Armor (biological)

https://foxsuperpowerlist.com/armor-biological/

Armor (biological) The armor is alive and/or composed of organic matter.

Spawn (Image) has armor that mutated in First Metamorphosis (Spawn V1 #41).

Venom (Marvel) has armor that is alive but can corrupt the user.
 Armor (biological)
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X-O Manowar (Valiant) has an armor that looks like a machine on the outside but is
clearly biologically based on the inside (X-O Manowar Database #1).
 Armor (biological)
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In 4001 AD: X-O Manowar, the X-O Manowar biological armor has been grown into a
much larger armor.

Cannonbolt (Ben 10) is an alien with natural armor.

 Armor (biological)
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Asheiran Armor is made up of micro crustaceans (Dragon Magazine Annual 1).

 Armor (biological)
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Rabak Armor is made of wood (Dragon Magazine Annual 1).

Sindar Web Armor is made of spider webs (Dragon Magazine Annual 1).
 Armor (biological)
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Sul Armor is made out of living insects (Dragon Magazine Annual 1).
 Armor (biological)
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Taboo (Wildstorm) has an organically based armor (WildCATs Adventures

Sourcebook).