TRNG THPT NG QUYN K THI TRUNG HC PH THNG QUC GIA NM 2017

THAM KHO Bi thi : Khoa hc t nhin; Mn: Ha hc

( thi gm c 4 trang) Thi gian lm bi: 50 pht, khng k thi gian giao
Cho bit: H = 1; Li = 7; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; Ca = 40; K = 39;
Fe = 56; Cu = 64; Zn = 65; Ag = 108.
Cu 1. Tn gi ca este c cng thc cu to HCOOCH(CH3)2 l:
A. Isopropyl fomat B. Propyl fomat C. Propyl metanoat D. Etyl fomat
Cu 2. Cho cu hnh electron nguyn t trng thi c bn ca cc nguyn t nh sau:
(1) 1s22s22p63s23p64s1 (2) 1s22s22p63s23p4 (3) 1s22s22p63s23p1
(4) 1s22s22p3 (5) 1s22s22p63s2 (6) 1s22s22p63s1
Cc cu hnh electron khng phi ca kim loi l:
A. (2), (4) B. (2), (4), (5), (6) C. (1), (2), (3), (4) D. (2), (3), (4)
Cu 3. Cho hn hp kh H2 v Co d i qua ng s ng cc cht sau: CaO, CuO, PbO, Fe3O4, Al2O3, Na2O,
CuSO4, AuCl3, MgO, NiO. S cht b kh thnh kim loi:
A. 5 B. 4 C. 6 D. 7
Cu 4. Mt este c cng thc phn t l C4H6O2, khi thy phn trong mi trng axit thu c axetanehit. Cng
thc cu to thu gn ca este l:
A. HCOOC(CH3)=CH2 B. HCOOCH=CHCH3
C. CH3COOCH=CH2 D. CH2=CHCOOCH3
Cu 5. Cho 700 ml dd KOH 0,1M vo 100 ml dd AlCl3 0,2M. Sau phn ng khi lng kt ta to ra l
A. 0,78 g B. 1,56 g C. 0,97 g D. 0,68 g
Cu 6. Cho cc dung dch sau: (1) H2N-CH2-COOH, (2) Cl-NH3+-CH2-COOH, (3) H3N+CH(CH3)COO-, (4)
H2N(CH2)2CH(NH2)COOH, (5) HOOC(CH2)2CH(NH2)COOH. Dung dch no lm qu tm ha ?
A. (3) B. (2) (C). (2), (5) D. (1), (4)
Cu 7. Dy gm cc cht u tc dng vi Cu l
A. AgNO3, O2, H3PO4. B. FeCl3, O2, H2SO4 c, Cl2.
C. FeCl3, HNO3, HCl c, Cl2. D. HNO3, H2SO4 long, AgNO3.
Cu 8. Ha tan m gam Fe trong dung dch HNO3 c nng, d thu c 8,064 lit NO2 (sn phm kh duy nht,
ktc). Gi tr ca m l:
A. 8,96 B. 6,16 C. 6,72 D. 10,08
Cu 9. Cho 14,92 gam hp kim st v ng vo dd HCl d thy thot ra 2,688 lit kh (ktc) v cn li m
gam cht rn. Gi tr ca m l:
A. 8,2 B. 5,6 C. 10,0 D. 6,4
Cu 10. Loi t no sau y thuc t thin nhin?
A. nilon-6,6 B. T visco C. T tm D. T lapsan
Cu 11. Cho cc nhn nh sau:
(a) Ch c hai ng phn este n chc ca C4H8O2 tc dng vi dung dch AgNO3/NH3 sinh ra Ag.
(b) Este to bi ancol isoamylic v axit isovaleric c cng thc phn t C10H20O2.
(c) Khi thy phn HCOOC6H5 trong mi trng kim d ch thu c hai mui.
(d) Etyl axetat kh tan trong nc hn axit axetic.
(e) Triolein tc dng c vi Cu(OH)2 iu kin thng.
(f) Benzyl axetat l este c mi chui chn.
S nhn nh ng l
A. 3 B. 5 C. 6 D. 4
Cu 12. Cho s chuyn ha cc cht ca crom:
+ +(2 + ) +2 4 +4 + 2 4
Cr(OH)3 X Y Z T.
Trang 1 / 4
 Cc cht X, Y, Z, T theo th t ln lt l:
A. K[Cr(OH)4], K2CrO4, K2Cr2O7, Cr2(SO4)3 B. K2CrO4, K[Cr(OH)4], K2Cr2O7, Cr2(SO4)3
C. K[Cr(OH)4], K2Cr2O7, K2CrO4, Cr2(SO4)3 D. K[Cr(OH)4], K2Cr2O7, K2CrO4, CrSO4
Cu 13. Cacbohidrat no sau y khng phn ng vi hidro (xc tc Nt, un nng)?
A. Glucoz B. Saccaroz C. Mantoz D. fructoz
Cu 14. Cho 4 kim loi X, Y, Z, T ngu nhin tng ng vi Ag, Al, Fe, Cu v bng gi tr in tr ca cc kim loi
tng ng nh sau:
Kim loi X Y Z T
in tr () 2,82.10 -8
1,72.10 -8
1,00.10 -7
1,59.10-8
Y l kim loi
A. Fe B. Ag C. Cu D. Al
Cu 15. Cho m gam glucoz phn ng hon ton vi lng d dung dch AgNO3 trong NH3 un nng thu c
21,6 g Ag. Gi tr ca m l
A. 9,0 B. 18,0 C. 16,2 D. 36,0
Cu 16. Mt loi qung st sau khi loi b tp cht cho tc dng vi HNO3 khng c kh thot ra. Tn ca qung
l:
A. Hemantit B. Manhetit C. Pirit D. Xierit
Cu 17. X phng ha 14,43 gam este CH3COOCH3 bng dung dch NaOH. Khi lng dung dch NaOH trong
dung dch cn dng l:
A. 7,80 gam B. 6,00 gam C. 9,30 gam D. 8,74 gam
Cu 18. Pht biu khng ng l
A. Glyxin tc dng c dung dch NaOH v dung dch HCl v khng lm i mu qu tm.
B. Riu cua ni ln khi un nng l hin tng ng t protein.
C. C hai lin kt peptit trong phn t ipieptit mch h.
D. Dung dch lng trng trng ha tan c Cu(OH)2 cho phc mu tm.
Cu 19. Cho cc phn ng sau:
(1) BaCO3 + dung dch H2SO4
(2) dung dch Na2CO3 + dung dch CaCl2
(3) dung dch NaHCO3 + dung dch Ba(OH)2
(4) dung dch (NH4)2SO4 + dung dch Ba(OH)2
(5) dung dch Na2S + dung dch CuSO4
S phn ng to ng thi kt ta v kh bay ra l:
A. 1 B. 2 C. 3 D. 4
Cu 20. Thy phn hon ton 76,95 gam mt pentapeptit (to t valin) bng dung dch NaOH va th lng
mui thu c l:
A. 105 gam B. 106,8 gam C. 104,25 gam D. 108,04 gam
Cu 21. T 4 tn etilen cha 30% tp cht tr c th iu ch bao nhiu tn P.E. bit hiu sut phn ng t 90%.
A. 2,55 B. 2,52 C. 2,8 D. 3,6
Cu 22. Cho m gam hn hp X gm Al, Cu vo dung dch HCl (d), sau khi kt thc phn ng sinh ra 3,36 lt kh
( ktc). Nu cho m gam hn hp X trn vo mt lng d axit nitric (c, ngui), sau khi kt thc phn ng sinh
ra 6,72 lt kh NO2 (sn phm kh duy nht, ktc). Gi tr ca m l
A.11,5 B. 10,5 C. 12,3. D. 15,6
Cu 23. Ion kim loi X khi vo c th vt mc cho php s gy nguy him cho s pht trin c v tr tu ln th
cht con ngi. cc lng ngh ti ch c qui c, nhiu ngi b ung th, tr em chm pht trin tr th, ci cc v
nhim c ion kim loi ny, kim loi X y l:
A. Pb B. Mg C. Cu D. Fe
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Cu 24. Khi cho hn hp nhm v bari vo nc, nhn thy hn hp tan ht. iu ny chng t:
A.Nc d v nAl 2nBa B.Al tan hon ton trong nc
C.Nc d D.Nc d v nBa 0,5nAl
Cu 25. Sobitol l cht kch thch thiu ha, dng tt cho tr bing n, tr b ri lon tiu ha do ung khng sinh.
Sobitol c iu ch bng cch hidro ha glucoz. Tnh khi lng glucoz dng iu ch c 100 kg
sobitol thnh phm gn ng vi gi tr no sau y ( hiu sut phn ng l 85%, trong qu trnh iu ch c 3%
sobitol b tht thot)
A. 116,40 kg B. 120 kg C. 111,4 kg D. 112,9 kg
Cu 26. Khi tin hnh sn xut nhm bng phng php in phn nng chy Al2 O3, ngi ta tin hnh ha
tan oxit ny trong criolit (Na 3 AlF6) nng chy. Pht biu no sau y khng ng vi mc ch s dng
criolit?
A. Cung cp thm nhm cho sn xut.
B. H nhit nng chy ca oxit nhm.
C. To c cht lng dn in tt hn
D. Hn hp Al2O3 + Na3AlF6 ni ln trn , bo v Al nng chy nm pha di khi b khng kh oxi ha.
Cu 27. Dung dch X cha 0,02 mol ClH3N-CH2-COOH v 0,1 mol HCOOC6H5. Cho dung dch X tc dng vi
130 ml dung dch NaOH 2M un nng phn ng xy ra hon ton. C cn dung dch sau phn ng thu c m
gam rn khan. Gi tr ca m l
A. 23,93 B. 26,78 C. 22,31 D. 28,92
Cu 28. Khi nhng thanh km vo dung dch H2SO4 long, sau mt thi gian phn ng, nh thm vi git dung
dch CuSO4. Hin tng quan st c l:
A. Khng c kh m ch c ng bm vo thanh km.
B. Thy bt kh thot ra chm hn.
C. Dung dch chuyn sang mu nu.
D. Thy bt kh thot ra nhanh hn.
Cu 29. t chy m gam cht bo X cha triglixerit ca axit stearic, axit panmitic. Sau phn ng thu c 13,44 lit
CO2 (ktc) v 10,44 gam nc. x phng ha m gam X (H = 90%) th thu c khi lng glixerol l:
A. 0,92 B. 1,656 C. 0,828 D. 2,484
Cu 30. Cho a mol bt Mg vo dung dch c ha tan x mol Fe(NO3)3 v y mol Cu(NO3)2. Tm iu kin lin h
gia a, x, y sau khi kt thc phn ng thu c hn hp rn gm 3 kim loi.
A. + 2 B. 2 + < 2 C. 2 > 3 + 2 D. 2a = x + 2y
Cu 31. Cho 13,2 gam mt cht hu c X c cng thc phn t l C2H10O3N2 tc dng vi 300 ml dung dch NaOH
1M. c cn dung dch sau phn ng thu c phn rn ch cha cc hp cht v c c khi lng m gam v phn
hi cha hai kh u lm qu tm m ha xanh. Gi tr ca m l:
A. 15,90 gam B. 15,12 gam C. 17,28 gam D. 12,72 gam
Cu 32. t chy hon ton mt amin n chc, mch h X bng mt lng khng kh (cha 20% th tch oxi, cn
li l nit) va thu c 0,08 mol CO2, 0,1 mol H2O v 0,54 mol N2.khng nh no sau y l ng.
A. S nguyn t H trong X l 7.
B. Gia cc phn t X khng c lin kt hidro lin phn t.
C. X khng phn ng vi HNO2.
D. S ng phn cu to tho mn iu kin ca X l 1.
Cu 33. Tin hnh in phn dung dch cha Cu(NO3)2 1,2M v KCl 0,4M bng in cc tr vi cng dng
in khng i I = 5A trong thi gian 6176 giy th dng in phn thy khi lng dung dch gim 15,0 gam. Cho
0,25 mol bt st vo dung dch sau in phn, kt thc phn ng thy kh NO thot ra (sn phm kh duy nht),
ng thi thu c m gam hn hp rn. gi tr ca m l:
A. 10,16 gam B. 8,48 gam C. 8,32 gam D. 9,6 gam
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 Cu 34. Phn ng in phn dung dch CuSO4 vi in cc tr v phn ng n mn kim loi xy ra khi
nhng hp kim Zn Cu vo dung dch HCl c c im ging nhau l:
A. Phn ng xy ra lun km theo s pht sinh dng in.
B. Phn ng cc dng u l s oxi ha Cl -.
C. cc dng u to ra kh.
D. Catot u l cc dng.
Cu 35. Ha tan hon ton 12,42 gam Al bng dung dch HNO3 long (d), thu c dung dch X v 1,344 lt (
ktc) hn hp kh Y gm hai kh l N2O v N2. T khi ca hn hp kh Y so vi kh H2 l 18. C cn dung dch X,
thu c m gam cht rn khan. Gi tr ca m l
A. 97,98 B. 106,38 C. 38,34 D. 34,08
Cu 36. Hn hp A gm este n chc X v hai este no, hai chc, mch h Y v X (MY < MZ). t chy hon ton
8,85 gam A cn va 0,4075 mol O2, thu c 4,95 gam H2O. Mt khc 8,85 gam A tc dng va vi 0,13
mol NaOH, thu c 4,04 gam hai ancol no, n chc k tip trong dy ng ng, c cn dung dch thu c m
gam hn hp mui T. Gi tr ca m l:
A. 9,74 B. 10,01 C. 8,65 D. 12,56
Cu 37. Ha tan hon ton 51,3 gam hn hp X gm Na, Ca, Na2O v CaO vo nc thu c 5,6 lit kh H2
(kc) v dung dch Y, trong c 28 g NaOH. Hp th 17,92 lit SO2 (ktc) vo dung dch Y thu c m gam kt
ta. Gi tr ca m l:
A. 60 B. 54 C. 72 D. 48
Cu 38. Cho CO2 t t vo dung dch hn hp gm
Ca(OH)2 v KOH, ta c kt qu th nghim c
biu din nh th sau ( s liu tnh theo n v
mol). Gi tr ca x l:
A. 0,12 B. 0,10
C. 0,13 D. 0,11

Cu 39. em 52,88 gam hn hp X gm Al v Fe3O4 thc hin phn ng nhit nhm trong iu kin khg c khng
kh, sau mt thi gian thu c hn hp Y. chia Y thnh hai phn bng nhau:
- Phn 1: cho phn ng vi dung dch HNO3 c, nng d thu c 10,304 kit kh NO2 (sn phm kh duy
nht, ktc)
- Phn 2: cho phn ng va vi m gam dung dch gm HCl 14,6% v H2SO4 14,7%, sau phn ng thu
c 2,8 lit kh H2 (ktc). Gi tr ca m l
A. 160 B. 150 C. 320 D. 200
Cu 40. Hn hp X gm FeO, FeCO3, CuO, CuCO3, Fe3O4 trong oxi chim 31,381% khi lng. nung 36,2 gam
hn hp X trong iu kim khng c khng kh n khi lng khng i thu c 30,48 gam hn hp Y. Cho
36,2 gam hn hp X tc dng vi dung dch H2SO4 c nng d thu c 5,04 lit hn hp kh ( kc, SO2 l sn
phm kh duy nht). Cho 36,2 gam hn hp X tc dng vi HNO3 thu c hn hp kh gm CO2, NO v NO2 c
t khi vi hidro l 21,125 ( ngoi NO v NO2 khng cn sn phm kh no khc). S mol HNO3 tham gia phn
ng l:
A. 1,40 B. 1,20 C. 1,60 D. 0,80

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 P N
1A 2A 3B 4C 5A 6C 7B 8C 9A 10C
11D 12A 13B 14C 15B 16A 17A 18C 19B 20C
21B 22C 23A 24A 25B 26A 27C 28D 29C 30C
31B 32D 33D 34C 35B 36A 37C 38B 39B 40B

Cu 1.
HCOOCH(CH3)2 : isopropyl fomat
p n A
Cu 2.
(1), (3), (5), (6): kim loi
(2), (4): phi kim
p n A
Cu 3. C 4 cht b kh l CuO, PbO, Fe3O4, NiO
p n B
Cu 4. :
+
CH3COOCH=CH2 + H2O CH3COOH + CH3CHO
p n C
Cu 5.
0,07
= = 3,5 to Al(OH)3 x mol v AlO2- y mol
3+ 0,02
x + y = 0,02 v 3x + 4y = 0,07 x = y = 0,01
m kt ta = 0,01 . 78 = 0,78
p n A.
Cu 6.
(1), (3): qu tm khng i mu
(2), (5): qu tm ha
(4): qu tm ha xanh
p n C
Cu 7. .
p n B
Cu 8.
Bo ton e: 3nFe = nNO2 = 0,36 nFe = 0,12 m = 6,72
p n C
Cu 9.
Fe + 2HCl FeCl2 + H2
= 2 = 0,12 m = mCu = 14,92 0,12 . 56 = 8,2 g
p n A
Cu 10.
Nilon-6,6: t tng hp
T visco: t nhn to
T tm: t thin nhin
T lapsan: t tng hp
p n C
Cu 11.
a ng. 2 ng phn l HCOOCH2CH2CH3 v HCOOCH(CH3)2.
b ng. Ancol isoamylic (C5H12O) v axit isovaleric (C5H10O2) to este c cng thc C10H20O2
c ng. HCOOC6H5 + 2 NaOH HCOONa + C6H5Ona + H2O
d ng. Axit axetic to lin kt hidro lin phn t trong nc nn tan tt troong nc. etyl axetat phn
cc km, khng to c lin kt hidro lin phn t torgn nc nn kh tan.
e sai. Triolein khng cn nhm OH gn vi hai C k nhau nn khng cn kh nng to phc vi
Cu(OH)2
f sai. Isoamyl axetat l este c mi chui chn. Cn benzyl axetat c mi hoa nhi.
p n D
Cu 12.
p n A
Cu 13.
Saccaroz l khng cn nhm CHO nn khng phn ng c vi hidro.
p n B
Cu 14.
Y c in tr nh th 2 trong 4 kim loi nn kh nng dn in ca Y tt th 2 trong 4 kim loi Y l Cu
p n C
Cu 15.
nglucoz = nAg / 2 = 0,1 mglucoz = 0,1 . 180 = 18 g
p n B
Cu 16.
Qung st phi cha hp cht trng thi oxi ha cao nht ca st: Fe2O3
p n A
Cu 17.
14,43
= = = 0,195 = 40 .0,195 = 7,8
74
p n A
Cu 18.
A ng. Glyxin (H2N-CH2-COOH) c 1 nhm NH2 v 1 nhm COOH nn tc dng c vi NaOH, HCl v
khng lm i mu qu tm.
B ng. Trong nc lc cua cha nhiu protein, khi gp nhit cao s b ng t.
C sai. Ch c 1 lin kt peptit trong phn t ipeptit.
D ng. Dung dch lng trng trng cha nhiu protein ( bn cht l polipeptit) nn c th tham gia phn ng
biure vi Cu(OH)2
p n C
Cu 19.
(1) BaCO3 + H2SO4 BaSO4 + H2O + CO2
(2) Na2CO3 + CaCl2 CaCO3 + 2 NaCl
(3) 2NaHCO3 + Ba(OH)2 BaCO3 + Na2CO3 + 2H2O
(4) (NH4)2SO4 + Ba(OH)2 BaSO4 + 2NH3 + 2H2O
(5) Na2S + CuSO4 Na2SO4 + CuS
C phn ng (1) v (4) to ng thi kt ta v kh bay ra
 p n B
Cu 20.
Pentapeptit + 5 NaOH mui + H2O
76,95
npentapeptit = 117 . = 0,15
5 18 . 4
m mui = 76,95 + 0,15 . 5 . 40 0,15 . 18 = 104,25
p n C
Cu 21.
mPE = 4 . 0,7 . 0,9 = 2,52 tn
p n B
Cu 22.
2
X + HCl = 3
2 = 0,1 mol
1
X + HNO3 c, ngui = 2 = 0,15
2
m = 0,1 . 27 + 0,15 . 64 = 12,3
p n C
Cu 23.
p n A
Cu 24.
Ba + H2O Ba(OH)2 + H2
nBa nBa
Al + OH + H2O AlO2- + 3/2 H2
-

nAl nAl
Kim loi tan nn nc d v = 2 nBa nAl
p n A
Cu 25.
Glucoz + H2 Sobitol
Khi lng sobitol thc t cn iu ch l 103 kg
103 . 180
Khi lng glucoz cn l 182 . = 119,85 120
0,85
p n B
Cu 26.
.Trong thnh phn criolit cha nhm nhng lng nhm ny khng tham gia phn ng.
p n A
Cu 27.
ClH3N-CH2-COOH + 2 NaOH mui + 2 H2O
HCOOC6H5 + 2NaOH mui + H2O
S mol nc: 2. 0,02 + 0,1 = 0,14
Bo ton khi lng: m = 111,5 . 0,02 + 122. 0,1 + 0,26 . 40 18 . 0,14 = 22,31 g
p n C
Cu 28.
Khi nhng thanh km vo dung dch H2SO4 long thy c kh H2 thot ra. Sau khi thm vi git CuSO4, trong
dung dch xut hin hai in cc: Zn (anot), Cu (catot) lm cho kh H2 thot ra nhiu hn catot v Zn tan
nhanh hn anot
p n D.
Cu 29.
Triglixerit X c bi lin kt k = 3 2 2 = 2 . = 0,01 mol
thc t = 92 . 0.01 . 90% = 0.828
p n C
Cu 30.
Hn hp rn gm 3 kim loi: Cu, Fe, Mg d 2a > 3x + 2y
p n C
Cu 31.
X: NH4OCOONH3CH3
NH4OCOONH3CH3 + 2 NaOH Na2CO3 + NH3 + CH3NH2 + 2 H2O
0,12 0,24 0,12
m = (0,3 0,24) . 40 + 0,12 . 106 = 15,12
p n B
Cu 32.
1
.Bo ton oxi: 2 = 2 + 2 = 0,13 2 () = 0,13 . 4 = 0,52 2 () = (0,54 0,52) = 0,02
2
= 0,04
X: CxHyN. do : x = 0,08/0,04 = 2, y = 2. 0,1 / 0,04 = 5 C2H5N (CH2=CH-NH2)
p n D
Cu 33.
Cho thm bt Fe vo dung dch sau in phn thy c kh NO thot ra xy ra in phn nc anot to H+.
Sau phn ng thu c hn hp rn Cu2+ cn d
1
Cu2+ + 2 Cl- Cu + Cl2 ; Cu2+ + H2O Cu + 2 H+ + 2 O2
x 2x x x y y y 2y 0,5y
64(x+y) + 71x + 32 . 0,5y = 15
5 .6176
x + y = 2. = 0,16
96500
x = 0,04 , y =0,12
nKCl = 2x = 0,08 v (3 )2 = 3. 0,08 = 0,24
dung dch sau in phn: Cu2+ = 0,24 0,16 = 0,08 mol, H+ = 0,24 mol, NO3- = 0,48 mol
3Fe + 8H+ + 2NO3- 3Fe2+ + 2NO + 4H2O ; Fe + Cu2+ Cu + Fe2+
0,24 0,08
3
m = mCu + mFe d = 0,08 . 64 + 56 . (0,25 - 8 . 0,24 0,08) = 9,6
p n D
Cu 34.
Phn ng in phn dung dch CuSO4:
Catot ( - ): Cu2+ + 2e Cu v Anot ( +): 2Cl - Cl 2 + 2e D sai
Phn ng n mn in ha: Zn ng vai tr cc m (anot), Cu ng vai tr cc dng (catot):
Catot (+): 2H + + 2e H2 v anot ( - ) Zn Zn2+ + 2e B sai
A sai do in phn khng to ra dng in.
p n C
Cu 35.
N2O: a mol v N2: b mol
 Ta c: nY = a + b = 0,06 v mY = 44 a + 28 b = 0,06.2.18 = 2,16 a = b = 0,03 ne = 0,54 mol
nAl = 0,46 mol ne = 0,46 . 3 = 1,38 > 0,54 c mui NH4NO3: x mol
ta c: 0,54 + 8x = 1,38 x = 0,105 mol
m mui = 0,46 . 213 + 0,105 . 80 = 106,38
p n B
Cu 36.
t s mol ca X l a, Y v Z l b
Bo ton khi lng: 2 = 8,85 = 32 . 0,4075 4,95 = 16,94 g 2 = 0,385 mol
Bo ton nguyn t O: 2a + 4b = 2 . 0,385 + 0,275 2 . 0,0475 = 0,23
nNaOH = a + 2b = 0,115 < 0,13 A cha este ca phenol nphenol = 0,13 0,115 = 0,015
A + NaOH mui + ancol + H2O
Bo ton khi lng: m = 8,85 + 40 . 0,13 4,04 0,015 . 18 = 9,74 gam
p n A
Cu 37.
quy hn hp X v Na (a mol ), Ca (b mol ), O (c mol)
23a + 40b + 16c = 51,3
nNaOH = a = 0,7
BT electron: a + 2b = 2c + 2. nH2 a + 2b 2c = 0,5
a = 0,7, b = 0,6, c = 0,7 s mol OH- = a + 2b = 1,9
1,9
= = 2,375 mui CO32-: 0,8 mol
2 0,8
m kt ta = 0,6 . 120 = 72 gam
p n C
Cu 38.

Khi cho 0,15 mol CO2 thu c kt ta cc i: 2 = 2+ = 0,15

Khi cho 0,45 mol CO2 kt ta bt u tan, dung dch cha KHCO3:
2 = + 3 = 0,15 + 3 = 0,45 3 = = 0,3
Khi cho 0,5 mol CO2: kt ta tan mt phn. t CO32-: x mol , HCO3-: y mol
2 = x + y = 0,5 v = 2x + y = 0,6 x = 0,1, y = 0,4
p n B
Cu 39.
52,88 g X c 2x mol Al v 2y mol Fe3O4
27.2x + 232 . 2y = 52,88
Bt electron: 3x + y = nNO2 = 0,46
x = 0,12 v y = 0,1
Phn 2 + dung dch (HCl, H2SO4) mui + H2O + H2
 S mol H2O = nO (oxit) = 4y = 0,4
BT nguyn t H: nHCl + 2. nH2SO4 = 2. nH2O + 2. nH2
.14,6 .14,7
+ 2. 100.98 = 2 .0,4 + 2.0,125 m = 150
100.35,5
p n B
Cu 40.
36,2 .31,381%
S mol O trong X = = 0,71
16
Bo ton khi lng: mCO2 = mX mY = 5,72 n = 0,13
Quy i X thnh x mol Fe, y mol Cu, 0,71 mol O v 0,13 mol C.
56x + 64y + 0,71 . 16 + 0,13 . 12 = 36,2
X + H2SO4 c nng:
5,04
nSO2 = 22,4 0,13 = 0,095 mol
BT electron: 3x + 2y + 4. 0,13 = 2. 0,71 + 2 . 0,095
x = 0,29 v y =0,11
X + HNO3 hh kh (CO2: 0,13 mol, NO a mol, NO2 b mol)
BT electron: 3.a + b = 2, nSO2 = 0,19
44.0,13+30 +46
= 2.21,125 = 42,25
0,13++
a = 0,04, b = 0,07
nHNO3 = 3x + 2y + 0,04 + 0,07 = 1,2 mol
p n B