: 2017

03 : :

06( : )

ABC AB =30
BC R = 5cm
t =0 ( )S m = 100 g A
V0 ( )S
) (O ,x .AB
V2 x ( )2-
-I : AB ( )S .
-1 (.)S
-2 .a
.AB -3
-4 .B

-II : BC
( )S

2- ( )S B VB BC
C .VC=10m/s
BC ( )S C -1

-III C ( )S VC ()S
C .P
P (.)S ) ( xP , y P -1
g = 10 N/Kg : P . VP -2

1 4
 - IV S - ) (R
. k
( )S x0 . t=0
.

-1- )(S1
- T0 .
-2 :
- ).(S
- .
- k .x0
06( : (
- ( )1-
UR UL K E= 6 V . R 50 t =0 s

( . )2-
uR
. E r R uL uR -1
uL

( .)2- r -2
-3 ) i(t . u R
R
u R (t ) E. . -4 ) (1 e t
Rr

-5 ) . u L ( t
. L -6
K - 7

2- 1-
 2 4
08 ( : )

.
-I S V=200mL C=5.10-2mol/L
=37,2s.m-1 :
-1 .
-2 f .
-3 KA CH3COOH/CH3COO- ] [H3O+ C
. KA=1,84.10-5
-4 ( ) CH3COOH /CH3COO- .S 2
-5 ) .(Na++OH-
VA=20mL . CH3COOH VB
.CB=2.10-2mol/L -pH pH
VBE=49mL
-1-5 .
-2-5 .
3-5 .
-4-5 VB=VB.E/2 ][CH3COOH ]/[ CH3COO-
pH
-II

B R-OH . A
-1 B A
.
-2 .
 3 4

-3 n(A)= 1mol n(B)= 1mol

R-OH

t=0 C

). (Na++OH-

( nester=f(t) : ) 1-
-3-1
-3-2 . .
-3-3
-4-3
-4
-4-1
-4-2
V=VA+VB
V nester .t
-4-3 t=30min
-4-4 .
1 -4-5
(H3O+)=35mS.mmol-1 : (CH3COO-)=4,1mS.mmol-1Ke(H2O /OH-)=10-14

; M(CH3COOH)=60g/mol (B)=0,903g/mL ; (A)=1,05g/mL

M(B)=156g/mo

4 4