Sistema metanol(1)/agua(2)

T= 333.15 K
T= 60 C

P(kPa) x1 y1 x2 y2 1 2 ln1 ln2

19.953 0 0 1 1 #DIV/0! 1 #DIV/0! 0
39.223 0.1686 0.5714 0.8314 0.4286 1.571984 1.013386 0.452339 0.013297
42.984 0.2167 0.6268 0.7833 0.3732 1.470285 1.026389 0.385457 0.026047
48.852 0.3039 0.6943 0.6961 0.3057 1.319847 1.075222 0.277516 0.072527
52.784 0.3681 0.7345 0.6319 0.2655 1.245527 1.111502 0.219558 0.105712
56.652 0.4461 0.7742 0.5539 0.2258 1.162682 1.157443 0.150729 0.146213
60.614 0.5282 0.8085 0.4718 0.1915 1.097184 1.233036 0.092747 0.209479
63.998 0.6044 0.8383 0.3956 0.1617 1.049702 1.311028 0.048507 0.270811
67.924 0.6804 0.8733 0.3196 0.1267 1.030973 1.349537 0.030503 0.299762
70.229 0.7255 0.8922 0.2745 0.1078 1.02133 1.382244 0.021106 0.323708
72.832 0.7776 0.9141 0.2224 0.0859 1.012475 1.409848 0.012398 0.343482
84.562 1 1 0 0 1 #DIV/0! 0 #DIV/0!

METANOL AGUA
A1 B1 C1 A2 B2 C2
16.5785 3638.27 239.5 16.3872 3885.96 217.625 Cha
0.7
P1sat= 84.562 kPa
P2sat= 19.953 kPa f(x) = - 0.2075161757x + 0
0.6
R = 0.8280031281
0.5
A12 0.6828
A21 0.4753 0.4

0.3

0.2

0.1

0
0.1 0.2 0.3 0.4
 b) checar
Ecuacion van Laar
GE/RT GE/(x1x2RT) x1x2/(GE/RT) x1 x2 1 2
1.00E-09 1 2.023786 1
0.087319 0.6229350492 1.6053037974 0.1686 0.8314 1.523033 1.025442
0.103931 0.6122922707 1.6332069631 0.2167 0.7833 1.431589 1.040682
0.134823 0.6373254892 1.5690569685 0.3039 0.6961 1.302186 1.075819
0.147619 0.6346412582 1.575693334 0.3681 0.6319 1.229848 1.107329
0.148228 0.5998827942 1.666992302 0.4461 0.5539 1.16157 1.151511
0.147821 0.5931706293 1.6858555541 0.5282 0.4718 1.107659 1.204548
0.13645 0.5706820356 1.7522892568 0.6044 0.3956 1.070419 1.259437
0.116558 0.5360073141 1.8656461839 0.6804 0.3196 1.04301 1.319377
0.10417 0.5230737721 1.9117762221 0.7255 0.2745 1.030576 1.357326
0.086031 0.4974679734 2.0101796566 0.7776 0.2224 1.01927 1.403325
1 1.00E-09 1 1.624923

A'12
A'21
Chart Title

2.5
f(x) = - 0.2075161757x + 0.6827602795
R = 0.8280031281
2

f(x) = 0.641
1.5
R = 0.8147

0.5
0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

0
0.1 0.2 0.3
P y1
19.9530001512 8.576925E-09
38.72509194 0.5607245224
42.4982833692 0.6172784556
48.4064411579 0.6913147361
52.2433483269 0.7327594412
56.5445018837 0.7749300978
60.8137322022 0.8135386953
64.6495803634 0.8462287016
68.4242728387 0.8770372365
70.6597856932 0.8947886863
73.2498656378 0.9149852496
84.5620000324 0.9999999996

0.7049700388
0.4854604592

Chart Title
2.5

f(x) = 0.6414195419x + 1.4184678757

1.5
R = 0.8147846638

0.5

0
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9