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PAPER - 1 : PHYSICS, CHEMISTRY & MATHEMATICS Test Booklet Code
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 PART A PHYSICS A
1. The current voltage relation of diode is 1. U U U- U
given by I5(e1000V/T21) mA, where the I5(e1000V/T21) mA , V
applied voltage V is in volts and the U U U T U
temperature T is in degree Kelvin. If a l 300 K U 5 mA U
student makes an error measuring 60.01 V U U ,
60.01 V while measuring the current of U mA U ?
5 mA at 300 K, what will be the error in
the value of current in mA ?

(1) 0.2 mA (1) 0.2 mA

(2) 0.02 mA (2) 0.02 mA

(3) 0.5 mA (3) 0.5 mA

(4) 0.05 mA (4) 0.05 mA

2. From a tower of height H, a particle is 2. H U , u

thrown vertically upwards with a U U U
speed u. The time taken by the particle, to U
hit the ground, is n times that taken by it n
to reach the highest point of its path.

The relation between H, u and n is : H, u n

(1) 2 g H5n2u2 (1) 2 g H5n2u2

(2) g H5(n22)2u2 (2) g H5(n22)2u2

(3) 2 g H5nu2(n22) (3) 2 g H5nu2(n22)

(4) g H5(n22)u2 (4) g H5(n22)u2

E/Page 2 SPACE FOR ROUGH WORK / U

3. A mass m is supported by a massless 3. R m
string wound around a uniform hollow U U UU
cylinder of mass m and radius R. If the m UU U
string does not slip on the cylinder, with , U U
what acceleration will the mass fall on U U?
release ?

2g 2g
(1) (1)
3 3
g g
(2) (2)
2 2
5g 5g
(3) (3)
6 6
(4) g (4) g

4. A block of mass m is placed on a surface 4. cU U m U

with a vertical cross section given by x3
cU U S U y5
x3 6
y5 . If the coefficient of friction is 0.5, 0.5 , U U
6
the maximum height above the ground at , U U
which the block can be placed without ,
slipping is :
1 1
(1) m (1) m
6 6
2 2
(2) m (2) m
3 3
1 1
(3) m (3) m
3 3
1 1
(4) m (4) m
2 2

E/Page 3 SPACE FOR ROUGH WORK / U

5. When a rubber-band is stretched by a 5. U U x U
distance x, it exerts a restoring force of ; U F5ax1bx2
magnitude F5ax1bx2 where a and b are a b SU
constants. The work done in stretching U U L U
the unstretched rubber-band by L is :

(1) aL21bL3 (1) aL21bL3

1 1
(2) (aL21bL3) (2) (aL21bL3)
2 2

aL2 bL3 aL2 bL3

(3) 1 (3) 1
2 3 2 3

1 aL2 bL3 1 aL2 bL3

(4) 1 (4) 1
2 2 3 2 2 3

6. A bob of mass m attached to an 6. l U m

inextensible string of length l is suspended U U U
from a vertical support. The bob rotates U U v rad/s
in a horizontal circle with an angular U
speed v rad/s about the vertical. About U
the point of suspension :

(1) angular momentum is conserved. (1) U U

(2) angular momentum changes in (2) U U U

magnitude but not in direction.

(3) angular momentum changes in (3) U U

direction but not in magnitude. U

(4) angular momentum changes both in (4)

direction and magnitude. UU

E/Page 4 SPACE FOR ROUGH WORK / U

7. Four particles, each of mass M and 7. M U U
equidistant from each other, move along U U , U L
a circle of radius R under the action of their R U
mutual gravitational attraction. The speed
of each particle is :

GM GM
(1) (1)
R R

GM GM
(2) 2 2 (2) 2 2
R R

GM GM
(3)
R
(1 1 2 2 ) (3)
R
(1 1 2 2 )

1 GM 1 GM
(4)
2 R
(1 1 2 2 ) (4)
2 R
(1 1 2 2 )

8. The pressure that has to be applied to the 8. 10 cm SU U U U

ends of a steel wire of length 10 cm to keep h 1008C
its length constant when its temperature SU U U U
is raised by 1008C is :

(For steel Youngs modulus is (SU S 231011 N m22

231011 N m22 and coefficient of thermal U U U 1.131025 K21 )
expansion is 1.131025 K21)

(1) 2.23108 Pa (1) 2.23108 S

(2) 2.23109 Pa (2) 2.23109 S

(3) 2.23107 Pa (3) 2.23107 S

(4) 2.23106 Pa (4) 2.23106 S

E/Page 5 SPACE FOR ROUGH WORK / U

9. There is a circular tube in a vertical plane. 9. U U ,
Two liquids which do not mix and of U d1
densities d1 and d2 are filled in the tube. d2 , U U
Each liquid subtends 908 angle at centre. 908 U U cU
Radius joining their interface makes U a
d1 d1
an angle a with vertical. Ratio d is : d2
2

1 1 sin a 1 1 sin a
(1) (1)
1 2 sin a 1 2 sin a

1 1 cosa 1 1 cosa
(2) (2)
1 2 cosa 1 2 cosa

1 1 tan a 1 1 tan a
(3) (3)
1 2 tan a 1 2 tan a

1 1 sin a 1 1 sin a
(4) (4)
1 2 cosa 1 2 cosa

E/Page 6 SPACE FOR ROUGH WORK / U

10. On heating water, bubbles being formed 10. U U,
at the bottom of the vessel detatch and rise. U U U U U
Take the bubbles to be spheres of radius R R U
and making a circular contact of radius r S r r << R
with the bottom of the vessel. If r << R, U cU T ,
and the surface tension of water is T, value U r
of r just before bubbles detatch is :

(density of water is r )
w
( rw )

rw g rw g
(1) R2 (1) R2
3T 3T

rw g rw g
(2) R2 (2) R2
6T 6T

rw g rw g
(3) R2 (3) R2
T T

3rw g 3rw g
(4) R2 (4) R2
T T

E/Page 7 SPACE FOR ROUGH WORK / U

11. Three rods of Copper, Brass and Steel are 11. , SU U Y - U
welded together to form a Y - shaped U U U
structure. Area of cross - section of each S U 54 cm2 U
rod54 cm 2 . End of copper rod is U 1008C
maintained at 1008C where as ends of SU U 08C U U ,
brass and steel are kept at 08C. Lengths of SU U
the copper, brass and steel rods are 46, 13 46, 13 12 cms U , U
and 12 cms respectively. The rods are UU, U c U
thermally insulated from surroundings , SU c
except at ends. Thermal conductivities of 0.92, 0.26 0.12 CGS U
copper, brass and steel are 0.92, 0.26 and c U
0.12 CGS units respectively. Rate of heat
flow through copper rod is :
(1) 1.2 cal/s (1) 1.2 cal/s
(2) 2.4 cal/s (2) 2.4 cal/s
(3) 4.8 cal/s (3) 4.8 cal/s
(4) 6.0 cal/s (4) 6.0 cal/s
12. One mole of diatomic ideal gas undergoes 12. mU
a cyclic process ABC as shown in figure. ABC U
The process BC is adiabatic. The BC Lhc A, B C
temperatures at A, B and C are 400 K, 400 K, 800 K 600 K
800 K and 600 K respectively. Choose the
correct statement :

(1) The change in internal energy in (1) U

whole cyclic process is 250 R. U 250 R
(2) The change in internal energy in the (2) CA U U
process CA is 700 R. 700 R
(3) The change in internal energy in the (3) AB U U
process AB is 2350 R. 2350 R
(4) The change in internal energy in the (4) BC U U
process BC is 2500 R. 2500 R

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13. An open glass tube is immersed in mercury 13. U U U
in such a way that a length of 8 cm extends U SU 8 cm U
above the mercury level. The open end of U U
the tube is then closed and sealed and the U U U U
tube is raised vertically up by additional 46 cm U U U U
46 cm. What will be length of the air S ?
column above mercury in the tube now ?
(Atmospheric pressure 576 cm of Hg) (U 5Hg 76 cm)
(1) 16 cm (1) 16 cm
(2) 22 cm (2) 22 cm
(3) 38 cm (3) 38 cm
(4) 6 cm (4) 6 cm

14. A particle moves with simple harmonic 14. U U U

motion in a straight line. In first t s, after US U U
starting from rest it travels a distance a, t U U a U t U U 2a
and in next t s it travels 2a, in same U
direction, then :
(1) amplitude of motion is 3a (1) 3a
(2) time period of oscillations is 8t (2) 8t
(3) amplitude of motion is 4a (3) 4a
(4) time period of oscillations is 6t (4) 6t

15. A pipe of length 85 cm is closed from one 15. 85 cm U

end. Find the number of possible natural U S
oscillations of air column in the pipe whose
frequencies lie below 1250 Hz. The 1250 Hz
velocity of sound in air is 340 m/s. 340 m/s
(1) 12 (1) 12
(2) 8 (2) 8
(3) 6 (3) 6
(4) 4 (4) 4

E/Page 9 SPACE FOR ROUGH WORK / U


16. Assume that an electric field E 5 30 x 2 i 16. l E 5 30 x 2 i
exists in space. Then the potential U VA2VO, VO U
difference V A 2V O , where V O is the VA, x52 m U ,
potential at the origin and VA the potential
at x52 m is :
(1) 120 J (1) 120 J
(2) 2120 J (2) 2120 J
(3) 280 J (3) 280 J
(4) 80 J (4) 80 J

17. A parallel plate capacitor is made of two 17. U, U 5 mm ,

circular plates separated by a distance of U ^ U
5 mm and with a dielectric of dielectric Ul SU 2.2 Ul U
constant 2.2 between them. When the Ul l 33104 V/m ,
electric field in the dielectric is 33104 V/m, U
the charge density of the positive plate will
be close to :
(1) 631027 C/m2 (1) 631027 C/m2
(2) 331027 C/m2 (2) 331027 C/m2
(3) 33104 C/m2 (3) 33104 C/m2
(4) 63104 C/m2 (4) 63104 C/m2

18. In a large building, there are 15 bulbs of 18. , 40 W 15 , 100 W

40 W, 5 bulbs of 100 W, 5 fans of 80 W 5 , 80 W 5 1 kW 1 UU
and 1 heater of 1 kW. The voltage of the U 220 V
electric mains is 220 V. The minimum $
capacity of the main fuse of the building
will be :
(1) 8A (1) 8A
(2) 10 A (2) 10 A
(3) 12 A (3) 12 A
(4) 14 A (4) 14 A

E/Page 10 SPACE FOR ROUGH WORK / U

19. A conductor lies along the z-axis 19. z- 21.5 [ z < 1.5 m
at 21.5 [ z < 1.5 m and carries
U U U 2 az SU U

a fixed current of 10.0 A in 2 a z
10.0 A U ( )
direction (see figure). For a field

B 53.0310 24 e 20.2x a y T ,
B 53.0310 24 e 20.2x a y T, find the
power required to move the conductor at SU x52.0 m, y50 m
constant speed to x52.0 m, y50 m in 531023 s U
531023 s. Assume parallel motion along x- U U
the x-axis.

(1) 1.57 W (1) 1.57 W

(2) 2.97 W (2) 2.97 W
(3) 14.85 W (3) 14.85 W
(4) 29.7 W (4) 29.7 W

20. The coercivity of a small magnet where the 20. UU ,

ferromagnet gets demagnetized is , 33103 A m21
33103 A m21. The current required to be 100 10 cm U
passed in a solenoid of length 10 cm and U ,
number of turns 100, so that the magnet U U U ,
gets demagnetized when inside the
solenoid, is :
(1) 30 mA (1) 30 mA
(2) 60 mA (2) 60 mA
(3) 3A (3) 3A
(4) 6A (4) 6A

E/Page 11 SPACE FOR ROUGH WORK / U

21. In the circuit shown here, the point C is 21. U , C A
kept connected to point A till the current U U
flowing through the circuit becomes U SU , ,
constant. Afterward, suddenly, point C C A UU B t50
is disconnected from point A and U t5L/R U U
connected to point B at time t50. Ratio U U U U U
of the voltage across resistance and the
inductor at t5L/R will be equal to :

e e
(1) (1)
12 e 12 e

(2) 1 (2) 1

(3) 21 (3) 21

12 e 12 e
(4) (4)
e e

22. During the propagation of electromagnetic 22. l U U

waves in a medium : U

(1) Electric energy density is double of (1) l

the magnetic energy density.

(2) Electric energy density is half of the (2) l

magnetic energy density.

(3) Electric energy density is equal to the (3) l

magnetic energy density. UU

(4) Both electric and magnetic energy (4) l

densities are zero.

E/Page 12 SPACE FOR ROUGH WORK / U

 3
23. A thin convex lens made from crown glass 23. m 5
2


m 5 3 has focal length f. When it is f
4

2 3
5
measured in two different liquids having
3
UU ,
4 5
refractive indices
3
and , it has the focal
3 f1 f2
lengths f1 and f2 respectively. The correct
relation between the focal lengths is :

(1) f15f2 < f (1) f15f2 < f

(2) f1 > f and f2 becomes negative (2) f1 > f U f2

(3) f2 > f and f1 becomes negative (3) f2 > f U f1
(4) f1 and f2 both become negative (4) f1 f2

24. A green light is incident from the water to 24. U U - UcU

the air - water interface at the critical U (u)
angle(u). Select the correct statement.
(1) The entire spectrum of visible light (1) 908 U
will come out of the water at an SU U
angle of 908 to the normal.

(2) The spectrum of visible light whose (2) SU, U

frequency is less than that of green U ,
light will come out to the air U
medium.

(3) The spectrum of visible light whose (3) SU, U

frequency is more than that of green U ,
light will come out to the air U
medium.

(4) The entire spectrum of visible light (4) SU

will come out of the water at various U U
angles to the normal.

E/Page 13 SPACE FOR ROUGH WORK / U

25. Two beams, A and B, of plane polarized 25.
light with mutually perpendicular planes A B U mU
of polarization are seen through a S A
polaroid. From the position when the (U B ) UU
beam A has maximum intensity (and 308 l
beam B has zero intensity), a rotation of U
polaroid through 308 makes the two beams IA
appear equally bright. If the initial IA IB , IB
intensities of the two beams are IA and IB
IA
respectively, then I equals :
B

(1) 3 (1) 3

3 3
(2) (2)
2 2

(3) 1 (3) 1

1 1
(4) (4)
3 3

26. The radiation corresponding to 32 26. U U 32 U

transition of hydrogen atom falls on a cU U U UU
metal surface to produce photoelectrons. U U 331024 T
These electrons are made to enter a U U mU
magnetic field of 331024 T. If the radius 10.0 mm ,
of the largest circular path followed by
these electrons is 10.0 mm, the work
function of the metal is close to :

(1) 1.8 eV (1) 1.8 eV

(2) 1.1 eV (2) 1.1 eV

(3) 0.8 eV (3) 0.8 eV

(4) 1.6 eV (4) 1.6 eV

E/Page 14 SPACE FOR ROUGH WORK / U

27. Hydrogen (1H1), Deuterium (1H2), singly 27. U (1H1), UUU (1H2),
ionised Helium ( 2 He 4 ) 1 and doubly (2He4)1 U m
ionised lithium ( 3Li 6 ) 11 all have one (3Li6)11 U U
electron around the nucleus. Consider an U n52 n51 U U
electron transition from n52 to n51. If U U U
the wave lengths of emitted radiation are l1, l2, l3 l4 ,
l 1 , l 2 , l 3 and l 4 respectively then ?
approximately which one of the following
is correct ?

(1) 4l152l252l35l4 (1) 4l152l252l35l4

(2) l152l252l35l4 (2) l152l252l35l4

(3) l15l254l359l4 (3) l15l254l359l4

(4) l152l253l354l4 (4) l152l253l354l4

28. The forward biased diode connection is : 28. U

(1) (1)

(2) (2)

(3) (3)

(4) (4)

E/Page 15 SPACE FOR ROUGH WORK / U

29. Match List - I (Electromagnetic wave type) 29. - I (l U U )
with List - II (Its association/application) - II ( h/)
and select the correct option from the U
choices given below the lists :
List - I List - II - I - II

(a)
Infrared
(i)
To treat muscular
waves strain
(a) U U (i)

(b) Radio waves (ii) For broadcasting (b) UU U (ii) U
To detect fracture
(c) X - rays (iii) a S
of bones (c) -U (iii)

Absorbed by the
Ultraviolet U U
$
(d) (iv) ozone layer of the (d) (iv)
rays
atmosphere U U mU
(a) (b) (c) (d) (a) (b) (c) (d)
(1) (iv) (iii) (ii) (i) (1) (iv) (iii) (ii) (i)
(2) (i) (ii) (iv) (iii) (2) (i) (ii) (iv) (iii)
(3) (iii) (ii) (i) (iv) (3) (iii) (ii) (i) (iv)
(4) (i) (ii) (iii) (iv) (4) (i) (ii) (iii) (iv)

30. A student measured the length of a rod 30. l U U

and wrote it as 3.50 cm. Which instrument 3.50 cm U
did he use to measure it ? ?
(1) A meter scale. (1) UU S
(2) A vernier calliper where the (2) U U S
10 divisions in vernier scale matches 10 S 9
with 9 division in main scale and U S 1 cm 10
main scale has 10 divisions in 1 cm.
(3) A screw gauge having 100 divisions (3) S $ U S
in the circular scale and pitch as 100 U 1 mm
1 mm.
(4) A screw gauge having 50 divisions (4) S $ U S 50
in the circular scale and pitch as U 1 mm
1 mm.

E/Page 16 SPACE FOR ROUGH WORK / U

 PART B CHEMISTRY B U
31. The correct set of four quantum numbers 31. MU U (Z537) U
for the valence electrons of rubidium atom U U U U
(Z537) is :
1 1
(1) 5, 0, 0, 1 (1) 5, 0, 0, 1
2 2
1 1
(2) 5, 1, 0, 1 (2) 5, 1, 0, 1
2 2
1 1
(3) 5, 1, 1, 1 (3) 5, 1, 1, 1
2 2
1 1
(4) 5, 0, 1, 1 (4) 5, 0, 1, 1
2 2

32. If Z is a compressibility factor, 32. Z U U

van der Waals equation at low pressure U
can be written as :
RT RT
(1) Z511 (1) Z511
Pb Pb
a a
(2) Z512 (2) Z512
VRT VRT
Pb Pb
(3) Z512 (3) Z512
RT RT
Pb Pb
(4) Z511 (4) Z511
RT RT

33. CsCl crystallises in body centred cubic 33. CsCl U SU

lattice. If a is its edge length then which U a
of the following expressions is correct ? - U ?
(1) rCs1 1 rCl25 3a (1) rCs1 1 rCl25 3a

3a 3a
(2) rCs1 1 rCl25 (2) rCs1 1 rCl25
2 2

3 3
(3) rCs1 1 rCl25 a (3) rCs1 1 rCl25 a
2 2

(4) rCs1 1 rCl25 3a (4) rCs1 1 rCl25 3a

E/Page 17 SPACE FOR ROUGH WORK / U

34. For the estimation of nitrogen, 1.4 g of an 34. U 1.4 .
organic compound was digested by U U
Kjeldahl method and the evolved ammonia M
60 10 U
M
was absorbed in 60 mL of
10
sulphuric
acid. The unreacted acid required 20 mL M
U 20 10
U
M
of sodium hydroxide for complete UU U
10
neutralization. The percentage of nitrogen
in the compound is :
(1) 6% (1) 6%
(2) 10% (2) 10%
(3) 3% (3) 3%
(4) 5% (4) 5%
35. Resistance of 0.2 M solution of an 35. l U 0.2 M U
electrolyte is 50 V. The specific 50 V cU
conductance of the solution is 1.4 S m21. 1.4 S m21 l U 0.5 M
The resistance of 0.5 M solution of the same U 280 V l U
electrolyte is 280 V. The molar 0.5 M U S m2 21
conductivity of 0.5 M solution of the
electrolyte in S m2 mol21 is :
(1) 5310 24 (1) 5310 24
(2) 5310 23 (2) 5310 23
(3) 5310 3 (3) 5310 3
(4) 5310 2 (4) 5310 2
36. For complete combustion of ethanol, 36. ,
C2H5OH(l)13O2(g) 2CO2(g)13H2O(l), C2H5OH(l)13O2(g) 2CO2(g)13H2O(l),
the amount of heat produced as measured UUU 258C U
in bomb calorimeter, is 1364.47 kJ mol21 1364.47 kJ mol21
at 258C. Assuming ideality the Enthalpy , DcH,
of combustion, DcH, for the reaction will
be :
(R58.314 kJ mol21) (R58.314 kJ mol21)
(1) 21366.95 kJ mol21 (1) 21366.95 kJ mol21
(2) 21361.95 kJ mol21 (2) 21361.95 kJ mol21
(3) 21460.50 kJ mol21 (3) 21460.50 kJ mol21
(4) 21350.50 kJ mol21 (4) 21350.50 kJ mol21

E/Page 18 SPACE FOR ROUGH WORK / U

37. The equivalent conductance of NaCl at 37. C U U U NaCl
concentration C and at infinite dilution are U lC U l:
l C and l : , respectively. The correct
relationship between lC and l: is given
as :
(where the constant B is positive) (B SU )
(1) lC5l:1(B)C (1) lC5l:1(B)C
(2) lC5l:2(B)C (2) lC5l:2(B)C
(3) lC5l:2(B) C (3) lC5l:2(B) C
(4) lC5l:1(B) C (4) lC5l:1(B) C

38. Consider separate solutions of 0.500 M 38. 0.500 M C2H5OH(),

C 2 H 5 OH(aq), 0.100 M Mg 3 (PO 4 ) 2 (aq), 0.100 M Mg 3 (PO 4 ) 2 () , 0.250 M
0.250 M KBr(aq) and 0.125 M Na3PO4(aq) KBr() U 0.125 M Na3PO4()
at 258C. Which statement is true about 258C U
these solutions, assuming all salts to be UU
strong electrolytes ? - ?
(1) They all have the same osmotic (1) U
pressure.
(2) 0.100 M Mg 3 (PO 4 ) 2 (aq) has the (2) 0.100 M Mg 3 (PO 4 ) 2 ()
highest osmotic pressure. U
(3) 0.125 M Na3PO4(aq) has the highest (3) 0.125 M Na 3 PO 4 ()
osmotic pressure. U
(4) 0.500 M C 2 H 5 OH(aq) has the (4) 0.500 M C 2 H 5 OH ()
highest osmotic pressure. U

1 1
39. For the reaction SO2(g)1 O2(g) SO3(g),
2
39. , SO2(g)1 O
2 2(g)
SO3(g)
if KP5KC(RT)x where the symbols have KP5KC(RT)x U
usual meaning then the value of x is : U UM x
(assuming ideality)
(1) 21 (1) 21
1 1
(2) 2 (2) 2
2 2
1 1
(3) (3)
2 2
(4) 1 (4) 1

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40. For the non - stoichiometre reaction 40. U U 2A1B C1D
2A1B C1D, the following kinetic data 298 K U
were obtained in three separate
experiments, all at 298 K.

Initial Initial Initial rate of

U U C U
Concentration Concentration formation of C
(A) (B) (mol L2S2)
(A) (B) U ( L2S2)
0.1 M 0.1 M 1.2 3 10 23 0.1 M 0.1 M 1.2 3 10 23
0.1 M 0.2 M 1.2 3 10 23 0.1 M 0.2 M 1.2 3 10 23
0.2 M 0.1 M 2.4 3 10 23 0.2 M 0.1 M 2.4 3 10 23
The rate law for the formation of C is : C U
dc dc
(1) 5k[A] [B] (1) 5k[A] [B]
dt dt
dc dc
(2) 5k[A]2 [B] (2) 5k[A]2 [B]
dt dt
dc dc
(3) 5k[A] [B]2 (3) 5k[A] [B]2
dt dt
dc dc
(4) 5k[A] (4) 5k[A]
dt dt

41. Among the following oxoacids, the correct 41.

decreasing order of acid strength is : U
(1) HOCl > HClO2 > HClO3 > HClO4 (1) HOCl > HClO2 > HClO3 > HClO4
(2) HClO4 > HOCl > HClO2 > HClO3 (2) HClO4 > HOCl > HClO2 > HClO3
(3) HClO4 > HClO3 > HClO2 > HOCl (3) HClO4 > HClO3 > HClO2 > HOCl
(4) HClO2 > HClO4 > HClO3 > HOCl (4) HClO2 > HClO4 > HClO3 > HOCl

42. The metal that cannot be obtained by 42.

electrolysis of an aqueous solution of its U (l U)
salts is :
(1) Ag (1) Ag
(2) Ca (2) Ca
(3) Cu (3) Cu
(4) Cr (4) Cr

E/Page 20 SPACE FOR ROUGH WORK / U

43. The octahedral complex of a metal ion 43. M31 U U,
M31 with four monodentate ligands L1, L1, L2, L3 U L4 cU U
L2, L3 and L4 absorb wavelengths in the , U, U S UZ
region of red, green, yellow and blue, U U U U
respectively. The increasing order of ligand
strength of the four ligands is :

(1) L4 < L3 < L2 < L1 (1) L4 < L 3 < L 2 < L 1

(2) L1 < L3 < L2 < L4 (2) L1 < L 3 < L 2 < L 4

(3) L3 < L2 < L4 < L1 (3) L3 < L 2 < L 4 < L 1

(4) L1 < L2< L4 < L3 (4) L1 < L 2 < L 4 < L 3

44. Which one of the following properties is 44. NO - U ?

not shown by NO ?

(1) It is diamagnetic in gaseous state (1) S

(2) It is a neutral oxide (2) U
(3) It combines with oxygen to form (3) U U
UU
nitrogen dioxide
(4) Its bond order is 2.5 (4) U 2.5

45. In which of the following reactions H2O2 45. H2O2

acts as a reducing agent ? U ?
(a) H2O21 2H112e2 2H2O (a) H2O21 2H112e2 2H2O

(b) H2O222e2 O21 2H1 (b) H2O222e2 O21 2H1

(c) H2O212e2 2OH2 (c) H2O212e2 2OH2

(d) H2O21 2OH222e2 O212H2O (d) H2O21 2OH222e2 O212H2O

(1) (a), (b) (1) (a), (b)

(2) (c), (d) (2) (c), (d)

(3) (a), (c) (3) (a), (c)

(4) (b), (d) (4) (b), (d)

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46. The correct statement for the molecule, 46. CsI3
CsI3 , is :

(1) it is a covalent molecule. (1)

(2) it contains Cs1 and I2

3 ions. (2) Cs1 U 2
I3

(3) it contains Cs31 and I2 ions. (3) Cs31 U I2

(4) it contains Cs 1 , I 2 and lattice I 2 (4) Cs1, I2 U I2
molecule.

47. The ratio of masses of oxygen and nitrogen 47. U U

in a particular gaseous mixture is 1 : 4. The 1 : 4
ratio of number of their molecule is :
(1) 1:4 (1) 1:4

(2) 7 : 32 (2) 7 : 32

(3) 1:8 (3) 1:8

(4) 3 : 16 (4) 3 : 16

48. Given below are the half - cell reactions : 48. U h

Mn2112e2 Mn ; Eo521.18 V Mn2112e2 Mn ; Eo521.18 V

2(Mn311e2 Mn21) ; Eo511.51 V 2(Mn311e2 Mn21) ; Eo511.51 V

The Eo for 3Mn21 Mn12Mn31 will be : 3Mn21 Mn12Mn31 Eo

(1) 22.69 V ; the reaction will not occur (1) 22.69 V ;
(2) 22.69 V ; the reaction will occur (2) 22.69 V ;
(3) 20.33 V ; the reaction will not occur (3) 20.33 V ;
(4) 20.33 V ; the reaction will occur (4) 20.33 V ;
E/Page 22 SPACE FOR ROUGH WORK / U
49. Which series of reactions correctly 49. - M
represents chemical relations related to U U
iron and its compound ? M U ?

(1) dil H SO H SO , O H2 SO 4 H2 SO 4 , O 2
Fe
2 4
FeSO 4
2 4 2
(1) Fe FeSO 4

heat
Fe 2 (SO 4 )3
Fe Fe 2 (SO 4 )3 Fe

(2) O , heat dil H SO (2) O 2 , H2 SO 4

Fe
2
FeO
2 4
Fe FeO

heat
FeSO 4
Fe FeSO 4 Fe

(3) Cl , heat heat, air (3) Cl 2 , ,

Fe
2

FeCl 3 Fe FeCl 3

Zn Zn
FeCl 2 Fe FeCl 2 Fe

(4) O , heat CO, 6008 C (4) O 2 , CO, 6008 C

Fe
2
Fe 3O 4
Fe Fe 3O 4

CO, 700 8 C CO, 700 8 C

FeO
Fe FeO
Fe

50. The equation which is balanced and 50. U U

represents the correct product(s) is : ,
(1) Li2O12KCl 2LiCl1K2O (1) Li2O12KCl 2LiCl1K2O

(2) [CoCl(NH3)5]115H1Co21 (2) [CoCl(NH 3)5]115 H1 Co 21

1 1
15 NH4 1Cl2 15 NH4 1Cl2

(3) [Mg(H2O)6]211 (EDTA) 42 (3) [Mg(H2O)6]211(EDTA)42

excess NaOH NaOH
[Mg(EDTA)]21
[Mg(EDTA) ] 21
1 6H2O 1 6H2O

(4) CuSO 414 K C N K 2[Cu(CN) 4] (4) CuSO 41 4 K C N K 2[Cu(CN) 4]

1K2SO 4 1K2SO 4

E/Page 23 SPACE FOR ROUGH WORK / U

51. In S N 2 reactions, the correct order of 51. CH3Cl, CH3CH2Cl, (CH3)2CHCl U
reactivity for the following compounds : (CH3)3CCl SN2 U
CH 3 Cl, CH 3 CH 2 Cl, (CH 3 ) 2 CHCl and SU
(CH3)3CCl is :

(1) CH3Cl > (CH3)2CHCl > CH3CH2Cl (1) CH3Cl > (CH3)2CHCl > CH3CH2Cl
> (CH3)3CCl > (CH3)3CCl

(2) CH3Cl > CH3CH2Cl > (CH3)2CHCl (2) CH3Cl > CH3CH2Cl > (CH3)2CHCl
> (CH3)3CCl > (CH3)3CCl

(3) CH3CH2Cl > CH3Cl > (CH3)2CHCl (3) CH3CH2Cl > CH3Cl > (CH3)2CHCl
> (CH3)3CCl > (CH3)3CCl

(4) (CH3)2CHCl > CH3CH2Cl > CH3Cl (4) (CH3)2CHCl > CH3CH2Cl > CH3Cl
> (CH3)3CCl > (CH3)3CCl

52. On heating an aliphatic primary amine 52. U U U U

with chloroform and ethanolic potassium U UU U U
hydroxide, the organic compound formed U U
is :

(1) an alkanol (1)

(2) an alkanediol (2) U
(3) an alkyl cyanide (3) U
(4) an alkyl isocyanide (4) U

53. The most suitable reagent for the 53. R2CH22OH R2CHO
conversion of R2CH22OH R2CHO U
is :

(1) KMnO4 (1) KMnO 4

(2) K2Cr2O7 (2) K2Cr2O7

(3) CrO 3 (3) CrO 3

(4) PCC (Pyridinium Chlorochromate) (4) PCC (UU U)U

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54. The major organic compound formed by 54. 1, 1, 12 UU
U UU
the reaction of 1, 1, 12 trichloroethane U U U
with silver powder is :

(1) Acetylene (1) U

(2) Ethene (2)

(3) 2 - Butyne (3) 2- U

(4) 2 - Butene (4) 2- U

55. Sodium phenoxide when heated with CO2 55. U $U U 1258C U

under pressure at 1258C yields a product CO2 U U
which on acetylation produces C. U U C

The major product C would be : C

(1) (1)

(2) (2)

(3) (3)

(4) (4)

E/Page 25 SPACE FOR ROUGH WORK / U

56. Considering the basic strength of amines 56. U U
in aqueous solution, which one has the pKb
smallest pKb value ? ?

(1) (CH3)2NH (1) (CH3)2NH

(2) CH3NH2 (2) CH3NH2

(3) (CH3)3N (3) (CH3)3N

(4) C6H5NH2 (4) C6H5NH2

57. For which of the following molecule 57. m0

significant m0 ? ?

(a) (b) (a) (b)

(c) (d) (c) (d)

(1) Only (a) (1) (a)

(2) (a) and (b) (2) (a) U (b)

(3) Only (c) (3) (c)

(4) (c) and (d) (4) (c) U (d)

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58. Which one is classified as a condensation 58. U ?
polymer ?

(1) Dacron (1) UU

(2) Neoprene (2)

(3) Teflon (3) U$

(4) Acrylonitrile (4) U

59. Which one of the following bases is not 59. U DNA ?

present in DNA ?

(1) Quinoline (1)

(2) Adenine (2) U

(3) Cytosine (3) U

(4) Thymine (4)

60. In the reaction, 60. ,

LiAlH PCl Alc. KOH LiAlH PCl Alc. KOH

CH3COOH
4
A
5
C ,
B CH3COOH
4
A
5
B
C

the product C is : C

(1) Acetaldehyde (1) UUU

(2) Acetylene (2) U

(3) Ethylene (3)

(4) Acetyl chloride (4) U UU

E/Page 27 SPACE FOR ROUGH WORK / U
 PART C MATHEMATICS C
61. If X5{4 n 23n21 : n e N} and 61. X5{4 n 23n21 : n e N}
Y5{9(n21) : n e N}, where N is the set of Y5{9(n21) : n e N} , N,
natural numbers, then XY is equal to : , XY UU
(1) X (1) X
(2) Y (2) Y
(3) N (3) N
(4) Y2X (4) Y2X

62. If z is a complex number such that ?z?/2, 62. z ?z?/2 ,

1 1
then the minimum value of z 1
2
: z1
2

5 5
(1) is strictly greater than
2
(1)
2
UU

3 3 5
(2) is strictly greater than
2
but less (2)
2
UU U 2

5
than
2

5 5
(3) is equal to (3)
2
UU
2
(4) lies in the interval (1, 2) (4) U (1, 2) S

63. If a e R and the equation 63. aeR U

23(x2[x])212 (x2[x])1a250 23(x2[x])212 (x2[x])1a250
(where [x] denotes the greatest integer ( [x] Z
[ x) has no integral solution, then all [ x ) Z , a
possible values of a lie in the interval : U S ,
(1) (22, 21) (1) (22, 21)
(2) (2:, 22) (2, :) (2) (2:, 22) (2, :)
(3) (21, 0) (0, 1) (3) (21, 0) (0, 1)
(4) (1, 2) (4) (1, 2)

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64. Let a and b be the roots of equation 64. a b U px21qx1r50, p0
px21qx1r50, p0. If p, q, r are in A.P. p, q, r U
1 1 1 1
and 1 5 4 , then the value of ?a2b? 1 54 , ?a2b?
a b a b
is :

34 34
(1) (1)
9 9

2 13 2 13
(2) (2)
9 9

61 61
(3) (3)
9 9

2 17 2 17
(4) (4)
9 9

65. If a, b0, and f (n)5an1bn and 65. a, b0, f (n)5an1bn

3 1 1 f (1) 1 1 f (2) 3 1 1 f (1) 1 1 f (2)
1 1 f (1) 1 1 f (2) 1 1 f (3) 1 1 f (1) 1 1 f (2) 1 1 f (3)
1 1 f (2) 1 1 f (3) 1 1 f (4) 1 1 f (2) 1 1 f (3) 1 1 f (4)

5K(12a) 2 (12b) 2 (a2b) 2 , then K is 5K(12a)2 (12b)2 (a2b)2 , K UU

equal to :
(1) 1 (1) 1
(2) 21 (2) 21
(3) ab (3) ab
1 1
(4) ab
(4) ab

66. If A is an 333 non - singular matrix such 66. 333

A
that AA95A9A and B5A21 A9, then BB9 AA95A9A B5A21 A9 , BB9 UU
equals :
(1) B21 (1) B21
(2) (B21)9 (2) (B21)9
(3) I1B (3) I1B
(4) I (4) I

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67. If the coefficients of x 3 and x 4 in the 67. (11ax1bx2) (122x)18 x
expansion of (11ax1bx 2 ) (122x) 18 in U x3 x4, , (a, b)
powers of x are both zero, then (a, b) is UU
equal to :

(1) 14 , 272 (1) 14 , 272
3 3

(2) 16 , 272 (2) 16 , 272
3 3

(3) 16 , 251 (3) 16 , 251
3 3

(4) 14 , 251 (4) 14 , 251
3 3

68. If (10) 9 12(11) 1 (10) 8 13(11) 2 (10) 7 1... 68. (10)912(11) 1 (10)813(11)2 (10)71...
110 (11)95k (10)9, then k is equal to : 110 (11)95k (10)9 , k UU
(1) 100 (1) 100
(2) 110 (2) 110

121 121
(3) (3)
10 10

441 441
(4) (4)
100 100

69. Three positive numbers form an increasing 69. U

G.P. If the middle term in this G.P. is U U
doubled, the new numbers are in A.P. , U
Then the common ratio of the G.P. is : U
(1) 22 3 (1) 22 3

(2) 21 3 (2) 21 3

(3) 21 3 (3) 21 3

(4) 31 2 (4) 31 2

E/Page 30 SPACE FOR ROUGH WORK / U

 sin ( p cos 2 x ) sin ( p cos 2 x )
70. lim is equal to : 70. lim
x 0 x2 x 0 x2

(1) 2p (1) 2p

(2) p (2) p

p p
(3) (3)
2 2

(4) 1 (4) 1

1
71. If g is the inverse of a function f and 71. g f f 9 (x)5 1 1 x 5
1
f 9 (x)5
1 1 x5
, then g9 (x) is equal to : , g9 (x) UU

1 1
(1) 1 1 { g ( x )}
5 (1) 1 1 { g ( x )}
5

(2) 11{g(x)}5 (2) 11{g(x)} 5

(3) 11x 5 (3) 11x 5

(4) 5x 4 (4) 5x 4

72. If f and g are differentiable functions in 72. f g, [0, 1]

[0, 1] satisfying f (0)525g(1), g(0)50 and f (0)525g(1), g(0)50 U f (1)56 cU
f (1)56, then for some ce]0, 1[ : U , ce]0, 1[

(1) f 9(c)5g9(c) (1) f 9(c)5g9(c)

(2) f 9(c)52g9(c) (2) f 9(c)52g9(c)

(3) 2f 9(c)5g9(c) (3) 2f 9(c)5g9(c)

(4) 2f 9(c)53g9(c) (4) 2f 9(c)53g9(c)

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73. If x521 and x52 are extreme points of 73. x521 x52,
f(x)5a log ?x?1bx21x then : f(x)5a log ?x?1bx21x U ,
1 1
(1) a52, b52 (1) a52, b52
2 2
1 1
(2) a52, b5 (2) a52, b5
2 2
1 1
(3) a526, b5 (3) a526, b5
2 2
1 1
(4) a526, b52 (4) a526, b52
2 2

1 1
1 x1 1 x1
74. The integral 1 1 x 2 e x d x is 74. 1 1 x 2 e x d x UU
x x
equal to :
1 1
x1 x1
(1) (x11) e x 1c (1) (x11) e x 1c
1 1
x1 x1
(2) 2x e x 1c (2) 2x e x 1c
1 1
x1 x1
(3) (x21) e x 1c (3) (x21) e x 1c
1 1
x1 x1
(4) x e x 1c (4) x e x 1c

75. The integral 75.

p p
x 2 x x x
1 1 4 sin 2 4 sin d x equals : 1 1 4 sin 2 2 4 sin d x UU
2 2 2 2
0 0

(1) 4 324 (1) 4 324

p p
(2) 4 3 2 42 (2) 4 3 2 42
3 3
(3) p24 (3) p24
2p 2p
(4) 2 42 4 3 (4) 2 42 4 3
3 3

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76. The area of the region described by 76. A5{(x, y) : x21y2 [ 1 y2 [ 12x}
A5{(x, y) : x21y2 [ 1 and y2 [ 12x} is : mU
p 2 p 2
(1) 2 (1) 2
2 3 2 3

p 2 p 2
(2) 1 (2) 1
2 3 2 3

p 4 p 4
(3) 1 (3) 1
2 3 2 3

p 4 p 4
(4) 2 (4) 2
2 3 2 3

77. Let the population of rabbits surviving at 77. t U U

dp(t) 1
a time t be governed by the differential U dt
5 p(t) 2200
2
mU
dp(t) 1
equation
dt
5 p(t) 2200.
2

If p(0)5100, then p(t) equals : p(0)5100 , p(t) UU
(1) 6002500 et/2 (1) 6002500 et/2

(2) 4002300 e2t/2 (2) 4002300 e2t/2

(3) 4002300 et/2 (3) 4002300 et/2

(4) 3002200 e2t/2 (4) 3002200 e2t/2

78. Let PS be the median of the triangle with 78. PS

vertices P(2, 2), Q(6,21) and R(7, 3). The P(2, 2), Q(6,21) R(7, 3) (1, 21)
equation of the line passing through U U, PS U ,
(1, 21) and parallel to PS is : U
(1) 4x17y1350 (1) 4x17y1350

(2) 2x29y21150 (2) 2x29y21150

(3) 4x27y21150 (3) 4x27y21150

(4) 2x19y1750 (4) 2x19y1750

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79. Let a, b, c and d be non-zero numbers. If 79. a, b, c d U U
the point of intersection of the lines 4ax12ay1c50 5bx12by1d50
4ax12ay1c50 and 5bx12by1d50 lies U Z
in the fourth quadrant and is equidistant US ,
from the two axes then :
(1) 3bc22ad50 (1) 3bc22ad50
(2) 3bc12ad50 (2) 3bc12ad50
(3) 2bc23ad50 (3) 2bc23ad50
(4) 2bc13ad50 (4) 2bc13ad50

80. The locus of the foot of perpendicular 80. x213y256 S

drawn from the centre of the ellipse U U
x213y256 on any tangent to it is :
(1) (x21y 2)256x 212y 2 (1) (x21y 2)256x 212y 2
(2) (x21y 2)256x 222y 2 (2) (x21y 2)256x 222y 2
(3) (x22y 2)256x 212y 2 (3) (x22y 2)256x 212y 2
(4) (x22y 2)256x 222y 2 (4) (x22y 2)256x 222y 2

81. Let C be the circle with centre at (1, 1) and 81. C (1, 1) U
radius51. If T is the circle centred at 51 T (0, y)
(0, y), passing through origin and touching U C s M
the circle C externally, then the radius of S U , T UU
T is equal to :

1 1
(1) (1)
2 2

1 1
(2) (2)
4 4

3 3
(3) (3)
2 2

3 3
(4) (4)
2 2

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82. The slope of the line touching both the 82. U y254x x25232y S
parabolas y254x and x25232y is : U U

1 1
(1) (1)
8 8

2 2
(2) (2)
3 3

1 1
(3) (3)
2 2

3 3
(4) (4)
2 2

83. The image of the line 83. 2x2y1z1350 U

x 21 y 23 z 24 x 21 y 23 z 24
3
5
1
5
25
in the plane
3
5
1
5
25

2x2y1z1350 is the line : U

x 23 y 15 z 22 x 23 y 15 z 22
(1) 5 5 (1) 5 5
3 1 25 3 1 25

x 23 y 15 z 22 x 23 y 15 z 22
(2) 5 5 (2) 5 5
23 21 5 23 21 5

x 13 y 25 z 22 x 13 y 25 z 22
(3) 5 5 (3) 5 5
3 1 25 3 1 25

x 13 y 25 z 12 x 13 y 25 z 12
(4) 5 5 (4) 5 5
23 21 5 23 21 5

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84. The angle between the lines whose 84. U , - , U
direction cosines satisfy the equations l1m1n50 l25m21n2 cU U ,
l1m1n50 and l25m21n2 is :
p p
(1) (1)
6 6

p p
(2) (2)
2 2

p p
(3) (3)
3 3

p p
(4) (4)
4 4

2 2
85. If a3b b3c c3a 5l a b c then l is 85. a3b b3c c3a 5l a b c
, l
equal to : UU
(1) 0 (1) 0

(2) 1 (2) 1

(3) 2 (3) 2

(4) 3 (4) 3

86. Let A and B be two events such that 86. A B U

1 1 1 1
P (A B) 5 , P (A B) 5 and P (A B) 5 , P (A B) 5
6 4 6 4
1 1
P (A ) 5 , where A stands for the P (A ) 5 A U A U
4 4
complement of the event A. Then the U A B
events A and B are :

(1) independent but not equally likely. (1) S U

(2) independent and equally likely. (2) S
(3) mutually exclusive and independent. (3) USU S
(4) equally likely but not independent. (4) U S
E/Page 36 SPACE FOR ROUGH WORK / U
87. The variance of first 50 even natural 87. 50 U
numbers is :

(1) 437 (1) 437

437 437
(2) (2)
4 4

833 833
(3) (3)
4 4

(4) 833 (4) 833

1 1
88. Let f k ( x ) 5(sin k x 1 cosk x ) where 88. fk ( x ) 5 (sin k x 1 cosk x ) ,
k k
x e R and k/1. Then f4(x)2f6(x) equals : x e R k/1 , f4(x)2f6(x) UU

1 1
(1) (1)
4 4

1 1
(2) (2)
12 12

1 1
(3) (3)
6 6

1 1
(4) (4)
3 3

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89. A bird is sitting on the top of a vertical 89. 20 . U U
pole 20 m high and its elevation from a U U O
point O on the ground is 458. It flies off 458 O U
horizontally straight away from the U , O
point O. After one second, the elevation U U 308 U (. . )
of the bird from O is reduced to 308. Then
the speed (in m/s) of the bird is :
(1) 20 2 (1) 20 2

(2) 20 ( 3 2 1) (2) 20 ( 3 2 1)

(3) 40 ( 2 2 1) (3) 40 ( 2 2 1)

(4) 40 ( 3 2 2) (4) 40 ( 3 2 2)

90. The statement ~(p ~q) is : 90. ~(p ~q)

(1) a tautology (1) L (tautology)
(2) a fallacy (2) (fallacy)
(3) equivalent to p q (3) p q
(4) equivalent to ~p q (4) ~p q

-o0o- -o0o-

SPACE FOR ROUGH WORK / U

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 SPACE FOR ROUGH WORK /

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 Read the following instructions carefully :
1. The candidates should fill in the required particulars 1. U U S U U (D -1) U U
on the Test Booklet and Answer Sheet (Side1) with
Blue/Black Ball Point Pen.
U / U U
2. For writing/marking particulars on Side2 of the 2. U D-2 U U / U
Answer Sheet, use Blue/Black Ball Point Pen only. / U U
3. The candidates should not write their Roll Numbers 3. U S/U U U S U
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Test Booklet/Answer Sheet.
4. Out of the four options given for each question, only 4. U
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5. For each incorrect response, onefourth () of the total 5. U U
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- () U
however, will be made if no response is indicated for U U ,
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as under no circumstances (except for discrepancy in
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will be provided. S UU), U U S
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Room/Hall. However, the candidates are allowed to U U
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U U U S U SU
again. Cases where a candidate has not signed the U U
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E/Page 40