CS Meas Re eT Rf ° BEAARRR (Eases ART) LUI 2. RUIKOPV TRE 2.1 SEAS HAAR EEA) tit, AKA FARMC SI NOtERET, BF AROKRAMET SE, B FRI ZEN 2 LS AONE TUK, OO, FROME LOE G. RARE FORK (REM) TEENAGE (BE RABRUKICIE OC. 21.1 BAAR REY (1) Ret LORY AR 7 (1660) (2 SEMRHDIS "—sEIR REIS J5 17 2 AKO v IED p RMIT 3.5 CL ERL ke thbt, pos ay tnd. (2) Yeo eR vray (1787) RUT A -y 7 (1808) 13, SMRIC EN ENE Te ROPE I HAT SOE SAM L, COMME MAT S EH —273°C TU=0 LGEDEERL Ores ESOREE OE LCM SRR EOHIRET Co, PERIL (CC) LOMICKOBRAA SZ. T(K)=#-C)+273.15 (1.2) Yar NOEMS TEND BE SIL, —BRORUAOAPULHIR RIC ICL TRS.) Ob eA LEOOTKATRENS, of T= (1.3) 3) Kf Wd LOA RANE oe VOTER EA ERO RKO dob SAKAUZEETI IC EGIL, HONE EMITS. LEEMLELDTKATRENS, bof T= —8 (1.4) () BRR ROR WHOREERTED, Kk, REOMRERTAL OH ORBHRALILKRBA (equation of state) &0vs, —ARODICE S(d, v T)=0 (1.5) CRENS. BBR T RY FO ORR (IE, EDA bIE, TO TORRO RIE KRAROFFE LEU.) £9 Lmol ORES, EACH CHAR RRA (0°C, Latm) T 22.4141) E5HSP5, (1.4) RORMT STOMA TERME CS, LA eREGHE, Rl mol kIT, bu=RT (1.6) nmol KOT,6 1. Atk — AHH RE bV=2RT (1.7) 1.9 WERE (= EM) eed, (1.6), CREME Am | En ] = mR it ft PRERE OV, CLEOKTHE 1 atm 0.082 Latmimol-K NEMKEMARKO BE. cm | ayn/em® | 1.986 calmolK RIGERTE FE, RIGED, OR cm | ayn/em® | 8.14 x10" | erg/monK frie EBM TX OAS £9 MiLB B28, ole ara kaf-mikmol-K TORK LEME LOT, a pa Tena Vimo CE RRR ISA AE %& (universal gas constant) ¢ 5. RR (RIMM) BRC SRUA, AKOMME m (LAMREC), SFREMETSL, n=m/M CRE (LIRCRALT, R = aRT= "RT =m E DV =mRT=ERT = m( FE) T= mRT (1.8) Re, BHMRTH, DV=GRT bd, (1.8) ROMER RAALCAT EIR, RO CERGSEMELS. F110 URRORIRER, HeMh, Wi REL SEEM, | sBeLLA, Cu R (ore) (ore) Rk | 258 lore, okt |e [crear og) KerK | kg-C | ke-K | ke-C | ke-K] 7 He 4.00 2.0772 |1.251 | 5.238 |o.7550 | 3.160 | 1.66 Ar | 39.94 0.2081 ]0.124 | 0.520 Jo.0746 | 0.31 | 1.66 He 2.016 4.1249 3.392 [14.200 }2.4069 |10.0754) 1.409 Ne | 28.02 (0.2969 |o.2482 | 1.0389]0.1773 | 0.7421 1.400 Os | 32.00 0.2598 {0.2186 | 0.9150|0.1565 | 0.6581] 1.397 — | 28.97 0.2872 }0.240 | 1.005 Jo.1713 | 0.7171) 1.400 co |} 2.01 0.2970 |0.2485 | 1.0403]0.1776 | 0.7433] 1.400 NO | 30.01 0.2772 |0.2385 | 0.9983]0.1723 | 0.7211] 1.384 Hel | 36.47 0.2280 {0.1910 | 0.7997]0.1366 | 0.5717| 1.40 HO | 18.02 0.46163]0.4446 | 1.861 [0.3340 | 1.398 | 1.33 CO: | 44.01 0.1890 }o.1952 | 0.8169/0.1500 | 0.6279] 1.301 NiO | 44.02 (0.1890 |0.2032 | 0.8507]0.1581 | 0.6618) 1.285 SO: | 64.06 0.1300 [0.1455 | 0.6092/0.1245 | 0.4792] 1.271 7Tve=7| NH | 17.03 0.4883 0.4911 | 2.0557/0.3744 | 1.5674] 1.312 Tetuy| CH | 26.04 0.3196 ]o.3614 | 1.5127/0.2850 | 1.1931) 1.268 4 9 »| CHe | 16.04 0.5187 |0.5151 | 2.1562/0.3912 | 1.6376] 1.317 ZFLy| GH. | 28.05 0.2966 |0.3851 | 1.612 0.3142 } 1.3163) 1.225 = 7 v| GH | 30.07 0.2765 |0.4130 | 1.729 Jo.3470 | 1.4524] 1.20 Tey} Coe | 44.10 | 19.24 [0.1887 [0.3705 | 1.561 }o.3254 | 1.362 | 1.1392._Atho PVT st 7 CURE.) iE 20°C, FEF) 210° Pa (HGH) OBRANEH SM OF 7IA2THS, L OAMOEN & 35X10 Pa (#41) STH SCET OME (DOC GO. REL, MROEE JANIS 655.1 W/keK &L, BARRE LHL. (AR) nmol DERARAROAREIS pV =nRT SOT, =2x10°Pa, V=Sm', T,=293K, R=8314 J/kmolK BRORREm(kg)tE Se, n=m/M (M=32) £9 Mp. V _ 32x2x10°x5 _ RT 8314x293 13 (ke) MARI EDIBLE Tr EB PH, Tem Ty bt = BA BSIO" 515 (K) MARICBET 2 Aa QI Q= mC Te Tr) 3.1 655.1 x (513-293) 89 10°(J)Ki1.89(MJ)- 2.1.2 RAMBO BBRORUCE RERIRTH oT LBBRRTH IE, BARUROEAUIMATT SB, () Fark yosR RETO ERARUEIME ORO E ELIA L, LIEN ENAMORED ETS EARS S AEM EGET, KV by OREO M-SHA EO MKE ETS WE, ROMKOLT SLE piLENTNOMARKOBE p. OWL, VHCRS, tub, Sp. (sei, BE) la (= Vil V) } bus, + UAE ERA ORO EAH, Vi ld i RAO MOTD D. (2) 7YH— (Amagat) OizAI RET SERA ODS BEDS 2 EOBSC, MOSM ST CHORE BFKO 5S SERV AA-ENT KA SERPRAOBI Vi OMSL.) ABST S, tubs, (1.10) WRITS. RERACBO TS MUby, TeY-ORME DK, EADRTRAEW bee ERLE CHB. PILI, Ar & CoH, (49.94%) DHSWTIL, KMS 17 VHE 30.00 KU 110.00 atm HF LC, eile 4 rfid 29.15 RU 101.85 atm £23. 3) BFR, MAEM, ke8 1. tk REAKODFRRVEREROHA CHE L ESRERAORKER, HAEO BRE (1.11) ~(1.16) ERT. (2) RERODFR (Mn) bt Mn=X(MiViIV) (1.1) (vb) RAMMORBEM (Rn) Rn=X(GRiIG) (aa) Ru=RiMn (1.12b) {c) RAMBOLM (Cx) Ca=Z(CiGIG) (1.13) (¢) ROMO MBH (G/C)e BME (V/V) G=IGa=rv (1.14) r=Z(nViV) (1.15) > nin=VdV, G=nM £9 ERS. IO, yA MSRS ORR (LER) THO, (PUEET.2) Ar 50 v01%, Hz 50 vol %OBS THRE L 2 RMOBELMERD LE, RL, AF Bis Ar 40, Ha 2, BiARHR (7=Co/Ce) 1k Ar 1.66, Hi 140 ¢43. CH) RARKOD FA Mn (3 (1.11) EO =ox-. de. Mn=2x5+40x-3-=21 PRAM BB Held (1.16) KD aly 2, Gul G= 7X Fy = 0.048 oh MO, GarlG= 2 x 21 0.952 Co~Co=ARn ((1.48b)KE9) RU Co/Co=y 9 —1ARn OT 32, Ra=R/Mp (1.12b) £1) C= Ay Fe el, R=848 (kefm/keK) fio Tt, = 166x848 Com = THRE Tym 427 KAD = 0-125 (kcal/ keK) =-__1.40x848 Com == T) x AT KT = 8475 (kcal/kgK) BAKO EEE Heh Cog 1d (1.13) KIC ED2. tho PVT ASHE 9 Com =0.125 x 0.952 + 3.475 x 0.048 = 0.286 (Ieeal/keg-K) + ~() 2.2 RARE BUCY £5 kc, GERBIL eS LBA RKO MLTR eC, BC OS LETK SEER 5 RTS. 2.2.1 PTB IRE HERMOPVIBIREBLZCAT. ACAD, BCRMAMRERT. O2, iE TO FRRLORMAI SD EEMTSL, AX CHILAIE , BACHILAHT TS, AB MILK MORWBAT, EN pad BLES. CNA T CBU SRAETH S, BEMIS 3.8 BA CCK L DIORAMA L, DOI Tee 16 (S, 2A (HORDE) OTLAC (RIAL) CE 14 HURL ARBRE 2S, Pub, MIKE HUD EA WRC LEVRBEES, LOEEO Te REFORMS | RIB F ME NORA T 2 LAIR Li SBRRT, CHEMRBRLYG, FR, COLE CEN MRED pe, SRE MRSM ve (OFERERT FS) ton, hb emMRewev 5. MAORMKOMRERERIIUCAT, BIRT UK DMT > BBORETH , COIR be Se PVT “S700 B00 FOO 400 SOD G00 BORA RATUK AMICI (, Seb CRRA ISL TE A(atm) 9 VRE EVER MIETS. GILL, SezEStK (po) HEAR BRA OE OAEMIIRE bit, = OBUBIC IESE aceon COHEN SRRYDS, Febdb, HOMME LESH fh, AMEN, BAKE CES. Eh, DT ATEN BALE) BRAKE CBMGL, WEEHKE CS. OROBRAETE ABRR (WRI YZ IEEO G6) PROUD, BRAE OD LAVIREMTH, OKT SMI £5 TEL TO 80%, MIMRIE CIE < KON, COBARRL TI IAI— LIEN SAE TH HLT, SFL ORME LCommacemBINe ae DRERR ARE BY, DRA LORE ERE DLE CHEN b MIRE 2B LC BARE RA de 2.2.2 RERGORR AEA (1) 774 Fb I-Wat Dry Fu 7-WA (van der Waals) (1873) (29RD RM ROME te €0,100°C. > (pe)/(po)a inh BL2 RERAOPVTREE10 1. tke He HI SHR AROMRIERE van der Waals 2% (a,b) AS | BRE | ARS | BEES |. Her [cdltttinbtentimen NAV 268.9 — 267.9 2.26 0.0693 0.300 0.034 x 10° 23.6 ak * 252.8 239.9 12.80 0.0310 0.305, 0.246 x 10° 26.68 as & 195.8 147.0 335 0.311 0.292, 1.351 x 10°) 38.64 = a 194 140.7, 37.2 0.35, 0.282 _ = —BULRR!) —192 -140 34.5 0.301 0.286 1.456 10° 39.54 Tray 185.7 122 48.0 0.531 0.291 1.353 x 10°| 32.31 xe x 183.0 1184 50.1 0.41 0.292 1,362 10° (31.87 Ag y¢ -1615 82.1 45.8 0.162 0.290 2.256 x 10° 42.71 LHe 103.9 9.2 50.0 0.227 0.279 4.508 x 10° 57.50 Hit KO 83.7 S14 815 042 0.266 (3.672 x 10° 40.85 Teter 83.8, 35.50 61.65 0.2315 0.276 4.417X 10° ‘51.54 =wetemem| (57568, aio | 729 0.468 0279 | 3.606x10°} 42.80 Tory 421 96.8 42.0 0.220 0.277 = - fa * 33.7 144 76.1 0.573 0.275 6.491 x 10° 56.21 TYrtaTt — 33.35 132.3, 11S 0.235, 0.243 4.197 10° 37.37 Cab —10.0 157.5 178 0.524 0271 6.773 x 10° 56.78 ae 100.00 374.2 218.3 0.32 0.231, 5.454 10° 30.42 WRAE LT, RAAF AROMA URED PHAM ORD SMRRLEC LI LS EBL, WAR FUROR RID FOUN ES HIE D RUD FM OG DIRT ( HIER a/v* EMAL, SAK L mol EDV TRKORBRE BR (0+-3)o-v=ar (in) £2, mmol (V=nv) Tht (o+ ua oY -nb)=mRT (1.18) EGS ARM a, DIGRLIUCAT E I ERACBHLERT, Try FL I-A RHE OS, ERS CMSB Lebo, (ap/d0)re=0 BU (8 p/d0*)r=0 (1.19) HK SE, (1.17), (1.18)KM a, DILO.1NAOMRERY, DO, T=Te, p= bey v=vet Lt a=27R*T.*/64p6 (1.204) b=RTi/ BP. (1.20b) DEFIRM SNS. ER, doy Ter veld, be=a/ 27d", Te=8a/27R, ve=3b (1.21) EGS. LOL, RARCIE (1.2) ROMRMBIIRILEM, Try FY TAK 2H BCBG E RG te CERI RS OTM SH, HEROIC RALZERTHS,(2) €OtbOARMESt (2) Redlich-Kwongst (1949)? (1.22) TTY Th I-WARKEME 2EBNTH OM, COWORP TIMED. LOL, & SEMOPV TBR EMICRTS LISTE (b) Benedict-Webb-Rubinst (BWR3t) (1940)”” pa ADs BeRT= As (GIT?) DRT =a, a prize (1.23) SHEBAT, Ao, Bor Co a, d, Cr a, YILBET, RADBULARES < OMe CHE PRONTO B. (6) Virialst be} 4A4 BC, RTS tet at (1.24) BERROREAEMIEL LR BORMRE EIT UBREVG. A, By ikl, MIE YT HL RAE MEE IS EM CRE OBE CS. CY TIME DEE AY ea FP awbY eM & DRDSIEMTR ENT, MEDBBATIL EM, SC OWRCWTE | TILER AN DD b TBD, RERKORMAIP THRO AR HEMT HB, 2.2.3 SRR FORMED, 0, TERERRM AE (De ve Te) CH AMT } (1.25) MORTAR (ir vy Tr) THRT SE, AAROMIIC BURG (DLL RERERT. WHE p= p/Pe (1.254) RRS vr =v/ve (1.25b) HERIBBE = T/=T/Te (1.25¢) TTY Fh P—WAB(LD) He (1.20) KE (1.25) KERAT S EARIBL NS. (0+ Ss)(o--4 (1.26) IE FOr vr, Tr)=0CERERT, ROM BURT EMER OT, BBS It TATORAK OM TRMUBE LS. CORTHENSHRENGREMA (principle of corre- sponding state) Eo, Pry FU T-VARED AMER, COMRWHE OHM £ ¢ AmanS. 2.2.4 EE RRME 2 RE FERE ORB BILD. 2.271 bOI VERO LOARRE NTO SA, OFS RA, FET, BRERA OL ROC NITE OT, BARBI RO FORMS S. TLC, LHHIC IEPVT Onde 13 SARE BUS & IL eA Se gr (1.26)2 L_ Aiko — soot (1) Bat RMRE LCERED BOA > LOMATH SI, CUCMERRE PIR BOKRE RI RMRE RAIS Bo pu=2RT pV =2nRT ERODE 2 & EHR (compressibility factor) L456 zl RAOMM PRI LOB PONT, COL THAT AMIE LOA, (1.27) hE NEIMECH SRL BE za bebe Bete =z bate (1.28) (1.27) EBB. Ze(=Peve/RTe) bd Ra RE MAR (Rid MILs) LOK, AICS IT — se MX te SLI KRSN(RLMSM), 2=f(d,, Tr) COHCKRORBORLTS. $( OWKO 2. ER LIZCRT, 2 AT STOWREN L TEM Eb EOA, FERORL SV RILARMT (2 ze OFMMHIL0.27E eS. F7, MEL LAMM H0.24~0.30OMICD, OFM L O.27E 2B, Conte MIS Le 2 AE CDMA OARS NTH BZ mmenean, 1-3! -MUbS Ne zRAORMERT. HL. Meow ROR AHR 0.20081 0.200~0.220| 2.5 | x7 7—v1, mene 0.220~0.240 1.3. | #(ze=0.232), NOx Te b> 0.240~0.260] 24.0 | =F 72-2, 2 AFR, 73 — ISH, NHS 0.260~0.280 | 50.6 | KBBAORILAAM, <- Frese tHe 0.280~0.300 | 13.9 | O2,Nz, CO%2MFHA, 4 Fv,xF >, CS2, HS, Ar 0.30024. 3.9 | Ha, He, Ne, Bra, tthe RIRAS = [Re eR 3.8 2.5 ZIRT S &, SARIS TE, PUTER ELEMIS HE CHEMT 2 = be TES. REL, He Hele TI, Te (K) & (Te+8) (K) ic, pe (atm) & (pe+8) (atm) ELT TRU pf CHAT SLEDS, KR zMORREERT. Ci) dy Tv RATV ARMORED 2 ORD Tr=TilTo br=Pilbe CBM b, alt Tr & hr Miter SEM.3C EN SBCRALEIE WTRB. Gi) Vi, Ti tT p PHRMOBEO 2 ORDA (PI81.3) BROIL, (ii) Vi, pr aBAT, THRMOBED 2 ORDA br=bilbeltBo TOBA, Tr PASE, LOL, a1=(Vibi/mRTeM1/Tr) 3 RY HBT, ET OFF 7 EME, BCBS p-=pilde KMSFS Tr OUWERAT, LOTFTIRAT S. BROAN 2, ERT.2._ Rik PVT HE 13 " a = 8 4 DUS 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 65 80 95 100 HIRE, 7, @) 4.9] 3.0 a : 201+ 109} 0 5 i0 15 20 5 30 35 40 HARE, p, o B13 2486 (ONEEI.3) BARI OME ASHI NH 7A S10 g EHTAL, WE 173°C $TLITS CENLY HEGSD REL, SROBRERMTS. (ALE, te=132.3 (°C), pe= 111.5 (atm) dV =2nRT BOT14 1. Ako — Het BE P=1L5pr (atm), V=2 (1), n= = 5130 (mol), T=273-+173= 446 (K), R=0.082 (J-atm/ molK) ERALT rx 111.5% 2=2 X30 0.082% 446, pr=4.922 Blsaicswct, Mais, (2=0.2, pr=0.984) & (2=1.0, pr=4.92) D2. Re MABMRE Tr _ 2734173 7 “pF ia g 711 Ome rh, PSI ANS. = (B) °.p=111.5%1.9=212 (atm) Q) 2HLFR- 7H F— (fugacity) SAD FHLBRO-—IT, RAMAN GT AVY—PRBOHM bY BLonechs. ERIC BITS BBX AVX—COBAUMKARKTRENS, (4G)r=vdp (1.29) PBARORE £9 (dG)r=RTdinp=v*dp (1.30) cv EBITD E LMT H Bo RARE (1 mol) KOO TOMEBORERY URES RDI, UROL I LENO DICT HVS —f BRT S. (dG)r=RTdlnf = vdp (1.31) TALF-WENOKTEMO, (1.31) Keb (1.30) REGS, P=0S PS CHATS. P=0T ERARORBRT fap Le VKREBS. inka gp foo ao= ["(e-F ao (1.32) Sip & 7 70 F—KRM (fugacity coefficient) E~5. TC, REAR ORBH (1.27) K€ (1.32) MERATS LE, = [ey ing= (“Ce ye (2.33) EUS. CNESSEMMRE 9, TREE, La f?"(g—1) doe Inga [ea Pe (1.34) 2D. KIRA RDS MIL C1) REMMI L TROL 7 ALF Sd eo RU T, ORE BRL ROPAMAMRT 7 ALFERD TH Be 22.5 BEFORGAROHR RIERA OREO PVR ER BBE, MMO I IC BR OARM (1.27) LBA HERA, ERIC RERAD FEMME 2m ERTS. bV=2znmRT (1.35) Ki, EGAKO ER zm EROSIOMAKERT.2. Kiko PVT HE 1s () 7RH-OBR FLRAUKIC BUY SEN PS MOMBE £ RAAKICMAT SOOT, URE LORDS NS. (y (2 ELH) 2m=Ziyitzayator=Z, (1.36) SMOMMECONT 0.99 ores—oiRMsse ||P MENBERIEI, 2 go HRORROIERLE Sy o4 OFT, Bie, KL b OPE OAD Mangcacis, 2 Soo nemircomme — § 070) BROT CHMLE 050 REGU, HLT # 5 og dl = = 0.01 002003005 0.1 0.20305 1. 2 3 5 10 20 20 TPH OEE RAE HORE SIC HEAT LC BLA RARER 7 42 F—HRRARED (ze=0.27) vw (2) 44 (Kay) Di (ARERR GK) FH (1.37) RTRBSNSRERAO AREA (Tele (Del) 27RD, NEAR WRB ALT, Tr RU pe BRD, MRO 24RN (GLI) Pb z(=2m) EHAL Bo (Te)m= Testi t Testa Zev (1.37a) (pen = Pett Peet Lhawe (1.37b) I, (Te)m (E(ERBFBIE, (De)m SRE RENTH Be (BIE .4) 4 9 50 voIBETFL > 50 vo EDGAR VC, SVatm IoHIF SARE HE wk a) Q) Te7-OK ays t za3h=0.965X0.50+0.851 X0.50= 0.908 RT /p=0.908 X 0.082 X 363.2/50=0.541 (J/mol) -~ 2) 71 nt (Te) m= Testi + Texy2= 191.1% 0.5+282.4%0.5=236,8(K) (be) m= Pestn + beste=45.8%0.5+ $0X0.5=429 (atm) Tr= (273.2490) /236.8=1.53 r= 50/429-= fog EMIS DO THIGH ZERDSL, ee= OF 18S. c.v=2aRT/p= @9 X0.082%363.2/50 $361 mol) reo (FE)16 1. Rko— sate He 3. RRO PERE CHER LEO RR CAAOMMAHEL I, FRE EIFS DS. FMM EE DDANFIERTH 0, SER MAEM A RF vor MRK 5S RRO BRE HERTS DbMBERTH SOO, 21 RAORABOEH PNBAVEICIL, 2 NCU re PV TREE OI Kc RAR AT OO ANNIE (HER, FL eo, ny bee eIIM) ach 2, 11 SERRE () SR aH FMERORE—-RMICKRTHE NS, G=flre G=1, 2 en) (1.38) » TID, VRRUB, LIMB, S17 ALF — CHS. ER RMAC 2 eS DIA LF — (LART Yo) MELVILERL TS. AARUMAEORD 1 OT AY F-BURTHELONS. LO = 94d (1.39) fs raser (1.40) LE, OIE F CMR OMSERTE, x1, ys 2 i RAOMARU RO ENE, 7 SER, Li ROB, ENC BU BMI OTALF—, PILSETHS. (2.39), (1.40) %& (1.38) KERAL T, a (1.41) EBD. CNYRMEMOREATA D. BEE TRBBRRLALL SOT, prt], Ei, MRT Li =90 RE) L EBD, Puc= 1b ers (1.42) PRON, Lh, MBM v=1 £9 di=PU= PELs (1.43) CERMPBALGS. (0: Mi OMMBOBE) (1.43) Hit SRMEMRTSAMASAM, & BERLE F, RAMS, BRASS, LOLEMAREOKS SOSFEMINOME BOBS, HSBC S—-WKRLFORAGER, TORMPMHIBIS SDHC HAT Soy CLEML, FV—NPEE (1882) EG, RBI cA FBR MLS@ORT. COL 5 AMER EE CODER RTO BRT —7ELTERCINTHS. (2) BER MP GC HA