: 2017 ()07

:
03 : 00 :

( 13 )
7( : )

.
:
A . B :
A B C 3H 7COOH H 2O
n mol - . 1
- 2
A . B
- 3
1
- 25 C 4
n 0 A 1mol t 0
n 0 B 1mol :
. V 132 mL
- .
0,2 2 -
( )2( )1
t min
0 300
A . B
.

. t 0
. t 1/ 2
:
S A A AH C A . V 0
C A V A 20 mL S A S B
Na , HO . C B 2 102 mol / L
- 1 .
- 2 C A . V BE 10mL
- 3 pH S A 25C . pH 3, 4
. AH / A

1 3
 6 ( : )

.
O :
i
S O t=0 S m 0, 2 kg
30 ( . ) 1-

f .

O ,i .
1-
- 1 :
f
m / s . a g .sin
m
- 2
( t . ) 2-
2-
. a

- 3 f . g 10 m / s 2 :
- 4 x t .
:
S
k ( +
) (. )3-
0,6
0, 6
. O ,i
t s
0 , 25
0 0,25 . t 0 .
- 1 10 . t 8, 9 s
- T 0 .
- . k
S 1 G
- F
T0
.t
o 2
3- i - 2 4- E C
E Pe ET .
-
E mJ
.
ET - x 2 x 1

EC EC 3E Pe . x 1 x 2 :

- w F


E Pe x 1
2
. x 2
x m
0 , 01

2 3
 ( 7 )
:
L , r . C

R

L , r .
:
1 - :
. E 6V
K 1-
. L , r
. R 16
. K
E
t 0 . K
u V - 1
di
2 B A Ai ( t ) B :
dt
.
- 2
u R t ( .)2-
.
2- .
1 1
- 3 I 0 :
t ms . I 0 0, 25 A
0 1010 - 4 . r
- 5 . L
C L , r
:
L , r C
(. ) 3-
K 3- 4 -
uC t .
- 1 :
uC V T 4 40 ms ,T 3 4 ms ,T 2 20 ms ,T1 2 ms
- 2 C
.
- 3 E t 0 0
. t1 8 ms .
2 - 4 .
.
t ms
0 2

3 3


: 7( :)
-1 : :
)AH (aq) + OH- (aq) == A- (aq) + H2O ( -1 : .
-2 :CA -2 :
CA .VA = CB.VBE : C3H7 COOH :A
= CA
.
=

CA = 10-2mol/L CH3 OH :B
-3 - : - - ( ) .
-3 :Ka -4 - :

] [ ] [ + )(. ) A () + B () == C3H7-COO-CH3 () + H2O (
= Ka = Ka = .
][ )x(mol
Ka = 1.64 10-5 )n(mol
6( :) 0 )n0 (A )n0(B 0 0
)(S :

-1 a = g sin - : x n0 (A) -x n0(B) x x x


- : ).(S
- : xf n0 (A) -xf n0(B) xf xf xf
X
) . (o ,
,
,
- ):(S n0(A) = n0(B) = 1mol
ext = m. + + = m.
- : .
)Px f = m.a P sin f = m.a :(OX =r = . 100 .100 =r .100 = 67 % :


=a a = g sin -

-2 a : -1 :
. -2 - : - .
=a = =. = 2.4
a = 2.4 m/s -3 .

-3 : f : t =0

f = m g sin ma f = m( g sin- a )= 0.2 ( - 2.4 ) f = 0.52 N .

-4 ): x(t = vvol = . (. )


x(t) = a t + v0t + x0 : vvol = 1.34 10-2 mol/L.min


- t = 0 x0 = 0 v0 = 0 : x(t) = at : xf = 0.67 mol = 0.33 mol : t

x(t) = 1 ,2 t
( )1 t = 210 min :
 :

(R+ r ) i + L = E + :
)(+
= )i(t -1 - :T0
.
=B

= A
+ = T0 = T0= 0.89s

-2 ..
T0 = 2 =K = :K
: .
R )(L ,r K =9.95 N/m

=: t -

- : .

= t - : t = 0 ) . (Xm

K .

= t .

- Xm = ? :
F = K . Xm
) UR (t ( )2UR (t) = R .i- (t) :+ ET = K


= Cte -2 - :
t = 0 i = 0 UR (0) = 0
-3 I0 = 0.25 A : UR = R.I0 : - ).(OX

EPe = .K .X
(UR =R.I0 = 4 V I0 = = = 0.25 A : )2
E = =
-4 :r { { :
= =
E = UR + U0 :
0 EC = ET Epe EC = K - K X
E = R.I0 + r.I0 + 0 .
= =
= E = (R + r) I0 r
.
=

r=8 { { :
= =
.
-5 :L - X1 X2 EC = 3 EPe :

ET = EC + EPe ET = 3 EPe + EPe = 4 EPe EPe = = 2 mJ :
= ) L = .(R +r
+ = .
=L 1010-3 = 10 ms : (16 + 8 ) L = 0.24 H : { :
= .
: (: W - )
-1 T0 = T4 = 4 ms : ( ) = F.X1X2 = K
(W ) . ( ) = K(X1X2)

= T0 = 2 . C -2 :C C = 1.69 10-6 = 1.69 F : (W) = 9.95 0.02 (W ) = 3.98 10-3 = 3.98 mJ

7( :)
:

+ A i(t) = B
-1 :

E = UR + Ub E = R.i + r.i +L. :