DEUTSCHE NORM September 1998 Extenders for paints - Specifications and methods of test DIN Part 6: Precipitated calcium carbonate (ISO 3262-6 : 1998) English version of DIN EN ted 3262-6 y EN ISO 3262-6 Ics 87,060.10 This standard, together with DIN EN ISO 3262-4 and DINEN ISO 3262~ September 1998 editions, supersedes DIN 55918, September 1984 edition Descriptors: Paints, extenders, precipitated calcium carbonate, Fillstoffe fir Beschichtungsstoffe ~ Anforderungen und Prafverfahren - Teil 6: Gefalltes Calciumcarbonat (180 3262-6 : 1998) European Standard EN ISO 3262-6 : 1998 has the status of a DIN Standard. ‘A comma is used as the decimal marker. National foreword ‘This standard has been published in accordance with a decision taken by CEN/TC 298 to adopt, without alteration, International Standard ISO 3262-6 as a European Standard. ‘The responsible German body involved in its preparation was the NormenausschuB Pigmente und Fullstoffe (Pigments and Extenders Standards Committee), Technical Committee Priftverfahren und Kennwerte far Falistoffe. ‘The DIN Standards corresponding to the International Standards referrad to in clause 2 of the ENare as. follows: ISO Standard DIN Standard(s) 1s0 787-2 DINENISO 787-2 1$0 787-3 DINENISO 787-3 1SO787-8 DINENISO 787-8 180 787-9 DINENISO 787-9 180 787-14 DINISO 787-14 ISO 787-18 DINENISO 787-18 Iso 842 DIN V 3242-1 and DIN 53242-4 180 3262-1 DIN EN1SO3262-1 1s03698 —_—DINISO. 3696 Amendments DIN 55918, September 1984 edition, has been superseded by the specifications of EN ISO 3262-6. Previous editions DIN 1280: 1942x-10; DIN 55918: 1973-10, 1984-09. Continued overleat. EN comprises 6 pages. eS Se Hat No. DINEN TSO 3260-6 1006-09 Ne TT a acct tr Om St RA Ero een ois 07 Set, 07Page 2 DIN EN ISO 3262-6 : 1998-09 Standards referred to (and not included in Normative references and Annex ZA) DIN V 83242-1 DIN 59242-4 DIN EN ISO 787-2 DIN EN ISO 787-3, DIN EN ISO 787-8 DIN EN ISO 787-9 DIN ENISO 787-18, DIN EN ISO 3262-1 ‘Sampling of raw materials for paints and varnishes - Concepts and general information Raw materials for paints and varnishes ~ Sampling of solid matter General method of test for pigments and extenders ~ Part 2: Determination of matter volatile at 105 °C (ISO 787-2: 1981) General method of test for pigments and extenders ~ Part 3: Determination of matter soluble in water - Hot extraction method (ISO 787-3 : 1979) General methods of test for pigments and extenders ~ Part 8: Determination of matter soluble in water - Cold extraction method (ISO 787-8: 1979) General method of test for pigments and extenders ~ Part of an aqueous suspension (ISO 787-9 : 1981) General methods of test for pigments and extenders - Part 18: Determination of oversize using a mechanical flushing procedure (ISO 787-18 : 1983) Extenders for paints ~ Specifications and methods of test - Part 1: Introduction and general test methods (ISO 3262-1 : 1997) Jetermination of pH valueEUROPEAN STANDARD EN ISO 3262-6 NORME EVUROPEENNE EUROPAISCHE NORM July 1998 ICs 87,060.10 Descriptors: Paints, extenders, precipitated calcium carbonate, testing, English version Extenders for paints — Specifications and methods of test Part 6: Precipitated calcium carbonate (ISO 3262-6 : 1998) Matiares de charge pour peintures ~ _Filllstoffe flir Beschichtungsstoffe — Spécifications et méthodes d'essai~ _Anforderungen und Priifverfahren — Partie 6: Carbonate de calcium Teil 6: Gefilltes Calclumcarbonat précipite (ISO 3262-6 : 1998) (ISO 3262-6 : 1998) This European Standard was approved by CEN on 1998-06-21. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national stand- ards may be obtained on application to the Central Secretariat or to any CEN member. The European Standards exist in three official versions (English, French, German). Aversion in any other language made by translation under the responsibility of a ‘CEN member into its own language and notified to the Central Secretariat has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, the Czech Republic, Denmark, Finland, France, Germany, Greece, Iceland, Ireland, Italy, Luxembourg, the Netherlands, Norway, Portugal, Spain, Sweden, Switzerland, and the United Kingdom, CEN European Committee for Standardization Comité Européen de Normalisation Europaisches Komitee fiir Normung Central Secretari : rue de Stassart 36, B-1050 Brussels © 1998, CEN ~ All rights of exploitation in any form and by any means Rot. No, EN ISO 3262-6: 1998 E reserved worldwide for CEN national members,Page 2 EN ISO 9262-6 : 1998 Foreword International Standard 180 3262-6 : 1998 Extenders for paints ~ Sp. carbonate, which was prepared by ISO/TC 35 ‘Paints and varnishes’ of the International Organization for Standardization, has been adopted by Technical Committee CEN/TC 298 ‘Pigments and extenders’ as a European Standard. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, and conflicting national standards withdrawn, by January 1999 at the latest. In accordance with the CEN/CENELEC Internal Regulations, the national standards organizations of the follow- ing countries are bound to implement this European Standard: Austria, Belgium, the Czech Republic, Denmark, Finland, France, Germany, Greece, Iceland, Ireland, Italy, Luxembourg, the Netherlands, Norway, Portugal, Spain, Sweden, Switzerland, and the United Kingdom. ications and methods of test ~ Part 6: Precipitated calcium Endorsement notice ‘The text of the International Standard ISO 3262-6 : 1998 was approved by CEN as a European Standard without any modification. NOTE: Normative references to international publications are listed in Annex ZA (normative)Page 3 EN ISO 8262-6: 1998 1 Scope This part of ISO 3262 specifies requirements and corresponding methods of test for precipitated calcium carbonate. 2 Normative references ‘The following standards contain provisions which, through reference in this text, constitute provisions of this part of ISO 8262, At the time of publication, the editions indicated were valid. All standards are subject to revision, and parties to agreements based on this part of ISO 3262 are encouraged to investigate the possibilty of applying the most recent ‘editions of the standards indicated below. Members of IEC and ISO maintain registers of currently valid International Standards. ISO 787-2:1981, General methods of test for pigments and extenders — Part 2: Determination of matter volatile at 105°C. ISO 787-3:1979, General methods of test for pigments and extenders — Part 3: Determination of matter soluble in water — Hot extraction method. ISO 787-8:1979, General methods of test for pigments and extenders — Part 8: Determination of matter soluble in water — Cold extraction method. ISO 787-9:1981, General methods of test for pigments and extenders — Part 9: Determination of pH value of an aqueous suspension. ISO 787-14:1973, General methods of test for pigments — Part 14: Determination of resistivity of aqueous extract. ISO 787-18:1983, General methods of test for pigments and extenders — Part 18: Determination of residue on sieve — Mechanical flushing procedure. ISO 842:1984, Raw materials for paints and vamishes — Sampling. ISO 3262-1:1997, Extenders for paints — Specifications and methods of test — Part 1: Introduction and general test methods. ISO 3696:1987, Water for analytical laboratory use — Specification and test methods. 3 Definition For the purposes of this part of ISO 3262, the following definition applies: 3.1 precipitated calcium carbonate: A synthetic calcium carbonate, consisting of trigonal crystals (like those of calcite) or thombic bipyramidal crystals (lke those of aragonite).Page 4 EN ISO 3262-6 : 1998 4 Requirements and test methods For precipitated calcium carbonate complying with this part of ISO 3262, the essential requirements are specified in table 1 and the conditional requirements are listed in table 2. Table 1 — Essential requirements Characteristic Unit Requirement Test method CaCO, content, min. % (mi) 98 180 3262-1 Residue on 45 um sieve, max. % (mir) on ISO 787-18 Matter volatile at 105 °C, max. % (m/e) 1,0 Iso 787-2 Loss on ignition, max. % (reve) a Iso 3262-1 Matter soluble in water, max. % (rv) 02 1SO 787-3 or ISO 787-8” pH value of aqueous suspension 9t010” 1S0 787-9 Matter insoluble in hydrochloric acid, max. | _% (m/m) 02 See clause 6 1) These values do not take account of the effect on the result of any surface treatment. 2) Method to be agreed between the interested parties. Table 2 — Conditional requirements Characteristic Unit Requirement Test method Particle size distribution (instrumental % (m/m) To be agreed between the interested parties” method) Colour 'S0 3262-1 Lightness Tobe agreed between | To be agreed between the interested parties _| the interested parties” Resistivity of aqueous extract am 180 787-14 41) A general description of a sedimentation method using X-ray absorption is given in EN 725-5:1996, Advanced technical ceramics — Methods of test for ceramic powders — Part5: Determination of the particle size distribution. 2) Test method in preparation. 5 Sampling ‘Take a representative sample of the product to be tested, as described in ISO 842. 6 Determination of matter insoluble in hydrochloric acid 6.1 Reagents During the analysis, use only reagents of recognized analytical grade and only water of at least grade 3 purity as defined in ISO 3696.Page 5 EN ISO 3262-6 : 1998 6.1.1 Hydrochloric acid, approximately 25 % (m/m), p= 1,125 g/m 6.2 Apparatus Use ordinary laboratory apparatus and glassware, together with the following: 6.2.1 Membrane filter, pore size 0.8 um. 6.2.2 Air oven, capable of being maintained at (105 + 2) °C. 6.3 Procedure Weigh, to the nearest 0,1 mg, approximately 10 g (7) of the test sample into a 600 mi beaker. Add 50 mi of water and, carefully, approximately 50 ml of hydrochloric acid (6.1.1). Cover the beaker with a watch glass and boil the solution for 15 min, Dry the membrane filter (6.2.1) in the air oven (6.2.2) at (105 + 2) °C to constant mass, cool in a desiccator to room temperature and weigh it to the nearest 0,1 mg (m,). Then filter the solution through it. Wash the residue on the fiter eight times with hot distilled water. Dry the residue on the filter in the air oven at (105 * 2) °C for about 1 h. Allow to cool in a desiccator to room temperature and weigh to the nearest 0,1 mg (m,). 6.4 Expression of results Calculate the matter insoluble in hydrochloric acid w(Ml,..), expressed as a percentage by mass, using the equation w(Minc) = 72— x 100 mo where im, is the mass, in grams, of the test portion; ‘m, is the mass, in grams, of the dried membrane filter; ‘m, is the mass, in grams, of the dried membrane filter plus the residue. 7 Test report The test report shall contain at least the following information: a) all details necessary to identity the product teste 'b) a reference to this part of ISO 3262 (ISO 3262-6); ©) the results of the tests and whether or not the product complies with the relevant specification limits; 4d) any deviation from the test methods specifi €) the dates of the tests.Page 6 EN ISO 3262-6 : 1998 Annex ZA (normative) Normative references to international publications with their relevant European publications This European Standard incorporates by dated or undated reference, provisions from other publications. These normative references are cited at the appropriate places in the text and the publications are listed hereafter. For dated references, subsequent amendments to or revisions of any of these publications apply to this European Standard only when incorporated in it by amendment or revision. For undated references the latest edition of the publication referred to applies. Publication Year Title EN Year ISO 787-2 1981 General methods of test for pigments and EN ISO 787-2 1995 extenders - Part 2: Determination of matter volatile at 105 degrees C ISO 787-3 1979 General methods of test for pigments and EN ISO 787-3 1995 extenders - Part 3: Determination of matter soluble in water - Hot extraction method ISO 787-8 1979 General methods of test for pigments and EN ISO 787-8 1995 extenders - Part 8: Determination of matter soluble in water - Cold extraction ISO 787-9 1981 General methods of test for pigments and EN ISO 787-9 1995, extenders - Part 9: Determination of pH value of aqueous suspension ISO 787-18 1983 General methods of test for pigments and EN ISO 787-18 1995 extenders - Part 18: Dete ion of residue ‘on sieve - Mechanical flushing procedure ISO 3262-1 1997 Extenders for paints - Specifications and EN ISO 3262-1 1998 methods of test - Part 1: Introduction and general test methods 180 3696 1987 Water for analytical laboratory use EN ISO 3696 1995 - Specification and test methods