: 2017 ()8

:
03 : 00 :

( 13 )
) 7( :
C m C 6 H 8O6
. .
( / ) . C 6 H 6O6 / C 6 H 8O6 , I 2 / I , S 4O62 / S 2O32 :
( / ) . C 6 H 8O6 / C 6 H 7O6 , H 2O / HO :
: 33

I 2
V 1 10 mL . V 2 20 mL . C 2 3, 5 102 mol / L

2Na ,S 2O32 C 3 2, 5 102 mol / L V E 20 mL
.
- 1 .
- 2 .
- 3 .
- 4 .
- 5 .
- 6 C m . .

pK a C 2 H 5COOH / C 2 H 5COO 4, 9 , C 12 ,H 1O 16 g / mol
:
pH pH
V 0

V a 20 mL

K ,OH
C B 5 102 mol / L
) . pH f (V B
- 1 .
1 - 2
.
0 1 )Vb(mL
. C 6 H 8O6 / C 6H 7O6 - 3 pK a

1 3
 - 4 C m .
- 5 .
- 6 .
- 7 . C 2 H 5COOH
- 8
: . 3,1 4, 4
: . 8, 2 10
: . 6 7 , 6

6 ( : )

C 11011 F
R E 500 V
( K 1
K 2 )
.
( )2- t 0 0 ( K 2 K 1
6
K 1 ( uC K 2 t 0 0 ) t 1 E
10
) . t . t t1 t 0 :

G K2
K1 G E

R
R

1-
2-

uC V
2760Co
1-
. 3-
- 1 .
- 2 .
- 3 2760Co

. 25 Mn , 28 Ni , 26 Fe :
- 4
100
100 3- .
- 5
0 0 ,1
0,1 t m s :
t

. uC t E .e

2 4
 - . t t1 t 0 6
t
- 7
E
ln
u C t 1
- . R 8
- 9
% 8 .

( 7 )
:
m . S
:
S .
) ( f ( t ) 4- . t
f k . : : g 10 m / s 2 ,K 3, 57 Kg / s :
- 1
m / s
- 2 .
- 3 :
- .
- lim
- . t 0
- t 8s
22,8
,8 - 4 :
d K
g
0 1 4- t s dt m
- 5 . m

Oi :
( + S )
x
)(S 5- :
. K
5-
G ) (S G m .
m t 0
X 0 . x
(. )6
- 1 . X 0
- 2 .

3 4
 )x(cm - 3 : T 0
X 0 . 0
- 4 .
- 5 m .
2 2 10 :
)t(s

0 0,1

-
63-

4 4

:
.I
)1 :
6 8 O6 = 6 6 O6 + 2 + + 2e :
I2 + 2e = 2 :
6 8 O6 + I2 = 6 6 O6 + 2 + 2+
)2 :
6 8 O6 + I2 = 6 6 O6 + 2 + 2+
1 1 2 2 0 0
1 1 2 2 2
1 1 2 2 2
)3 : - : .
- I2 .
)4 :
2 2 O3 = 4 O6 + 2e :

I2 + 2e = 2 :

2 2 O3 + I2 = 4 O6 + 2
1
n( )= 2 3 3 )5 :
2
2.5102 20103
=) (n = 0.25 mol 2
2
)6
mol2 2 = n(I2 ) = 22 n(I2 ) = 3.510220103 0.25 103 = .
n (I2 ) 0 : n (6 8 O6 ) = 0:
0.45103
= 1 1 = 0 1 = = 0.045
1 0.1
= 1 = 1760.045 = . :
: .II

)1 6 8 O6 + = 6 7 O6 +
= )2
( = 9 P =8.2) )3

= =P P : =. : =4.5ml
2

5102 9
= = = 2.25102 )4 = :
20
1
= 22.25102 = 4.5102 = = . 1

= 1 = 7.92 :

)5 AH:

)=3P (, 6 8 O6 + = 6 7 O6 +

P 3 ][
10 10
= = = = 0.02 < 1 =
1 4.5102 1

[6 8 O6 ] = 1 [] = 4.5102 103 = 4.4102 0
.. )6

(
6 8 O6 /6 7 O6 ) < (3 6 O2 /3 5 O2 ) )7

)8 : .
:
= 27
{ )1
= = 60 27 = 33
)2 : .
60 0
27 = + 1e )3 :
:
60 = + 0 = 60
{
27 = 1 = 28
60
28 :
60 60 0
27 = 28 + 1e
)4 :

)5
+ = 0 : :
+ = 0

+ =0

1
+ = 0



= Ee = e :

:
1
( = ) e + Ee = 0

)6 = 0,1 :

= )7
( )
) (1
 1
(1 ) = Ee

1
) (1 1
= =
E ( )
) (1
= 1 0 1 = + 0
0 = 0 = 1

= :
( )
) (1
)8 R
0,1103
= = = = =, +
(
) (1
) (
) (1
) ( )
300
)9
: 1 :
1
= =+ 1

:
8 100 + 100
=, + { 1 A= 1 =
100 8 8
:
:
)o, , .1 (
.
.2 :
=m
.3
= 1,4
= 14 -
- 0 ( 0 ) = 0
14 0
= 0 = = 10 2
1,4 0
= = 14 = 0 2 : - = 8:
.4 :
)o, (
=m
= +
:

P-f=ma=m mg K = m m:

K
+ =g
m

= = : .5 = 0:

3.57
= = = = 1,4
10
:
.1 :

.2 0 +0
0 = 0,2 .3
0 = 6
t x(0) = 0 : 0
) X(0) =0 cos(0 +
cos = 1 = 0
) X(t) =0 cos(0 + .4
) X(t) =0 cos(0
)X(t) =6. 10 cos(10

0 = 2:

2
0
=
4 2