T1 273 K

r2 50 r1
T2 373 K
r2 8.314 KJ/mol K
Ln 50r1/r1 (1/T1-1/T2)/R
3.9120230054 0.0001181187
E 33119 KJ/mol

C A1 n Ao n 1kt
C 1 n

Orde Reaksi 0.5

t1 10 mnt
X1 0.75
t2 60 mnt
X2 ?
Asumsikan Cao 1 mol/L
Hit k 4
-0.5 -5
k 0.1
4
X2

TK 273 279 285 291 297

1/T 0.0036630037 0.003584 0.003509 0.003436 0.003367
k 10^5 5.6 11.8 24.5 48.8 100
250

200

150
f(x) = - 505020.332628188x + 1822.2175344191
R = 0.7846884573

100

50

0
0.00325 0.0033 0.00335 0.0034 0.00345 0.0035 0.00355 0.0036 0.00365 0.0037
0.693147
0.086643

303
0.0033
208
0.0036 0.00365 0.0037
 t (mnt) 0 2,5 5,0 10,0 15,0
20,0
Pt (mmHg) 7,5 10,5 12,5 15,8 17,9
19,4
PA (mmHg) 7,5 6 5 3,3 2,3
1,5
t 0 2.5 5 10 15 20
Pa 7.5 6 5 3.3 2.3 1.5
(-ra) 7.47 8.8813 10.02 11.664 12.779 13.738
ln Pa 2.0149 1.7918 1.6094 1.1939 0.8329 0.4055
ln(-ra) 2.0109 2.1839 2.3045 2.4565 2.5478 2.6202

0.627045 n 0.9996
7.469555 k 1.004

INTEGRAL
t 0 2.5 5 10 15 20
Pa 7.5 6 5 3.3 2.3 1.5
ln (Pa) 2.0 1.8 1.6 1.2 0.8 0.4
1/Pa 0.1 0.2 0.2 0.3 0.4 0.7

Orde nol Orde 1

t 0 2.5 5 10 15 20 t 0
Pa 7.5 6 5 3.3 2.3 1.5 ln (Pa) 2.0

Orde nol Orde 1

10 3.0
2.0
5 f(x) = - 0.2913684211x + 6.8161403509
Pa, mmHg Pa, mmHg 1.0 f(x) = - 0.079510644
R = 0.9527483022 R = 0.9994315853
0
0 5 10 15 20 25 0.0
0 5 10
t, mnt
t, m
0 15,0 3

8 17,9 2.5

2,3 2

ln(-ra) 1.5

8 0.5
7
f(x) = - 0.000465582x^3 + 0.0256328661x^2 - 0.6253552304x + 7.4788908217
0
R = 0.9996239485 0 0.5 1 1.5 2 2.5
6
5 ln PA

Pa 4
3
2
1
0
0 5 10 15 20 25

Orde 2
2.5 5 10 15 20 t 0 2.5 5 10 15
1.8 1.6 1.2 0.8 0.4 1/Pa 0.1 0.2 0.2 0.3 0.4

Orde 1 Orde 2
3.0 1.0

2.0
g 1.0 f(x) = - 0.0795106449x + 2.0037843268 Pa, mmHg 0.5 f(x) = 0.0257274808x + 0.0922978064
R = 0.9994315853 R = 0.9522492097
0.0 0.0
0 5 10 15 20 25 0 5 10 15 20 2

t, mnt t, mnt
 20
0.7

e2

274808x + 0.0922978064
92097

10 15 20 25
t, mnt
 t (menit) 0 4,5 6,0 9,0 10,5 2
CA (mol/m3) 181 141 131 119 111 6

t, mnt 0 50 100 150 200 250

Ca, mol/m3 50 38 30.6 25.6 22.2 19.5

Metode Diferensiasi

60
50
f(x) = - 1.26666666666666E-006x^3 + 0.0009328571x^2 - 0.2744761905x + 49.8714285714
40
R = 0.9996876161

Ca, mol/m3 30
20
10
0
0 50 100 150 200 250 300 350
t, mnt

Hasil dif dca/dt 0.00000381 0.001866 0.27

ln Ca 3.9120230054 3.637586 3.421 3.242592 3.100092 2.970414

(-ra) 0.27 0.186239 0.121528 0.075867 0.049256 0.041695
ln(-ra) -1.30933332 -1.680724 -2.107611 -2.578773 -3.010724 -3.177374
ln Ca 3.9120230054 3.637586 3.421 3.242592 3.100092 2.970414
50 38 30.6 25.6 22.2 19.5

n 1.8
k 0.0002036923

ln(-ra)
0
2.8 3 3.2 3.4 3.6 3.8 4
-0.5

-1 ln(-ra)
-1.5 f(x) = 1.8449955942x - 8.4988664364 Linear (ln(-ra))
R = 0.9390558147
-2

-2.5

-3

-3.5
 R = 0.9390558147
-2

-2.5

-3

-3.5
10,5 24,0 27,5
111 68,3 64,4

300
17.4

Metode Integrasi
Orde nol
t, mnt 0 50 100 150 200
Ca, mol/m3 50 38 30.6 25.6 22.2

Orde nol
60

40
f(x) = - 0.1022857143x + 44.3857142857
Ca
20 R = 0.9073396931

0
0 50 100 150 200 250 300 350
t, min

Orde satu
2.85647021 t, mnt 0 50 100 150
0.053184 Ln ca 3.91202301 3.63758616 3.42100001 3.24259235
-2.93399768
2.85647021
17.4
Orde satu
6

4
Ca f(x) = - 0.0034442211x + 3.8223729451
2 R = 0.9751454967

0
0 50 100 150 200 250 300 350
t, min

Orde 2
t, mnt 0 50 100 150
1/Ca 0.020 0.026 0.033 0.039

Orde dua
0.100

Ca 0.050 f(x) = 0.000124794x + 0.0201175245

R = 0.9999241694
0.000
0 50 100 150 200 250 300 350
 Orde dua
0.100

Ca 0.050 f(x) = 0.000124794x + 0.0201175245

R = 0.9999241694
0.000
0 50 100 150 200 250 300 350
t, min
 250 300
19.5 17.4

0 300 350

200 250 300

3.10009229 2.97041447 2.85647021

0 300 350

200 250 300

0.045 0.051 0.057

0 250 300 350

0 250 300 350