Qu Q2 Q3 Q4 Qs Q6 Q7 [SINGLE CORRECT CHOICE TYPE] ‘The correct order of ionic radius is~ (A) Ce> Sm>Tb> Lu (B) Lu> Th> Sm>Ce (©) Tb>Lu>Sm> Ce (D) Sm>Tb> Lu> Ce [2010110651] The Zfor 3d electron of Cr dselectron of Cr 3d electron of C+ 3selectron of Cr* are in the order respectively (A) 4.6, 2.95, 4.95, 8.05 (B) 4.95, 2.95, 4.6, 8.05 (C) 4.6, 2.95, 5.3, 12.75 (D) none of these 2010110575] According to the Periodic Law of elements, the Vs of elementsis related to their? (A) Nuclearmasses (B) Atomic numbers (C) Nuclear neutron-proton number ratio: (D) Atomic masses [2010112297] Atomic radius decreases in a period, butafter halogens, the atomic radius suddenly increases. ‘Thus, inert gases has almost highest radius in a period. The explanation for such an increase is- (A) Inert gases has most stable configuration (B) Inert gases do not take part in bonding (©) Vander Wall’s radius is reported in case of inert gases (D)None ofthese [2010110748] Which one of the following groups represent a collection of isoelectronic species ? (At. no. Cs = 55, Br=35) (A) N*, F, Na* (B) Be, A", Cr (C)Ca™*,Cs*, Br (D) Na*, Ca", Mg* [2010110847] Consider the following statements: 1. The radius of an anions larger than that of parent atom Il The LE. increases from left to right in a period generally IIL The electronegativity ofan elementis the tendency ofan isolated atom to attract an electron The correct statements are - (A)Lalone (B) alone (©) and It (D) and iit [2010110542] ‘The atomic numbers of vanadium (V). Chromium (Cr), manganese (Mn) and iron (Fe) respectively 23, 24,25 and 26. Which one of these may be expected to have the higher second ionization enthalpy ? (ayer (B)Mn (©Fe wmv [2010111695]Qs Qo Qu0 Qui Qu2 Qu3 Qu4 Qus Element P, Q, R and S belong to the same group. The oxide of P is acidic, oxide of Q and R are amphoteric while the oxide ofS is basic. Which of the following elements is the most electropositive? (AP. @B)Q (COR (D)S [2010111644] Among Al,O,, SiO,, P,O, and SO, the correct order of acidic strength is : (A) Al,0, < SiO, < SO, < P,O; (B) SiO, < SO, Pb** > Pb (B) Pb> Pb** > Pb** (C) Pb > Pb** > Pb?* (D) Pb**> Pb > Pb? [2010110524]Q6 Qu7 Qus Quis Q.20 Q21 A Ketelaar triangle showing a plotof average electronegativity (ean) against electronegativity difference (AZ) can be used to classify the bond type forbinary compound. Which of the following compoundshas highest (4%) percentage of ionic character? (aye, (B)XY (aB (D) All have equal ionic character mies [2010110544] Match list-1 with list-Il and select the correct answer using the codes given below: List List (element) (Cleetronie configuration) @ Gallium 15%28*2p%3s?3p%ds*3d! (b) Vanadium ii, 13*2822p%3s?3p%4s?3d!” © Zin 1322322p%3st3p%4s"3d!4p! (d) Scandium 1372s*2p%3s?3p%4s?3d3 Codes - ® © @) (a) ii v ® # w i i OQ a oy eri Mota © ii [2010112595] Theac sxhibit more number of oxidation states in general than the lanthanoids. Thisis because (A) the Sforbitals are more buried than the 4f orbitals (B) there isa similarity between 4fand 5forbitals in their angular partof the wave function (C) the actinoids are more reactive than the lanthanoids (D) the Sforbitals extend farther from the nucleus than the 4f orbitals, (2010111245), For the process X(@) +e —> X(w), aH =xand X12) —> X(g)+e. AH=y Select correct alternate (A) lonization energy of X-(g) isy (B) Electron affinity of X(g) isx (C) Electron affinity of X(g) is—y (D)Allarecorrectstatements [2010111939] Sodium forms Nat ion but it does not form Na’ because - (A) Very low value of IE, and IE, (B) Very high value of IE, and IE (© High value of IE, and low value of IE, (D) Low value of IE, and high value of IE, [2010111196 Lanthanoids are - (A) 14elements in the seventh period (Atomic no. = $8 to 71) thatare filling 4f subshell (B) 14 elements in the sixth period (atomic no. = 90 to 103) that are filling 4fsubshell (C) 14 elements in the seventh period (atomic no. = 90 to 103) that are filling 5fsubshell (D) 14 elements in the sixth period (atomic no. = 58 to 71) that are filling 4f subshell {2010111641}Q22 Q.23 Q.24 Q.25 Q.26 Q27 2.28 Q.29 230 Bond distance CF in (CF,) & Si-F in (SiF,) are respective 1.33A & 1.54 A. C-Si bond is 1.87 A. Calculation the covalent radius of F atom ignoring the electronegativity differences, EB SeeIS (]osA oa [2010111545] (A) 0.64 A (B) ‘The lowest electronegativity of the element from the following atomic numbers. (A)37 (B)55 ©9 (D)35 [2010110897] ‘The correct order regarding the electronegativity of hybrid orbitals of carbon is? (A) sp < sp? < sp* (B) sp> sp? sp?> sp? (D) sp < sp? > sp* [2010112250] fthere were 10 periods in the periodic table then how many elements would this period ean maximum comprise of. (a)50 (72 (©32 (D) 98 [2010111251] The conect order of increasing hydration energy of following ion is (A) Fe"?< Co? < Fe" (B) Fe"? Fe® (©) Fe? >Co™ > Fe? (D) Fe"? < Fe" < Co [2010112300] Consider the M(OH), formed by all the group 13 elements. The correct sequence of acidie strength of hydroxides [M(OH),] is- (A) BOH), Ga(OH), > InOH), > THOH), (B) BOH), > TKOH), > Al(OH), > InOH), > Ga(OH), (C)AIOH),> Ga(OH), > BCOH),> —In(OH),>TOH), (D) B(OH), > AIOH); > Ga(OH), > In(OH),> TIOH), [2010112850] (a), (b) and (¢) are elements in the second short period. Oxide of (a) is ionie, that of (b) is amphoteric and of (c) a gaint molecule. (a), (b) and (c) have atomie number in the order = A @<6)<© (B) ()<(b) <@) © @<@<) (D) (b)<(@) <@) [2010111270] Set containing isoelectronic species is - (A) C3, NO*, CN-, 03" (B) CO, NO, O,, CN (©) CO,, NO,, 0,, N,O5 (D) CO, CO,,NO,NO, [2010111850] Mendeleev’s periodic table is based on atomic masses of elements. It was the first successful attempt classify all the known elements (63) that time. One of the most important advantage of this classification, ‘was that mendeleev predicted the physical and chemical properties of three elements : Eka-boron, Eka- silicon and Eka-aluminium, These elements were discovered as (A) germanium, scandium, gallium (B) scandium, germanium, gallium (C) iron, sulphur and germanium (D)iton, sulphur and scandium [2010111234]Q31 Q32 Q.33 Ifthe ionic radii of each K* and Fare 1.34A, then the atomic radii of K and F will be respectively : (A) 1.34A,1.34A — (B) 0.724, 1.96A (C) 1,964. 0.72A (D) 1.96A, 1.344 [2010111288] ‘The As-Cl bond distance in AsCI, is 2.20 A. Estimate the SBCR (single bond covalent radius) of As. (Assume EN of both to be same and radius of Cl=0.99 A.) (A) L214, (B)13IA (141A (D) 1.514 [2010110242] The IE values of Alig, = Al* + ¢ is 577.5 kJ mol“! and AH for Al.) = AI +3e is 5140 kJ mol"! If second and third IE values are in the ratio 2:3. Calculate IE, and IE. (A) IE, = 1825 ki/mole, IE, =2737.5 ki/mol] (B) IE, = 1600 kJ/mole, IE, = 1737.5 kJ/mol] (C)IE, = 1925 ki/mole, 1E, = 2037.5 kI/mol] (D) IE, = 1252 kitmole, IE, = 1237.5 ki/mol] {2010111448}SS ee Pee eA ee een eS PD eR a Qu Q2 Q3 od Qs Q6 Q7 [PARAGRAPH TYPE] Paragraph for Question Nos. 1 to2 Fourelements P, Q, R&S have ground state electronic configuration as: P > Is? 2s? 2p* 3s? 3p* Q- Is? 2s? 2p* 3s? 3p! R-+ Ie? 2s? 2ph 352 Spo 3d!" ds? 4p? $+ Is* 2st 2p* 3s? 3p? 3d" 4s* Ap! (2010111148) ‘Comment which of the following option represent the correct order of true (T) & false (F) statement I size of PR>S%Q (B)PS>P>Q_ (D)P>S>R>Q Paragraph for Question Nos. 3 to4 ‘The electron affinity isa inherent property of the atom and it depends upon several factors, [2010111642] The conect electron affinity order is (A)F>Cl (B)CI>F (s

O ‘Choose the incorrect statement. (A) 11.8. of A“ is equal to electron affinity of A (B)2™ electron affinity is always greater than. 1* electron affinity. (C)O—> O* process (D) Li Li process is endothen endothermic n Nos.5to7 Paragraph for Ques ‘Atoms of metals have only a few electrons in their valence shells while atoms of non-metals generally ‘have more electrons in their valence shells. Metallic character is closely related to atomic radius and ionization enthalpy. Metallic character increases from top to bottom ina group and decreases from left to right ina period. Metallic characteris inversely related to clectronegativity. [2010111495] Which of the following groups contains metals, non-metals and metalloids ~ (A) Group | (B) Group 17 (C)Group 14 (D) Group2 Non-metals belong to- (A) s-blockelements. (B)p-blockelements (C)d-blockelements — (D). f-block elements Considering the elements B, C,N, and F the correct order of their non-metallic character is (A)B>C>N>F (B)C>B>N>F (C)F>N>C>B_ (D)F>N>C>BQs Qo Q10 oO @ Qui Qu2z Paragraph for Question Nos. 8 to 10 Nature of bond can be predicted on the basis of electronegativity of bonded atoms, greater difference in clectronegativity (X), more will be the polarity of bond. and polar bond are easily broken in polar solvent like water. For hydroxy acids Xq,—X,, difference predict the nature of oxide formed by the element. [Xy~Xql>[Xq—Xyj then A-O-H show basie nature (NaOH) IXy—X,l<[Xy—Xj| then A-O-H show acidic nature (H-O-Cl) With the help of EN values [EN, = 1.8, ENg = 2.6, EN¢ = 1.6, EN, questions for the compounds HAO, HBO, HCO, HDO. 2.8] answer the following [2010110545] Compounds whose aqueous solution is acidic and order of their acidic strength (A)AOH,COH ; AOH HBO (C)AOH, COH ; AOH>COH (D) HDO, HBO ;_ HDO HBO (C)AOH, COH ; AOH>COH (D) HDO, HBO ; HDO Mg?* > Na* (B) APY < Mg?! O* is associated with energy absorbed but yet several oxides are stable enough Statement-II : The lattice energy involved to form its oxides overcomes the other energy absorbed. [2010110700 ‘Statement-I : Electron gain enthalpy of oxygen is less than that of fluorine but greater than that of nitrogen. Statement-II : Ionization enthalpy follows: N>O>F [2010110167] Statement-I : Cs and F combines violently to form CsF, Statement-II : Cs is most electropositive and F is most electronegative. (2010110571) Statement-I:: Lithium isa better reducing agent than Cs, Statement-II :Sublimation energy and Ionization energy of lithium is less than that of Cs. [2010112947] Statement-I:_IE, of Mn is more than IE, of Fe. Statement-II: After the removal of2 electron Fe acquire half filled electronic configuration. 12010112600] Statement-I: Fluorine shows maximum oxidising property in aperiodic table. Statement-II: Electron gain enthalpy of fluorine is maximum ina periodic table. [2010111195] ‘Statement-I : The ionisation potential of Sn is greater than Pb. Statement-II : Usually ionisation energy decreases down the group. [2010112042] Statement-I : (LE.), ofan atom is always greater than (LLE.),_; (nis integer number) Statement-II : ne/Z ratio decreases on successive elimination of electrons. [2010111639]Q23 Q24 Q25 Q.26 Q27 Q28 Q29 Q30 Statement-I: Nitrogen atom has higher ionization energy than fluorine atom. Statement-II: Nitrogen atom has extra stable electronic configuration due to halffilled p-subshell. [2010110951] [MULTIPLE CORRECT CHOICE TYPE] Which ofthe following is correct order of EA. (A\NCI>Br>1 (C)CI>F>Br>1 (D)C A® (g) AH may be negative (©) For A (g) +e" —> A* (g) AH must be positive (D) For A (g) +e" —> A? (g) AH must be negative [2010111900] Which of the following is false (A) C*(g) ion has greater magnetic moment compared to Co*(g). (B) The magnitude of ionization potential of iron anion (monoanion) would be equal to electron gain enthalpy of iron. (©) lanthanide contraction is cause of lower LP. of Pb than Sn. (D) Ifsuccessive ionization energy are 332, 738, 849, 4080, 4958 (in ki/mol). Then this element ean be of 15th group. 12010112246] Select the correct order (s). (A) IE, of F>IE, of Cl (B) EAof O>BAof § (©)lonic radius of CI”> Ionic radius of K* (D)None of these 12010112697]Q31 Q32 Q33 Q34 Q.35 Q.36 [MATCH THE COLUMN] Match Column-I (atomic number of elements) with Column-II (position of element in periodic table) Column-T A) 19 ®) 2 © 2 @) 64 Column (Orders) (A) Increasing orderofionic ‘mobility in water (B) _ Decreasing order of size (C) Decreasing order of ionisation energy Ma Columnl A O@+e>07@) ®) O@te 90 @ (C) Na (g)>Nalg)+e~ (D) Mg*(g)+e > Mg) Match the column : Columnt (A) Highest density (B) Metallic character (C) __Lightest Metal (D) Liquid at room temperature Match thecolumn : Column t @ a @®) F «© cu (D) He Match the column Column (A) Ni @) ® K @Q (©) Mn ® (D) Pd (Ss) Column-IT (P) — p-block (Q) block ®) — d-block (S$) sblock [2010111250] Column IL (Sequences) () — Si,Mg.Al,Na (@ Lit, Nat, K*, Rbt, Cs* ) 0, 0°07, 0 (8) Se, S,0,F [2010110898] + the characteristics mentioned in Column II with the process in Column | Column I (P) _Positiveelectron gainenthalpy (Q) Negative electron gain enthalpy (BR) Exothemie (S)_—_Endothermic [2010112247] Column I (@) Lithium (Q) Osmium Mercury (S) Bromine [2010112596] Column IL () Metallic (Q) Highestelectron affinity (R)__Electronegativeelement (S) _ Highestionisation energy. [2010111950] Column-It Elements having number of unpaired electron in theirdipositive ion=2. Atleast 13 electrons are having magnetic quantum number'zero’. Atom is paramagnetic. Element isnot transition element 12010112037}EXERCISE-1 Qi) Q2 © Q3 B) Qa © Qs A) a6 © Q7 Q8 ©) Qo Q.10 (A) Qu @) Q.12 (B) Q.13 B) Qs © Q15 (B) Q16 (B) am © Q.18 (0) Q19 ©) Q20 ©) Q21 ©) a2 © 223 (8) a2 © Q25 B) 0.26 (A) Q27 (0) Q.28 (A) Q29 (A) Q30 (B) Q31 © Q.32 (A) Q.33 (A) EXERCISE-2 Qi B) Q2z A) Q3 B) Q4 B Qs © Q6 B) Q7 © Qs @) Q9 (A) Q10 (C) Qu © Q.12 (B) Q13 (Dd) Q14 (A) Q.15 (A) Q.16 (C) QA7 (A) Qus © av © Q20 © Q21 () Q2 (A) Q23 0) Q.24 (A). Q25 (A),(B). (©) Q26 (B),(D) Q.27 (A),B).(©) Q28 (A),(©),D) 229 (A).©.() Q30 (A).(C) Q31_ [(A)S(B)R (CP (D)Q] Q.32 [(A) Q(B) S.(C)P QI Q.33 [(A) QR: B) PS: (C)S;(D) QR] Q34 [(A) Q(B) P.Q.R(C)P(D)RS] Q35 [(A)QR(B)R(C)P(P)S] Q.36 [(A)P.QR(B)RS(C)QRD)PQ]