f.

Reaktor Deoksigenasi (R-202)

34 7

36

Gambar 13 Reaktor Deoksigenasi (R-202)

Fungsi : menurunkan nilai TAC (Total Acid Number) dan

menghilangkan oksigen pada Hydrocarbon Oxygenated
sehingga menjadi minyak nabati mentah
Kondisi operasi
Suhu : 286C
Tekanan : 62,053 bar
(Jr. Morris, 2014)

Pada reaktor deoksigenasi terjadi beberapa reaksi berikut

n-C5H12O + H2 n-C5H12 + H2O
n-C6H14O + H2 n-C6H14 + H2O
n-C7H16O + H2 n-C7H16 + H2O
Iso-C5H12O + H2 Iso-C5H12 + H2O
Iso-C7H16O + H2 Iso-C7H16 + H2O
n-C8H18O + H2 n-C8H18 + H2O
n-C9H20O + H2 n-C9H20 + H2O
n-C10H20O + H2 n-C10H20 + H2O
n-C11H24O + H2 n-C11H24 + H2O
n-C12H26O + H2 n-C12H26 + H2O
n-C13H28O + H2 n-C13H28 + H2O
n-C14H30O + H2 n-C14H30 + H2O
n-C15H32O + H2 n-C15H32 + H2O
3-MethylHexane+ H2 3-MethylHexane + H2O
(Jr. Morris, 2014)

Asumsi:
1. Tidak ada akumulasi energi dalam sistem
2. Ek = Ep = w = 0
3. Tidak ada perubahan fasa dalam sistem

Deskripsi :
H34 = Entalphy reaktan reaktor deoksigenasi
H7 = Entalphy dari hydrogen
H36 = Entalphy produk reaktor deoksigenasi
Q = nilai kalor yang digunakan dalam reaktor deoksigenasi
H34 = Entalphy reaktan reaktor deoksigenasi
H7 = Entalphy dari hydrogen
H36 = Entalphy produk reaktor deoksigenasi
Q = nilai kalor yang digunakan dalam reaktor deoksigenasi
Tref = 25oC
m = Massa
Cp = kapasitas panas
T = perubahan temperatur

Rumus Dasar
H= m x Cp x T

Enthalpy Reaktan H23

H34 = m Reaktan x Cp x (Tref T286C)

Enthalpy Hydrogen H7
H7 = m H2 x CpH2 x (Tref T286C)

Enthalpy Produk H36

H7 = m produk x Cpproduk x (T286C - Tref)

Enthalpy Reaksi Standar pada Tref (25oC)

Hr = Hf produk Hf reaktan
Enthalpy pada reaktor Deoxygenation
HDeoksigenasi= H34 + H7 + H36 + Hr
Supaya reaksi terus berjalan maka perlu disuplai Q dikarenakan reaksi Deoksigenasi bersifat
eksotermis. Nilai Q sebesar nilai HDeoksigenasi. Nilai kalor tersebut disuplai dengan pendingin
Q = HDeoksigenasi

Perhitungan Cp dilakukan dengan dua cara yaitu

1. Interpolasi jika data Cp berbentuk tabel (Data Cp C55H98O6)
2. Menggunakan rumus Cp (Data Cp Produk Oxygenated Fuel). Dengan memasukkan T
rata-rata dari T kondisi pada reaktor (286oC) dan T Referensi (25oC).
CpL = C1 + C2T + C3T2 + C4T3 + C4T4
(Jr. Morris, 2014)
(Js. Alakali, 2010)
(CRC Press, 2000)
(Cherneo, 2016)
(Green dan Perry, 2007)

Sehingga akan diperoleh data perhitungan sebagai berikut

 Table 13 Entalpi Reaktan pada Reaktor Deoksigenasi (R-202)
Entalpi Reaktan
Komponen Massa Reaktan (Kg) Cp (Kj/Kg.C) Enthalpy Reaktan (Kj)
C55H98O6 16916.82 2.595 -11457677.6
n-C5H12O 0.109028004 183.3054188 -5216.195625
n-C6H14O 6.833150294 516405.526 -920984585.3
n-C7H16O 6.44628578 823144.3728 -1384924429
iso-C5H12O 7.218255152 201.8301776 -380240.9087
iso-C6H14 10.33199922 183.089987 -493729.9424
iso-C7H16O 6.44628578 242.6183744 -408200.7053
C6H12 10.49343629 45682.09931 -125113533.9
C6H6 15.1047478 128.4219488 -506282.8795
C6H5-CH3 13.80185102 146.5971238 -528084.3436
H20 6.044162687 60663.68355 -95698566.05
CO2 10.19346182 2559213.09 -6808769879
n-C7H16O 11.80685253 823144.3728 -2536592241
n-C8H18O 10.66855052 92738.09361 -258228450.5
n-C9H20O 9.530247932 3664936.01 -9116142444
n-C10H22O 8.391945349 1611543.459 -3529759991
n-C9H10 48.8332903 184.5408 -2352062.694
n-C11H24O 7.253640868 265769.1651 -503154254.2
n-C12H26O 6.115337002 111.93455 -178659.0663
n-C13H28O 4.97703468 121.618 -157982.518
n-C14H30O 3.838731836 148.86452 -149148.7037
n-C15H32O 0 144.9707 0
3-MethylHexane-O 11.80685253 823144.3728 -2536592241
3-MethylHepthane 10.66855052 92738.09361 -258228450.5
H20 14.5329468 60663.68355 -230103364.4
CO2 0 2615788.871 0
C10H8 16.94554529 164.57625 -727885.7517
C10H12 15.43012014 198.10959 -797839.0963
C10H18 13.60436711 285.0238014 -1012045.36
C10H14 14.77049539 226.5028278 -873190.8924
C10H20 13.06784523 18958.16889 -64660770.8
C10H22 12.58684021 298.1453994 -979456.9188
C14H10 9.060802642 144.993165 -342889.9121
C15H18 6.519816823 112.20538 -190936.7748
C15H30 7.241934582 129.300885 -244397.4117
C15H32O 4.997484297 144.9707 -189091.576
C20H28 0.339819252 180.329345 -15993.91899
C20H34 1.41749493 196.093695 -72548.03463
C20H40 4.633000957 209.487005 -253314.4621
C20H42 0.513305032 214.82951 -28781.27085
H20 0 60663.68355 0
CO2 125.8176876 2559213.09 -84040505273
H2 400 14.4688 -1510542.72
 Entalpi Reaktan
Komponen Massa Reaktan (Kg) Cp (Kj/Kg.C) Enthalpy Reaktan (Kj)
Total H Reaktan -112433314673

(Jr. Morris, 2014)

(Js. Alakali, 2010)
(CRC Press, 2000)
(Cherneo, 2016)
(Green dan Perry, 2007)

Table 13 Entalpi Pembentukan Standar Reaktan

Hf Reaktan
Hf Reaktan
Komponen Mol Reaktan (Kmol) Kj/mol Hf Reaktan (Kj)
C55H98O6 19.80892272 -1256.17 -24883374.45
n-C5H12O 0.109028004 -351.6 -38334.24606
n-C6H14O 6.833150294 -377.5 -2579514.236
n-C7H16O 6.44628578 -403.3 -2599787.055
iso-C5H12O 7.218255152 -365.2 -2636106.781
iso-C6H14 10.33199922 -198.7 -2052968.245
iso-C7H16O 6.44628578 -392.8 -2532101.054
C6H12 10.49343629 -74.2 -778612.9729
C6H6 15.1047478 49.1 741643.1168
C6H5-CH3 13.80185102 12.4 171142.9526
H20 6.044162687 -285.8 -1727421.696
CO2 10.19346182 -393.5 -4011127.226
n-C7H16O 11.80685253 -403.3 -4761703.625
n-C8H18O 10.66855052 -426.5 -4550136.795
n-C9H20O 9.530247932 -453.4 -4321014.412
n-C10H22O 8.391945349 -478.1 -4012189.071
n-C9H10 48.8332903 100.3 4897979.017
n-C11H24O 7.253640868 -504.8 -3661637.91
n-C12H26O 6.115337002 -528.5 -3231955.605
n-C13H28O 4.97703468 -463.88 -2308746.847
n-C14H30O 3.838731836 -484.52 -1859942.349
n-C15H32O 0 -505.16 0
3-MethylHexane-O 11.80685253 -403.3 -4761703.625
3-MethylHepthane 10.66855052 -426.5 -4550136.795
H20 14.5329468 -285.8 -4153516.196
CO2 0 -393.5 0
C10H8 16.94554529 150.6 2551999.121
C10H12 15.43012014 0 0
C10H18 13.60436711 -178.9 -2433821.275
C10H14 14.77049539 -63.2 -933495.3088
C10H20 13.06784523 -173.8 -2271191.501
C10H22 12.58684021 -300.9 -3787380.218
 Hf Reaktan
Hf Reaktan
Komponen Mol Reaktan (Kmol) Kj/mol Hf Reaktan (Kj)
C14H10 9.060802642 0 0
C15H18 6.519816823 34.98 228063.1925
C15H30 7.241934582 -337.57 -2444659.857
C15H32O 4.997484297 -505.16 -2524529.168
C20H28 0.339819252 -62.94 -21388.22371
C20H34 1.41749493 -224.88 -318766.2599
C20H40 4.633000957 -338.91 -1570170.354
C20H42 0.513305032 -461.41 -236844.0746
H20 0 -285.8 0
CO2 125.8176876 -393.5 -49509260.08
H2 400 0 0
Total Hf Reaktan -143472710

Table 13 Entalpi Pembentukan Standar Produk

Hf Produk
Mol Hf Produk
Komponen Hf Produk (Kj)
Produk(Kmol) Kj/mol
C55H98O6 19.80892272 -1256.17 -24883374.45
n-C5H12O 0 -351.6 0
n-C6H14O 0 -377.5 0
n-C7H16O 0 -403.3 0
iso-C5H12O 0 -365.2 0
iso-C6H14 10.33199922 -198.7 -2052968.245
iso-C7H16O 0 -392.8 0
C6H12 10.49343629 -74.2 -778612.9729
C6H6 15.1047478 49.1 741643.1168
C6H5-CH3 13.80185102 12.4 171142.9526
H20 33.0971677 -285.8 -9459170.528
CO2 10.19346182 -393.5 -4011127.226
n-C5H12 0.109028004 -173.5 -18916.35862
n-C6H14 6.833150294 -198.7 -1357746.963
n-C7H16 6.44628578 -224.2 -1445257.272
iso-C5H12 7.218255152 -173.5 -1252367.269
iso-C7H16 6.44628578 -392.8 -2532101.054
H2 22.94699499 0 0
n-C7H16O 0 -403.3 0
n-C8H18O 0 -426.5 0
n-C9H20O 0 -453.4 0
n-C10H22O 0 -478.1 0
n-C9H10 48.8332903 100.3 4897979.017
n-C11H24O 0 -504.8 0
n-C12H26O 0 -528.5 0
 Hf Produk
Mol Hf Produk
Komponen Hf Produk (Kj)
Produk(Kmol) Kj/mol
n-C13H28O 0 -463.88 0
n-C14H30O 0 -484.52 0
n-C15H32O 0 -505.16 0
3-MethylHexane-O 0 -403.3 0
3-MethylHepthane 10.66855052 -426.5 -4550136.795
H20 88.92214004 -285.8 -25413947.62
CO2 0 -393.5 0
n-C7H16 11.80685253 -224.2 -2647096.337
n-C8H18 10.66855052 -250.1 -2668204.484
n-C9H20 9.530247932 -274.7 -2617959.107
n-C10H22 8.391945349 -300.9 -2525136.356
n-C11H24 7.253640868 -327.2 -2373391.292
n-C12H26 6.115337002 -350.9 -2145871.754
n-C13H28 4.97703468 -377.8 -1880323.702
n-C14H30 3.838731836 -337.57 -1295840.706
n-C15H32 0 430.8 0
3-MethylHexane 11.80685253 -224.2 -2647096.337
H2 65.61080676 0 0
C10H8 16.94554529 150.6 2551999.121
C10H12 15.43012014 0 0
C10H18 13.60436711 -178.9 -2433821.275

C10H14 14.77049539 -63.2 -933495.3088

C10H20 13.06784523 -173.8 -2271191.501

C10H22 12.58684021 -300.9 -3787380.218

C14H10 9.060802642 0 0
C15H18 6.519816823 34.98 228063.1925
C15H30 7.241934582 -337.57 -2444659.857
C15H32O 0 -505.16 0
C20H28 0.339819252 -62.94 -21388.22371
C20H34 1.41749493 -224.88 -318766.2599
C20H40 4.633000957 -338.91 -1570170.354
C20H42 0.513305032 -461.41 -236844.0746
H20 -1.18896E-07 -285.8 0.03398046
CO2 125.8176876 -393.5 -49509260.08
C15H32 4.997484297 430.8 2152916.235
H2 4.997484297 0 0
Total Hf Produk -151339880

(Jr. Morris, 2014)

 (Js. Alakali, 2010)
(CRC Press, 2000)
(Cherneo, 2016)
(Green dan Perry, 2007)

Table 13 Entalpi Produk pada reaktor Deoksigenasi (R-202)

H Produk
Massa Reaktan Cp
Komponen Enthalpy Reaktan (Kj)
(Kg) (Kj/Kg.C)
C55H98O6 16916.82 2.595 11457677.6
n-C5H12O 0 183.3054188 0
n-C6H14O 0 516405.526 0
n-C7H16O 0 823144.3728 0
iso-C5H12O 0 201.8301776 0
iso-C6H14 10.33199922 183.089987 1891685.603
iso-C7H16O 0 242.6183744 0
C6H12 10.49343629 45682.09931 479362198.9
C6H6 15.1047478 128.4 1939781.147
C6H5-CH3 13.80185102 146.6 2023311.661
H20 33.0971677 60663.68355 2007796108
CO2 10.19346182 2559213.09 26087240914
n-C5H12 0.109028004 154945.2524 16893371.54
n-C6H14 6.833150294 183089.987 1251081399
-
n-C7H16 6.44628578 68359.46059 -440664619
iso-C5H12 7.218255152 154945.2524 1118434367
-
iso-C7H16 6.44628578 68359.46059 -440664619
H2 22.94699499 14.4688 332015.4811
n-C7H16O 0 -403.3 0
n-C8H18O 0 -426.5 0
n-C9H20O 0 -453.4 0
n-C10H22O 0 -478.1 0
n-C9H10 48.8332903 100.3 4897979.017
n-C11H24O 0 -504.8 0
n-C12H26O 0 -528.5 0
n-C13H28O 0 -463.88 0
n-C14H30O 0 -484.52 0
n-C15H32O 0 -505.16 0
3-MethylHexane-O 0 -403.3 0
3-MethylHepthane 10.66855052 -426.5 -4550136.795
H20 88.92214004 -285.8 -25413947.62
CO2 0 -393.5 0
n-C7H16 11.80685253 -224.2 -2647096.337
n-C8H18 10.66855052 -250.1 -2668204.484
n-C9H20 9.530247932 -274.7 -2617959.107
 H Produk
Massa Reaktan Cp
Komponen Enthalpy Reaktan (Kj)
(Kg) (Kj/Kg.C)
n-C10H22 8.391945349 -300.9 -2525136.356
n-C11H24 7.253640868 -327.2 -2373391.292
n-C12H26 6.115337002 -350.9 -2145871.754
n-C13H28 4.97703468 -377.8 -1880323.702
n-C14H30 3.838731836 -337.57 -1295840.706
n-C15H32 0 430.8 0
3-MethylHexane 11.80685253 -224.2 -2647096.337
H2 65.61080676 14.4688 949309.6409
C10H8 16.94554529 150.6 2551999.121
C10H12 15.43012014 0 0
C10H18 13.60436711 -178.9 -2433821.275

C10H14 14.77049539 -63.2 -933495.3088

C10H20 13.06784523 -173.8 -2271191.501

C10H22 12.58684021 -300.9 -3787380.218

C14H10 9.060802642 0 0
C15H18 6.519816823 34.98 228063.1925
C15H30 7.241934582 -337.57 -2444659.857
C15H32O 0 -505.16 0
C20H28 0.339819252 -62.94 -21388.22371
C20H34 1.41749493 -224.88 -318766.2599
C20H40 4.633000957 -338.91 -1570170.354
C20H42 0.513305032 -461.41 -236844.0746
H20 -1.18896E-07 -285.8 0.03398046
CO2 125.8176876 -393.5 -49509260.08
C15H32 4.997484297 430.8 2152916.235
H2 4.997484297 14.4688 72307.6008
Total H Produk 29993684185

(Jr. Morris, 2014)

(Js. Alakali, 2010)
(CRC Press, 2000)
(Cherneo, 2016)
(Green dan Perry, 2007)

Table 13 Neraca Energi pada reaktor Deoksigenasi (R-202)

IN OUT
H (kJ) H (kJ)
Reaktan -112433314673 Produk 29993684185
Reaksi= Hf Product- Hf Reactant -151339880
 Q 142578338738
H in Total 29993684185 H Out Total 29993684185