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Chemistry Johor Trial SPM 2011 Paper 1, 2, 3 [myschoolchildren.

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4541tl
Kimia
Kertas1
Sept
24fi
1%jam

JABATANPELAJARAN
NEGERI
JOHOR

PEPERIKSMN
PERCUBAAN
SPM2011

KIMIA

Kertas1

Satujamlimabelasminit

JANGANBUKAKERTASSOALANINISEHINGGA
DIBERITAHU

1. Kerfassoalanini adalahdalamdwibahasa.
2. Soa/andalambahasalnggerismendahului soalanyang sepadan
dalambahasaMelayu.
3. Calondikehendakimembaca maklumat
dihalamanbelakangkertas
soalanini.

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suuT 4*1/,1

ofthefollowingreleasesheatto thesurrounding?
1 Vrrhich
Antarayang Mrikut,yangmanakahmembebaskan habake persekitann?
A Addacidto alkali
TambahasidRepadaalkali
B Heata carbonate
salt
Panaskansatugaramkarbonat
C someammonium
Dissolve saltin water
Larutkansedikitgaramammonium di dalamair
oarbonate
D Adddiluteacldto sodiumhydrogen
Tambahasidcalrkepadanaftiumlrydrqenkarfunat

2 Nametheprocessof soappreparation.
Namakanprosspenyediaan eahun.

A Dehydration
Pendehidratan
Sulphonation
Pengsulfonan
Saponification
SaponflTkast
Polymerisation
Pempotirnenn

proron

l/Vhoproposedthe abovemodel?
Siapakah modeldi atas?
yang mencadangkan

A ErnestRutherford
B JamesChadurick
C J.JThomson
D NeilsBohr

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4 The followingequationrepresentsa reaction.


Persamaanberikut mewakili satu tindak balas.

+ N2tu;
3H21d 2NHqsy

What is the relativemolecularmass of the product?


[Relativeatomicmass .'H=l; N=!4 ]
Apakah jisim molekul relatif bagi hasil tersebut?
[Jisim atom relative: H=l; N=l4 ]

A2

817

c28
D34

5 \/V}richof the followingare the specialcharacteristicsof transitionelements?


Antara yang berikut, yang manakah merupakan ciri istimewa bagi togam
peralihan?

I Formcolouredcompounds
Membentuk sebatian benuarna

ll Can be used as catalyst


Boleh digunakan sebagaimangkin

lll Have low meltingpoint


Mempunyaitakat lebur yang rendah

lV Haveonly one oxidationnumber


Mempunyai satu nombor pengoksidaansahaja

A lonly
I sahaja

B land llonly
I dan ll sahaja

C l, ll and lll only


I, ll dan tll sahaja

D l, ll, lll and lVonly


I,ll,lll dan lV sahaja

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Diagram t
Rajaht
Diagram1 showsthe numberof atomsin a molecute.
Whichof the followingcould
bethemolecule?
Rajah1 menunjul<Ranbilanganatamdalam satumateku!.Antarc yang berikut,
yangmanakah mungkinmolekulitu?
A Carbondioxide
Katbondioksida
B Ammonia
Ammonia
C Chlorine
Korin
D Water
Air

Whichof thefollowingis anelectrolyte?


Antarayang berikut,yangmanakahmerupakan
eteWrolit?
A Copper{ll} sulphatesolution
Larutan
kuprum(ll) suffat
B Moltennaphthalene
Lebunnnaftalena
C Glucosesolution
Larutanglukosa
D Zincmetal
Lqam zink

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Diagram2 shovrsthe pH valuesfor solutionP, Q, R and S with the same concentration.


Rajah 2 menunjukkan nilai pH bagi larutan larutan P, Q, R, dan S dengan kepekatanyang
sama.

pH
scale

Diagram2
Rajah2

\Mrat are the possiblesolutionsof P, Q, R and S?


Apakah larutan yang mungkin bagiP, Q, R dan S?

Ethanoic acid Sulphuric acid Sodium hydroxide Sodium chloride


Asid etanoik Asid suffurtk Natrium hidroksida Natrium klorida
A P o R S

B P o S R

c o P R S

D o P S R

\Altrichof the followingsalts can be preparedby precipitationreaction?


Antara garam yang berikut, yang manakah boleh disediakan melalui tindak halas
pemendakan?

A Bariumsulphate
Barium sulfat

B Sodiumchloride
Natrium kloida

C Aluminium nitrate
Aluminium nitrat

D Potassiumcarbonate
Kalium karbonat

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10 AlloyX is madeby mixingironwithcarbon,chromium


andnickel.what is X?
AloiX diperbuatdenganmencampurkanbesidenganRarbon, kromiumdannikel.
ApakahX?

A Steel
Keluli

B Pewter
Piuter

C Bronze
Gangsa

D Stainlesssteel
Kelulitahan karat

11 \Mich of the followingdoes not affectrate of reaction?


Antara yang berikut, yang manakah tidak mempengaruhikadar tindak balas ?

A Total surfacearea of reactant


Jumlah luaspermukaan bahan tindak balas

B Concentrationof solution
Kepekatan larutan

C Presenceof catalyst
Kehadiran mangkin

D Volumeof solution
lsipadu larutan

12 Wtich of the followingorganiccompoundwill undergohydrogenation reaction?


Antara yang berikut, yang manakah sebatianorganik yang akan mengalami tindak
balaspenghidrogenan?

A Propene
Propena

B Propane
Propana

C Propanol
Propanot

D Propanoicacid
Asid propanoik

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13 \A/lrich
of the followingexplainsan oxidationprocess?
Antarayang herikut,yang manakahmenerangkanprosespengoksidaan?

Loss of oxygen
Kehilangan oksigen

Gain of electrons
Penerimaan electron

Loss of hydrogen
Kehilangan hidrogen

Decreasein oxidationnumber
N ombor pengol<sidaan berkurang

1 4 Pickled mango is prepared by soakingmango in vinegar. What typ of food


additiveis vinegar?
Jeruk mangga disediakandengan merendambuah 'mangga di dalam cuka.
Apakahjenisbahantambahmakananbagicuka?

Dyes
Pewama

Thickener
Pemekat

Antioxidant
Pengantioksidd

Preservative
Pengawet

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15 The thermochemicalequationfor the decompositionof calciumcarbonate,CaCO3


is as follovus:
Persamaan termokimia bagi penguraian kalsium karbonat, caco3 adatah seperti
berikut:

CaCO3 + CaO + COz AH=+l7gkJ

wrich of the followingenergyleveldiagramrepresentsthe equation?


yang berikut, yang manakah gambarajah aras tenagi mewakiti persamaan
lntlra
itu ?

A
trnergy
Tenaga
= +178
CaO + COz

B
Energy
Tenaga
= +178
CaC03

c
Energy
Tenaga

AH = +178

D
Energy
Tenaga

AH = +178

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to
ill

Diagram3
Rajah3

Whatare thethreestatesof matter?


Apakahkeadaanfizikaljirimdi atas?

tl ill
A Gas Liquid Solid
Gas Cecair Pepejal

Solid Liquid Gas


Pepejal Cecair Gas

Liquid Solid Gas


Cecair Pepejal Gas

D Liquid Gas Solid


Cecair Gas Pepejal

17 Whichof the substance


belowcontains
the samenumberof atomsas in one mole
gas?
of chlorine
Antarabahan yang berikut,yang manakahmengandungibilanganatom yang
samadengansatumol gas klorin?

A 1 molneon
I rnolneon

Tzmolsodium
% mol natrium

T"mol carlcondioxide
% mol karbon dioksida

D 1 mol nitrogendioxide
1 mol nitrogen dioksida

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18

W Y z

Diagram4
Rajah4
Diagram 4 shovus parts of the periodic Tabre of Erements.
Tle symbolsw x, y andz are notthe actuarsymborsof the erements.
\Mich of the followingshoursthe correctarrangement
of elementsw, X, y and Z in
orderof increasingatomicsize?

laian + menuniukkansebahagianJadua! BerkalalJnsur.simbot-simbolw, x, y dan


Z tidakmewakilisimbo!sebenir unsur.
Altara yang berikut,yang manakahmewakilisusunanyang betut pertambahan
atombagi unsur-unsurW,X, y dan Z ? saiz

A W,X,Y,Z

B X,Y,W,Z

C Y, Z, X,W

D Z,Y,WX

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19

Diagram5
Rajah5

In Diagram5, substanceX lightsupthe bulbin the moltenstate.\Mich statement


bestexplainsthe observation?
Dalam Rajah5, bahanX menyalakanmerrtotdalamkeadanleburan.Pemyataan
yangmanakahpalingbaikmenerangkan pemerhatiantersebut?

X consistsof ions
X terdiri daripada ion-ion.

X consistsof molecules
X terdiri daripada molekul-mole4ul

X has freely movingions


X mempunyaiion-ion bebas bergerak

X has ions in fixed position


X mempunyaiion-ion dalam kedudukan tetap

20 A studentconstructeda chemicalcell using a copper rod, a zinc rod, copper (ll)


sulphate solution and connectingwires. \A/hichof the following will act as the
positiveterminal?
Seorang pelajar membina safu se/ kimia menggunakan rod kuprum, rod zink,
larutan kuprum (ll) sulfat dan wayar penyambung. Antara yang berikut, yang
m an akah akan m eniadi terminal positif?

Copperrod
Rod kuprum

Zinc rod
Rod zink

Connectingwires
Wayar penyambung

Coppe(ll) sulphatesolution
Larutan kuprum (ll) sulfat

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21 Diagram6 shouvsthe set-upof apparatusfor the titrationof 25 cm3 1.0 mol drn3sodium
hydroxidesolutionwith 0.5 mol dm-3of sulphuricacid.
Rajah 6 menunjut<Ransusunan radas bagi titratan 25 cmslarutan natrium hictroksida1.0
^
mol dm' dengan asid sulfurik 0.5 moldm'".

0.5moldm-3 of sulphuric
acid
0.5 mol dm'"asidsulfurik

25 cm31.0mol dm-3sodiumhydroxide
solution+ phenolphthalein
25 cm' larutannatium hidroksida1.0 mol dm'
3 + feno!ftalein

Diagrarn6
Rajah 6

What is the volume of 0.5 mol dm-3of sulphuricacid solutionrequiredto completely


neutralize25 cm31.0 mol dm-3sodiumhydroxidesolutions?
Berapakah isi padu 0.5 mol dm' asid sulfurik diperlukan untuk meneutralkanlengkap 25
cm3 larutannatrium hidroksida1.0 mol drn?

A 12.50cm3

B 25.00 cm3

C 50.00 cm3

D 75.50 cm3

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22 Wftich of the followingions form white precipitatethat dissolvesin excessamrnonia


solution?
Antara ion-ion berikut, yang manakah menghasilkanmendakan putih yang larut
dalam larutan ammonia berlebihan?

A Mgt*
B AI3*
c znz*
D Pb2*

23 The equationbelowshowsthe formationof a compositematerialfrom its original


component.
Persamaandi bawah menunjukkanpembentukan satu bahan komposit daripada
komponen asalnya.

Plastic + Glass fibres Fibreglass


Plastik + Gentian kaca --| Kaca gentian

Why is fibre glass betterthan common plastic?


Kenapakah kaca gentian lebih baik daripada plastik biasa?

A Hightensile strength
Kekuatan regangan tinggi

B Resistantto corrosion
Tahan kakisan

C Able to withstandheat
Tahan haba

D Good conductorof electricity


Konduktor elektrik yang baik

24 Whichof the followingwill makemeat last longer?


Antara yang berikut, yang manakah boleh menyebabkan daging tahan tebih lama?

A Boilthe meatfor an hour.


Mendidihkan daging untuk satujam.

B Dry the meat under the sun


Mengeringkan daging di bawah matahari

C Keep the meat in a refrigerator.


Menyimpan daging di dalam petisejuk

D Fry the meat and keep intoa container.


Menggorengkan dagingdan menyimpandidalam bekas,

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25 The equationbelow shovvsa reactionof alkene.


Persamaandi bawahmenunjukkan tindak balasalkena.

CH3CH=CH2+ Y +CH3CH2CH2Br

Which of the followingis Y?


Antara yang berikut, yang manakah Y?

A Bromine,Br2
Bromin, Br2

B Hydrogenbromide,HBr
Hidrogen bromida, HBr

C Sodiumbromide,NaBr
Natrium bromida, NaBr

D Magnesiumbromide,MgBr2
M agnesium bromida, MgBr2

26 The followingshows an ionic equation.


Yang berikut menunjukkan suatu persamaanion.

P 1s;+ Qtn("d * P2*("0 + Q

Based on the equation,which of the followingis true?


Berdasarkanpersamaan tersebut,yang manakah benar?

A P is oxidised.
P dioksidakan.

B P2*is oxidised.
f dioksidakan.

C Qz* is a reducingagent.
Q2*adalahagen peneurunan.

D Q2' donateselectrons.
Q2* menderna elektron.

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27 Diagram7 showsthe resultsobtainedwhen metalX is added intosolutionA.


Rajah 7 menunjukkan keputusanyang diperoleh apabila logam X ditambah ke
dalam larutan A.

SolutionA before addingmetalX


Larutan A sebelum ditambahkanlogam X

ffi
SolutionA after addingmetalX
Larutan 4 se/epas ditamhahkan logam
Diagram7
Rajah 7

Which of the followingexplainsthe reaction?


Antara yang berikut, yang manakah menjelasRantindak balas tersebut?

A Displacementand endothermic
Penyesaran dan endotermik

B Displacementand exothermic
Penyesaran dan eksotermik

C Precipitation
and endothermic
P emendakan dan endotermik

D Precipitation
and exothermic
Pemendakan dan eksotermik

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tl nl IV
o
o-
tl
s- o-
CHsf ( C H z ) r r t Na*
tl
o

Diagram 8
RaiahI

partin sodiumdodecylsulphate?
Basedon Diagram8 , whichis the hydrophilic
BerdasarkanRajah8, yangmanakahbahagianhidrofilikdalamnatium dodekil
sulfat?

AI

Bll

c lll

DIV

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29 Chlorine-35andchlorine-37
arehruoisotopesof chlorine.\Mratarethe differences
in theseisotopes?
Kortn4l dan klorin3T adalah dua isotopklorin. Apakahperhezaandi antara
isotopisotopini?

I Protonnumber
Nomborproton

ll Nucleon
number
Nombornucleon

lll Physicalproperties
Sifat-sifatfizikal

lV Chemicalproperties
Sifat-sifatkimia

A landll
I dan ll

B l l a n dl l l
ll dan lll

C landlll
t danttt

D l l a n dl V
ll danlV

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30 Diagram9 showsthe set-upof apparatusto determinethe empiricalformulaof


metaloxide.
n/1h 9 menuniukkan susunan radas untuk menentukanformula empirik bagi
ol<sida
logam.

MethodI Methodll
Kaedah I Kaedah ll
Crucible Chemicalsubstance
tid Dryhydrogen BahanKimia
Penufup Chemical gas
mangkuk substance Gashidrogen
p'jar Bahan kering
kimia

Diagram9
Rajah9

\Nhichof thefollowingis the correctmatchfor MethodI and Methodll?


Antarapadananbeikut, yang manakahbetulunfukKaedahI danlt?

MethodI Methodll
KaedahI \aedah ll

A Copper(ll)oxide Lead (ll) oxide


Kuprum(ll) oksida plumbum (ll) oksida

B Lead(ll)oxide Copper(ll) oxide


Plumbum(ll) oksida Kuprum (ll) oksida

C Magnesiumoxide Lead (ll) oxide


Magnesiumoksida Plumbum (ll) oksida

D Copper(ll)oxide Magnesiumoxide
Kuprum(ll) oksida Magnesiumoksida

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31

X
Y

Diagram10
Rajah 10

An atom of element X reacts with element Y to form a compound.\A/hatis the


formulaof the compoundformed?
satu atom unsur x beftindak balas dengan unsur y menghasilkan safu
sebatian.Apakahformula bagi sebatianyang terbentuk?

AXY
B X,Y
G XYZ

D XzYz

32 Manycovalentcompoundsare usedas solvents.\fthichof the followingis not a


solventfor paint?
Kebanyakansebatiankovalen digunakansebagaipelarut. Antara yang berikut,
yangmanakahhukan pelarutuntukcat?

A Ether
Eter

B Water
Air

C Ethanol
Etanol

D Turpentine
Turpentin

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33 Diagram11 showsthe apparatusset-upIn flrs elec{roplating


of an iron spoonwith
silver.
Raiah 11 manuniul<katsosunanradasuntuk menyadursatu sudu fusi dengan
aryentum.

Silver foil /
kepinganargenttmt
SolutionYllarutan

Diagram 11
Rajil tl
IMratcouldbe solutionY?
larutany?
Antanyangbeikut,yang manakah
A lron(ll) sulphate
Ferum(ll) sultat
B lron(ll) chloride
Ferum(ll) klofda
C Sllverchtoride
Argentum klafida
D Silvernitrate
Aryentunnttrct

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34 pH = 1.0 pH= 5.0

1.0 moldm-3
H
t-----t 1.0 moldm-r
hydrochloricacid
t:_':F ethanoicacid

Diagram12
Rajah 12

In Diagram12, the pH value of ethanoicacid is higherthan the hydrochloricacid.Which


of the following,explainthe difference?
Dalam Rajah 12, nilai pH asid etanoik lebih tinggidaripada asid hidroklorik. Antara yang
berikut, yang manakah menerangkan perbezaan tersebut?

A Ethanoicacid has low concentrationof H*


Asidetarnik mempunyaiRepekatanlf yang ren&h

B Ethanoicacid is a strongacid
Asid etanoik iatah asid kuat

C Hydrochloric acid is a weak acid


Asid hidroklorik ialah asid lemalt

D Hydrochloricacid has highconcentration


of OH
Asid hidroklorikmempunyaikepekatanOH-yangtinggi

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35 Diagram13showsa seriesof reactionthatinvolves


compound G.
Rajah13 menunjukkansatusii tindakbalasyang metibatkansebatianG

Added with dilute hydrochloricacid and


filtered.
Tambah asid hidroklorik cair dan dituras

Addedwithammoniasolution
untilexcess.
Tambahlarutanammonra
sehinggaberlebihan

Whiteprecipitate
dissolves
Mendakan putihmelarut

Diagram 13
Rajah 13
G is a mixtureof trrrcsalts.Amongthefollowing,
whatis G?
G adalahcampuranduagaram.ApakahG?
A Lead(ll) nitrateandzinccarbonate
Plumbum(ll)nitrat dan zink karbonat

B Lead(ll)nitrateandaluminium nitrate
Plumbum(ll)nitrat dan aluminiumnitrat

C Silversulphate
andcopper(ll)carbonate
Argentumsulfatdan kuprum(ll)karbonat

D Magnesiumsulphateandlead(ll)carbonate
Magnesiumsulfatdanplumbum(il)kahonat

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36 Diagrum14shorrns
a camera,
Rajaht4 menunjukkansejeniskarnora.

Quarts
lens
Kantakuarba

Diagram14
Rajaht4

T/haJtypeof glassis usedto makethequartztens?


Apakahjeniskaeayangdigunakanuntukmembuatkantakuartza?
A Fusedglass
Kacasilikatedakur
Sodalimegfass
Kacasodakapur
Borosilicate
glass
Kacabonsilikat
Leadcrystalglase
Kacaplumbum

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37 A student carried out an experimentto determinethe rate of reaction behoeen


calcium carbonateand dilute hydrochloricacid. The volume of carbon dioxidegas
collectedat intervalsof 0.5 minutesis recordedin Table 1.
Seorang pelajar menjalankan eksperimen untuk menentukan kadar tindak balas
antara kalsium karbonat dan asid hidroklorikcair. lsipadu gas karbon diot<siJa
yiig
terkumpulpada selang masa 0.Sminit direkod dalam Jadial I.

Time (min) 0 0 . 5 1 . 0 1 . 5 2.0 2.5 3.0 3.5 4.0 4.5 5 . 0


Masa (minl
sas 0 2 7 46 59 70 79 86 92 95 95 95
F#i""orco2
f'#r,*sasco2
Table1
Jadual 1

What is the averagerate of reactionin the third minute?


Apakah kadar tindak balaspurata dalam minit ketiga ?

A 28.67cmsmin-1

.B 23.75 cm3min'1

C 16 cm3min'1

D 14 cm3min-

38 Propane,CgHaundergoes
completecombustion
to produce carbon dioxide, COz
andwater,H2O.
Propana, cslla mengalami pembakaran lengkap untuk menghasilkan karbon
dioksida, COzdan air, H2O.

calculate the volume of carbon dioxide producedwhen 0.5 mol propane burns
completelyat roomtemperature.
[Molarvolume = 24 dmsmol'latroomtemperature]
Kira isipadu gas karbon diaksidayang terhasil ipabila 0.5 mo! propana terbakar
dengan lengkap pada suhu bilik
fisipadumolar= 24 dm3mollpadasuhu bilik]
I
A 72.0 dm3

B 36.0 dm3

C 24.0 dm3

D 1 2 . 5d m 3

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SULIT 454111

39 \Nhat is the oxidationnumberof X in X,.'ot?-ion?


Apakahnombor pengoksidaanbagiX dalam ion XrOrz-?

A+3

B+4

C+5

D+6

40 Table2 shovrrs
the temperature
readingsfor the reactionbetween25 cm' of 0.1
moldm3hydrochloric acidand25 cm3of 0.1moldm-3 sodiumhydroxidesolution.

Jadual 2 menunjukkanbacaan suhu untu? tindak batasdi antara 25 cm3 asid


hidroktorik0.1 mol dm'3 dan 25 cmr larutannatriumhidroksida0.1 mol dmn.

Averageinitialtemperature beforebothsolutionsare mixed


Suhu awaI kedua-dua larutan sebelum dicampurkan 300c

Highest
temperature afterbothsolutions
aremixed
Suhuteftinggilarutanse/epasdicampurkan 43"C

Table2
Jadual 2

Calculatethe heat producedfrom the reaction.


Krakan haba yang terhasil daripada tindak balas tersebut.

A 25cm3 x 4.2J g-1oC-l x 13oC

B 25cm3 x 4.2J g-1oC-l x 43oC

c 50cm3 x 4.2J g-1oc-1x 13oC

D 50cm3 x 4.2J n-l og-r x 43oC

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SUUT 4547t1

41 Diagram15 shovrethe molecularformulaof an organiccompound.


Rajah 15 menunjukkan formula moteku!hagi suafu sebatiai organik

csHz
coo czHs

Diagram 15
. Rajah t5
Thecompoundis an ingredient jam.l/r/tratis the functionof the
in makingpineapple
compound?
sebatian itu adalah suafu bahandalam penyediaanjem nenas. Apakahfungsi
sebatiantersebut?

To make the jam thicker


Untuk memekatkan jem

To enhancethe flavor
Untuk menambah pertsa

To preventoxidation
Urttuk m engelakkan pep ksidaan

To sweetenthe jam
Unfuk menambah kemanisanjem

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42
Substance Meltingpoint/oC Boilingpoint/ "C
Bahan Takat lebur/" C Takatdidih/ "C

W -123 7B

X ,10 104

59 224

z 120 445

Table3
Jadual3

Whatarethe physicalstatesof substances


W, X, Y andZat 11e"C?
ApakahkeadaanfizikalbahanW,X, Y dan Z pada 119 C?

W X z
Liquid Liquid Solid Gas
Cecair Cecair Pepejal Gas

Gas Solid Liquid Gas


Gas Pepejal Cecair Gas

Solid Liquid Gas Gas


Pepejal Ce air Gas Gas

Gas Gas Liquid Solid


D Gas Gas Liquid Pepejal

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43 Table4 shorncthe percentage by massof eachelementin a compoundand their


relativeatomicmasses.
Jadual 4 menuniukkanperatusanmengikutjisim bagi sefi.bpunsur dalam safu
sebatiandanjugajisim atomrelatifmasingrmasing.

Elements
Unsur c H o
Percentage(%)
Peratus(T) 26.70 2.20 71.10

Relativeatomic lmss
Jisim atom relative 12 1 16

Table4
Jadual 4

\Mrat is the empiricalformulaof the compound?


Apakah formula empiik untuk sebatian tersebut?

A CHO

B cH()2

c cH20

D CzHO

44 ElementZ forms an oxide with the chemicalformulaof 2203.\Attrich


of the following
is true aboutthis oxide?
Unsur Z membentuk oksida dengan formula molekul ZzOs. Antara yang beikut,
yang manakah henar tentang oksidaini?

A The oxide of Z reactswith acid only.


Oksida Z bertindak balas dengan asid sahaja.

B The oxide of Z reactswith alkali only.


Qksida Z beftindak balas dengan alkalisahaja.

The oxideof Z reactswith bothacid and alkali.


Oksida Z bertindak balas dengan kedua-dua asid dan alkali.

The oxide of Z does not react with both acid and alkali.
Oksida Z tidak bertindaKbalas dengan kedua-dua asid dan alkali.

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45 Atom X has an electronarrangementof 2.4. Atom Y has protonnumberof 17.What


are the propertiesof the compoundformedbetweenelementsX and Y?
Atom X mempunyai susunanelel<trom 2.4. Atom Y mempunyainomborproton 17.
Apakah ciri-ciri sebatianyang terbentuk antara unsur X dan unsur Y?

I lt has highboilingpoint.
la mempunyaitakat lebur yang tinggi.

ll lt does not conductelectricity.


la tidak boleh mengkonduksi elektrik.

lll lt does not exist as a solidat roomtemperature.


la tidak wujud sebagai pepejal pada keadaan bilik.

lV lt is solublein organicsolvent.
la larut dalam pelarut organik.

A I andll only
I dan II sahaja

B lll and lV only


lll dan lV sahaja

C l, ll and lll only


l, ll dan lll sahaja

D ll, lll and lV only


ll, lll dan lV sahaja

46 The electrolysisof copper (ll) sulphatesolution was carried out using copper
electrodes.What are the observationat anodeand the productat cathode?
Eleldrolisis larutan kuprum (ll) suffat menggunakan elel<trod-elel<trodkuprum
dijalankan.Apakah pemerhatiandi anod dan hasildikatod?

Observationat anode Productat cathode


Pe,msrhatiandianod Hasitdikatod

A Electrodebecornesthicker Coppermetal
Elel<trodmenjadi lebih tebal Logam kuprum

Electrodebecomesthinner Coppermetal
Electrodemenjadilebihnipis Logam kuprum

c Colourlessgas bubbles Oxygengas


Gelembung gas tidak berwarna Gas oksigen

D gasbubbles
Colourless Hydrogengas
Gelembunggastidak berwarna Gas hydrogen

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47 The equationbelow shoue the reactionbetrrr,een


magnesiumand hydrochloricacid.
Persamaandi bawah menunjukkantindak batas di antara magnesium dan asid
hidroklorik.

Mg + 2HCl -' MgCl2 + Hz


lf 0'48 g of magnesiumis used,calculatethe volumeof 0.5 mol dm-3hydrochloric
acid
needsto be addedfor completereaction.
[Relativeatomicrnss : H=1: Mg=24;Cl=35.5]
Jik10.a8 g magnesiumdigunakan,hitungkln isipaduasidhidroktonkO.Smol dm'3yang
perluditambahuntuktindakbalasyanglengkap.
fJisin atomrelatif.'H=1;Mg=24;Cl=35.5]
A 0.08cm3

B 0.8 cms

C Scmo

D B0 cm3

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48 Diagram16 shows the set up of the apparatusforthe action of heat on zinc carbonate,
After a few minuteslime water turns cloudy.
Rajah16 menunjukkansusunanradas bagikasan habake atasbahan W.
Se/epas beberapaminft air kapur menjadi keruh.

tI
I
Heat Lime
Panaskan water

Diagram16
Rajah'16

The mass of the boilingtube with the contentbeforeand afterthe heatingis recordedin
Table 5 below.
Jisim tabung didih dengan kandungannya sebelum dan se/epas dipanaskan dicatatkan
dalam Jadual 5 di bawah.

Beforeheating 31.25s
Sebelumpemanasan
Afterheating 2O.259
Se/eoasDemenasan

Table 5
Jadual 5

Calculatethe volumeof the gas releasedin dm3at roomtemperature.


[Rejativeatomic mass: c=12; o=16; Zn=65; Molar volume at room temperature= 24
dm'mol'tl
Hitung isipadu gas yang terbebas datam dmspada suhu bitik.
[Jisim atom relatif:c=12 0=16; zn=65; lsipadumolarpada suhu bilik= 24 dmsmoIl]
A3

11

12

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SUUT

4(t Qiagrarn fourironnailsintesttubes,p, e, R andS.


18shoruE
laigh16 menuniukkanempatpakudiletakkan ai oaam empattabunguji
P,Q RdanS"

Hotjellysolution+ potassium
hexao/anofenate(lll)
solution
Larutanagar-agarpanas+ larutankalfumheksdsilnofent(ilt)

#{\
lronnail
withsilver
Pakubesi
lronnail
withlead
Pakubesi
lronnail
withzinc
Pakubesi
lronnaifwith
magnesium
Pakubesi
dengan dengan denganzink dengan
argentum Plumbum magnesium
P 0 R S
Diagram16
Rajah16
whichtesttubeshowsthehighestintensity
of bluecolouration
afiera day?
TaPu!1g.uii manakahyang mempunyaiieamatanwamabii yang tiiggi setepas
satuhari?
AP
BO
CR
DS

I
,i

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50 Table 6 shovrrsa data recordedwtren 100 cm3of water rltrasheated using methanol,
CH3OHas a fuel.
Jadual 6 menunjukkan data yang direkodkan apabita 100 cm3 air dipanaskan
dengan menggunakanmetanol, CH3OHsebagaibahan api.

Massof vrrater
JEim air 10Og

Changein temperatureof r,trater,


I
Perubahan suhuair,0 200c

Massof methanolburnt
Jisimmetanolterbakar 0.32s

Table 6
Jadual 6

\Alhatis the heat of combustionof methanolin the reaction?


Apakah haba pembakaran metanol di dalam tindak balas tersebut?

[Specificheat capacityof solution:4.2 J g'1oC-1;molarmass of methanol,CHOH is


32 g mol-l1
tHiba kapasffispesifik larutan:4.2 J g'1"CI;Jisim molar metanol,CH3OH adalah
32 g mofll

A 0.84 kJ nrcl-r

B 8.4 kJ mol-r

C 84 kJ mol'l

D 840 kJ mol'l

END OF QUES'IIQNPAPER

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n
ttlt \
tlttl
JABATANPELAJARAN
NEGERI
JOHOR

, vrta-l I
, w- I
r ,L> \
\---.-/

PEPERIKSAAN
PERCUBMNSPM2011 454112
CHEMISTRY
Kertas2
September

2%jan
Duajamtigapuluhminit

JANGANBUKAKERTAS
SOALAN
INISEHINGGA
DIBERITAHU

1, Tuliskan pada
namadantingkatan
ruangyangdisediakan. UntukKegunaan
Pemeriksa
2. Kerfassoalan
iniadalah
dalam
dwibahasa. BahagianSoalan Markah Markah
Penuh Diperoleh
3. Soa/andalambahasa/nggens
mendahului yangsepadan
soalan 1 10
dalambafiasaMelayu. 2 10
4. Calon dibenar{<a
n menjawab 3 10
kesel
uruhanatausebahagian A
4 10
soalansa/naadadalambahasa
lnggeisataubahasaMelayu. 5 10
5. Calondikehendaki
membaca 6 10
maklumatdi halaman
belakang 7 2A
keftassaalanini. B
I 20
I 2A
c
10 20
Jumlah

Kertas
soalan
inimengandungi29
halaman
bercetak

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SectionA
Bahagian A

[50 marks]
160markahl
all questions
Ansvr,er in thissection.
Jawab semua soalandalambahagianini.

1 (a) Diagram1.1showsthe manufactureof ammonia.


Rajah 1.1dibawah menunjukkanpembuatanammonia.

The unreactedN2and H2
N2 dan H 2 yang tidak bertindak balas

-l Mixtureof
Nzand Hz
lroncatalyst
200 atm
450r
I Campuran
H2gas
Gas H2
_l N2 dan H2
200atm
Mangkinbesi
45eC

Liquidammonia
Cecairammonia
Diagram1.1
Rajah1.1

Basedon Diagram 1.1:


BerdasarkanRajah 1.1:

(D Namethis industrialprocess.
Namakanprosesindustriini.

[1 mark]

(iD State the names of reactantsused.

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Nyatakan nama unfuk bahan-bahan tindak balasyang digunakan.

[1 mark]
(iiD Theammoniagasformedis condensed andseparated.\ Jhy?
Gasammoniayang terhasildikondensasikan
dan diasingkan.Kenapa?

[1 mark]
(iv) Write two main uses of ammonia.
Tuliskan dua kegunaan utama ammonia,

[2 marks]
(b) Diagram1.2 showsthree sourcesof traditionalmedicines.
Rajah 1.2 menunjukkan tiga sumber ubat tradisional.

P o
Diagram1.2
Rajah1.2

Matchthe threesour@sof traditionalmedicinewiththeirusesby usinga line"


P adankan ketiga-tiga contoh-contoh sumber dengan keguna anny a.

Curesorethroat

Treatskinwounds
Merawatluka kulit

[1 mark]
(c) Thefollowingshowsfourexamples
of modernmedicines.

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SULIT 4

Di bawahmenunjukkanempatcontohubatmoden.

Haloperidol n Barbiturates
Haloperidol - Barbiturat

Paracetamol l--l Streptonrycin t_]


Paracetamol Strefromysin

0 Tick({) in the boxprovidedaboveto indicateanalgesics


that relievepain.
Tanda(l) di dalam kotakdi atasuntukubat analgesikyang mengurangkan
kesakitan.
[1 mark]
(iD Nameanotherexampleof analgesics
thatis usedin headache
tabletsandin
Whatis the sideeffectof thismedicine?
coughmedicines.

Namakancontohlain analgesikyang digunakandalamubat sakitkepaladan


ubat batuk Apakah kesansampingancontohubatini?

[2 marks]
(iiD An attentiondeficithyperactivity
disorderchildmaytakedextro-amphetamine,
a
psychotherapeuticmedicine.Stateits function.

Seorangkanak-kanak hiperal<tif
dan bermasalah kurangtumpuanbolehdiberi
ubat dertroamfetamin,satu contoh ubat psikoter
aputik . Nyatakan fun gsinya.

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SULIT 5

2 Diagram2 showspartof the PeriodicTableof Etenrents.


V, \N,X,Y,Z and U do not representthe actualsymbolsof the elements.

Rajah2 menunjul<kan sebahagiandaipada JadualBerkala.


V, W, X, Y, Z dan U tidakmewakilisimbolsebenarunsur berkenaan.

1 18

Diagram2
Rajah2
Usingthe lettersin diagram2,answerthe followingquestions:
Denganmenggunakanhuruf-hurufdalamrajah2,jawab soa/an-soalanberikut:

(a) (D Vvhichelementis a halogen?


Unsuryang manakahadalahhalogen?

[1 rarkl
(iD tMich elementis transitionelernent?
Unsuryang manakahlogamperalihan?

[1 rmrkl

(iiD \Mich elementis monoatomic?


Unsuryang manakahmonoatom?

[1 markl

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(b) (D Writethe electronarrangementfor an atomof elementX.


Tuliskansusunaneleldronbagi atom unsurX.

[1 mark]
(iD write the formulaof the ionformedfroman atomof erenrentX.
Tuliskanformulabagi ion yang terbentukdaripada satuunsur X.

[1 mark]
(c) (D \Mry are elementsX, Y andZ placedin the sameperiod?
MengapakahunsurX, Y dan Z terletakdalam kalayang sama?

[1 mark]
(ii) furangeelernentsX, Y andZ accordingto the decreasein the sizeof atoms.
Susununsur X, Y dan Z mengikutpengurangansaizatom.

[1 markl
(d) (D Writethe balancedchemicalequationfor the reactionbetureenelementX and
oxygengas.

Tuliskanpercamaan
kimia seimbangbagitindakbalasdi antaraunsurX dan gas
oksigen.

[2 marks]
(ii) ElernentZ dissolvesin waterto produoea solution.
Completethe equationfor the reac.tion.

Zz + HzO '-+ +
.....................

[1 mark]

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the apparatusset upto determinethe meltingpointof substanceX. In


Diagram3 shovrrs
thisexperiment,
solidX is heateduntilit changesto moltenstate.

Rajah3 menunjukkansusunanradasuntukmenentukantakatleburbahanX. Dalam


ekspermenini, pepejalX dipanaskansehinggaia berubahkepadacecair.

Thermometer
Termometer

Boilingtube
Water Tabungdidih
Air t--

SubstanceX
BahanX

m
D ipanaskan

Diagram3
Rajah3

Basedon diagram3, ansu,er questions.


thefollowing
Berdasarkanrajah 3,jawab soalan-soalan
berikut.

(a) Whatis the nameof the processwhensolidchangesto moltenstate?


Apakah prosesapabilapepejalberubahmenjadileburan?

[1 mark]

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(b) SolidX hasa nreltingpointof 90oC.lf a testtubeof moltenX at 150oCis allora,ed


to
coolat roomtemperature,

PepeialX mempunyaitakatleburg}o2. Sekiranyatabunguji yang mengandungi


leburanX pada suhu 150oCdisejukkanpada suhu bilik,

0 Sketcha graphof temperatureagainsttimefor the coolingof moltenX.


Lakarkangraf suhu melawan masaunfukpenyejukanleburanx.

[2 marks]
(iD Howto avoidsupercooling
process?
Bagaimanauntuk mengelakkanproses penyejukanlampau?

[1 mark]
(iiD Drawa labelledapparatusset-upfor the coolingprocessof substanceX.
Lukissusunanradas berlabelunfuk prosespenyejukanbagi bahanX.

[2 marks]

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(c) Particlesconsistof atom,moleculeor ions.\A/hyis an atomneutral?


Zarah-zarahterdiridaripada atom,molekulatauion. Mengapakahatom adalah
neutral?

[1 mark]

(d) A bromineatomhas35 protonsand 45 neutrons.Writethe standardrepresentation


of bromineatom.
Satuatombrominmempunyai3Sprotondan 45 neutron.Tuliskanperwakilanpiawai
untukatombromin.

[1 mark]
(e) (D Whatare isotopes?
Apakahisotop?

[1 mark]
(iD and phosphorus-32
Phosphorus-31 of phosphorus.
areisotopes Stateoneuse
of phosphorus-32.

Fosforus-3| dan fosforus-32adatahisotopuntuk fosforus.Nyatakansatu


kegunaanfosforus32.

[1 mark]

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4 Thethermochemical equationrepresent
the displacement
reactionof copperfromcopper(ll)
sulphatesolutionby zinc.

Persamaantermokimiaberikutmewakilitindakbalaspenyesdran
kuprumdartpadalarutan
Ruprum(ll)sulfatoleh zink

Zn (s) + Cusoa (aq) + ZnSoa(aq) + cu (s) AH=-190kJ/molr

(a) Statethe meaningof heat of displacement.


Nyatakan maksud haba penyesaran.

.1markl
(b) ls it an exothermic
reactionor endothermic
reaction?
Adakahia tindak balaseksotermikatauendotermik?

[1 mark]
(c) Statetwo observations
in this experirnent.
Nyatakandua pemerhatiandalamtindak balasini.

[2 marks]
(d) Drawan energyleveldiagramforthisreaction.
Lukisgambarajaharastenagabagitindak balasini.

[2 marks]

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(e) In the experiment,excesszinc povrderwas reactedwith25 cmsof 0.2 rnoldm'3


copper(l l) sulphatesolution.
Dalam.eksperimen itu, serbukzinkbertebihanditindakbalaskandengan23 cm3
larutan kuprum(ll)sulfat 0.2 mol dm'?.

Calculate
the heatenergyreleasedin thisexperiment.
Hitungkantenagahabayang dibebaskandidalam eksperimenini.

heatcapacityof solution:4.2Jg-t og't'Densityof solution:1 g crn3]


[Specific
lMuatanhaba tentularutan:4.2 J g't oc-,;Kefumpatanlarutan:t g cm'-1

[2 marks]
(b) In anotherreaction,zincwas replacedwith magnesium
to reactwithcopper(ll)
sulphatesolution.
Predicfthe valueof heatof displacernent,
AH andexplainwhy.
Dalam satutindak balaslain, zink telah digantikandenganmagnesiumuntuk beftindak
balas denganlarutankuprum(ll)sulfat.
Ramalkannilaihaba penyesaran, LH dan terangkanmengapa.

[2 marks]

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-I

SULIT 12

Diagram5.1 shovvsa flowchartfor the qualitativeanalysisof substanceX.


Rajah5.1 menunjukkancartaalir analisiskualitatffbagisebatianX.

BlackpowderX
SerbukhitamX

ProcessI Add hydrochloricacid, HCIsolution


Proses / Tambah larutan asid hidroklorik, HCI

BluesolutionY Processll
ProcessIII Larutanbiru Y Prosesll
ProsesIII
Solution Y + Silver
SolutionY + Sodiumhydroxide, nitrate,AgN()3solution
NaOHsolution
LarutanY + Larutan
LarutanY + larutannatrium argentumnitrat,AgNOs
hidroksida,NaOH

\Mriteprecipitate
Mendakan putih

Diagram5.1
Rajah5.1

(a) Basedon Diagram5.1,


BerdasarkanRajah5.1,

(i) Name the black povrderX.


Namakan serbuk hitam X.

[1 mark]
(ii) Namethe processl.
Namakanproses/.

[1 mark]

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(iiD Writea balancEdchemicalequation


for the reaction.
Tuliskanpersamaankimiayang seimbangbagitindakbarasyangberlaku.

t2 marksl
(iv) \Nhyis the blackpovrderX addedin excessin the reaction?
MengapaserbukhitamX ditambahsecaraberlebihandalamtindak balasini?

[1mark]
(b) Basedon processll,
Berdasarkankepadaprosesll,

0 Namethe process.
Namakanproses /a.

[1 markl
(iD Writethe ionicequationfor the reaction.
Tuliskanpersdmaanionikbagitindak balasitu.

[1 mark]
(iiD Howto obtainthe wtriteprecipilatein the processll?
Bagaimanamendapatkanmendakanputih dalam prosesini?

[1 markl
(c) Basedon the process1 and processlll, statethe cationandanionpresentin solution
Y.
proses I danproseslll, nyatakankationdan anionyang hadirdi datam
Berdasarkan
larutan Y.

Cation: Anion
Kation Anion
[2 marks]

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Diagram6.1 showsan experiment to investigatea factorthat influences


the rateof reaction.
Theexperimentis repeatedfivetinresat differenttemperatures.

Raiah 6.1 menuniukkansuatuekspeimen unfuk mengkajisatu faktoryang mempengaruhi


kadartindakbalas. Eksperimenini diulangisebanyaklima kalipada suhuyang berlainan.

50 cm3of sodiumthiosulphatesolution
0.2 mol dm'3+ 5 cm3of sulphuricacid 1
moldrn3.

:_ 50 cm3larutan natrium ti\sutfat 0.2 mol


dm's + 5 cm3 asidsulfurik 1 mol dma.

Diagram6.1
Rajah6.1

Table6 shovr,sthe temperatureand timetakenfor "X' rmrk to disappearfromviewwhen


observedverticallyfromthe top.
Jadual6 menuniukkansuhu dan masayang diambitunfuktanda"X' hilangdaripandangan
biladiperhatikandari atas.

Experiment I oC Tinre/ s
Temperature
ERsperimen Suhu/oC Masa/ s
1 30.0 55.5
2 40.0 33.0
3 50.0 23.O
4 60.0 17.A
5 70.0 13.0

Table6
Jadual6

(a) Stateone observation


fromthis experiment.
Nyatakansatupemerhatiandaripadaeksperimen
ini.

[1 mark]

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(b) Completethe chemicalequationfor the reactionthat occurred.


Lengkapkan peraamaan kimia untuktindak baIas yang berlaku.

Na2S2O3+ HrSO4 +
[1 markl

(c) comparethe rateof reactionbetueenExperiment


1 and Experiment
5.
Bandingkadartindak balasantaraEkspeimenI dan Experimen5.

[1 mark]

(d) Explainyouranswerin (c) usingtheCollision


Theory.
Jelaskanjawapdnandapada (c) denganmenggunakanTeoriperlanggaran.

[4 marks]

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(e) By usingthe datain table6, drawthegraphof temperature


againsttimefor this
experimentin the graphprovidedbelow.

Denganmenggundkandata dalamjadual 6, lukiskangraf suhumelawanmasabagi


eksperimenini di dalamkerfasgrafyang disertakandi bawah.

[1 mark]

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(0 Diagram6.2 shov'lsa @nversationbetweenUmmu and Qistina-


Rajah 6.2 menuniukkanperbualan diantara Ummu dan Qistfna.

When I placed a small sized ButUmmu,whenI placed


egg in boilingraaterat 100oC, sarrp sizedegg in hotwater
it becomehard boiledwithin at 70oC,it took me a much
12 minutes. longertimethanyours.

Apabila saya meletakkan sebiii TapiUmmu,apabilasaya


telur bersaiz kecil ke dalam air meletakkanteluryang sarna
mendidih pada 10fC, ia saizke dalamair panas
menjadi keras dalam temPoh pada 70"C,ia mengambil
12 minit. lebihlama daripada
,??asa
awak

Diagram6.2
Raiah6.2

the effectof differenttemperatures


Threestudentsaboveare investigating to prepare
hardboiledeggs.Basedon the conversation above, statethe between
relationship
temperatureandtimetakento preparehardboiledegg.

Tiga pelajardi atassedangmeng4ajikesansuhuyang berlainanRe atasteluryang


direbus.Berdasarkanperbualandiatas,nyatakanperkaitanarfara suhu denganmasa
yang diambiluntukmenyediakantelur rebus.

[2 marks]

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SectionB
Bahagian B

l2Omarksl
any one questionfromthis section.
Ansr,rier
Jawab mana-mana satu soalandaripadabahagian ini.

(a) A studentwantsto carryout an experirnent


to electroplate
an ironkeywith silver.
Seorangpelajaringinmenjalankansatu eksperimenuntukmenyadursatu kuncibesi
denganargentum.

(i) Statethe anode,cathodeand electrolyte


that mustbe usedto carryoutthe
experiment.
yang mestidigunakanuntukmenjalankan
Nyatakananad, katoddan elel<trolit
eksperimentersebut.
[3marks]
(ii) Writethe half-equations
for the reactionat the anodeandthe cathode.
Tuliskansetengah persamaan bagitindakbalasdi anoddan katod.

[2marks]

(iiD Suggesttwo vralBto obtaina smoothand beautifulcoatingof the ironkey


withsilver.
Cadangkan dua cara untukmemperolehpenyaduranargenfumyang rata
dan cantikpada kuncibesi.

[2marks]

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(b) Diagram7 showsapparatusset-upusedto investigate the reactionof metal


fromits salt solutionby somemetalsandthe observations
displacement obtained
in 1 minute.
fromthe experiment

Rajah7 menunjukkansusunanradasyang diguna4anuntukmengkaiitinda?belas


penyesaran
'dai logam daripadalarutangaramnyaoleh beberapaienislogamtertentu
pemerhatianyang di perotehdaripadaeksperimendalamtempah1 minit.

Chemical
formulafor
Apparatusand observationafter I minute product
Alat radasdan panerhatin selepasI minit aqueous
solution
Brownsolid
deposited
25 cmsof 0.1 mol Pepejal
perang Pz(SOa)g
sulphatesolution terenap
25 cmslarutan
MetalP
kuprum(ll)sulfat
0.1moldm'" LogamP

25 cm3of 0.1 nrol Brownsolid


drn3of coppe(ll)
sulphatesolution

25 cmslarutan
kuprum(ll) sulfa!
0-1moldm''

25 cm3of 0.1mol
dm3of Q sulphate
solution

25 cmslarutanQ
sulfatA.1moldma

Diagram7
Rajah7

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(i) givenin Diagram7, comparethe differences


Basedon the infornution
between:
Berdasarkanmaklumatyangdiberikandalam Rajah7, bandingkanperbezaan
di antara:

. ExperimentI andll,
EksperimenI dan Il,

r I andlll.
Experiment
Eksperiment dan lll.

Explainyouranswerin termsof:
Terangkanjaunpanandadarisegi:

r Positionin the elecfrochemicalseries.


Kedudukan dalam sirieleldrokimia.

o Observationin allthreeexperiments.
Pemerhatian dalam ketiga-tigae ksperimen.

[8 marks]
(iD ldentifymetalP andQ.
Kenal pastilogamP dan Q.
[2 marks]
(iiD ln experimentll, 25 cm3of 0.1moldm-3copper(ll)
sulphatesolutionreact
completelywith metalQ.
Calculatethe massof copperproduced.

Dalam eksperimen !!, 25 cms larutankuprum(tt)sulfat0.1 mol dm-3bertindak


balaslengkapdenganlogamQ.
Krakan jisim kuprumyang terbentuk.

[Relativeatomicrrnss:Cu = 64]
lJisim atomrelatif:Cu = 641

[3 marks]

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(a) A coveredgasjar contains1.5molof ammoniagas,NH3.


Satubalanggasbertutupmengandungil.Smolgas ammonia,NH3.

Howmanyammoniamolecules aretherein the gasjar?


Berapakahbilanganmolekulammoniadi dalambalanggas tercebut?

[2 marks]

(b) Urea,CO(NH2)2,?rrltTloniumnitrate,NH+NOs and hydrazine,N2Haare fertilizersthat


are used in agriculture.\Mich fertilizerhas the highest percentagemass of
nitrogen?

Urea, CO(NH)z, ammoniumnitrat, NHNO1 and hydrazin, Nzltaadalah bajayang


digunakan dalam pertanian. Baja yang manakah mengandungi peratusjisim
nitrogenteftinggi?

[4 marks]
(c) Diagram8.1 shornethe electronarrangement
of molecules
A and B.
Rajah8.'l menunjukkansusunaneleldronbagimolekulA dan B.

eO eO
A

Diagram8.1
Rajah8.1

Elased
on diagram8.1:
Berdasarkanrajah8.1;

Statethe type of covalentbondin eachrrcleculeand explainwhy.


Nyatakanjenis ikatankovalendalam setiapmolekuldan terangkanmengapa.

[4 marks]

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(d) Diagram8.2 shorars


the formulaof trapdifferentcompounds.
Rajah8.2 menunjukkanformulabagidua sebatianberbeza.

KzO SOe
Diagram8.2
Rajah8.2

Basedon Diagram8.2:
Berdasarkan
Rajah8.2:

(i) Compareand contrastthe two compoundsin termsof physicalstatesat room


temperature, rneltingpoint,electricalconductivity
andsolubility
in water.
Bandingdan bezakedua-duasebatiandari segi keadaanfizikalpada suhu
bilik, takatlebur, kekonduksian elektrikdan kelarutandalamair.
(iD Explainthe differences
of the meltingpointfor the tvr,rc
compounds.
Terangkanperbezaantakatleburbagikedua-duasebatian.

, [10marks]

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Section C
Bahagian C

BOmarksl
anyonequestion
Ansvr,er fromthissection.
Jawab mana-manasatu soalandaripadabahagianini.

I (a) Diagram9.1showsa structuralformulaof butene,


Rajah9.1 menunjukkanformulastrukturbagi butena.

H H HH
llrl
H-C-C-C:C-H
tl
HH
Diagram9.1
Rajah9.1

Drawanothertwo structuralformulaeof buteneandwritetheirrespectivenames


according
to the IUPACnomenclature.

Lukisdua formulastrul<tur
lainbagi butenadan tuliskannama masing:masing
berdasarkan penamaan IUPAC.

[4 marks]
(b) Diagram9.2showsthestructuralformulaof an ester.
Rajah9.2 menunjukkanformulastrukfurbagisuatuesfer.

HHOHH
ttil tl
H-C-C-C-O-C-C-H
rttl
HHHH

Diagram9.2
Rajah 9.2

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Basedon diagram9.2:
Berdasarkanrajah 9.2:

(D ldentifythe tvrrcorganicchemicalsneededto producethe esterabove.


Kenalpastidua bahankimia organikyangdiperlukanunfukmenghasitkanesterdi
afas.
[2 marks]
(iD Statetwo chemicalproperties
for eachorganicchemicats
thatyou statedin
e(bxD.
Nyatakandua sifatkimiabagisefiapbahankimiaorganikyang andanyatakan
datam9(b)(il.

[4 rmrksl
(c) You are givenan apparatusand chemicalsas follow:
Anda diberikanalat radasdanbahan-bahankimia sepeftiberikut

Apparatus:
testtube,dropper.
Radas;tabunguji, penitis

chemicals: Brominein trichloroethane, acidified potassiummanganate(vl


l)
solution
Bahankimia:bromindalamtrikloroetana, larutankaliummanganat(Vtl)berasid

Describetwo chemicaltestsusingthe apparatusand chemicalsgivenaboveto


differentiate
betweenhexaneand hexene.
Yourdescriptionmustincludethe procedureandobservation.
Huraikandua uiian kimia menggunakanalat radasdan bahan kimiayang diberikandi
atasuntukmembezakanantara heksanadan heksena.
Dalamhuraiananda mesitidiseftakanprosedurdanpemerhatian.

[10marks]

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10 (a) Diagram10.1showsthe apparatusset-upfor a voltaiccetl.


Rajah 10.1menunjukkansusunanradasuntuksafase/ voltan.

MetalA Copper
LogamA kuprum

AqueoussolutionAYz AqueoussolutionCuY2
LarutanakueusAYz LarutanakueusCuYz
Diagram10.1
Rajah10.1

MetalA is rnoreelectropositivethancopper.
Suggestone possiblecationfor X2*ion.
LogamA lebih eleffiropositifdaripadakuprum.
Cadangkansatu kationyang mungkinbagiion **.

Basedon the elec{rodefactorwhichaffeits the selec{ivedischargeof ionsat the


electrode,
Berdasarkanfal<torelel<todyang ma,nakah mempengaruhi pemilihanion yang
dinyahcaspada eleldrod,

(D Writethe halFequationfor the reactionat the electrodeof metalA.


Tuliskansetengahpersamaanbagitindak balasdi elel<todlogamA.

[3 marks]
(iD Statethe $pe,of reactionat the anode.
Nyatakanjenis tindak balasdi anod.

[1 markl

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(b) Table10.1shotnrs
the resultof chemicaltests
usedto changethe solution
X and
SolutionY.
Jadual 10.1menunjukkankeputusanujiankimiauntukmenukarkanlarutanX dan
larutan Y.

Experiment Procedure Observation


Eksoerimen Prosedur Pemerhatian

Bromineurateris addedintoX
solutionandwarmed.Sodium
hydroxidesolutionis addedinto Green precipitate
mixtureuntilexcess. formed
Mendakan hijau
Air brominditambahkanke dalam brberrtuk
larutanX dan dihangatkan.
Larutan natrium hidro ksida
ditambahkanRedalamcampuran
sehinggaberlebihan.

Zinc pourderis addedintosolution


Y andthe mixtureis shaken.
Sodiumhydroxidesolutionis then
addedintothe mixtureuntil
excess. Brownprecipitate
formed
SerbuKzinkditambahke dalam Mendakan
larutan Y dan digoneangkan perang terbentuk
ingga tiada perubshd tr.
si,eh
Larutan natriumhidroksida
ditambahkan sehingga berlebihan
ke dalam campuran.

Table10.1
Jadual10.1

Basedon Table10.1:
o ldentifythe solutionX andsolutionY.
o Statethe reducingagentin experimentI andoxidisingagentin experimen
ll andgiveone reasonfor eachof yourchoicesbasedon the changesof
oxidationnumber.
BerdasarkanJadual I 0.I :
o Kenalpasti larutanX danlarutanY.
o Nyatakanbahanyangbertindaksebagaiagenpenurunandalam
eksperimenI dan agenpengoksidaandalam eksperimenll serta beri satu
sebabuntuk setiappilihananda berdasarkan
perubarhannombor
pengoksidaan.

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SULIT 27

(c)
Chlorineis goodoxidizing
agent.
Korin adalahagen pengoksidaan yang baik.

You are giventhe followingapparatus:


Anda dibeikan alat-alatradasberikut:

U-tube,galvanometer, wires,stopper,dropper,carbonelectrodes
connecting and
retortstandwith clamps.
TiubU, galvanometer,wayarpenyambung,penyumbat,penitis,elektrod-eleldrod
karbondan Rakiretot dan pengapit.

Suggesta suitablechemicalanddescribean experimentto verifythe above


statementusingthe givenapparatus.
Cadangkanbahan kimiayang sesualdan huraikan satu ekspertmenuntuk
mengesahkan pernyataandi atasdenganmenggunakanalat radasyang diberi.

[10marks]

ENDOF QUESTTON PAPER


KERTASSOATA/\'TAMAT

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-:5. =i 9*otg, nt$* *oiit *E5fi

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-
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tr orgn si$! n ; !E
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Nama: Tingkatan
:

JABATANPELAJARANNEGERIJOHOR

PEPERIKSAAN
PERCUBAAN
SPM2011
CHEMISTRY 454tt3
Kertas3
September

1%jax Satujamtigapuluhminit

JANGANBUKAKERTAS
SOALANINI SI|IilI'{GGADIBERI.TATIU

1. Tuliskan pada
namadantingkatan
ruangyangdisediakan. UntukKegunaanPemeriksa
2. Keftassoalan
ini adalah
dalam Soalan Markah Markah
dwtbahasa. Penuh Diperoleh
3. Soa/andalamBahasalnggerts
mendahuluisoalanyangsepadan 1 18
dalamBahasaMelayu.
4. Calondibenarkan
menjawab
kesel
uruhanafausebahagian
soalan a 15
samaadadalamBahasalnggerisatau
BahasaMelayu.
3 17
5. Calondikehendaki membaca
maklumat di halamanbelakanakertas
soalanini. JUMLAH

Kertas
soalan
inimengandungi
13 halaman
bercetak
dant halaman
tidakbercetak.

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1 Table 1 shows the observationsin three test tubes used to investigatethe effectof
other metals on rusting.A mixtureof jelly solution,potassiumhexacyanoferrate(lll),
K3Fe(CN)6solution and phenolphthalein were used as mediumin each test tube. The
observationsluererecordedafterone week.

Jadual I menunjukkanpemerhatian dalam tiga buah tabung ujiyang digunakan untuk


menyiasat kesan logam lain ke atas pengaratan. Medium yang digunakan di dalam
setiap tabung uji adalah campuran larutan agar-agar, larutan katium
heksasianoferat(lll), KsFe(CN)6dan fenalftalein. Pemerhatian direkod se/epas safu
minggu.

Testtube Observation
Tabunq uii Pemerhatian

1 week
1 minggu
4
--F\__

lron nailcoiledwith copperstrip


Paku besi dililit dengan
kepingan kuprum

1 week
I minggu
tl
lronnailcoiledwithzincstrip
Paku besi dililit dengan
kepingan zink

1 week
I minggu

ill -

lronnail
Paku besi

Table 1
Jadual I

ReferenceiPetunjuk:lE*l Blue spot I tompokbiru


r.TFf Pink spot I tompok merahjambu

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r
II
I

SULIT
II
E^F

for eachtesttubesl,.lland l1l.


(a) Stateone inference Examinefs
Nyatakansatu inferensuntuksetiaptabung uiil, tl dan lll. Use

Tesltube l:
Tabungujil:

Testtubell:
Tabunguji It:

Testtubelll:
Tabunguji IIt: 1(a)

tE
(b) Forthisexperiment,state:
ini, nYatakan:
Bagi eksperimen

(i) Thenunipulatedvariable.
"
Pembolehubah dimaniPYIasi.

(iD The respondingvariable.


Pem bolehubah bergerak b alas.

(iiD The constantvariable.


Pembolehubahdimalarkan.
1(b)

m
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For
Examiner's (c) Statethe hypothesis
Use
for theexperiment.
Nyatakanhipofeslsbagi eksperimentersebut.

1(c)

m
(d) State the operationaldefinitionfor the rustingof iron nail.
Nyatakan defrnisi secara operasibagi pengaratanpaku besi.

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(e) Diagram1 showsthe apparatusset-upof an experiment. rof


Rajah 1 menunjukkansusunanradasbagi satu ekspeimen. Examiner's
Use

Jellysolution/ Larutanagar-agar
+
potassium hexacya nofenate(lll), K3Fe (CN)6solution
Iarutan kaIium he ksasianoferat(ttI), KsFe(CN)a

Phenotphtha
tJinI fenotftatein

lronnailcoiledwithleadstrip
Paku besidililit dengankepingan
plumbum

Diagram1
Rajah I

Predictan observationfor the experimentaftera ueek.


Ramalkansatu pemerhatiandaripada eksperimenitu selepassatuminggu.
1(e)

[E
Total
1
l1
I | ._ |

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SULIT

Fd
Examiner's Diagram2 shovra theapparatus setupforanexperiment theendpointof
to determine
Use
titration
in neutralisation
reaction.
Rajah2 menunjukkan susunan radassatuekspeimen
bagimenenfukan takatakhir
pentitratan dalamtindakbalaspeneutralan.

Burette
Buret

Hydrochloricacid
Asidhidroklorik

ConicaltlaskI kelalang
kon
50cm3of 1.0rnoldm-3sodiumhydroxide
+ phenolphthalein
solution
50 cm3larutannatium hidroksida
1.0moldm-3
+ fenolftalein

Diagram2
Rajah2

thatyoucouldobtainduringtheexperiment.
(a) Statetwo observations
duapemerhatian
Nyatakan yangbolehandadapatisemasa
eksperimen.
,l

2(a)

[E 2.

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-I

SULIT

For
The experimentis repeatedthreetimesand the volumeof hydrochloricacid usedfor Examiner's
each set is shownin Table 2. Use
Eksperimenitu diulangtiga kali dan isipadu asidhidroklorikyang digunakanbagi setiap
set ditunjukkanpada Jadual 2.

Set Initialreading Finalreading


Sef Bacaanawal Bacaanakhir

...cm' ,..cm'

II

....cm3 ......cm3

ilt

,..cm' ...cm'

Table 2
Jadual 2

(b) Recordthe burettereadingsin the spacesprovidedin Table 2.


Catatkanbacaanburetpada ruangyang disediakandalam Rajah2.

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SULIT 8

For
Examinels (c) Constructa table to recordthsdata from sets l, ll and lll.
Use The table shouldinclude
the initialreadlng,final readingand the volume of hydr,ochloric
used in the 4
14
titration.
Bina satujadual untuk merekod data bagisetl, ll danill itu.
Jadual tersebut
hendaklah mgngandungi bacaan awat, Sacaanakhir dan iipiii.asia
yang digunakan dalam titratan. hidroktorik
W 1I
/
t4
/-

t/vl/rl
rht
2(c)
r-r I

rtr (d) The chemicalequationfor the reactionis shown below:


ry
lft
Persamaankimia tindak balasditunjukkandi bawai:"' N' '1

HCI + NaOH -, NaCl + HzO


calculate the average,vorume
of hydrochroricacid, HCrneededto neutrarise
50 cm3of 1.0 mol dm-3sodiumtryciroxiOe, --
NaOH ,of uiion.
Hitungkan isipa6.rlpq!?tagagi aii d hidrokrorik,i c i
meneutrarkan.s0 vii g'j iperrukan untuk
cm"rarutan natriumhidroksida t.o mitd;-i, N;oH.'--'
2(d)

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la

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ror
(e) Duringthe titrationprocess,statethe relationship
betweenthe concentration Examiner's
use
hydroxide ion,OH-in sodiumhydroxide, NaOHsolutionwithtimeuntiltheend
pointof titration.
Semasa prosespentitratan,nyatakanhubunganantarakepekatanion Ol-f dalam
larutansodiumhidroksida,NaOHdengan masasehinggatakat akhirpentitratan.

2(e)

m
(f) diproticandtriproticacid.
Classifythe followingacidsintomonoprotic,
Kelaskanasid-asidberikutkepada asidmonoprotik,diprotikdan triprotik.

Hydrochloricacid Sulphuric acid


Asidhidroklorik Asid sulfurik

Ethanoicacid Nitricacid
Asid etanoik Asidnitrik

Phosphoric acid
Asid fosforik

acid
Monoprotic Diproticacid Triproticacid
Asidmonoprotik Asiddipratik Asid triprotik

2(f)

r-;
I l3l

Total
z

tE
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SULIT 10

Diagram2 shorussomesamples of battery.


Battery
is a voltaiccellthatcanbe built
usinganytrruo
different
metalsandsuitable electrolyte.
Raiah2 menuniukkan heberapacontohbateri.Bateriialahse1'enr.s
setkimiayang
bolehdibinamengguna&ansebarangdualogamberlainan dan elektroftyang sesuai.

Diagram2
Rajah2

Voltmeter
readingof voltaiccelldepends
onthepairof metalsusedas electrodes.
BacaanvoftmeterselRimia bergantungkepadapasanganlogamyangdigunakan
sebagaieleltrod.

Plana laboratoryexperiment to investigate pairsof metalproduce


thatdifferent
different
voltageof a voltaiccell.Yourplanningshouldincludethefollowing
aspects:
Rancangsafu ekspermenuntuk menyiasat bahawapasanganlogamyang berbeza
menghasilkanvoftan se/ kimia yang herbeza. Perancangan anda hendaklah
mengandungi aspeft-asp ek berikut:

(a) Problemstatement
Pernyataanmasalah

(b) Allthevariables
Semuapembolehubah

(c) Hypothesis
Hrpofesrb

(d) Listof material


andapparatus
Senaraibahandanalatradas

(e) Procedure
Prosedur

(t) Tabulation
of data
Penjadualandata
117marksl
h [17markahl

t
E H DO FQ U E S T I OPi lA P E R
KERIAS SOALA,\,TAMAT
I

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SULI I
JABATANPELAJARANNEGERIJOHOR

SETARANEGERIJOHOR2011
PERCUBAAN
PEPERIKSAAN

SKEMAPEMARKAHAN

CHEMISTRY

PAPER1

PAPER2

PAPER3

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JULANGJOHOR2011
CHEMISTRY
PAPERT
ANSWER

QUESTION ANSWER QUESTION ANSWER


1 A 26 A
2 C 27 B
3 A 28 c
4 B 29 B
5 B 30 C
6 B 31 c
7 A 32 B
8 D 33 D
I A 34 A
10 D 35 A
11 D 36 A
12 A 37 c
13 c 38 B
14 D 39 D
15 c 40 c
16 D 41 B
'17 c 42 D
18 D 43 B
19 c 4 c
20 A 45 D
21 B 46 B
22 c 47 D
23 A 48 B
24 c 49 A
25 B 50 D

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No. Mark scheme Sub Total
mark mark
2 (a) (i) z 1
(ii) U 1
(iii) W 1 3
(b) (i) 2.8.1 I
(ii) X* 1
2
(c) (i) Theyhavesamenumberof shellsnbOloccupieO
witn 1
electrons

(ii) x,Y,z il x>Y>z 1 2


(d) (i)
4X+O, -* 2XzO ll
2 X + T " Q , + XeO 1+1
Conectreactantsandproducts- 1
Conectlybalance- 1 3
(ii)
Zz + HrO ---+ HZ + HOZ 1

Total 10
Mark

No. Markscheme Sub Total


mark mark
3 (a) Melting 1 1
3 (bxi)

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Correctaxiswithunits 4
I

Correctgraph and90oCis stated 1

3(bxii) ThemoltenX is stirredcontinuously


throughout
the 1
experiment

(iii)
Thermometer

Boilingtube

MoltenX

Conicalflask

Labelleddiagram 1i
Conect and func{ionalapparatus 1l 5

3(c) Becausean atomconsistsof an equalnumberof 1 1


electronsand protons.

3(d) 80 1 1
Br
35
3(eXD Atoms of the same elementwith the same numberof 1
protons / proton number but different number of 2
neutronVnucleonnumber

3(eXii) Use in phosphatefertilizers// to studythe metabolism


of I
phosphorus in plants
Total mark 10

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Section A

(a) (i) Haber 1


(iD Nitrogenand Hydrogen 1
(iii) To get a betteryield 1
(iv) 1. To make fertilisers
2. To produce nitric acid 1+1
(b)
Curesorethroat
Merawatsakittekak
Treatskin wounds
Merawatluka kulit

1
(c) (i) Paracetamor 1
lI
(ii) Codeine/ 3-methytmorphine 1

Addiction/ depression/ nausea/ vomiting/ itching/


drowsiness/ dry mouth / orthostatichypotension/
urinaryretention/ miosis / constipation
(iiD Activatelevelof alertness//
Reducenormalfatiguell
Elevatemoodl/
Stimulateactivityof brain/ centralnervous
system.

Total 10
mark

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-:

MarkScheme Sub Total


Mark , Mark
:
Heatreleased when1 moleof metalis displaced
fromits
saltsolutionby a moreelectropositive
metai. 44
t't:
ai

a: heatchange

exothermic

1. Brorrvn
soliddeposted.
2. Thecolourof solutionchangefromblueto lightblue/
colourless.
3. Containerbecomeshot
4. Massof zinc decreased
5. Sizeof zincbecomes thinner
[Anytwo]
Energy

AH = -190 kJ mofl
ZnSOa+ Cu

o Conecttwo energylevelsand axislabeledenergy.


. Conectreactants,productsandvalueof AH.

(0.2\(25]'
No.of mofeCUSO+= i/ 0.005mol
1000

Heatenergyreleased= 0.005motx 190kJ mol'1il


= 0.95kJ / 950J

1 . Valueof AH more/ higherthan-190kJ.


2 . Magnesium is moreelectropositive
comparezincin
electrochemical
series/l
Distancebetweenmagnesium andcopperis further
thanthe distancebetweenzincandcopperin
electrochemical
series.

Total mark

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No. Mark Scheme Sub Total
Mark Mark

5 (aXi) Copper(ll)oxide 1 1

(ii) Neutralisation 1 1

(iiD Conectreactantsandproducts 4t 2
Balancethe equation 1

2 H C l+ C u O ) C u C l 2 + HzO

(iv) To completethe reaction 1 1

5(bXD DoubleDecomposition/ Precipitationreaction 1 1

(ii) Ag"+Cl-)AgCl 1 1

(iiD Filtration 1 1

(c) Cation : Cu2* 1


Anion : Cf 1 2

Total mark 10

No. Mark Scheme Sub Total


Mark Mark
6 (a) Yellowprecipitate 1 1

(b) + HzSO+-+
NazSzOg S + HzO+ SO,
NazSOe+ 1 1

(c) 1. Rateof reactionfor Eiberiment5 is hiqherthan 1 1


Experiment1 (orviceversa).

(d) 1. Temperature in Experiment 5 is higher. 1


2. The kineticenergyof the particlesis higher. 1
3. Thefrequencyof collisions betweenH*ionsandSzOr2-
ionsincreases 4
I

4, Thefrequency of effectivecollisionsincreases. I
I
A

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Temperature/oC

Time/s
(0 The higherthe temperature
the shorterthe timetakenfor the eggto becomehard-
boiledllvice versa

Section B

No, Mark Scheme Sub Total


mark Mark
7(a) (r) Anode:Silver(rod/foil) 1
Cathde: lron key I
Electolyte:Silvs nihatesolution 1 3

(iD Anode : Ag +Ag' +s 1


Cathode: Ag'+e*Ag 1 2

(iiD 1. Usea smallelectricalcurrent


2. Uselow concentration of the silvernitratesolution.
3. Turn the iron key slowlyduringexperiment.
4. Cleanthe ironkeywithsandpaperbeforecarryingout
experiment. 2 2

Any two

7(b) 0 ExperimentI and ll


I

1. Rateof reactionin 2. MetalP is more


experimentI is higher electropositive
llThe reaction in compared withmetal 1+1
experimentI is faster Q in the
elec'trochemical
series

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I 3. Depositof brown A
-.
Distancebetween 1+1
II metalis morein metalsP and Cu is
I expr;menlI furtherthan metalQ
i comparedwith and Cu in the
i experimentll electrochemicalseries

ExperimentI and lll

Comoarison Exolanation
5. Thereis a reactionin 6. MetalP is more
experimentI and no electropositive
reactionin comparedwithcopper 1+1
experiment lll metalin the
electrochemical series
7. Thereis brown 8. MetalPis placed
depositin experiment higherthancopperin
I andno depositin the electrochemical
experiment fll seriesl/ Coppermetal
is placedbelowmetal
R in the
electrochemical series
Il metalP is more 1+1 I
electropositivethan Cu
(ii) MetalP :Aluminium,
Al
MetalQ:ZnlFe/Sn 1
r: Pb 1 2
(iiD Molof CuSO+solution= t0.1\{SI ll 0.0025mol
1000 1

Ratio: 1 molofCuSO+produced1 molCu


0.0025molof CUSO4produced0.0025molCu
1
Massof copper = 0.0025molx 64
= 0.16g 3
1
Total mark 2A

No. Markscheme Sub Total


mark mark
8(a) = 1.5i6.0ZiT0F
The numberof molecules 1 2
= 9.03x 1023 1
8(b) Urea,CO(NH2)2

2n4\ xl}Oo/o = 46.670/o 1


12 + 16 +(14+2)2

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Ammoniumnitrate,NH4NO3

2(14], x 100o/o= 35.0olo 1


14+4+14+3(16)

Hydrazine,N2Ha

zfi4\ x lA9o/o = 87.5o/o 4


I

2(14)+ 4(1)
Hydrazinehasthe highestpercentagemassof nitrogen 1 4

8(c) 1. Doublebond 1
Formedwhentwo pairsof electronsare sharedbetween
two non-metalatoms. 1

2- Triplebond 1

Formedwhenthreepairsof electronsare shared


behreentwo non+netalatoms. 1 4

8(d) (i)
Compound KzO SO,
1 Physicalslateat Solid Gas
roomtemoerature 1+1
2 Meltingpoint High Low
Accept:A meltingpointof KzO 1+1
is hiqherthanSO,
3 Eledrical Ganconduct Cannot
conductivity electricityin conduct
moltenor elecficityin all 1+1
aqueousstate physicalstate

4 Solubilitv
in water Soluble lnsoluble 1+1 8

Answerscanbe in sentenceformto showcomparison.


(d) (ii) KrO:
1. forcesof attractionbetweenionsin KzOis strongerthan
SO,
2. moreheatis neededto overcome/ breakthe attraction 1
force
ll viceversafor SOz 1 2

Total mark 20

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9

Section G

No. Mark Scheme S u b Total


Mark Mark
9(a)

HHHH
tltl
H-C-C:Q-C-H But-2-ene
tl 1+1
HH

HH
tl
H-C:C-C - H
ll 2-methylpropene ll
IH
H- C-H 2+netfrylpropl-ene 1+1 4
I
H
(b) 0 Propanoicacid, Ethanol 1+'t 2

(ii) tAcceptif studentnamethe reactantsorthe productsl

Chemicalpropertiesfor propanoicacid:
1. Reactwithreadive metralproducesalt and hydrogengas
II
2. Reactwithbasesproducesaltand waterll
3. Reactwith carbonatesmetalprduce salt, carbon
dioxidegasand waterll
4. Reactwithalcoholproduceester
1
[Anytwo answers] 1

Chemicalpropertiesfor ethanol:
1. Undergocombustionproducecarbondioxideandwater
// Bumtin orygento produceCOzandHzO
2. Undergooxidationproducecarboxylicacidlethanoic
KMnOr to produce
acidIl Reactwith acidifiedKzCrzOt
carboxylicacid
3. Undergodehydration producealkene/ ethene.
1
[Anytwo answers] 1 4

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l0

1. Pourabout[2 -5 cm"]of hexaneintoa testtube.


2. Add4-J dropsof brominewaterandshake.
3. Observeanychangesandrepeatwithhexene.

Observation:
Hexane:browncolourremains
unchanged.
Hexene:Browncoloursdecolourise
/ turncolourless.

withacidifiedpotassium
Reac'tion manqanate(Vl
l) solution

Procedure:
1. Pourabout[ 2-5cm3] of hexaneintoa testtube.
2. Add 4-5 dropsof potassiummanganate(Vll)solution
andshake.
3. Observeanychangesand repeatwithhexene.

Observation:
Hexane:Purplecolourremainunchanged
Hexene:Purplecoloursdecolourise.

[Anytwo tests]

No l/lark scherne Sub Total


mark mark
10(aXD Sampleanswer: 1
MetalA: Magnesium/Mg

Mg -+ Mgt* + 2e
Readantand produc-tconect 1
Balancethe equationconectly 4
t ?

(ii) Oxidation 1 1

(b) SolutionX : Ferum (ll) sulphatetreSOa 1

Solution Y : Ferum (lll) sulphate/ Fez(SO+h 1

Reducingagent '. Fe2*!Ferum (ll) sulphate/ FeSOn/ lron(ll) 1


ion
Reason : oxidationnumber increasefrom +2 to +3 1

Oxidisingagent: Fe3*/ Ferum(lll) sulphate/ Fez(SO+)g


/
lron(lll)ion 1
Reason: Oxidationnumberdecreasefrom +3 to +2
.l
I o

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l1

Galvanometer

Carbon
electrodes

Chlorine water Potassium


bromide
solution

U-tube
Dilutesulphuricacid

Conectand fundional apparatus 1


Conectlylabelled' 1
1. Suitablechemical: potassiumbromidesolution//any
suitablechemicalsolution
2. Dilutesulphuricacidis pouredintoa U-tube 1
3. A dropperis usedto fill one arm of the U-tubewith 1
chlorinewater
4. Potassiumbromidesolutionis addedcarefullyto
anotherarm of the U-tube
5. Botharm of the U-tlbe is fitted with carbonelectrode 1
6. Reducingagent: potassiumbromidesolution 1
7. At negativeelectrode,bromideions are oxidizedto 1
bromine 1
8. 2Br- Brz + 2e 1 Max=
9. At positiveelectrode,chlorineare reducedto chloride 1 10
rcns
1O.Cl2+2e+2Cf
Totalmark 20

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SULIT 4s4r/3(PP\

JABATANPELAJARANNEGERIJOHOR

PEPERIKSAAN
PERCUBAAN
SPM2011
CHEMISTRY 4s4u3
Kertas 3
September

SKEMA PEMARKAHAN

UNTT]K KEGTINAAI\IPEMERIKSA SAHAJA

Peraturanpemarkahanini SIILIT dan Hak Cipta Jabatan Pelajaran Negeri Johor.


Kegunaannyaldtusus untuk pemeriksa yang berkenaansahaja.Sebarangmaklurnat
dalam peraturan pemarkahanini tidak boleh dimaklumkan kepadasesiapa.Peraturan
pemarkahanini tidak boleh dikeluarkan dalam apa-apabentukmedia.

Peraturan pemarkahan ini mengandungi18 halaman bercetak

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SULIT 2 4s41l3(PP)

Marking SchemePaper3

Question MarkScheme Score


1(a) Able to stateone inferencefor each experiment-

Sampleanswers:
I Testtube | : lronrusuoxidisedlliron atomreleasedelectron//
iron(ll)ions/ Fe2*formed//
iron(ll)ionspresenU/rustingoccur
Testtubell : lrondoesnotrust// iron(ll)ionsarenotpresent// 3
zincconodesIIzinc atomreleasedelectron//
zincionsformedllzinc oxidised

Testtube lll : lronrusuoxidised ll ironatomreleasedelectron//


iron(ll)ions/Fe2*formexJ tlrustingoccurll
iron(ll)ionspresent

Able to state any two inferences


2

Able to state any one inference


1

No responseorwrong response
0

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SULIT 4541/3(PP)

Question MarkScheme Score


1(b) Able to statethe hypothesisaccurately

Sampleanswer

\A/hena moreflesselectropositive
metalis in contactwith
ironfferum/Fe,
the metalinhibitV(speeds up) rusting/corosionof
iron ll

Whena more/lesselectropositive metalis in contactwith


iron/ferumlFe,
rustingof ironlferumlFe
is faster/slowerll 3
lf the metalin contactwithironis higherflower
thanironlferum/Fe in
electrochemical series,the rusting/conosion
of ironis slower/faster
tl

The higherllowerthe mdal in contactwith iron in electrochemicaf


series/than iron/brum/Fe,the rustingfconosionof ironfierum/Feis
slower/fiaster

Able to state the hypotesis conectly

Sampleanswer

lMren a morcy'less
elec-tropositive
metal,the metalinhibits(speeds
up) rustinglconosion
otironll

lf the metalin contactwithironis higherthanironlferumlFe 2


in
reactivityseries,the rusting/conosionof iron is slorerlf,aster//

The rustingof iron/ferumlFe is faster/slower,


if a more/less
electropositivemetalis in contactwith ironfferum/Fe

Able to state the idea of hypothesis

Sampleanswer

Differentmetalin contactwithiron,will causeironto rust// 1

Metalcancauseironto rust.

No responseor wrong response 0

:lt itl:,. Prlri:,irn \g g' i .1..i . :ti-l-r:


'

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.SLIL[T 4541/3(PP)

Question Mark Scheme Score


1(c) Able to statethe threevariablescorrectly

Sampleanswer:

(i) Manipulatedvariables:
metals// positionof metalin electrochemical
Type/different
series
a
J
(ii) Responding variable:
Rusting/ conosion// presenceof blue/pinkcolour
(iii)Constantvariable:
Size/massof iron nail lltype of nailll cleanironnails//
temperature// mediumin whichthe ironnailsarekept

Able to state any two variablescorrectly. 2

Able to state any one variablecorrectly. I

No responseorwrong response
0

l
I i:,1.i' S{ILIT

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SULIT 4s41l3(PP)

Question MarkScheme Score


1(d) Able to give the operationaldefinition accurately

Sampleanswer

\A/henironis in contactwithmetallowerthanironin electrochemical


series,bluecolouration rusting//
indicates a
J

Rustingoccurswhenironnailis in contactwith copper/tinfless


metalandformbluecolouration//
electropositive

Bluecolourationis formedwhenironis in contactwith metallower


series
thanironin electrochemical

Able to give the operationaldefinition correctly.

Sampleanswer:

indicatesrustingll
Bluecolouration 2

Rustingoccutrswhenironnailis in contactwithcopperftinlless
metal
electropositive

Able to give an idea of the operationaldefinition '

ggpte l: I
Rustingoccurswhenthe colourof solutionchanges.//
Rustingoccurs

No responseorwrong rcsponse 0

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SULIT 4s4U3GP)

Question MarkScheme Score


1(e) Able to predic'tany one the obseruationsbasedon the
laboratoryexperiment correctlY

Sampleanswers
/l
BluespoUcolouration 3

lronnailbecomessmaller//

Leadstripremainsunchanged

Able to predict one observationsless correctly.

$ampleanswgl: 2
PinkspoUcolouration

Able to give an idea of observations.

Sampleansuter; 1
lron rus{s// BrowndeposiUspot

No responseorwnong response 0

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SULIT 4s4113(PP)

Question MarkScheme Score


2(al Able to state both two observationsaccuratelyduring the
experiment.

Sampleanswer:
3
1. Pinksolutiontumscolourless.

2. Conicalflaskbecomeswarm/hot.

Able to state one obseryationaccuratelyduring the


experiment. 2

Able to state any idea of obseruation.

Samoleanswer:

1- Volumeincreases
1
2. Pink

3. Colourless

4. Warm/hot

No responseor wrong response 0

454113 o 201I Hak Cipta JabatanPelajaranNegeri Johor SULIT

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SULIT 4s41l3(PP)

Question MarkScheme Score


2(b) Able to recordthe burettereadingsaccuratelywith 2 decimal 3
points.

Answer

Set Initialreadinq Finalreadinq


I 0.00 26.00
u 0.50 24.50
til 5.50 30.50

Able to recordthe burettereadingscorrectly. 2

Answer

Set lnitialreadino Finalreadinq


I 0 // 4.0 26// 26.0
il 0.5 24.5
Iil 5.5 30.5

Able to record any readingfrom the the burctte completely. 1

SampleAnswer:

Set Initialreadinq Finalreadino


I 0 26
II 1.5 25.5
ill 6.5 31.5

No responseorwrong response 0

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SULIT 4s41l3(PP)

Question Mark Scheme Score


2(c) Able to makea tableto recordthe the datafrom three 3
experimentsaccuratelywith units.

SampleAnswer:

lnitialreading/ Final reading/ VolumeHCI/


Set cm- cm- cmu
I 0.00 26.00 26.00
il 0.50 24.50 24.00
ilr 5.50 30.50 25.00

Able to makea table to recordthe data from three experiments 2


accuratelywithout units or correctlywith units.

1. Answer:
Set Initialreading Finalreading Volume HCI
I 0.00 26.00 26.00
il 0.50 24.50 24.00
ilI 5.50 30.50 25.00

2. answer:
Initialreading/ Finalreading/ VolumeHCI/
Set cm'
cm- cm"
I 0 // 0.0 26// 26.0 26// 26.0
ll 0.5 24.5 24// 24.0
III 5.5 30.5 25// 25.0

Able to make a table to record any data including the 1


following:

- Readingfrom 2(b)
- Headingwithoutunits
- Set of experimenl

or wrongresponse
No response 0

4541/3 O 2011 Hak Cipta JabatanPelajaranNegeriJohor SULIT

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SULIT 10 4s4r/3(PP\

Question MarkScheme Score


2td) Able to calculatethe averagevolumeof hydrochloricacid
accurately.

Answer: 3
26.00+ 24.00+ 25.00= 25.00cm3
3

Able to state the averagevolume of hydrochloricacid


accuratelywith units,

@r: 2

25.00 cm3

Able to statethe ideaof averagevolumeof hydrochloricacid.

Sampleanswen : ' r':r ' ':' 1


'
25.00 ll25.Ott25 tt (Awragereadingdatafrorn2b)i + v {2
3
No responseorwrongresponse 0

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454113 O 2011 Hak Cipta JabatanPelajaranNegeri Johor
SULIT t1 4s41l3(PP)

Question Mark Scheme Score


2(e) Able to state the relationshipbetweenthe concentrationof
hydroxideion, OH-in sodium hydroxide,NaOHwith time until
the end point of titration accurately.

Sampleanswer:
3
of hydroxideions/OH-decreaseswithtime. //
The concentration
of hydroxide
The longerthe timetaken,the lowerthe concentration
ions/OH-

Able to staG tre relationship betweenfie concenfation


hydroxide ion, OH-in sodium hydroxide,NaOHwith time until
the end point of titration inaccurately.

Sampleanswer:
2
decreaseswithtime- //
The concentration

The longerthe timetaken,the loter the concentration

Able to state an idea of the relationship beturcenthe


concentrationhydroxideion, OH'in sodium hydroxide,NaOH
with time until the end point of titration.
'l
Sampleanswer:

decreases// Lowerconcentration
Concentration

No responseorwrongresponse 0

4541/3 o 2011 Hak Cipta JabatanPelajaranNegeri Johor SULIT

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SULIT l2 4s41l3GP)

Question MarkScheme Score


2(fl monoprotic,diproticand triprotic 3
acid accuratelY.

Answer:
Monoprotic,acid Dioroticacid Trioroticacid
acid
Hydrochloric acid
Sulphuric Phosphoricacid
Ethanoicacid
Nitricacid
to monoProtic,diProticand 2
triprotic acid accuratelY.
into monoProtic,diProtic and 1
triprotic acid accuratelY.

No responseor wrong response 0

454113 O 201 t Hak Cipta JabatanPelajaranNegeri Johor


SULIT

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SULIT I3 454u3(PP) :
:

Question MarkScheme Score


3(a) Able to give statementof the problemaccuraGly. 3

Sampleanswer:

Doesthe position/distance betweentwo metalsin electrochemical


difference?II
series affectthe voltmeterreading/voltage/potential

Doesthe positionldistance betweenpairof metalsin


electrochemical seriesaffectthe voltmeterreading/voltage/
potentialdifference?//

Doesthe furtherthe distanceof two metalsin electrochemical


series.increasethe potentialdifference?

Able to give statementof the problem correctly. 2

Sampleanswer:

Doesthe positionidistancebetweenmetalsin Electrochemical


Seriesaffectthe voltmeterreading/voltage/potenti
al difference?|I

affectthe voltmeter
Doespairof metalsin electrochemicalseries
difference?
reading/voltage/potential

Able to give an idea of statementof the problemcorrectly 1

Sampleanswer:

Doesthe position/distance betweentwo metalsin reactivityseries


al difference?II
affectthe voltmeterreading/voltage/potenti

Metalsproducea voltage.

No responseorwrong response 0

454113 @ 2011Hak Cipta JabatanPelajaranNegeri Johor SULIT

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SULIT t4 4s41l3(PP)

eUe to state the three variablescorrectly

Sampleanswer:
variable: Pairsof metals
Manipulated
Respondingvariable:'Voltage// voltmeterreading// potential
difference
variable
Constant : Electrolyte// the metalas the
positive/negative terminal//
volumeandconcentration of electrolyte

Abletbstate any two variablescorrectly

Able to stateany one variablecorrectly

No responseor wrong response

NegeriJohor
Pelajaran
454113O 2011Hak CiptaJabatan SULIT

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SULTT l5 4s41l3(PP)

Able to statethe relationshipbetweenthe manipulatedvariable


and the respondingvariableand statethe directionaccurately.

Samplqanswer:

Thefurtherthedistanceof the pairof metalsin the electrochemical


series,the voltage/ voltmeterreading/ potentialdifference
becomesgreater.//
series,the
Thefurtherthe positionof twometalsin electrochemical
higherthe voltage/ potentialdifferencereading
betweenthe manipulatedvariable
and the respondingvariableand without stating tfie direction.

S3mpleanswer:

The distanceof the pairof metalsin the Elmtrochemical Series.


inffuencesthe voltage/ volfrneterreadingI potentialdifference

Able to state the idea of hypothesiscorrectly

Sampleanswer;
Series,
Thefurtherthe distanceof electrodesin the Electrochemical
the voltage/ voltmeterreading/ potential
differencebecomes-
greater/smaller

Differentmetalsgivedifferentvoltage/ voltmeterreading/ potential


difference

No responseor wrongresponse

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SULIT t6 4s4113GP)

Question Mark Scheme Score


3(d) Able to give adequatelist of materialsand apparatusthat 3
involvesthe following

- Threesuitablemetals[belowcalcium]
- Onesuitableelectrolyte
- Voltmeter,beaker,connectingwires,sandpaper

. Onlytwo materialsand/orapparatuscanlist outfrom


diagram.

Sampleanswer:

Aluminum,zinc,copper,copper(ll)solution,

voltmeter,beaker,connecting
wires,sandpaper

Able to give a list of materialsand apparatusthat involvesthe 2


Following 3 items:

- Two suitablemetals[belowcalcium]
- One suitableelec.trolyte
and container
- Voltmeter

Sampleanswer:

Silver,iron , sivernitratesolution

voltmeter,basinltesttube

Able to give a list of materialsthat involvesthe following 2 1


items:

- Two metals
- Any namedelectrolyte

Sampleanswer:

LithiumandpotassiumllSilverandlead

Hydrochloric
acid

No responseor wrongresponse 0

454113 O 2011 Hak Cipta JabatanPelajaranNegeriJohor SULIT

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SULIT L7 4s41l3(PP)

Question MarkScheme Score


3(e) Able to state the following 6 steps correctly. 3
Sampleanswer:

1. Pour copper(ll)sulphatesolution/ suitableelectrolyte


intoa container/beaker
2. Cleanthe metalstrips/aluminium andcopperwithsand
paper
3. Dip bothmetal/aluminium andcopperintothe electrolyte
4. Connectthe metals/aluminium andcoppertothe
voltmeter//completethe circuit
5. Recordthe voltmeterreading
6. Repeatsteps1 to 5 by subtitutingonemetalfor .
another/aluminiumwithzinc

Able to state the following steps corectly basedon scoie & 2


- Steps 1 or 3
- Step4
- Step5
- Step6

Able to state the following steps conectly basedon score & 1


Step 1 or 3

No responseorwrong response 0

4541/3 @ 2011 Hak Cipta JabatanPelajaranNegeri Johor SULIT

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SULIT 18 4541/3GP)

Question MarkScheme Score


3tf) Able to exhibitthe tabulationof datawhich includesthe 2
I
following three information

1. Headingfor the manipulatedvariable


2. Examplesof two pairs of metals
3. Headingfor the respondingvariablewith units

Sampleanswer;

Pairof metals/Electrodes VoltageA/


Aluminium
andcopper
Zincandcopper

Able to exhibit the tabulationof data which includesthe 1


following information

1. Headingfor manipulatedvariable/responding
variable
without unit
2. Examplesof one pair of metals

Sampleanswer:

MetalVElectrodes Voltage
Aluminium
andcopper

No responseorwrong response 0

END OF MARKING SCHEME

454713 e 20i I Hak Cipta JabatanPelaiaranNeseriJohor SULIT

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