Advance Sol 1 PDF

1
AITS-FT-I-(Paper-1)-PCM(Sol)-JEE(Advanced)/16
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ANSWERS, HINTS & SOLUTIONS

FULL TEST I
(PAPER-1)
500 All India Ranks bagged by FIITJEE Students from All Programs have qualified in JEE (Advanced), 2015.
ALL INDIA TEST SERIES
Q. No. PHYSICS CHEMISTRY MATHEMATICS

1. C D B
2. C D C
3. B A D
4. B C A
5. B C D
6. C C A
7. B A C
8. C A, B, C A, B, D
9. A, B, C, D B A, B, C
10. A, B, C B, C B, C
11. A, B, C A, C A, B
12. A C C
13. B B D
14. C A D
15. D A B
16. A D A
(A) s, (B) pt, (A) r, (B) pt, (A) prt, (B) q,
1.
(C) q, (D) pr (C) qs, (D) qs (C) t, (D) s
(A) pqt, (B) prt, (A) pqs, (B) q, (A) qt, (B) q,
2.
(C) s, (D) qr (C) rt, (D) q (C) prs, (D) t
1. 3 4 1
2. 5 7 2
3. 9 3 1
4. 9 3 5
5. 2 2 7
6. 4 3 2
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2
Physics PART I
SECTION A
1. C
1
tan1 tan
e
vertical component after collision eucos
& Horizontal component u sin
u sin 1
tan tan1 tan
eucos e
2. C
Zero Ring
T f 2a
T
TR fR 2R 2
a
a R f
f 0.
3. B
V t /RC1 V
I1 e & I2 e t /RC2
R R
t 1 1
I1
eR C1 C2
I2
t
I1
e RC1
I2
4. B
1 1
f , f 50
2 LC 2 LC / K
2
f 50 50 100
K K 1 2 1
f f 10 4
K 1.01
5. B B
r1 2R sin30o , r2 2R sin 60o R 3 R
A
i i
BD B AC BCB 0 sin 60o 0 sin30 o
4 r1 4 r2 i i r2 r1
0 i o
30 30o
BD 30o
4 R 3 30 o
C R R D
6. C
V V V
Beats
4 4 4
V

4 2
3
7. B
3
sin60o sin90o
2
3 3
,
2 2
3 3

4
8. C
13.6 10.2 3.4eV
1st collision
& 3.4 15 11.6eV 2nd collision.
9. A, B, C, D
1
V
n
1
P.E.
r
T r 3/ 2
1
T.E.
r
10. A, B, C
2 2
Vs2 3 8 4 25 Vs 5 volt
Vs
Z 5
I
VR 3 1 R R 3
R 3
P.F. 0.6
Z 5
VL VC I lags V.
11. A, B, C
1 1 1 v v
1
f v u f u
since m is positive in the graph,
v v
m
u u
v v
m 1
f u
1
int ercept on m axis 1 & tan
f
12. A
V
, OP x 2 y 2
R
origin is ins tan taneous centre of rotation
V 2
VP r OP x y2
R
4
13. B a R 2a
a R
2 ac
V V2
ac 2R R
R R anet
2a
ac
tan 1
2a
45o
14. C
Q 300
Thermal heat capacity, C 15J / o C
T 20
15. D
Q 300
Specific heat capacity, S 600J / kg o C
m T 0.025 20
16. A
Molar heat capacity
Q 300

nT 25
20
50
30J / mol o C
SECTION B
1. (A s) (B p, t) (C q) (D p, r)
In wrist watch spring force is not dependent on gravity.
m
T 2
K
2. (A p, q, t) (B p, r, t) (C s) (D q, r)
In nuclear reactions energy, charge, mass and momentum remain conserved.
SECTION C
1. 3
2
for Rmax , 45o Hmax

20
sin2 45o 10m
2 10
Hmax allowed 5m,
2
20 sin2
5 30o
2 10
2
20 sin60o
Rmax m 20 3m.
10
2. 5
1

Mcylinder R2 3R . Icylinder 2
3R3 R2
2 22
Msphere R3 , Isphere R3 R2
3 53
29 5
Iremaining portion Icylinder 2 Isphere R .
30
5
3. 9 18 m/s
18 sin 30o
18 sin30o r 1
18cos 30o
9 m / s.
1m
60o
0.5m
4. 9
1 1 1

F f1 f2

1 1 1 1 2 1 1
1 1
24 4 20 20 4 20 20

3 3
5
1 2 .
9
5. 2
2
V 200 V 2 200
I 2.5A & P 500 watt
R 80 R 80
When the wire is divided into two equal parts and connected in parallel we get maximum power.
Re sis tance of each part 40
Imax 5A
2
V2 200
Pmax 2000W 2kw.
Req 20
6. 4
Q Q
VAP , VPB
3 6
Q Q
12 Q 24C
3 6
24
VAP 8
3
VA VP 8 VP 4volt.
6
Chemistry PART II
SECTION A
1. D
H
H H
B B
H
H H
H CH3 CH3
B 2 H6 B B
methylation
CH3
CH3
H
2. D
H
+
OH OH +
CH2 H
H+ ring. exp
+
-H2 O
HO HO
HO HO
OH HO
OH OH
+
H /excess
similar repetation
HO
HO
3. A
At nodal surface, = 0
2 2
r = 1
z z
4. C
+2
Co ordination no of Fe in D is 6
-
+
- Na +2
Fe (a sandwhich compound)
C
-
7
5. C
O
O
Zn(Hg) SOCl2
AlCl3 HCl
+ O
HO HO Cl O
O
A B O
O C
AlCl3
Br
NaBH4
NBS/CCl4 H2SO4

F E D
G OH O
ONa
OH
heat
6. C
O O O
H -
OH H OH
(a) -
+ OH
-
O-D D - OD D - OD
O O DO- O O
H
H -
- D D
(b)
-
DO
-
O O O
D O D D
D D H D - OD
D
D
D D
D
D H H
DO- DO - D -
OD
O O
O D D
D D D D
O-D D
D D
H
-
- D - OD
D D D D
D
DO - D
O O
D D
D D
D Repeat last two step
D
D D
D D D D D
D
8
O O O
H
-
(d) H OH
OH -
OH
H HO - H
7. A
Synergic bonding.
8. A, B, C
K2 Ho T2 T1
log K1 & K 2 are eq. cons tan t
K1 2.303R T1T2
K2 Ea T2 T1
log K1 & K 2 are rate cons tan t
K1 2.303R T1T2
9. B
H3C Me CH3
+
H3C N -
OH H2C
CH3
H3C Me CH3
(Major product)
Due to greater probability of losing -H (9 : 3 ratio).

10. B, C
(b) conjugate base of H2PO4 is HPO24
1
(c) pH of 0.1 M NaCl (aqueous solution) = pK w
2
11. A, C
A 3 3e Al
4.5
Number of moles of Al produced 0.166
27
Number of moles of electrons used 3 0.166
1
H e H2
2
1
Number of moles of H2 produced 3 0.166
2
Volume of H2 produced 1.5 0.166 22.4 5.57 5.6
12. C
2nd step is r.d.s. in sulphonation reaction.
13. B
2nd step is fast step in nitration.
9
14. A
a
P V b RT
V
on converting into virial equation from, we get
a
b 2 2 3
PV RT RT b b ....... to higher power of n (i)
V 2 4
V V

For Boyles temperature, 2nd virial co-efficient becomes zero
a
b
RT 2
a
TB
Rb
a
TB2
RB
2a
Ti Ti 2TB2
Rb
15. A
Let Boyles temperature, TB'
a
TB
Rb
8a a
TB' 2 2TB
R 2b Rb
16. D
b2 = 0.04
b = 0.2 lit/mol
Vreal = 4 22.4 + 4 0.2 = 90.4 lit
SECTION B
1. A r ,B p,t , C q,s D q,s .
(A) Sic covalent carbide (Not hydrolysed)
(B) Al4 C3 12H2O 4Al OH3 3CH4
(C) Cal2 2H2 O Ca OH2 H C C H
(D) Mg2 C3 4H2 O 2Mg OH 2 CH3 C CH
10
2. A p,q,s , B q , C r,t D q .
Al2 SO4 3 2Al3 3SO 4
0.2M 0.3M
3 3
AlPO 4 Al PO 4
0.1M 0.1M
Urea
Urea
0.1M
MgCl2 Mg2 2Cl
0.1M 0.2M
SECTION C
1. 4
Based on fact
2. 7
OH
-
B
O O
+
2Na HO B O B OH 8H2O
O -
O
B
OH
3. 3
OHC CHO CHO
, ,
Cl NO2 C
N
4. 3
OCH3 NH2
OCH3
, ,
H3CO OCH3 OCH3
H3CO
11
5. 2
1 1 100
t 99 n100; t 90 n
K K 10
t 99 n100 2
2
t 90 n10 1
hence x 2
6. 3
H H
S O
H Cl
C C C
, , Cl
H
0
O
S
H
H
0 0
12
Mathematics PART III

SECTION A
1. B Q

PQ r 2 1 2r cos r 2 1 r
3

& AT r 2 1 2r cos
Where 'Q ' is the angle between
3 P
OA and OT.
2 2 A
now, PQ 4 AT
2

1 r r 4 r 1 2r cos 2

2 2
3r r 3 3r r 3
cos 1 1; r 0
8r 8r
7 13 7 13 T
r , .
6 6
2. C
Here two balls are drawn and the result is known that the two balls are white, therefore Bayess
theorem should be used.
1
.1
Required probability = 4 1

1 1 6 1 3 1 1 2
.1 . . .
4 4 10 4 10 4 10
3. D
Let Q x f x g x in x0 x
By LMVT,
Q x Q x 0 Q' x Q' x 0 for some C x 0 ,x
Q x 0 0, Q' C f ' C g' C 0
Q x Q x0 Q x
F' C g' C x x0 0
Q x 0 f x g x .
4. A
A AP = 23
(-3, 4)
5
5
13
P
13
5. D
5 2n 5
Sn
4 2 n 1 n 2
5
K
4
6. A
Equation of tan gent at 'P ' is
Y y m X x
y mx
Now, x
1 m2
y 2 x 2 dy
putting y vx
2xy dx
Solving Differential equation
x 2 y 2 Cx
It passes through 1,2 C 5
Equation of curve x 2 y 2 5x 0
7. C
x cos y sin
T 1
3 2
x 0, y 2cos ec,
chord A 'P;
2 sin
y x 3
3 cos 1
2 sin
x 0, OM
1
cos
2
Now, OQ2 MQ2 OQ2 OQ OM
2 OM OQ OM2
OM 2OQ OM
2 sin 4 2 sin

cos 1 sin 1 cos
2sin 4 4 cos 2 sin 2
2
1 cos sin
4 sin 2 2cos 1 cos2
2
1 cos sin
4
8. A, B, D
f x 0 x 3 x 2 x 1 x 2 x 1 2 0
2
x 3 1
x2 x 1
-1 1
-2
2
x3
14
9. A, B, C
Take f x x and g x x and proceed.
10. B, C
cos 2x 1
I tan1 dx tan tan x dx
1 sin 2x 4

x dx
4
x2 x2
I x C gx x .
4 2 4 2
11. A, B

2 4 4 a2 1
, 1 a, 1 a
2 y
f 1 a 0 & f 1 a 0
1
a ,1
4
12. C
The value of K1 & K2 decide the opening of parabola
A max Area OBCO
A min Area OACO
13. D
Y 1
c K1
4
A
1
B K1
8
X' o (1,0) (2, 0) X
Y' 1 K2 = -1
K2
4
14. D
Area BFEC Area ABC AFE A
or AOB BOC COA AFE
sA
co
2R
1 2 2A
R sin 2C sin 2A sin 2B sin 2A F E
2
1 H O
R2 sin2B sin 2C
2
B C
15
15. B
AE R, AF 2Rcos A
EF R
16. A

AFE
3
AFE is equilateral
2
R 3 9
sum of square of altitudes 3 R2 .
2 4

SECTION B
1. (A p, r, t) (B q) (C t) (D s)

A tan 1 2 3 4 0 1 2 3 4 2n
2
B x 2 4 t 2 2, TR is diameter 6
2
Area of circle TR 9
4
C 6
2
D y A yB yC
2
3 3
2. (A
q, t) (B
q) (C
p, r, s) (D
t)
SECTION C
1. 1
D.C' s of OP are, Z
1 1 1 C (o, o, a)
, , M(a, o, a)
3 3 3
1 1 1
D.C' s of AL , ,
3 3 3 L
(o, a, a) P (a, a, a)
1 1 1
D.C's of BM , ,
3 3 3 A (a, o, o)
O X
1 1 1
D.C' s of CN , ,
3 3 3 B
(o, a, o) N (a, a, o)
Let D.C' s of required line be ,m,n
mn m n
Y
cos ,cos
3 3
mn mn
cosy ,cos
3 3
4 2 4
Hence, cos cos cos y cos2
2 2 2
3

m2 n 2
3

2 2 2 2 4
cos cos cos y cos 1.
3
16
2. 2
The gives equation is x 1 y 2 4 4
XY 4
A P t1 t
Equationof tan gent is,
Q B
4 4
Y 2 x t
t t
8
A 0, & B 2t1 0
t
1 8
Area 2t 8
2 t
4K 8 k 2.
3. 1
2 2
CE a b 2 3 25

DE C2 16 16
CE
1
DE
4. 5
10 1 1 1 1
f K 1 x dx f x dx f x 1 dx.......... f x 9
K 1 0 0 0 0
putting x 1 t, x 2 t............ x 9 t
1 2 3 10
f x dx f x dx f x dx.......... f x dx
0 1 2 9
10
f x dx 5.
0
5. 7
Every ball have two options
4 balls can be put in 24 ways.
Arrangement among themselves in 2!
1
24 23
2!
But, above count also includes the one case in which all the balls are put in one box,
Required number of ways = 23 1 = 7.
6. 2
3 3 3
K 1 K 2 K 3
K 1 K 2 K 3 0
1 1 1
K 2 K 2

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ANSWERS, HINTS & SOLUTIONS

ALL INDIA TEST SERIES

Q. No. PHYSICS CHEMISTRY MATHEMATICS

for Rmax , 45o Hmax

Due to greater probability of losing -H (9 : 3 ratio).

2nd step is fast step in nitration.

Let Boyles temperature, TB'

(C) Cal2 2H2 O Ca OH2 H C C H

(D) Mg2 C3 4H2 O 2Mg OH 2 CH3 C CH

Mathematics PART III

X' o (1,0) (2, 0) X

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