 35 to 40%. This reservoir is especially rich in condensate: GPM ~ 900 g/m’. 8.7. ENHANCED OIL RECOVERY 8.7.1 General Introduction ir often yield only average recovery ratios (25 10-50%). It was therefore logical to try to im- prove these recovery ratios, and rescarch has. been intensified in this field in the past twenty years. Recovery with conventional injecti reasons: imperfect for two technical +Ta) Incomplete sweep of the reservoir space (macroscopic trapping). .7(») Trapping of residual oil by capillarity in the swept zones (microscopic trapping). 282 R. COSSESECONDARY AND ENHANCED OIL RECOVERY What can be done to enhance recovery? st therefore mect the follow- Any development of more effect ing requirements: (a) Improve spatial sweep by redi io between the two fluids, especially by increasing the viscosity of the, injected fluid (or by fr ig that_of the oil). (b) Reduce, or-better,.climinate. capillary forces by achieving the misci- bility_of the two fluids. ve proc The method is even more eff It with simulta- neously. —— Three methods are distinguished: miscible, chemical and thermal. The following table shows the main fluids and/or products injected,.and the “ting .on trapping: ‘Trapping Carbon dioxide Hydrocarbon Action on micro- scopic trapping Chemical Action on macro- scopic trapping Reduction of Miscible crude oil viscosity ‘Thermal These three enhanced 4 physicochemical state of al R. COSSE 2838. SECONDARY AND ENHANCED OIL RECOVERY This is why basic and applied research is being conducted, jointly with the universities, to achieve a better understanding of the mechanisms involved in porous media, Figure 8.11 illustrates (in its own way!) the efforts made in this area. Drawing by Mick With the kind authorization of SNEA(P) Fig. 8.11 8.7.2. Miscible Methods 8.7.2.1 Miscible Displacements To_improve the oil recovery, it i is important to use an injected fluid, shat is no_ residual 284 R. COSsE8. SECONDARY AND ENHANCED OIL RECOVERY hence a considerable improvement in recovery, which may react for_injected_gas miscible with the oil in place. Note that two fluids are miscible if they caa_blendte-forma_single fluid. Water and whisky, for example... whereas water and oi) are not miscible. 8.7.2.2. Two Types of Miscibility In practice, some hydrocarbon components display the property of being miscible_with others: C, 10 C, and especially.C, and C, (intermediates). This is termed natural or absolute miscibility. It is convenient to represent_the components and any_composition..ofamixture by.a_ternary.diagram (Fig. 8.12) which shows.a two-phase. zone (Fig. 8.13) whose size. varies for different reservoir. pressures-and. temperatures. Ce 6 100% Fig. 8.12 Ternary diagram. R. COSSE 2858. SECONDARY AND ENHANCED OIL RECOVERY The boundary of the two-phase zone consists of the combination of the bubble- point and dew-point curves which. meet_at the critical. point. This boundary and the tangent to the critical point serve to distinguish four zones, including three one-phase zones, on this type of diagram: a gas zone, G jtowatd point, an oil zone H toward point C,+, and supercritical zone $ toward point C, ,. oa Fig. 8.13a Two-phase zone. two immiscible phases: or Cee YG \ Fig. 8.13b Total miscibility. Fig. 8.13¢ Dynamic miscibility. 286 R. COSSE8. SECONDARY AND ENHANCED OIL RECOVERY A. Natural Miscibility Any hydrocarbon of which the point indicating its composition lies in the supercritical zone is naturally miscible with a gas and an oil represented on ihe corresponding diagram at the reservoir pressure P and temperature T (dia- gram (a) in Fig. 8.13). This is because any composition resulting from the mixtures is located on segment SG or on segment SH, which remain outside the two-phase zone Giagram (b) in Fig. 8.13). If a slug (limited volume) of C,-C, is injected, followed by dry gas (essen- tially methane), miscibility is obtained between the oil and the C,-C, and bet- ween the C,-C, and the dry gas, This slug must be sufficiently large to form Parrier between the two fluids, and its volume is generally about 2 to 10% af the pore volume concerned. Diagram (d) in Fig. 8.13 shows a miscible displacement of this type. B. Dynamic Miscibility In cer ressure and temperature conditons, some gases become mis~ cible_w during displacement. This is termed dynamic (or thermo- dynamic) miscibility. Two cases can be distinguished: (a) Injection of lean gas in a high-pressure light oil: this process is called high-pressure gas drive. The oil enriches the gas in the mixing zone Giagram (©) in Fig. 8.13, pair G,,H,). A rather high reservoir pressure is necessary, in order to have a reduced two-phase zone, and hence a greater passibility of achieving miscibility. (b) Injection of wet gas (or enriched. with C,-C,) in a fairly heavy oil, @ process called,condensing gas drive: the gas enriches the oil in the mix- ing zone (diagram (c) in Fig. 8.13, pair G,, H,). 8 ° 2° Fig. 8.136 Slug injection. R. COSSE, 287