ng 46, el dién tich nguyén t; 21h difn tch hot nhin; e 1 Ning sb den; hla King sb {1a $0 lugng tir chinh (n= 1, 2,5, .. ); « (ke) 13 isgag cle oh eta 6 ace YBiE Mabe: = Grn ses): (ou hin> Mc) ue '#) Tinh bude sng daax (nm) cha diy phd Lyman khi electron chuyén tin = 2'v8 n= 1 tong ti hidro. x Am [By THH sh tuone mg vii buse sing nu cis diy Lyman coy Mke ident gion lle yk Moteri (mbt ding vj cha hidro, wong hat nhin cé méi proton va m6t ootron). Hiéu img ndy 01 Ik Syrehiuyén dich ding vj. Nguyén nbn la do sy Khe bigt vé khdi lugng nit gon gia ote va ido, ‘Tn sr kde bet vé ta s8 Av (H2) cs photon phat x9 kh electron chuydn rn = 28 n= 1 rong doteri vihideo. ©) Positront la mgt he gdm mpx positron, ti hat co dign ich +1, va mOt electron, Khi electon ehuyén Qiei=3 vem =2, be bic xo photon ob bude sing 1 = 1312.am. Tinh khbilagmg mr(kg) a poston. Chiu II (4,0 diém) L ed #m cho biét, NH phan Umg véi BF) tao ra mot chit rin X duy nb, eb miu tring. §) Viet phirong trinh hoa hoc ea phan img. Phin img niy thudc loai ndo? Gidi thie, 9) Viet Ong thie Lewis cba mdi phin ti trong phin img tréa. Cho biét dang binh hoe cia ‘nGi phn tir 26 theo thuyét VSEPR (thuyét vé sy diy gida céc cp electron & 16p vo hOs ir), peecae {gid tr) cha mbi géc lien ket trong phan te ehit X. }.Gin diy, nguti ta tim ra mot logi hyp chit moi, diy hira hen dé len ain liga cho dong eo da tén lia diy. Hyp chit d6 1A NHLAN(NO}) (anon dinitroemit), it che ofing thie Lewis cho anion NINO, vache dang cog hung btn nblt cia mo. Gik wide n ti trong anion nay ddu nim trong mot mat phiiny. ota tit amoni dinitroamit bj phin hiy thinh ki nito, hoi nude va Khi oxi, ha hgc va tinh higu ing nbigt cia phin ing 46,gid 3 dung dich Abu chia 0,166 p KI efe n eo et : i m 1: i i voi 4,04 h 7 eh Bee Ses Gas ct Vdd cl Ooo Ta nua) idm 3: dung dich K1 phn img vira du 6i 160,00 mL dung dich KMnO,. [apsgeiil alent on apn, Dae ‘b) Tinh néng €9 C (mol) eta dung dich KMin0O, 43 ope Sm eh 0040 ody Hc Mo ha ty hi nghigm 1, thu duge hon hi inh thé ic ) KMin Cpa ences tigi ee 2.6 trang thai hoi, cde nguyén tit cia cée nguyént6 kim Logi nhém TA vi nhém IB 6 Kha: hrinh thinh phan ti hai nguyén ti v6i cde ning lugng len ket nh sau: 4 Phin ti, Co | Ap | Au | Ky | Rb i Tagieap ewer esta a pee $0 sinh va gidi thich 5 ben liéu KEl trong eke phn tr kim logs cba nhOm TB vO 6 bea) én Ket trong cic phin tt kim logi cba nhém 1A. thich su khée nhau vé quy luit bién déi cts ede nfing Iugng lién két trong mbt diy phiin ti sau: Cun —Agy- Avr vi K; ~ Ry - Cs, Ciu Vi (4,5 diém) f 1. Tinh Ue Kho chun cis cp FE'7FE* wong mb tubme axit va thE Kt chek a ep | Fe(OH)\/Fe(OH)» trong moi tung kiém. Kha nding khireia Fe) trong mi tring ni manhhon? Cho bikt; E* .,, =-0.440 VE? . ., = -0,036 V : pRIFe(OH)) = 18,78; pRAP (OHH) =a azs 2, Them V (ml) dung dich KyCrs0; 0,02 M vo 100 mt. dung dich FeSOu 012 Mt (ipl Om KhOng déi trong svdt qui trinh phan img), dung dich A. Tinh thé Khu cia ep Pet? trong dung dich A o mei truimg hyp sau diy) = SO ni) = 100 mb i) Y= 101i Cho bit: £8 og OTIS Ee ype =1330V Moi bai (3p hoa phi tich co diu bis nhu saw: “Tin 15,00 mL. dung dich HCL inbag 9 C (moll!) sen Mineo ‘NaC304 0,100 M, thy duge dung dich X e6 pH™ 1,25. Tink réng 40 ClenoF =!" BE tinh nding d C (mol) 46, mot hoe sinh Xp tan nu sau ‘Vi pH = pKa" 125, f2y rh (F,C,0.) #1H1C,0;) >> (C,0% |, nn Us dug 18 dm. Nis wy, Is trung hda hit nic 1 va trung hoa hét nia nde 2 eta C04, te 18 trang hoa bit 15 nfeceia COP 4s. ‘i == 0 1h Do ds, C= Beam sil 4) Bing cdc Ifp 1uin va tinh todn, cho biét hac sn gist jing hay sai 1b) Tinh néng d C(mo! L') cua dung dich HCL da et ale ] inh dheoe $b, gids dung. dich X ch chita H2Cy0u 0,016 ee sii al a Sh 0 dpe i in 1M vbia ») sin entropy AS* (1K!) khi nhigt 66 ci co th tng ti Heats, i (9 Tith bién thin ning hog ty do Gibbs 8G" pki mht 6p cisco ting tr Kent. Bid ing, Cea nse ti 36,5°C, 5*= 72,6 }"!mor!. AC? trong trulng bop thy dape lah ey sng this: AG" = af? ~'A(TS*) = aH? — AT. TAS" Niu th sinh Yad tinh oe civ e.g nly 40° =1,2 10 58 tinh lp, 2 GUt 58 cao, co thé mit ntnglueng cbt cch vi ich: Gis cdg vl planing lnm Kbi libs, ngudi dy chay dupe ms quing duimg dai nbit ld bao nhieu kan? Diet ring, nfiag tugng. fiBu thy ki choy mdi 1 km la 200 6. 2 Mot més Ni(khi) (coi Nz 1a khi li rung) 19i 350 K vi 2,50 bar dupe cho ting thé tich tn gp ba ln trong qua trinh gin nd doan nhigt bas than nghich 16 lal ap sult ben ngodi khong Gb, Puyo = 0.25 bar. Ting cng gidn no cis bé 13-873} 9) Tinh ele bién thign entropy a (1K) cus hg. cus na ruoag wang quanh VA che We Bp trong qué trinh tréa : 1) Dai Iugng nto trong céc 43: Ivory di nh cho bk bh ntng ty didn bide ea Chu IV (3,5 diem) Ian yen chin 2 nei, °C 98.9% A vt (9 ne agg tng i png v9 "Ch fn ~ 570). Hot pg 9 lees sergio dag ast han 1 pe ho on lh Dg Cabo tong cia con thin nly eS hog png eng 180 BRE esa sg "or ATCC frog co Steg i ead BY 68 ding les gb dng yoy ven dupe doh vio ot to i 6 trung binh cia ede gid tj do duge, cho sai sb trang bln ag vt eeiea ee cra ago wn ao Ce ta aeetes hoa a ? IP rattcaed techiake os pp A PET 1c ole tg bp. PET ge wa “Sunil tin sui 1 Sn a nn aos pe Avi B.