Sep Project

Assume 99.
000% split of HHKC

Assume 95.800% split of Acrylonitrile (HKC)
Vr 176.4726
R 15.48044
Pressure 1 bar Lr 165.7646
BP Temp 76.910092928 C
temp of feed 100 C
Feed 100
Xf
HCN 7 0.07
Acrylonitrile 89 0.89 Ls 165.7646
water 4 0.04
Vs 76.4726
Cpf 67.03
Hv 33530
D 10.7080 Xd
HCN 6.9300 0.6472
Acrylonitrile 3.7380 0.3491
H2O 0.0400 0.0037
1mmHg 0.0013 bar

1 bar 14.5038 Psia
Assuming T condenser 56.8882
T at bottom 109.4897
W 89.2920 Xw
HCN 0.0700 0.0008
acrylonitrile 85.2620 0.9549
H2O 3.9600 0.0443
Lewis Mathy
comp
LKC HCN
HKC Acrylonitrile
HHKC H2O
dew pt. of feed Antoine's Coefficients
A B C P* @100/mmHg
HCN 8.0842 1655.8700 292.2280 7286.4723
Acrylonitrile 7.4321 1482.7600 248.4400 1502.0204
H2O 8.0557 1723.6400 233.0760 760.0024
A B C P*(condenser) /mmHg
HCN 8.0842 1655.8700 292.2280 2193.7450
Acrylonitrile 7.4321 1482.7600 248.4400 376.5456
H2O 8.0557 1723.6400 233.0760 129.2439
Using Fenske's
Component
LKC HCN
HKC Acrylonitrile
HHKC H2O
Calculating Nmin by varying 1.0000 < <

Rmin 10.750309
= 4.84776453
R = 15.4804447
q = -0.04521593
qfeed -0.04615916
Xd Xw X y*
0.6472 0.0008 5.1280 0.0040201 0.0041043788
0.3491 0.9549 1.0000 0.9548672 0.9748854141
0.0037 0.0443 0.4640 0.0205788 0.021010207
sum 0.9794661
Xlkc,F/Xhkc,f
0.0786516854
P*@100/bar K@100C dew point
9.7129 9.7129 4.8511 0.0072
2.0022 2.0022 1.0000 0.4445 For dew point calculation the sum of th
temperature is above the temperature
1.0131 1.0131 0.5060 0.0395
dont worry about the 0.4912.. thats th
0.4912
Bubble Point top Dew Point pressure @ T condenser
P*/bar Xd Pt @ top Xd P*/mmHg
2.9243 0.6472 1.8925 0.6472 2193.7450
0.5019 0.3491 0.1752 0.3491 376.5456
0.1723 0.0037 0.0006 0.0037 129.2439
sum 2.0684 bar
29.9994 30.0000 psia
therefore reset Pd to 30 psia condenser
Xf Xd Xw avg Nmin xdi/xwi

0.0700 0.6472 0.0008 5.1280 4.1341 0.0153
0.8900 0.3491 0.9549 1.0000
0.0400 0.0037 0.0443 0.4640
5.1280
Kirk bride Lewis
Nr/Ns= 0.211831082 0.25
x1 X y* x2 X y*
0.002315769 0.0118753545 0.0119764 0.005947403 0.0304985 0.03026063
0.964102241 0.964102241 0.9723082 0.962913291 0.9629133 0.95540279
0.03358199 0.0155827289 0.0157154 0.031139306 0.0144493 0.01433657
sum 0.9915603244 sum 1.0078611
xlkc/xhkc Xlkc,F/Xhkc,xlkc/xhkc Xlkc,F/Xhkc,f
0.0024019953 0.0786517 0.006176468 0.07865169
calculation the sum of the pressure =1 . This was done and the
s above the temperature of the feed.
out the 0.4912.. thats the sum of pressures at the feed temp
sure @ T condenser
P*/bar Xd/P* K xw
2.9243 0.2213 1.4138 5.8260 0.0008
0.5019 0.6955 0.2427 1.0000 0.9549
0.1723 0.0217 0.0833 0.3432 0.0443
sum 0.9385
1/sum 1.0656 <215Psia
dew point pressure
xwi xdi
0.0447 0.0007
gilly
RHS LHS
0.3802579265 0.3802945511
N= 7.2842089287
N actual 7
x3 X y* x4 X y*
0.0143825006 0.0737540279 0.0707118 0.033044 0.169451 0.1512619
0.9551142741 0.9551142741 0.9157179 0.9368063 0.936806 0.8362497
0.0305032253 0.0141541193 0.0135703 0.0301497 0.01399 0.0124884
sum 1.0430224213 sum 1.120247
xlkc/xhkc Xlkc,F/Xhkc,xlkc/xhkc Xlkc,F/Xhkc,
0.0150584082 0.0786517 0.035273 0.0786517
Bubbles Point bottom
P* @bottom Pt* @ bottom K
12.2201 0.0096 4.7902 4.7070
2.5961 2.4790 1.0177 1.0000
1.4093 0.0625 0.5524 0.5428
sum 2.5511
sum 36.9999
Assume 37 Psia at bottom
x5 X y* x6 X y*
0.0702043146 0.360010483 0.2826018617 0.259051 1.328424 0.643822
0.9001450864 0.9001450864 0.7065979723 0.7296925 0.729692 0.353646
0.0296505989 0.0137584832 0.010800166 0.0112565 0.005223 0.002531
sum 1.2739140527 sum 2.063339
xlkc/xhkc Xlkc,F/Xhkc,f xlkc/xhkc Xlkc,F/Xhkc
0.0779922211 0.0786516854 0.3550139 0.078652
x7 X y* x8 X y* x9
0.643605 3.300433 0.902864633 0.919381274 4.714623 0.983198 1.004904
0.353941 0.353941 0.0968239041 0.080528449 0.080528 0.016794 -0.004672
0.002454 0.001139 0.000311463 9.0277E-005 4.19E-005 8.74E-006 -0.000232
sum 3.655513 sum 4.795194 sum
xlkc/xhkc Xlkc,F/Xhkc,f xlkc/xhkc Xlkc,F/Xhkcxlkc/xhkc
1.818397 0.0786516854 11.41685065 0.078652 -215.1069
X y* x10 X y* x11 X y*
5.153185 1.000928 1.02378 5.249982 1.004523 0.463841 2.378597 0.819653
-0.004672 -0.000907 -0.023516 -0.023516 -0.0045 0.51228 0.51228 0.176529
-0.000108 -2.1E-005 -0.000264 -0.000122 -2.3E-005 0.023879 0.01108 0.003818
5.148406 sum 5.226344 sum 2.901957
Xlkc,F/Xhkcxlkc/xhkc Xlkc,F/Xhkcxlkc/xhkc Xlkc,F/Xhkc
0.078652 -43.53533 0.078652 0.905445 0.078652
x12 X y* x13 X y* x14 X
0.378555 1.941243 0.761588 0.351768 1.803879 0.739855 0.341741 1.752463
0.595795 0.595795 0.233742 0.622189 0.622189 0.255189 0.632083 0.632083
0.025651 0.011902 0.00467 0.026044 0.012085 0.004957 0.026176 0.012146
sum 2.54894 sum 2.438152 sum 2.396692
xlkc/xhkc Xlkc,F/Xhkcxlkc/xhkc Xlkc,F/Xhkcxlkc/xhkc
0.635378 0.078652 0.565372 0.078652 0.540659
y* x15 X y* x16 X y* x17
0.731201 0.820241 4.206228 0.932198 1.034222 5.303532 0.982491 0.453677
0.263731 0.303318 0.303318 0.067222 0.094115 0.094115 0.017435 0.522399
0.005068 0.005637 0.002615 0.00058 0.000858 0.000398 7.38E-005 0.023923
sum 4.512161 sum 5.398045 sum
Xlkc,F/Xhkcxlkc/xhkc Xlkc,F/Xhkcxlkc/xhkc Xlkc,F/Xhkcxlkc/xhkc
0.078652 2.70423 0.078652 10.98895 0.078652 0.86845
X y* x18 X y* x19 X y*
2.326476 0.81346 0.375698 1.926593 0.759359 0.350739 1.798604 0.73898
0.522399 0.182659 0.598622 0.598622 0.235945 0.623205 0.623205 0.256052
0.011101 0.003881 0.02568 0.011916 0.004697 0.026056 0.012091 0.004968
2.859976 sum 2.537131 sum 2.4339
0.078652 0.627604 0.078652 0.562799 0.078652
x20 X y* x21 X y* x22 X
0.341338 1.750395 0.730846 0.337585 1.731152 0.727525 0.336053 1.723294
0.632481 0.632481 0.264081 0.636185 0.636185 0.26736 0.637698 0.637698
0.026181 0.012149 0.005072 0.026229 0.012171 0.005115 0.026249 0.01218
sum 2.395024 sum 2.379508 sum 2.373172
0.539681 0.078652 0.53064 0.078652 0.526979
y* x23 X y* x24 X y* x25
0.726156 0.335422 1.720057 0.72559 0.335161 1.718717 0.725356 0.335053
0.268711 0.638321 0.638321 0.26927 0.638579 0.638579 0.269502 0.638686
0.005132 0.026257 0.012184 0.00514 0.02626 0.012185 0.005143 0.026262
sum 2.370562 sum 2.369482 sum
0.078652 0.525475 0.078652 0.524854 0.078652 0.524597
X y* x26 X y* x27 X y*
1.718163 0.725259 0.335008 1.717933 0.725218 0.334989 1.717837 0.725202
0.638686 0.269597 0.63873 0.63873 0.269637 0.638748 0.638748 0.269654
0.012186 0.005144 0.026262 0.012186 0.005144 0.026263 0.012186 0.005145
2.369034 sum 2.368849 sum 2.368772
0.078652 0.52449 0.078652 0.524446 0.078652
x28
0.334981
0.638756
0.026263
sum
xlkc/xhkc
0.524428
Assume 98.000% split of HHKC
Vr 148.8076
R 11.98496
BP Temp 76.910092928 C
temp of feed 100 C
Feed 100
Xf
HCN 7 0.07
water 4 0.04
Vs 48.8076
Cpf 67.03
Hv 33530
D 11.4600 Xd
HCN 6.9300 0.6047
H2O 0.0800 0.0070
1mmHg 0.0013 bar

1 bar 14.5038 Psia
W 88.5400 Xw
HCN 0.0700 0.0008
H2O 3.9200 0.0443
Lewis Mathy
comp
LKC HCN
HKC Acrylonitrile
HHKC H2O
dew pt. of feed Antoine's Coefficients
A B C P* @100/mmHg
HCN 8.0842 1655.8700 292.2280 7286.4723
Acrylonitrile 7.4321 1482.7600 248.4400 1502.0204
H2O 8.0557 1723.6400 233.0760 760.0024
HCN 8.0842 1655.8700 292.2280 2307.8216
Acrylonitrile 7.4321 1482.7600 248.4400 399.5536
H2O 8.0557 1723.6400 233.0760 139.5082
Using Fenske's
Component
LKC HCN
HKC Acrylonitrile
HHKC H2O

Rmin 9.9874664
= 4.83265205
R = 11.9849597
q = -0.0471405
qfeed -0.04615916
Xd Xw X y*
0.6047 0.0008 5.1114 0.0040411 0.0041252039
0.3883 0.9549 1.0000 0.9549356 0.9748140861
0.0070 0.0443 0.4660 0.0206312 0.02106071
sum 0.9796079
Xlkc,F/Xhkc,f
0.0786516854
9.7129 9.7129 4.8511 0.0072
2.0022 2.0022 1.0000 0.4445 For dew point calculation the sum of th
temperature is above the temperature
1.0131 1.0131 0.5060 0.0395
dont worry about the 0.4912.. thats th
0.4912
3.0763 0.6047 1.8603 0.6047 2307.8216
0.5326 0.3883 0.2068 0.3883 399.5536
0.1860 0.0070 0.0013 0.0070 139.5082
sum 2.0684 bar
29.9997 30.0000 psia

0.0700 0.6047 0.0008 5.1114 3.6622 0.0248
0.8900 0.3883 0.9549 1.0000
0.0400 0.0070 0.0443 0.4660
5.1114
Kirk bride Lewis
Nr/Ns= 0.200272585 0.25
Nr +NS 7.284208929
Ns 6.068795555
Nr 1.215413374
x1 X y* x2 X y*
0.0019755815 0.0100979718 0.0102115 0.004138389 0.0211529 0.0211836
0.9619996016 0.9619996016 0.9728125 0.961288338 0.9612883 0.96268216
0.0360248168 0.0167872879 0.016976 0.034573273 0.0161109 0.01613424
sum 0.9888848613 sum 0.9985521
0.0020536199 0.0786517 0.004305044 0.07865169
calculation the sum of the pressure =1 . This was done and the
s above the temperature of the feed.
out the 0.4912.. thats the sum of pressures at the feed temp
sure @ T condenser
P*/bar Xd/P* K xw
3.0763 0.1966 1.4873 5.7760 0.0008
0.5326 0.7291 0.2575 1.0000 0.9549
0.1860 0.0375 0.0899 0.3492 0.0443
sum 0.9632
1/sum 1.0382 <215Psia
dew point pressure
xwi xdi
0.0450 0.0011
gilly
RHS LHS
0.437222119 0.4903672298
N= 7.2842089287
N actual 7
x3 X y* x4 X y*
0.0080374254 0.0410824321 0.0404856 0.0148965 0.076142 0.0730017
0.9576884205 0.9576884205 0.943775 0.9509696 0.95097 0.9117482
0.0342741542 0.0159714926 0.0157395 0.0341339 0.015906 0.0152501
sum 1.0147423451 sum 1.043018
0.0083925264 0.0786517 0.0156646 0.0786517
12.2195 0.0097 4.7900 4.7071
2.5960 2.4790 1.0176 1.0000
1.4092 0.0624 0.5524 0.5428
sum 2.5511
sum 36.9999
x5 X y* x6 X y*
0.0264514302 0.13520363 0.1239698177 0.0445634 0.227781 0.195483
0.9395886045 0.9395886045 0.8615199754 0.9217396 0.92174 0.791041
0.0339599653 0.015825083 0.0145102069 0.033697 0.015703 0.013476
sum 1.0906173175 sum 1.165223
0.0281521403 0.0786516854 0.048347 0.078652
x7 X y* x8 X y* x9
0.069976 0.357675 0.2816559068 0.254700778 1.301876 0.638046 0.640827
0.896694 0.896694 0.7061137631 0.732630882 0.732631 0.359061 0.35662
0.03333 0.015531 0.0122303301 0.01266834 0.005903 0.002893 0.002552
sum 1.269901 sum 2.04041 sum
0.078038 0.0786516854 0.347652254 0.078652 1.796946
X y* x10 X y* x11 X y*
3.27552 0.90152 0.320872 1.640105 0.711873 0.25348 1.295634 0.639562
0.35662 0.098152 0.650471 0.650471 0.282331 0.71592 0.71592 0.353399
0.001189 0.000327 0.028657 0.013354 0.005796 0.0306 0.01426 0.007039
3.63333 sum 2.303929 sum 2.025813
0.078652 0.493293 0.078652 0.354062 0.078652
x12 X y* x13 X y* x14 X
0.227784 1.164291 0.606423 0.216007 1.104098 0.589979 0.210164 1.074228
0.741174 0.741174 0.386042 0.752775 0.752775 0.402248 0.758533 0.758533
0.031042 0.014465 0.007534 0.031218 0.014547 0.007773 0.031303 0.014587
sum 1.919931 sum 1.87142 sum 1.847349
0.307328 0.078652 0.286948 0.078652 0.277066
y* x15 X y* x16 X y* x17
0.581497 0.680472 3.47816 0.878393 1.002141 5.122333 0.969013 0.344857
0.410606 0.477266 0.477266 0.120531 0.162988 0.162988 0.030833 0.626548
0.007896 0.009137 0.004258 0.001075 0.001748 0.000814 0.000154 0.028595
sum 3.959684 sum 5.286135 sum
0.078652 1.425771 0.078652 6.148562 0.078652 0.550407
X y* x18 X y* x19 X y*
1.762697 0.733671 0.261226 1.335228 0.648891 0.231098 1.181235 0.610904
0.626548 0.260782 0.708262 0.708262 0.3442 0.737905 0.737905 0.381626
0.013325 0.005546 0.030512 0.014218 0.00691 0.030996 0.014444 0.00747
2.40257 sum 2.057709 sum 1.933584
0.078652 0.368826 0.078652 0.313182 0.078652
x20 X y* x21 X y* x22 X
0.2176 1.112237 0.592252 0.210971 1.078358 0.582683 0.207571 1.060977
0.751205 0.751205 0.400007 0.757737 0.757737 0.409438 0.761088 0.761088
0.031195 0.014537 0.007741 0.031291 0.014582 0.007879 0.031341 0.014604
sum 1.877979 sum 1.850676 sum 1.836669
0.289667 0.078652 0.278423 0.078652 0.272729
y* x23 X y* x24 X y* x25
0.577663 0.205787 1.051859 0.574999 0.204841 1.04702 0.573577 0.204335
0.414385 0.762846 0.762846 0.417011 0.763779 0.763779 0.418412 0.764278
0.007952 0.031366 0.014616 0.00799 0.03138 0.014623 0.008011 0.031387
sum 1.829322 sum 1.825422 sum
0.078652 0.269762 0.078652 0.268193 0.078652 0.267357
X y* x26 X y* x27 X y*
1.044436 0.572815 0.204064 1.043052 0.572406 0.203919 1.04231 0.572186
0.764278 0.419163 0.764544 0.764544 0.419566 0.764688 0.764688 0.419783
0.014626 0.008022 0.031391 0.014628 0.008028 0.031393 0.014629 0.008031
1.82334 sum 1.822225 sum 1.821626
0.078652 0.26691 0.078652 0.26667 0.078652
x28
0.203841
0.764765
0.031395
sum
xlkc/xhkc
0.266541
Vr 148.4925
R 14.34013
Temp 76.910092928 C
100 C
Feed 100
Xf
HCN 7 0.07
water 4 0.04
Vs 48.4925
Cpf 67.03
Hv 33530
D 9.6800 Xd
HCN 6.9300 0.7159
H2O 0.0800 0.0083
1mmHg 0.0013 bar

1 bar 14.5038 Psia
W 90.3200 Xw
HCN 0.0700 0.0008
H2O 3.9200 0.0434
Lewis Mathy
comp
LKC HCN
HKC Acrylonitrile
HHKC H2O
Bubble pt. of feed Antoine's Coefficients
A B C P* @100/mmHg
HCN 8.0842 1655.8700 292.2280 3966.8535
Acrylonitrile 7.4321 1482.7600 248.4400 749.3261
H2O 8.0557 1723.6400 233.0760 312.8611
HCN 8.0842 1655.8700 292.2280 2167.4596
Acrylonitrile 7.4321 1482.7600 248.4400 371.2683
H2O 8.0557 1723.6400 233.0760 126.9138
Using Fenske's
Component
LKC HCN
HKC Acrylonitrile
HHKC H2O

Rmin 11.950109
= 4.98938837
R = 14.3401312
q = -0.04609179
qfeed -0.04615916
Xd Xw X y*
0.7159 0.0008 5.2797 0.0040919 0.0041807177
0.2758 0.9558 1.0000 0.9558237 0.9765721906
0.0083 0.0434 0.4340 0.0188382 0.0192470918
sum 0.9787538
Xlkc,F/Xhkc,f
0.0786516854
5.2878 5.2878 5.2939 0.0132
0.9989 0.9989 1.0000 0.8910
0.4170 0.4170 0.4175 0.0959
1.0002
2.8892 0.7159 2.0684 0.7159 2167.4596
0.4949 0.2758 0.1365 0.2758 371.2683
0.1692 0.0083 0.0014 0.0083 126.9138
sum 2.2063 bar
32.0001 32.0000 psia

0.0700 0.7159 0.0008 5.2797 5.1004 0.0041
0.8900 0.2758 0.9558 1.0000
0.0400 0.0083 0.0434 0.4340
5.1155
x1 X y* x2 X y*
0.001964761 0.0103733711 0.0104928 0.0041698 0.0220153 0.02204116
0.9630719607 0.9630719607 0.9741569 0.962228196 0.9622282 0.96335689
0.0349632783 0.0151756948 0.0153504 0.033602004 0.0145848 0.01460195
sum 0.9886210266 sum 0.9988284
0.0020400978 0.0786517 0.004333483 0.07865169
sure @ T condenser
P*/bar Xd/P* K xw
2.8892 0.2478 1.3095 5.8380 0.0008
0.4949 0.5573 0.2243 1.0000 0.9558
0.1692 0.0489 0.0767 0.3418 0.0434
sum 0.8540
1/sum 1.1710 <215Psia
dew point pressure
xwi xdi
0.0443 0.0002
x3 X y* x4 X y*
0.0082040937 0.0433152475 0.042623 0.0153941 0.081276 0.0776216
0.9584553538 0.9584553538 0.943137 0.9513918 0.951392 0.9086102
0.0333405525 0.0144713561 0.0142401 0.0332141 0.014416 0.0137682
sum 1.0162419574 sum 1.047085
0.0085597036 0.0786517 0.0161806 0.0786517
12.2156 0.0095 4.7885 4.7073
2.5951 2.4804 1.0173 1.0000
1.4085 0.0611 0.5521 0.5428
sum 2.5510
sum 36.9995
x5 X y* x6 X y*
0.0276204569 0.1458280424 0.1326308454 0.0468373 0.247287 0.209231
0.9393302451 0.9393302451 0.8543224097 0.9203655 0.920365 0.778725
0.033049298 0.014344938 0.0130467448 0.0327973 0.014236 0.012045
sum 1.0995032255 sum 1.181888
0.0294044156 0.0786516854 0.0508899 0.078652
x7 X y* x8 X y* x9
0.173898 0.91813 0.5284912451 0.51542178 2.721278 0.849253 0.858551
0.813794 0.813794 0.4684335771 0.481864914 0.481865 0.15038 0.141632
0.012308 0.005342 0.0030751778 0.002713306 0.001178 0.000368 -0.000183
sum 1.737266 sum 3.204321 sum
0.213688 0.0786516854 1.069639571 0.078652 6.061855
X y* x10 X y* x11 X y*
4.532903 0.969718 0.339264 1.791214 0.735318 0.257379 1.358886 0.651891
0.141632 0.030299 0.632503 0.632503 0.259651 0.712624 0.712624 0.341863
-7.9E-005 -1.7E-005 0.028234 0.012255 0.005031 0.029997 0.01302 0.006246
4.674456 sum 2.435971 sum 2.08453
0.078652 0.536383 0.078652 0.36117 0.078652
x12 X y* x13 X y* x14 X
0.228234 1.205012 0.61494 0.215326 1.13686 0.597022 0.688578 3.635493
0.741344 0.741344 0.378322 0.75408 0.75408 0.396005 0.442855 0.442855
0.030422 0.013204 0.006738 0.030594 0.013279 0.006973 0.008036 0.003488
sum 1.959561 sum 1.904219 sum 4.081836
0.307866 0.078652 0.285548 0.078652 1.554862
y* x15 X y* x16 X y* x17
0.890651 1.002684 5.293882 0.974964 1.092876 5.77007 0.992058 0.347068
0.108494 0.135294 0.135294 0.024917 0.045889 0.045889 0.00789 0.624674
0.000855 0.00149 0.000647 0.000119 0.000704 0.000305 5.25E-005 0.028258
sum 5.429823 sum 5.816264 sum
0.078652 7.41113 0.078652 23.81562 0.078652 0.555598
X y* x18 X y* x19 X y*
1.832417 0.742063 0.259735 1.371325 0.654687 0.229211 1.21017 0.616255
0.624674 0.25297 0.71029 0.71029 0.339101 0.740379 0.740379 0.377023
0.012265 0.004967 0.029975 0.01301 0.006211 0.030409 0.013199 0.006721
2.469357 sum 2.094626 sum 1.963749
0.078652 0.365674 0.078652 0.309587 0.078652
x20 X y* x21 X y* x22 X
0.215786 1.139286 0.597677 0.209296 1.105021 0.588288 0.206016 1.087704
0.753627 0.753627 0.395358 0.760032 0.760032 0.404624 0.763269 0.763269
0.030588 0.013276 0.006965 0.030673 0.013313 0.007088 0.030716 0.013332
sum 1.906189 sum 1.878366 sum 1.864304
0.28633 0.078652 0.275378 0.078652 0.269912
y* x23 X y* x24 X y* x25
0.583437 0.204321 1.078755 0.580901 0.203435 1.074078 0.579568 0.202969
0.409412 0.764941 0.764941 0.411915 0.765816 0.765816 0.413231 0.766275
0.007151 0.030738 0.013342 0.007184 0.030749 0.013347 0.007202 0.030755
sum 1.857038 sum 1.853241 sum
0.078652 0.267107 0.078652 0.265645 0.078652 0.264878
X y* x26 X y* x27 X y*
1.071619 0.578864 0.202724 1.070322 0.578493 0.202594 1.069637 0.578296
0.766275 0.413925 0.766518 0.766518 0.414291 0.766646 0.766646 0.414485
0.013349 0.007211 0.030759 0.013351 0.007216 0.03076 0.013351 0.007218
1.851244 sum 1.850191 sum 1.849634
0.078652 0.264473 0.078652 0.26426 0.078652
x28
0.202525
0.766714
0.030761
sum
xlkc/xhkc
0.264147
Vr 149.0080
R 12.91558
Temp 76.910092928 C
100 C
Feed 100
Xf
HCN 7 0.07
water 4 0.04
Vs 49.0080
Cpf 67.03
Hv 33530
D 10.7080 Xd
HCN 6.9300 0.6472
H2O 0.0400 0.0037
1mmHg 0.0013 bar

1 bar 14.5038 Psia
W 89.2920 Xw
HCN 0.0700 0.0008
H2O 3.9600 0.0443
Lewis Mathy
comp
LKC HCN
HKC Acrylonitrile
HHKC H2O
Bubble pt. of feed Antoine's Coefficients
A B C P* @100/mmHg
HCN 8.0842 1655.8700 292.2280 7286.4723
Acrylonitrile 7.4321 1482.7600 248.4400 1502.0204
H2O 8.0557 1723.6400 233.0760 760.0024
HCN 8.0842 1655.8700 292.2280 2193.7277
Acrylonitrile 7.4321 1482.7600 248.4400 376.5422
H2O 8.0557 1723.6400 233.0760 129.2424
Using Fenske's
Component
LKC HCN
HKC Acrylonitrile
HHKC H2O

Rmin 10.762983
= 4.84806691
R = 12.9155797
q = -0.04660451
qfeed -0.04615916
Xd Xw X y*
0.6472 0.0008 5.1280 0.0040201 0.0041043813
0.3491 0.9549 1.0000 0.9548672 0.9748854304
0.0037 0.0443 0.4640 0.0205788 0.0210101882
sum 0.979466
Xlkc,F/Xhkc,f
0.0786516854
9.7129 9.7129 4.8511 0.0072
2.0022 2.0022 1.0000 0.4445
1.0131 1.0131 0.5060 0.0395
0.4912
2.9242 0.6472 1.8925 0.6472 2193.7277
0.5019 0.3491 0.1752 0.3491 376.5422
0.1723 0.0037 0.0006 0.0037 129.2424
sum 2.0684 bar
29.9991 32.0000 psia

0.0700 0.6472 0.0008 5.1280 4.1341 0.0153
0.8900 0.3491 0.9549 1.0000
0.0400 0.0037 0.0443 0.4640
5.1155
x1 X y* x2 X y*
0.0019605754 0.0100539137 0.0101682 0.004109368 0.021073 0.02110676
0.9619608498 0.9619608498 0.9729002 0.961257361 0.9612574 0.96279697
0.0360785747 0.01674118 0.0169316 0.034633271 0.0160705 0.01609627
sum 0.9887559435 sum 0.9984009
0.0020381031 0.0786517 0.004274992 0.07865169
sure @ T condenser
P*/bar Xd/P* K xw
2.9242 0.2213 1.4138 5.8260 0.0008
0.5019 0.6955 0.2427 1.0000 0.9549
0.1723 0.0217 0.0833 0.3432 0.0443
sum 0.9385
1/sum 1.0656 <215Psia
dew point pressure
xwi xdi
0.0447 0.0007
x3 X y* x4 X y*
0.0079855434 0.0409502043 0.0403625 0.014809 0.075941 0.0728242
0.9576771792 0.9576771792 0.943933 0.9509925 0.950993 0.9119584
0.0343372775 0.0159331832 0.0157045 0.0341985 0.015869 0.0152174
sum 1.0145605667 sum 1.042803
0.0083384501 0.0786517 0.0155722 0.0786517
12.2201 0.0096 4.7902 4.7070
2.5961 2.4790 1.0177 1.0000
1.4093 0.0625 0.5524 0.5428
sum 2.5510
sum 36.9998
x5 X y* x6 X y*
0.0263121373 0.1349297533 0.1237455738 0.0443567 0.227463 0.195246
0.9396620136 0.9396620136 0.8617744579 0.9218788 0.921879 0.791306
0.0340258492 0.0157886743 0.0144799684 0.0337645 0.015667 0.013448
sum 1.0903804412 sum 1.165009
0.0280017037 0.0786516854 0.0481155 0.078652
x7 X y* x8 X y* x9
0.069693 0.357391 0.2814551594 0.25313862 1.298106 0.636928 0.636134
0.896908 0.896908 0.7063399045 0.734000692 0.734001 0.360144 0.361001
0.033399 0.015498 0.0122049361 0.012860688 0.005968 0.002928 0.002866
sum 1.269796 sum 2.038074 sum
0.077704 0.0786516854 0.344875179 0.078652 1.762141
X y* x10 X y* x11 X y*
3.262121 0.900032 0.319442 1.63811 0.711216 0.252533 1.294999 0.639184
0.361001 0.099601 0.651795 0.651795 0.282989 0.71678 0.71678 0.353788
0.00133 0.000367 0.028763 0.013347 0.005795 0.030687 0.014239 0.007028
3.624452 sum 2.303252 sum 2.026019
0.078652 0.490095 0.078652 0.352316 0.078652
x12 X y* x13 X y* x14 X
0.227008 1.164105 0.606173 0.21531 1.104118 0.589796 0.68557 3.515633
0.741868 0.741868 0.386306 0.753392 0.753392 0.402446 0.460634 0.460634
0.031124 0.014442 0.00752 0.031298 0.014523 0.007758 0.008648 0.004013
sum 1.920415 sum 1.872033 sum 3.98028
0.305994 0.078652 0.285787 0.078652 1.48832
y* x15 X y* x16 X y* x17
0.883263 1.001759 5.137061 0.971196 1.0965 5.6229 0.989768 0.351241
0.115729 0.151718 0.151718 0.028683 0.057932 0.057932 0.010197 0.620114
0.001008 0.001375 0.000638 0.000121 0.000419 0.000195 3.42E-005 0.028646
sum 5.289417 sum 5.681026 sum
0.078652 6.602786 0.078652 18.92728 0.078652 0.566413
X y* x18 X y* x19 X y*
1.801177 0.73983 0.262672 1.346995 0.651371 0.231326 1.18625 0.612013
0.620114 0.254711 0.70676 0.70676 0.34177 0.73761 0.73761 0.38055
0.013292 0.00546 0.030568 0.014184 0.006859 0.031064 0.014414 0.007437
2.434583 sum 2.067939 sum 1.938274
0.078652 0.371657 0.078652 0.313616 0.078652
x20 X y* x21 X y* x22 X
0.217379 1.114731 0.592755 0.210555 1.079735 0.582895 0.207061 1.061816
0.751352 0.751352 0.39953 0.758078 0.758078 0.409248 0.761521 0.761521
0.031269 0.014509 0.007715 0.031367 0.014555 0.007858 0.031418 0.014578
sum 1.880592 sum 1.852368 sum 1.837916
0.289318 0.078652 0.277749 0.078652 0.271904
y* x23 X y* x24 X y* x25
0.577728 0.20523 1.052429 0.574989 0.204259 1.047451 0.573528 0.203742
0.41434 0.763326 0.763326 0.417039 0.764282 0.764282 0.41848 0.764793
0.007932 0.031444 0.014591 0.007972 0.031458 0.014597 0.007993 0.031466
sum 1.830345 sum 1.826331 sum
0.078652 0.268863 0.078652 0.267257 0.078652 0.266401
X y* x26 X y* x27 X y*
1.044795 0.572745 0.203464 1.043373 0.572325 0.203316 1.042611 0.5721
0.764793 0.419251 0.765066 0.765066 0.419665 0.765213 0.765213 0.419887
0.014601 0.008004 0.03147 0.014603 0.00801 0.031472 0.014604 0.008013
1.824189 sum 1.823042 sum 1.822427
0.078652 0.265943 0.078652 0.265698 0.078652
x28
0.203236
0.765291
0.031473
sum
xlkc/xhkc
0.265566

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Assume 99.

000% split of HHKC

1mmHg 0.0013 bar

Calculating Nmin by varying 1.0000 < <

Xf Xd Xw avg Nmin xdi/xwi

1mmHg 0.0013 bar

Calculating Nmin by varying 1.0000 < <

Xf Xd Xw avg Nmin xdi/xwi

1mmHg 0.0013 bar

Calculating Nmin by varying 1.0000 < <

Xf Xd Xw avg Nmin xdi/xwi

1mmHg 0.0013 bar

Calculating Nmin by varying 1.0000 < <

Xf Xd Xw avg Nmin xdi/xwi

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