Halogen % % %o % % % Present M+2 M+4 M+6 M+8 M+10 M+ cl 32.6 ch 65.3 10.6 Cl 97.8 31.9 3.5 Cla 131.0 63.9 14.0 1.2: Cl; 163.0 106.0 34.7 5.7 0.4 Cle 196.0 161.0 69.4 17.0 2.2. 0. Br 97.9 Br, 195.0 95.5 Bry 293.0 286.0 93.4 BrCl 130.0 31.9 BrCl, 163.0 74.4 10.4 Br2Cl 228.0 159.0 31.2 Relative Relative Relative Elements Isotope Abundance Isotope Abundance Isotope Abundance Carbon ue 100 HG Vl Hydrogen 'H 100 *H 0.016 Nitrogen 4N 100 ON 0.38 Oxygen 60) 100 "9 0.04 *O 02 Fluorine E 100 Silicon Si 100 Si SA XG) 3.35 Phosphorus "'P 100 Sulfur *§ 100 *S 0.78 4S 44 Chlorine XC 100 YC 325 Bromine “Br 100 Br 98 lodine ay 100Contribuciones Isotopica’ de Contribuciones Isotdpice debidas a Hidrégeno debidas a Carbono (M=100% EF cr ia 1S On c2 22 01 cir is 17 of c3 33 04 C18 20 1.9 O41 C4 44 or fos 21 21 ot cs 55 12, C20 22 2.3 02 cé 68 18 |cez 24 28 02 cr wT 25 C24 26 3.3 03 cs 88 34 cae 28 39 03 co 99 44 C28 34 45 o4 cio ii 54 cao 33 52 05 ci 121 67 Jess 38 72 08 ci2 132 80 cao 44 94 13 C13 14.30 0.94 C50 55 5 1.3 cis isa 11 [ceo jo 48 C15 165 13 C100 110 60 22 Fragmentos razonables a partir del ion molecular Mel loss of hydrogen radical MeH MAS loss of methy! radical MCH3 M29 loss of ethyl radical M-"CH:CHy M31 loss of methoxy! radical MOCK M43 loss of propyl radical Me'CH:CH;CH) M45 loss of ethoxy! radical M-OCH;CH; M3? loss of butyl radical M-'CH,CH,CH,CH, M2 loss of hydrogen M-H, M-18 loss of water M-H,0 M28 loss of CO of ethylene MeCO or M-CzHy M32 Joss of methanol M-CHOH Medd loss of CO; M-COz M-60 loss of acetic acid M-CHyCO:H M90 loss of silanol; HO-Si(CHy)3 M-HO-SI{CHa)s Unreasonable suggested loss M7 M3 M6Fragment Mass Fragment Mass Fragment — Ma: z cHs— 1s ‘CH3CH2— 2 we 29 NO 30 —CH,0H aL CH2=CH-CH. 41 2 ° = = pI 43 aa? 45 NO2 46 oe CHs 2 C.H; 55 CAH, st auc, e— 57 OH 60 CsHs 65 <> 77 CH,= Co OH Cots Ni <{ >-e cho a org 92 “ 4 ° CaHeN o Gtk Cts CHs~ Cre 119 I— 127 ° ‘CetHrOPérdidas del Ién Molecula M -X Perdidas M-7 H M-2 2H M3 3H M-4, M-6 e€asi nunca oeurre M-14 nunca ocurre M-15, cH M-16 O. CHa, NHz M-17 OH M18 H20 M139 F M20 HE M-21 a M-26 no hay mecanismos faciles para explicar estas pérdidas M-26 Debida a fragmentacion de anillo arom 4tico