PEbE SEE CUMIMUN ILO] IIT - JEE, 2014 |oeoe PAPER | (PHASE - 1) Ques TION PAPERS Time: 3 Hours Maximum Marks: 210 t ANS. KE (x INSTRUCTION: ENTIEE PASE TEST] f+ Masa ai nstvctions carculy cheek fla pages and no. of questions of your LY Waae Your Name, Enrolment number, Examination Cente, Question p Examination session in the boxes provided for STUDENT INFORMATION Darken the appropriate bubble under each digit of enrolment number, question con the OMR sheet IB. QUESTION PAPER FORMAT: The question peer consists of Three parts (P,C.M in any order). E 12. Seetion 1 centzins 10 MULTIPLE CHOICE QUESTION. EACH Q\ (C) (0) out of which only one is correct. ls. Section 2 contains § multiple choice questions. Each question has 4 choices its answer, out of which one or more are correct. l4. Section 3 contains § questions. The answer to each question is @ single dist in (both inclusive). c | | | MARKING SCHEME 1 For each question in Section 4, you will be awarded 3 marks it you darken the bubble corresponcing t2 the correct answer only and zero mark if no bubbles are darkened in all other cases minus one (~1) mark ‘wil be awarded in this section. 12. For each question in Section 2 you will be awarded 4 marks it you darken all the bubbles corresponding to the correct answer only. In all other cases zeco marks will be awarded. No negative marks wil be| ‘awarded for any incorrect in the section. [3 For each question in Section 3 you will be awarded 4 marks if you darken the bubbles correspond. the correct answer only in all other cases zero (0) mark will be awarded. No negative marks awarded for incorrect answer in the section fa$T2012- 24-P1-POM-Paper-1(1827.1).2 PART- I: PHYSICS SECTION=1: ingle Correct Answer Type ‘This section contains 10 multiple choice questions. Each question has four choices (A), (8), (C) and (D) out ROMEO YIONE Incorrect SS 1 9) LE Mg (u cos 6- sin 8)s. (D) None of the above A circular disc of radius R is rotating about its axis O with a uniform angular P velocity o radis as shown in the figure. P and Q are two points on the aise At any instant of time the magnitude of the relative velocity of P with respect to Qis Ro 0 6) zr Ro Ro © oe © ‘An enemy plane is fying horizontally at an attitude of 2km with a speed of 300 ms An army man with an anticraf gun on the ground fires @ shell wih speed of 600 ms, when the enemy plane is. directly overhead. At what angle from the verti! should the gun be fired so as to hit the plane ? (ay oo? + ween” 30° Case 4S y 60 & When a body of mass M slides down an inclined plane of inclination 8, through a distance s, the work gre by normal reacton i (u's coeicent of icton Gece nMy sno s A balls projected horizontally from an inclined plane with a velocity Yo a8 shown in the figure. It wil strike the plane after a time as 8 x Stoo « “% (0) vate z J A particle is given an inital speed u inside a fixed smooth spherical shel of radius R= velocity is vertical is (a) 910 ®)9 (© avz (0) 39 mY 4m that jst ale to compete the cle, Acceleration of the panicle when ts ( 7.) esif Nol’ ‘Space for rough work ie S°T Meese Sy byt ad ayt Veinot — st por z Sy =(Usino) E+ ee so0m|] 5 7 Dowd = 00x sind ~ hioor!s St% —Goosimayt + Reio3 Foes cae eae chyTwo blocks of mass 2kg and 3kg is passing over a frictioniess pulley as shown in figure. Find the work done by tension force on 3kg block after the ‘stem is released from the rest in frst second. [Take 9 = 10 m/s") (A) 245 8) 484 (©) 244 (0) zer0 ‘Acaris moving on a horizontal road when rain drops are faling vertically downward wrt. the ground ‘The rain will strike (Assume the screens of the car as completely vertical) ‘The front screen only (B) The rear screen only (C) Both the screens {D) Either front screen or rear screen depending upon the magnitude of the velocity Pe ee eas stops sng ores pt tenes putey.Tme 7} —7 ae te arate touts omasmtre crs eee LL eae ee een of beck wed eviey more Pe incistncsen's aire oop | m m ay) eam 9*) ©) mean m 2m ©) aemor?) Ome WA-B+|AxB > V2AB, find the value of 6 (A) O° (8) 90° (30° ors A force F = 10 J2N acts at an angle of 45° above the horizontal on a 2kg block placed on a rough horizontal surface. The coefficient of friction between the block and surface is 0.2. Find the work done by the force F ‘on the block in §s. Initially the block is at rest. [Take g = 10m/s"] (A) 2505 (®) 2500) (C) S005 (D) 50d w=02 ‘Space for rough workaot 24 -PeM Paper 4(1827.1)4 SECTION ~ 2: Multiple Correct Answer(s) Typo ple cholee questions. Each question has for correct 11 Which ofthe folowing slloment can be posse cases a aneive-Ginentana maieey— body has zero veocty andi sil aceeterang © The veloiy of an object revises drecion when acceleration is constant (©) An object increasing in speed as magnitude ofits acceleration decrcases (0) None of these, {choices (A), (B),(C) and (0) out 12, The force exerted by the floor of an el Weight of the person if the elevator is. (A) going up and slowing down (8) going up and speeding up (©) going down and slowing down (©) going down and speeding up tor on the foot of @ person standing there is more than the 13. vector A has magntude A and A is unit vector in the dzecion are corect, Of A. then which ofthe folowing 6 lAles a4 WO A sows Te pontoons ene (Thema tein wicecn cosine ners (©) He can reach the point Pin time & (©) He can reach the point Pin ime (0) He cannot reach P ifu > v. ‘One end of a light spring of spring constant k is fixed to a wall and the other end is tied to a biock x! The possible cases are (A) the spring was intially compressed by a distance x and the finaly in its naturat length gcc intially stretches by a distance x and finally was in its natural length Placed on a smooth horizontal surface. In a displacement, the work done by the spring is twas initially in its natural length and finaly in a compressed position twas intially in its natural length and finaly in a stretched postion ‘Space for rough workThis section contains § (both inclusiv 172012. 24-P PCM. Papor-(1827.1).5 SECTION ~ 3: Integer Answer Type questions, The answer to each question isa single digit intoger, ranging from 010 9 Peewee ae St MCA URIBE 16. ‘A small sphere of mass m = 2kg and radius r = 0.Scm is moving in a smooth horizontal Circular groove of radius R = 10m with constant speed of Srvs find the work done on, the sphere by the normal force exerted by the groove in minute. c) ‘A block of mass m= 1 kg is placed on the other block of mass M = 2 kg, which in tums placed on a smooth horizontal surface as shown in the figure. _F ‘The coefficient of friction between the blocks is 0.4. A constant horizontal ——]_M {force F = 6N is applied on M at time t = 0. Find the magnitude of the work ‘done (in joule) by friction on the block of mass m = 1kg in frst one second in ‘ground frame. Jn the adjacent figure intially block is at rest and two horizontal forces Fy m=5k9 and Fz of magnitudes 20N and 10N respectively are applied Fs 10N, Fis 20N ‘Simultaneously at time t = 0. The coefficient of friction between the block “J Ind the ground is y= 0.2. Calculate the work done by triction force on nae the block in fist two second.) v = ‘Two particles A and B are located at points (0, -10V3) and (0, 0) respectively in xy plane They star ‘moving simultaneously at time t = 0 with constant velocities ¥, = 51 m/s and vj, = 6/3) ms, fespectively Time when they are closest to each other is found to be Ki2 second Find K All distances are gwen in meter. 3 a Vectors P.QandR have magnitudes 5,12, and 13 units respectively and P Q=R tangle between @ and R is. Then find *Scos0. _S ‘Space for rough work{72042 24-P1-PCM Poper-1(1827.1)-6 PART- Il: CHEMISTRY SECTION 1: single c @ = 1: Single Correct Answer Type This section contains 10 multiple choice questions. Each queston nas four Irasestoncortans 1 mune ches aves ‘queton has four choices (A), 8), (C) and (0) ot 1. Artange the folowing species according io wereasing oxdalon no oT carbon () Cri (I) CHJOH fl HCHO. (V) HCOOH @) a tamsw @ 1O 6 F > Br: First electronaffinity (3) O>S > Se: Electronegativity \_- eee (4) Li> Be > B: Second ionization enthalpy) ge \ Gaye) OF >0> Mg’*: Electronegativity © Cons ) (6) 8 > Be > Li: Covalent radii eh at 2p oe inc By e for rough work (5725 Sy! Iss © ne ¢ . 6 Be bi s BSLV Sen 3 eo 2 tee oer Ss 3 a be < 2 tw 2 Te, = O22 WH ey Sey, S728 oO, , Oey FER ax 7, owls a s j 1 U Rattthe percentage (20% 142B. 9-04 (0) 50% han 10D Torano® 8 Which of the following is wrong statement? ioe (A) Ha and D; posses same physical properties (8) H, and D; can be separated by using thei rate of reactivity towards Cl, (C) H,0 is stronger acia than 0,0 (0) When water (H.0 + 0,0) is electrolysed, His liberated much faster than D; a) A) NV: GOF.CIS > WEF yo;.¢0F-.s0, (© ¥o;..Gi0;, 80, » (0) None dPinese Tenney Pes SECTION ~ 2 : Multiple Correct Answers) Dood) Geaner Neate 2 ay ‘This section contains § multiple choice questions. cf which ONE OR MORE are correct. Question has four choices (A). (8) (C) and (0) out ‘S moles of H,SO, will exactly neutralise “ JOSS Sr 12 Amolar volume ofa van der Waals’ gas can be liquefied A at Boyes temperature under high pressure {6) at ertcal temperature, under a pressure more than citcal pressure {C) at ertcal pressure when iis cooled below the critical temperature {0) at very high pressure and above critical temperature 13. Be and Al show diagonal relationship and thus (A) their oxides are soluble in alkali solution forming [Be(OH), |” and[ AN(OH), (8) they form complex anion BeF;” and AIF; (©) BeCt and AIC, are Lewis acids (0) ones are basic 14. Which of the following has tetrahedral structure? WS PCh BF, WF CCU OF NH, vine fe towing is ampieet A Me (B5 CO NOFAKOH), (0) Be(OH) 3 7, SPace Tor rough work oie 2oo gee igo i a/v 8: v; MG < aeVan: PART - Il: MATHEMATICS “ See 6 This section contains 40 multiple ch < tains 10 multiple choice questions. Each question has four choices (A), (8). (C) and (0) stench ONLY ONE eames" : " eT Ces) (+9) 50, then xis # (=2) ¥61-1,0) 00,2) Oc*-1VR» (C)-»,-1) 500. 1) OO. 1Wa= 2. The point A(2, 1) is translated parallel tothe line x - y = 3 by a distance of 4 units. If the new posit Ais in third quadrant, then the coordinates of A’ are W (2+2s2,14212) (0) (-2+ 242, -1- 248) (©) (2-212.1-248) (D) none of hese iy an fin fE-e.men & : ro x he a-° we Zh a: @» y x 6 2 Oh 0) ¥ ie y o Ne Boy au Shope of line through the point (1,2) whose distance from the point (3.1) is maximum. is wre Y (@y=xe1 a5 (C)x*2y=5 (O)y=3x-1 0 +8 oA WAS B45" eae ee 1) is equal to cot acot ~ COFA- CO wo (1 a nese We (03 30,18) 3 TB) = tee 4 1A 6 eG “BS 1i(3) + 20 4 ‘Space for rough work a Perens Latin Sb nies ks >} 11202: 24-P PCM Paper (1827.1) 10 6 qi 10. Consider point A(3, 4) and 8(7, 13). if P be a point on the line y = x such that PA + PE ys minimum then coordinates of P as 12 12 13 13 (A) { (F ‘2 OTT 31 31 (C) o(% 3) 0.0 ace Gute ago Many line makes an angle 0 with the positive direction of x-axis where cos = then tS slope is es A) 8 (e) 6 RC 1 be OF ‘The line 2x - y + 1 = O is tangent to the circle at the point (2, 5) and the centre of the circle lies on x- 2y = 4, then radius of the cifcle is (A) 3V5 (8) 53 (AS (0) 52 ‘There are two circles whose equation are x? + y? = 9 and x’ + y’ - 8x - by +n? circles have exactly two common tangents, then the number of possibie values of nis 2 (8)8 (0) none of these ne Z. ifthe two (c)9 Pet 2, then x is A) 3101.) (8) 3, 0)U (1,2) (0), Ue 0.5) 4(3)1) vl 1,.> ‘Space for rough work ae 7 ae172012. 24-P1-PCM-Paper-1(1827.4)-14 SECTION - 2: Multiple Correct Answer(s) Type This section contains § multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONE OR MORE are correct. " 12. 13. 14. 15, Ifthe circle x? + y? + 2x + 2ky + 6 = 0 and x’ + y! + 2ky + k = 0 intersect orthogonally, then k is (A2 (8) -2 3 : 3 Oo; (0) The lines x + 2y + 3 = 0, x + 2y- 7 = 0 and 2x~ y - 4 = O are the sides of a square. Equation of the remaining sides of the square can be (A) 2x-y+6=0 (8) 2x-y+8=0 (©) 2x-y-10=0 (0) 2x-y-14=0 ‘Suppose ABCD(in order) is a quadrilateral inscribed in a circle. Which of the following is/are always true? (A) sec = secC (B) cotA + cote (©) coseca = cosecc (0) tan + tan If logy logs = logS_k # 1, k > 0, then x is equal to wk w? (5 (0) none the these The line 4y ~ 3x + A = O touches the circle x’ + y’ ~ 4x - 8y - 5 = 0, the value of 2 is (A) 29 (@) 10 (C) -35 (0) none the these ‘Space for rough work172012. 24-P1-PCM-Papor SSS SECTION - 3: Integer Answer Type This section contains § questions. The answer to each question is a single digit integer, ranging from 0 to 9 (both inclusive), 16. The circle which is touched by y = x has its centre on the positive direction of the x-axis and cuts off a Chord of length 2 units along the line /3 y - x = 0. The distance of the centre from the origin is 17 The length of the common chord of the circle x? + y’ + 5x + 7y +9 =Oandx?+ y+ 7x + Sy +9=Ois 18. The value of is 2x’ + 7xy + 3y’ + 8x + 14y + A = O represents a pair of straight line 19. ‘The number of integral values of m for which the x-coordinate of the point of intersection of the lines 3x + 4y = 9 and y = mx + 1 is also an integer 20. The value of V3 cosec20° - sec20° is ‘Space for rough workflirs€e€ COMMON TEST spTR24A1-AS, B1-B4, C1-C2, SOTW24A1-AS, B1-B4, C1-C2, SOTX24A1-11, soTWOK IIT - JEE, 2014 ees PAPER Il (PHASE — 1) A Time: 3 Hours Maximum Marks: 198 (A. INSTRUCTION: Read all instructions carefully. Check total pages and no. of questions le’ Wete your Name, Enrolment number, Examination Centre, Question Examination session in the boxes provided for STUDENT INFORMATI: Darken the appropriate bubble under each digit of enrolment number, ques! 3, IB. QUESTION PAPER FORMAT: 1. The question paper consists of 3 parts (P,C,M in any order). Each pa l2. Section 1 contains 8 multiple choice questions. Each question has fou’ vs which only one is correct. Section 2 contains 3 paragraphs each describing theory, experimer choice questions relating to three paragraphs with 2 question on aac Section 3 contains 6 multiple choice question. Each has four choices (A more are correct . MARKING SCHEME: For each question in Section 1 and Section 2 you will be awarded 3 marks. If you darke corresponding to the correct answer only and zero(0) marks if no bubbles are darkened, in all ot minus one (~1) mark will be awarded in these sections, 1 3, you will be awarded 4 marks if you darken all the bubbles corres to the correct answer only. In all other cases zero marks will be awarded. No negative marks w For each question in Sec awarded for incorrect in this section.O This section contains 8 multiple choice questions. Each question has four choices (A), (8) (©) and (O) out 1. Skins and pute ae masses ang ictoies Te elaionn Accteraon a the lock a shown nin ges Gre ses: 2 Apartcie of mass m is subjected to a force F =F,{cos(t)i + sin(y). I intiay (120) the particle was at ‘est, the kinetic energy of the particle as a function of ime is given by: SECTION ~ 1 : Single Correct Answer Type Kot Wy eet rs 20} 14 Zam 3. A paticle moves over the sides of an equilateral tiangle of side ¢ with 7 « Ce4gonstant speed v as shown in figure, The magnitude of average acceleration as itmoves from Ato Cis ¥ iv « os nt ha cone It wor 2 ‘ Be > Cs ee (c) 7 ~ (0) ue 4A block of mass V3 hg fs resting on a horizontal plane (Coefficient of static friction p =1/2¥8), A force F is applied to the block as shown in the figure, The minimum magnitude of F for which the block begins to slide is (g = 10 m/s?) 7 (4) 20N () 5N (© @03)N (0) 10N 5 On a rough table, three blocks (including the first block) uy we ‘are placed as shown in the figure. Mass of each block is y os y je Md im and coefficient of triton for each block is. A force F z 7 grr is applied on the frst block so as to move the system. The minimum value of F should be: (A) 8umg (C)7 umg @) 91mg (0)5 umg ‘Space for rough workSoTWor-1-PCM-Paper-211828.1)2 6 WA=2i+3]-K and 6 =-i+3] + 4k. then projection of A on 6 will be 3 A 3 Ve IZ 3 is © \e 3 @ of of 7. A block of mass 10 kg slides down on an incline § m long and 3 m high. A man pushes up on the ice the incline so that it sides down at constant speed The coefficient of fricton between the ice and the incline is 0.1. Find the work done by the man on the block (A) - 2604 (8) + 260 (C)- 2500 (0) + 250J & A particle starts from origin, accelerates for first ty sec and then decelerates at the same rate till 2to sec ‘along the positive x-direction. The graph representing variation of displacement (x) with time (\) is “ @ ° & ze * ° & =f @ ae wh omnes © Oo 4 2 We ele ae ‘Space for rough workSECTION — Paragraph Type This section contains 6 multi Paragraph. Each que plo choice questions relating to three paragraphs with two questions on four choices (A). (B). (C) and (0) out of which ONLY ONE is cor Paragraph for Questions 9 and 10 ‘A block of masé 13kg is kept at rest ata point P whose poston vector {= 21 4] + 2k (m meter) The block is displaced to the point @ whose position vecior j= B0i +100} - 200k (in mete, by applying a constant force F = 31 4]-12k (in Newton) — 312¥ 9. Find the work done by the force on the biock (in Joule) (A) 130 (C) 8788 (0) 3562 10. If power delivered 'P to the block by a force F is defined as P= Fv where Vis the velocity of the body, the power to the block by applied force F at t = 2s from the instant when force is applied is fa, ) eauaito (A) 13 watt (8) 39 watt (©) 20 watt 26 watt Paragraph for Questions 11 and 12 The figure shows 3 blocks of masses 1kg, 2 kg and 3kg lying on 2 horizontal surface, The coefficient of friction is zero between 1 kg block and the surface, 0.2 between 2 kg block and the surface 0.1 between 3 kg block and the surface A force of 10 N is applied on 3 kg block and a force of 5 N is applied on 1 kg block as shown in the (a) 7N (AN (C)5N 2N — Space for rough work y The tension in the string connecting 2 kg block and 1 kg biock is:SECTION 3: Mutt Correct Answers Type « ‘This section contains 6 mul Of vhich ONE OR MORE mls chelee questions, Each question has four choices (A. (8), (©) and (0) out @ 1” 20 ety u Two partes projected trom he tom he same point with same speed u at angles of projection a ang 9 stnke the horzontal ground at thé same part hy and hy'are the masimum nehis atamed By Me Projectiles, Fis the range for both andy and tare etme of highs, especialy. then ~aas8 4, @)R-alhn, SM. (©Latane Dincwamm ge ene a! Leta ad averted dng ecto the olonlapremay be cht Paro Gyacomance Novae dard a, 0 Bhacdanaco A swimmer swims ia flowing ver = vy of simmer we wale, ge weloty a er water Wirt ground, and %,5= velocity of swimmer w.rt. ground. The swimmer intends to reach at the ‘opposite bank ofthe river. Itis possible only when A Weg > Ver Vas Mar () a < Ver (0) none of the above ‘A horizontal force of magnitude F is applied to a body of weight mg resbng on a frictionless inclined Plane to prevent & from siding down. The plane makes an angle of $ withthe horizontal. Then the ‘oggal reaction acting on the body satisfies the condition 4 ‘ Nemgcos 6+F sing (@)N=mg cos ae Axt, mgicos 6 (O)N= (mays)? ©) §- or Ina car race, car A takes time {less than car B and passes the finishing point with a velocity of 12 mis ‘more than the velocity with which car B passes the finishing point. Assume that the cars A and start. {rom rest and travel with constant accelerations of 9 mvs? and 4 mvs? respectively, If vq and ve be the veloies of cars A and B, respectively, then ne WS tas, (A) t= 2 sec 3sec (oa ss (C) Va= 24 rs, ve= 12. mis Va= 36 mis, vg=24mvs v= . ih, “ Read and examine the folowing statements. Which of these isiare true? (ByThe total work done by the conservative, non-conservative and external forces on a system ‘equals to the change in kinetic eneray of the system (©) Work done by conservative forces equals to the change in potential energy of the system. The teal work done by the non-conservative and external forces on system equals to the change in mechanical energy ofthe system. (©) Work is done by the battery in glowing an electric bulb. a ¥ Yn Spaceforroughwork2012-SOTRZIAN As, eiaaaiy SECTION - 1 : Single Correct A BR eine sorccr 1gle Correct Answer Type of which ONLY ONE ie eatibl Cholee questions, Each question has four choles (A), (),(C) and (0) out 1 The frequency of first ine of Bammer = iment ocadan cose me oe Ave 19) wa (0) v4 teaction follows the equation: 2NaCI+ MnO, +3H,SO, + 2NaHSO, +MnSO, +Cl, +2H,0, What volume of chlorine can be produced from 1 9 of sodium chloride under standard conditions of Sy — 1 temperature and pressure? Len, t pee AMEE pecsenr gat ere ET > 2 ses SOFON we 3. AL-400 K, the root mean square speed of a gas X (molecular weight = 40) is equal to the most probable speed of @ gas Y at 60 K. The molecular weight of te gas 3 20 @) 16 he ato: (0) 32 "w= * 4.4 grams of SO; a8 diftuses from a container in 8 min. Mass of helium gas diffusing from the same container over the same time interval under simiar condition is (A) 05 gram ‘)1 gram (©) 2 gram (©) 16 9am ‘ground state of hydrogen atom is 13.6 eVat 5 The fonisation potential forthe electron i is ionisation potential for the elect 4 A 3eev xOy ev 6 Among LiCl, Beis, BCI, and CCL, the covalent character folows the order" (A) Uti < Becl,> BCL > Col By Uicl> Bec}, < BC, < CCU a T) WUici< Bec, < ach BeCl, > BCI,> CCl »» li Be BC: BE 7. _ The shapes of PCI,,PCI, and ASCH, ae respectively ayy * Clete (A) square planar, evabedral, see-saw (@) letanedcal see saw and pyramidal * sia ae CY +N Gerretrahedral, square planar and pentagonal bipyramidal uee@ (©) trigonal bipyramidal, tetrahedral ana square pyramisal C The solubilty (in water) order ofthe following MgCOs, CaCOs, B2CO,, SICOs is (A) MgCOs > CaCOs > BaCOs > SCO; (8), CaCO3 > MgCO; > BaCO; > SiCOs (C) SCO, > CaCO; > BaCO5 > MgCOs WBF MigCO > CaCO; > SrCO5 > BaCO;, ‘Space for rough work od31-84, C1-C2, SOTA24A1-T1, SOTWOT-PI-PCM-Paper-2(1828.116 Pi £12012 SOTR24A1-A8, N84, C1-C2, SOTW24A1 ‘SECTION - raph Type ‘This section contains 6 multiple choice questions relating to three paragraphs with two questions on each Paragraph. Each question has four choices (A). (B). (C) and (0) out of which ONLY ONE is correct. Paragraph for Questions 9 and 10 ‘1.Lof 1 MNaOH ig mixed with 1 L of 1 M NaHCOs in a vessel. This mixture is trated with 1 MHCI. In another experiment, 3 L of 1 M NaOH and VL of ! M NaHCO, are mized and tated with 1 M HCI 8 ‘The volumes of HCI required for the end points for the two mixtures using phenoiphthalein as indicator are (A) 2L and 3 @) 1Land25t (©) 1Land2u (©) 1Land 3. 10. The volumes of HCI required for the end points for the two mixtures using methyl orange as indicator (®) 2L and 3L re (A) 2Land 4. (0) 2Land2L (©) 1Land 4 Paragraph for Questions 11 and 12 The observed wavelengths in the line spectrum of hydrogen atom sample were first expressed in terms of 8 series by Jakob Balmer, a Swiss teacher Balmer’s empirical formula is Beet inc ces Ry = 109678 cm’ is the Rydberg’s constant Ndi Bohr derived this expression theoretically in 1913, The formula is generalzed to any one elecron atomfon. 1 Calculate the longest wavelength in A in the Balmer series of singly ionized helium He" (A) 26514 1641.14 (C) 6569 (0) 3249.4 142, Howmany lines in the spectrum will be observed when electrons return form 7" shell to 2% shell? as 14 @ ors 0) 16 Space for rough work ian aeOTWO'-P1-PCM-Paper: 112012-SOTR24A1 61-C2, SOTW24A1-AS, 81-84, C1-C2, SOTX24A1 Paragraph for Questions 13 and 14 Johannes van der Waals’ suggested @ somewhat corrected version of the ideal gas law. It is one of the ‘simpler equations of state for real gases and is referred to as van der Waals’ equation (Pe 2 }ev-nb) or ‘where ‘n' is number of moles of gas ant ‘a’ and 'b’ are van der Waals’ constant 13. Select the INCORRECT statement: (A) The value of ‘b’is given by (s abe iz ) where ‘is radius of gas molecule } ; Pv (B) Atlow pressure the van der Waals’ equation is reduced to BF = 1- pr where Vm is molar volume of gas Pb (C) Athigh pressure the van der Waals’ equation is reduced to ee “tae (0) Higher is the value of compressibility factor, more easily can the gas be liquefied ~~ 14. Which of the following gases will have highest value of van der Waals’ constant ‘a’? (A) NH3(9) (8) Ha(9) (C) He(g) (0) F2(g) re ‘Space for rough work corrected PrCSuUre av Bo ee Sh |{12013 SOTR2UAY-As, 04.04, 01.62, SOTW HAYA B84, C1. SDTABUAL TY, SOTWOLPLPCH PART-II: MATHEMATICS —;; SECTION - 1 : Single Correct Answor Type ‘This section contains 8 multiple choice questions. Each queston hes four chloes (A), (8), (C) and (©) out sich ONLY ONE'S corres nn anbons, ER 1 Ragretogot se senna gy meet. 3 amma er eet enath riser. anny Reze! aie Ds ere = a res Bites ato fone Begs a ‘ je of 45° with 2. The equation of the two Ines each passing through (6, 6) and each making n acute angle ne the fine 2x-y+1=0is, % 6 oF x JE pty wo n-aye 1900 8! (aaeeyeH eons aye! iz a (hy 2xy= 3x \ 5'= 1+ a0) 3x2 Yi 21=0,x-3y-19=0X =e ib 11 oo A variable chord of circle x? + y= 4 Is deawn trom te point P(3, 8) meeting the circle at the points A J" ‘and 8A pont Gis taken on tis chord such that 2PQ = PA+ PB locus of is poe x+y 36 (0) 69! 3x Sy 20 0 and + y 2) Sintersects m or anny f1E0 Pig tem = [em -ms ’ sin (a 43R) = 7) toot + p)*0, men singe + 2p) 8 equalto W)-sina got (a+ 8D eins Jeo, my =, +1 (Ocoee (0) cosp eee 2, then the value of fanA, tanB and tanc vis 4% nA bane teunl Ab Q) tenk + tam @ = (OEE Ts aR Ba {©)none the the Zhan At con® 56 saad genes? 7 WA=(4,3,5.7,9.11. 13,15, 17), “IER On ©) MENAUIALB)NBIIs (ALNING mean os Jupve orn I re -s8$)8 Y 62 (OY None of these 40° aes 12473 von res marten, d eT Poe Ge TE 4 RSS =e) 2] make (O)none of these Reena 24 ccaes) Specs forrough won 777 7777777? ys wa we BO 9) 1498) Bt 6 = 5e34e 90 = c005O BIE tt cee) Ser Te (its @) v0 ¢4.0123 300 ragrapn Type This secton contain 6 multiple chok eragraphs wih two questions on "multiple choice questions relating io tee paran a each _Baragraph. Each question has four choices (a) (8). (C) and (0) out of which ONLY ONE Ia correct Paragraph for Questions ro ‘SECTION -2 (Mere s0Tm24At-As, 81-84. 61.62, SOTW: 9 and 10 Read the following write up carefully: Consider a tiangle POR win acs. weal Lt coordinates ofits verces as P(-8 8), O¢ a {he interior angle of P has the equation which ean be writen nthe form ax + 2y + C= 0,"Nen 49) and R(1, 7) The bisector of Now answer the following question: 9% The distance between the onhocenire and the cicumcentre of the triangle POR is 25 29 we @F 7 8 oz oF 10. Thesuma+cis (a) 129 (878 (09 (0) none the these Paragraph for Questions 11 and 12 Read the following write up carefully: family of circles passing through the points (3, 7) and (6, 5) Conse Now answer te folowing question: 11, Icicle which belong the given family cuts the circle x? + y? = 29 orthogonally, then centre of that ces a7 (34) of 2. Number of circles which belong to the family and also touching x-axis are wo 1 (2 (0) infrte ‘Space for rough workire 4 F ' Q 4 Sipt C é > 172012-SOTR24A1-AS, B1-B4, C1-C2, SOTW24A1-AS_ B1-84°61.C2, SOTX2AA1-T1, SOTWOT-PT. graph for Questions 13 and 14 2 BeinfsweosOre Es inp & Read the following comprehension carefully: etin® ¢ IfsinA + sinB = 3 and cosA + cosB = 4, then ; A = Ss sin A + Sia BF CL 7 Now answer the following question: > 13. The value of sin(A + B) is sin (ATED CIMA @%4 we 2 Ces, 25 25 12 oes (OD) none the these 7 B wry e8 5 14. The value of tan(A + 8) is 25 As oa +7 25 5 2 PR +COSA)> = Sin?A ater po 4 2Hepcvs O Eo Space for rough work — {'-(2-»?- OO Oe PO Pe md peTRIESCIRAAS BBA C102 SOTW24AY-As. 01.94 C12 SOTELAALT, SOTHOLLPCHAPape 2108114 a SECTION ~3 : Multiple Correct Answer(s) Type ‘ection contain = ‘Ol wtich ONE OR MORE ts chee questions. Each question ha fur choices (A) (8). (0) an (Oot 1S APolnt P(V5.1) moves on the cic x» y? = 4 and ater covering a quarter ofthe ele leaves Mt * tangentially. The equation of tine a ice is ion ofa line along which the point moves after leaving the circle A) y= Vesa eyayaees (©) VBy=x-4 (0) y= V3x-4 16. The equation ofa tangent tothe circ x + y= 25 passing trough (-2. 11) is aD det 3y = 25 Ox ty = 38 (©) 2ax-7y + 12520 WDI7K + 2hy = 250 17, tthe chord y = mx + 1 of the circle x7 + y? = 1 sublends an angle of measure 45° at the major segment ofthe cce, then the value of m is ‘ @) WA? @1 “ © <8) none the these 18. Hone of the ines of my? + (1 ~ m’jxy = mx = 0 isa bisector of the angle between the lines Hy then mis wt @2 4) © +4 wwh-1 19. fa=——1___ then for alt real x Beotxs W2sinx 1 ©) Wirwiesscetvesade ciate 5 prtn aren agate vate ota 7 1 1 + o)-4 “Sa errs 20. Let (0) = an$(1+ sec0)(1+ se020)(1+ sec4n) (1+sec2"8). then 6) ah on(s) ex as ors %. ja 128 ‘Space for rough workFIITSE€E COMMON TEST IIT - JEE, 2014 PAPER | (PHASE -) ANSWERS (PHYSICS) (CHEMISTRY) (MATHEMATICS) 1 A 2 c 3. B 4 5. c 6. c 7 A 8. 9. c 10. c 11. AC 12. 13. B,c,D 14, Bc § B,C 16. 7 6 18 8 19. 2 20 Paper Code 1827.1FIITJEE COMMON TEST SOTR24A1-AS, B1-84, C1.C2, SDTW24A1-A5, 81-84, C1.C2, SDTX24A1-T1, SOTWOT IIT - JEE, 2014 1828.1 PAPER II (PHASE - |) ANSWERS PEE TPATTY 1 a 8 3. 8 4 A 6. e 8 7. c 8 c Ana wo a) 2 6 3D nae tia 15. ABC 1% GD 7 8c 18 ACD 9 AD 20. A,C,D Cheinistry PART 1 8 2 aC 4 8 BS arc 7 8B eA 9. oO 10. A "1 B 12. c 3D “OA 16 ABC 16 A.B,C,0 17 ABCD 18 BC 19 AD 20. ABD athena (PARTI 1. c 2. A 3. D 4 B 5 D 6. A 7. B 8. B 9 A 10. c 11. c 12, c ta A. 14. =D 15. BC 16 AC 17. B,C 18. AD 19 AB ~ 20. A,B,C,0