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Problems ‘Working with Reaction Equations 131A vessel contains a mixture of 608 O, and 40% CO ‘on amass bass. Determine the percent exces or percent efieney of oxysen 8 appropriate. 152 Estimate the amount of CO; produce Ib, for every fallon of paslie burned by an automobile. In a yer, hhow much CO; would be produced, in Tb, by atypical sitomobile inthe US? 183. One fundred kmol of propane (CH) together with 43572 kinl of air enter a fureace per unit of time. Carbon oxide exrbon monoxide, and nurmed fel appear in the products of combustion exiting the furnace. Determine the percent excess or parent deficiency of ar, whishever is appropriate. 14 Propane (Ci) is burnéd with ir. For each case, ‘obtain the balanced reaction equation for complete om bustion (2) wih the theoretical amount of sir. (©) with 208 exces i, {) with 208 excess lr, but only $05 of he propane being consumed in the reaction, ‘RRR 18S Methane (CH) burns completely withthe stiochiome: ‘nc amoust of hydrogen peroxide (H,Os), Determine the balneed reseton equation, 1346 A uel minture withthe molar analysis 70% CH, 2055 (CO. $8 O;, and 35; burns completely with 208 excess si Determine (a) the balanced ceation equation (0) the air-fuel ratio, both on 4 moe and mass Basi 187 A fuel micure with the moat analyis 814% CH, 38 CH, 6% GH, 05% CH, L15 N; burns com pletely with 205 exces arin a eacor operating st steady State. If the molar flow rate ofthe felis 01 kmh, etermine the mola Now rae of the sr in mol 134 A fuel mixture with the mola analysis of 20% CH, 408 4050 NH, bras completly with 30% of theoret cal oxygen Determine the balaced reaction equation, 189 Coal with the mas analysis 77.54% C,4286 H, L465 8, 772% O, 134% N, 7.66% noncombustible ssh burs completly with 208 of theoretical ai. Determine (a) the balanced reaction equation, {) the amount f SO, produced, in ke per ke of cost 10. CHAPTER REACTING MIXTURES AND COMBUSTION 140A co sample baa mass analysis of 71395 carbo, “Lim hydrogen (i), 531% onygen(0,), 1625 ntzogen (11% sur, nd the ress noncombustible ath. For Somplete combustion with 110% ofthe theoretical amount ‘tay datermine the air-fuel rato ona mas basis 1311 A sample of died feet manure is being tested for ‘se aba foc, The mass analysis ofthe sample s 27% tarbon, 559% hydrogen (Fh), 313% oxygen (03. 24% hivogen (N3)0.3% sulfur and 178% soncombusbe as, “The sample is burned completly with 120% of theoretical si Determine (a) the balanced reaction equation. (@) he air-fuel aio on 8 mass Basis 1412 A sample of dried Appanoose County col has 2 ‘mas anal Of 71.16 eatbon, $1 hydrogen (Hi), 90% tonygen (Oy), 14% nitopen(N), 5.8% sulfa andthe rest ‘noncombasie eh For complete combustion with be the ‘tial amount ofa, determine (a) the amount of $0: produced, in kg perk of so (b) the ai=Atletio.on a mass bass 1815 Dodscane (Cys) bars completely with 10% of theoretical ai. Determine (0) the sr-fuel eto on # moar and mass basis (6) the dew point temperature ofthe combustion prod= uss, in °C, when cooled at 1834 Butane (Cy) burns completely with 150% of theo Tetcal ait the combustion products are cooled att fim to temperature T, plot the amount of water vapor Condensed, in kino per kno of fel versus T ranging from 200 6PC. 1348 Ethylene (CH) bums completely with sir and the Sombuson products ae coled to temperature Tat 1 Sm. The tirfuel rato on a mass basis is AF (@) Determine for AF = 18 and T = TOF, the percent exces iran the amount of water vapor condensed, {nth per bol of fe {oy Plot the amount of water vapor condense, in b per Tol of fac, versus Trangng from 70 to 1OFF, for AP = 18, 20,25,30 1846 A gsscous fuel mixture with a molar analysis of 7256 (CHL, 95 Hy, 146 N, 240s, and 39% CO, burns completely ‘th moist iro form gaseous products! atm consisting 151 C0, HO, and Non If he dew pat temperature ofthe products i UC, determine the amount of water ‘Vapor present inthe combustion a, nmol pet km of fuel mintre 18.17 The gas driven off when low-grade coal is burned ‘wth nsuffcen a for complete combustion i kaowa as Droducer gx. A parealar produce gs has the following Solum sna 38% CH,, 01% ill, 48% COs S1IW Hy, 06% Op, 23.2% CO, andthe remainder; Determine, or complete combustion withthe theoretical amount of ai (a) the mola analysis ofthe dry prodvets of combustion. (©) the amount of water vapor condensed, inomol/omol of procera, ifthe products are cooled to TOF at ' constant presure of I atm. 18 Propane (CHL) enters « combustion chamber and ‘burns completely with 140% of theoretical ar entering at {UPC, 1 atm, 75% relative humidity, Obtain the balanced reaction equation, and determine the dew point tempera~ ture of the products, nC. 1319 Butane (C.Hl) enter a combustion chamber and thrms completely with 150% of theoretical ar entering at (GSP. Lam, 15% relative humidity. Deternine (a) the balanced reaction equation (0) the amount of water condensed, in fomol per mol of fae, ifthe combustion products are cooked t0 68°F st Tatm, 1320 Methane (CHL) enters a furnace and burns com pletely with 150% of theoretical ar ontring at 25°C, 945 Pa, 79% relative humidity. Determine (4) the balanced reaction equation {hy the dew point temperature of the combustion pro ts, in °C, a 94.5 Pa 1821 Pentane (CoH) burns completely with he sheoret- ‘alamountofairat 73°F, ae, 75% relative humility. De termine (a) the balanced reaction equation, (0) the dow point temperature ofthe combustion products (e) the amount of water condensed, in thm per mol of fek ifthe combustion producis are cooled to 75°F at Tatm 1222 liquid uel mintore that is 49% octane (CAH) and Gok decane (Call) by mas it bursed completly with 10 excess ae at 25°C, 1a, 88% relative humidity (a) Determine the equivalent hydrocarbon composition, Gy, of fuel that would have the sume earbon- hydrogen ratio on 8 mass basis asthe fuel mixture (0) Te the combustion products are cooled to 25°C ata presture of 1 tm, determine the amount of water ‘apor that condenses, a kg per kg of fel mixture. 1323. Hydrogen (H) enters «combustion chamber wth mass flow sate of 2 kg/h and burns with ar entering a HPC, stm wih a volumetric fow rate of 120 nh. Deter. mine the percent of theoretical air used 1824 Carbon burns with 05 theoretial air yielding COs, (CO, and N; oaly. Determine (a) the balanced reaction equation. (0) the sir-fue ratio on a mass bass (6) the analysis ofthe products on a molar basis Propane (CiH.) rests with 80% of theoretical sir to frm prods ineluding CO;, CO, 1,0, and Ny only: De= (a) the balanced reaction equation. (©) the ariel ratio on # mas Bi (6) the analy ofthe prt ona dry moar basis 1326 Dodecane (CH) enters an engine and buns with Sir to give products with the dy molar snalse of CO, 121% 00, 3.4% 0, 058%; Hh, 18% Ns, 825%. Deter” rine the arfueeatio on & molar bai 1827 The components of the exhaust gs of sarki tion engine tsinga fel mixture represented as Cll hive ary molar analysis of 87% CO, 895 CO, 03% O37 4H, 03% CH, and 781% N. Determine the equva- eos eat, 13.38 Decane (CyH) burns with 985 of theoretical le, ‘producing a yaseous misture of CO;, CO, H.O, and N Determine (2) the air-fuel tio on 2 moar basis (©) the analysis of the products on dry molar basis 1829. Butane (Ca) bums wt air gving products having ‘the dry mola eli 1.0% C03, LOR CO, 3.5% Os B43 Ny, Determine (2) the percent theoreti ait. () the dew poin! temperature of the combustion prod tun, in"C, at ba 1830 A natural gs with the volumetric analysis 97.3% CHL, 235 CO, 4% Ns bermed with ai ina furnace (ogive products having acy molar analyse of920% COs, £3845 O,, 064% CO, and the remainder, Determine (a) the percent theoreti air () the dew point temperature, in“, ofthe combustion products at 1 atm 1831 fuel baving an analysis ons massbasis of 85.9% 142% 10.1% ine matter barn wth to give prow cts wth a dry molar analysis af 12.29% CO: 376% Os 84088 Ny. Determine the air-fuel aio on a nae bas 1332 Liquid methanol (CHOH) buses with ir. Te prod ct gn is analyzed and te laboratory report ves only the lowing percentages on a dry molar bass: 71% CO, 24% CO, 0. CH,OH. Assuming tbe remaining compo nents consist of O; and N, determine (a) the percentages of Oyand Nin the dry moar analy (h) the percent exces ai, 1933 A fut oil with the mas analysis 87% C115 H, 148 5, 06% iner mater bums with 120% of theoretical it ‘The hydrogen and sulfur are completly oxdze, but 95% ofthe carbon is oxdied to CO, ad the eemtindsr to CO. (9) Determiae the balanced reaction equation, (hy) For the ©O and S0,, determine the amount in mol pet 10" kmol of combustion products (tat i, he mount in pars per milion) 15.64 Pentane (CH) burns with aso that a faction ‘of he earon is converted to CO,. Te remaiing carbon 'ppeats as CO. Thete is 0 free Oa the pris, De- ‘elo plo of the air-fuel ratios the percent oftheoreti- cal ai versus x for x rangi fom zero fo ut. 1235-For each of the following mixtures, determine the ‘uivalence ran andindint fhe mines lam och (2) 1 towel of methane (CH) and 8 mol of ait (©) 1g of ethane (CH, and 172 kg ofa. 1226. Octane (CH) enters an engine and burs with ae {o give preducs with the dry molar analy of CO 105 CO, Si; CH, 09%; Hy, 26%; 05, 038%; Ne, 7595, Determine the equivalence ratio, 1337 Methane (CHL) burns with ae to form produets con: sisting of COs, CO, HO and Ns only. Ifthe equivalence ‘ato 125, deteaniae the Balaneed reaction equation, ‘Applying the Fit Law o Reacting Systems TA38_ Ethane (CHL) at 7, 1 stn enters a combustion ‘hamber operating at steady state and burns completely withthe heoreial amount of air entcrag atthe sme ondtons. If the products ext at L'a, determine the rate of heat transfer fom the combustion chamber, In Bu per Tomo of fuel. Kinetic and potenti energy lets are negligible. 1839 Propane (CH) at 25°C 1 am enters a combustion ‘chamber operaling at stoady state and burns completly With the @eoretcal amount of air entering atthe sme

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