> Il 1 2 3 4. (AL 2 “a 2013 tem refers to the following diagram, 5 on™ ca, Based on the IUPAC rules, the name of the ‘eompound abate is (A)? ephenylpropan-2-amine (B) _\-benzylpropen-1-ami (©) Thphenylbutan-2-amine (©) Vphenyloutan-I-amine ‘A hydrocarbon contains 87.8% carbon and 12.2% hydrogen by mass. Its empirical formule is a) cH @ o & ah @) OH ‘An electrophile has (AD) «positive charge (B) negative charge (©) anon-bonding electron (©) anoxygen or nitrogen stom Which of the following terme does NOT describe a nucleophile? (AL) Lewis acid (B) Lewis base (C) Species with alone pair ©) Electron donor ‘Whieh ofthe following compounds is hydro- lysed by water? @) GkoH ® cje00H ©) qHex,c1 © ~<-cx1 diem § refers tothe following information, A substance roasts with 1. NaOH to form an ionle produet Ml PCL giving of HCI WL Hy in the presence of « nickel satalyst IV. ethanol to produce an organie ‘compound and water ‘The substance with the properties above could be ° wa i CH-C-H ° ® 4 CH,~C-oH ° © ) i} CH,=CH-C-oH © cH cH-cr,—owCH, 7. Methylbenzene, } oan react to 9%. cH, pote @ . a Which of the following reagents and conditions are MOST suitable for the reaction? j Cap Chlorine with AICI, | {B) Chlorine in the dark {© Chlorine with UV Hight | (5) Concentrated HCI heated under i refioe ‘inzoniuim sets ar useful in the eynthesis of aromatic eorapounds. Which of the compounds below can be prepared from & diezonium salt? coor “© CAN ca212010/CAPE 2013 ‘Acompound, % reacts with 1.2, é-dinitrophenylhydrazine (DNPH) to give an orange presipiate 1, Tollen’s reagent to give « silver TH, aqueous alkaline iodine to give yellow orystals. Compound X is MOST likely wo & CH COCH 7 Which of the following compounds will NOT decalourize bromine water but will Gecoloutize potassium manganete(VI1) on ‘warming? (a) Butane @)> Beant © Bthene D)_—_Bihanoie avid G0 ONTO THE NEXT PAGEat ai. =i mL. 2 oe “Which ofthe following pairs of eompounds ere optical isomers? CEs CEs | 1 () CH -C-O8 HO-C-CHs | J Ci Cs x z fl | @ ) oH-c*0H BO-C=Cii : \ 1 CEs CH HORE HHBE riil rit Ree crcececede | Hse acaca aa Til Lilt HEHEE HEEE CHA H CH; 1 it (D2) H-C-C-O8 HO-C-C-CH; 1 i | CHE HOO “The complete rection of phenol with aqueous bromine is characterised EY & (A) brown precipitate, «brown solution and « sweet smell ()_ brown precipitate, a colourless solution and « sweet sre! ie smell {Gp sine prep, a colourlexs slain and an anisns (By? Whe precipita, «brown solution and an antiseptic sm15. Which of the options below, (A), (B) (C) and (D), is comeot forthe properties shown by the following struotures? on y (A) Nogative inductive coffee B) —Conjugative effect (©) Negative induetive cffost (D)) Positive inductive feet Positive inductive effet [Negative inductive effect Conjugative coffe Conjugative ffet x 1 Hea q i x Conjugative effet = Positive inductive effect, ) Positive inductive effect ~ [Negative inductive ffex 14, Which ofthe following statementsisNOT 16. Whi true about condensation polymerization? of the following factors affest the accuracy of the results in a NOT tvimetrc analysis? (AD) Themolecularmass ofthe polymer is a multiple of the combined w rmagses of its monomers. ©) The polymer can be hydrolysed to form its monomers. Purity of reagents (B)) Adding excess waterto the conical ‘ask (©) Blowing the reagent out of the (©) The polymer has physical and chernioal properties that ‘from the monomer units, lise ©) (D) Small moleoules are eliminated duting the condensation process, pipette tip Overshooting the calibration mark of te volumetric asc 17, Which ofthe following instruments is NOT used in ttrimetry? 435, The product formed by the polymerisation of propene, C,H may be used as a (A) task ®B) liquid (©) disinfectant (D)> plastic material 02212010/CAPE 2013, cco) ®) © ©) Barometer ‘Thermometer Potentiometer Conduosvity meter GO ON TO THE NEXT PAGE6+ 18. Which of the following graphs illustrates the titration of dilute sulfuric acid with potassium hydrostde selution? . 4 14 . ae ®) on 1 1 Vol of H, 80, Vol of, 50, | . 4 (Dp) ) 14 © om | ©) oz 7 < iG Vol of H, 50, ‘Val of, 50, Items 19220 refer tothe following information, ‘A student carries out the grevimettic analysis ofa soil sample teken ftom an area surrounding & ‘garage. The soil sample is found to be contaminated with Pb ions. 100 em ofa solution obtained from the semple when mixed with 25 em* of 0.100 mol dm? HCl yields 0.010 g of lead chloside. [The relative formule mass of lead chloride is 278.2.) 19. The balanced equation forthe reaction between lead ions and hydrochlorie acid is = (A) Pb(S)+2HCI (aq) > PECL) + H, (@) (B) Pb (6) +2HCI (aq) + 2POC G) +H, (@) (©) PL (aq) + 2HCI (aq) —> POC, (aq) +2 (aa) = (D)) Po (eq) + 2HCI (eq) > POC! (5) + 2H" (eq) _ 20. What is the concentration of Pb in the original solution? (AY 3.60 x 10 mol dm? (B)) 3.60 x 104 mol dm? (©) $.40x 10" mol dar? ©) 7.20% 10 mol dm?21, 25, ‘The complex ion [FeSCN}* hes # molar absorptivity (€) 7.0% 102 dav moter. ‘The coneentration of its solution, which gives an absorbance of 4.2 when tessuted ina 2-0 call, is (A) 3107 mol dm B_ 610% mol dm (OQ) 3104 mol dm? (DY 6 10% mol dm Which ef the following regions of the electromagnetic spectrum BEST matshes the wavelength ranges of P, Qaané R? Frequency Gi) one Uv IR radio @ oR UV radio (Q> IR UV says © UW IR xrays ‘The structural features which cause absorption in the UV/VIS region of the electromagnetic spectrum are known as (A) bonds {B)) chromophores (C) isolated m bonds (D) lone pairs ofelestrons ltem_2¢ refers to the diagram below ‘which represents the structure of a water molecule, os aN HOR No "Which of the following vibrations may be exhibited by the molecule? (A). Bending only (©). Bending and stretching. (©) Symmetrical stretching only D) Asymmetrical svetching only Which of the following alkenes has the wavelength of maximum absorption, Ay? ‘O"O"O'D . .| | A minnie of gases containing methanol 26. thenok propan-I-ol and propan-2-0), was obtained rom arefinery. What hethod cen beued to separate these gs Sr analyss? (A) Mass spectroscopy. | @)__RRepectroscony (©) Gas-liqud chromatography ©) High pressure liquid ehroma- tography 27, Which of the following compounds do ‘NOT absorb infrared radiation? 1 HO and HE i ML Hrandcl, | ML Niand Be, | (A) Lend Ilonly | @._ land only | (©) Mand lil only ©) Wendi | 28. Which of the following specie NOT a significant fregment from the mass spectrum of ean? ( a oF @®) CHY ©. GH @) GHOr | 29, Which ofthe following ene je NOT ® sing agent in chromatography? (A) Cellulose ®) Iodine | (©) Ninhyerin | D) —Uraviotet tight | | | i | 02212010/CAPE 2013 | 30, 3h 32, 33. > Which of the following statements about partition coefficient would be tus? It does not vary with temperature. I. The solute has to be in the same molecular stat in both solvents for ito be e constant. ML | The two solutions have to be ‘concentrated for itto be a constant Lonly )) only () Land Henly ©) Tae Sulfur contaminated coal is usually mixed ‘ith calolum carbonate at high temperatures to reduce SO, emissions, Which reaction() will ‘be important in helping to reduce atmospheric pollution? 1 Cx00, +80, + Ca80,+CO, I — 2CaC0,+280,+0,+2C280,+C0, WL €20+CO— Caco, (A) lonly Jand tf only (©) Wand Wl only ©) Lend Which of the following is represented by C,=C, hydrocarbons? A) Diesel oit B) Gasoline CQ Kerosine (D)> Refinery ges Which of the following may be a result of light-induced reaction of pollutants inthe air? 1. Global warming IL, Photochemical smog, BI. Greenhouse effect A Lonly @)> Monly (©) Tend only ©) Mend mt GO ONTO THE NEXT PAGE34, 35, 36 31. Fermentation of sugars to alcohol is 38. ‘controlled by an exzyme complex (mixture) Ienown as (8) amylase (3) lipase (C) suerase (D> zymase In the manufacture of chlorine by the electrolysis of brine using the diaphragm call, the anode is made of “(ay steel ©) graphite (© platioumwithacoatingofasbestos 39. (©) thanium with an inert coating In the production of sulfuric acid by the Contact Provess the following exothermic reaction takes place: 2804g)+0,) —— "= 280, Which ofthe following condition(s) would ‘favour the forward reaction? a 1, Low pressure I, Excess oxygen UL Lowtempersture (a) Loaly. B)_— Land only (Wand I only DY Wand Ut Flocculation is a process involved inthe (a) ) clarification of water (BP cleaningofthe fumes inthe Haber gy Process (©) conversionofexcessSO, gas inthe contact process into MgSO, (2) produstion of ethanol by For which TWO ofthe following industrial produats is chlorine MOST widely used in ‘their manufacture? 1. Solvents H,—Sodium chloride BI, Polyvinylchloride IV. Chloreffverocarbons (4) Tandt COBY) Land I (© wand it ©) Uandtv ‘The burning of polyvinylehlor, PVC, is considered an improper disposal technique because PVC (A) causes acid rain (B)_ destroys the ozone layer CQ) forms toxie products (DY hase very high melting point ‘Which ofthe following ions are significant contributors to eutrophication? 1 BOF NOS Mm 807" Noor C@)) Tand 11 only @) Yan I only (© | Wend It only ©) 1.1, Mendiv “The presence of phosphate fons (PO,") oan be detected using Cay) emmoniumn molybdate (@) sodium thiosutfte ‘fermentation (©) potassium thiosyenste solution = (D) potassium hexacyanoferrate(I1) solution GO ON TO THE NEXT PAGE——— r -10- 42, When chlorofluorcarbons in the upper atmosphere are impacted by ultraviolet fadiation, eblorine radicals are formed i preference to fivrine radicals, This ecoure the upper atmosphere because the eneTEY of the (a) C-Fond (484 kd mol) is greater than the energy ofthe ultraviolet radiation B) CL bond 40 kd mot is rete than the energy ofthe ultraviolet radiation (©) CCl bond is fess than the enerey of the O-F bond (©) C-Cl bond corresponds to the ‘nergy ofthe ultravioletmadiation 43. Chlorefiuoroearbons undergo homolytic ffesion by’ being exposed to ultraviolet ight in the stratosphere. Which radieal could resvlt from cHFCR,C!? CHER! >) CHFCFY (© ‘CHFCF,CL () CHF-CFCI 4, 45, Nitrogen monoxide, NO, is responsible for the destruction of ozone inthe stratosphere, How is NO Benerated in the atmosphere? 1, Combustion of fossil fuels II, Lightning discharge I, Reduction of NO, by SO, (A) Tend only @) Land tl only (©) Wand Ittonly @)) Mand 1 Which of the following plastics are biodegradable? (A) Polythene terephthalate (B) Low density polyethene (C)) Poly @— hydrowyoutenoie acid) (DY Polyvinylehloride END OF TEST uF YOU FINISH BEFORE TIME IS CALLED, CHECK YOUR WORK ON TSIS TEST.