Sm2Co17

2017.7.14


1.1

500
2:17 SmCo

Sm(CoFeCuZr)z 2:17 SmCo

2:17 SmCo

SmCoFeCuZr

2:17 SmCo Sm(CoFeCuZr)z

z (Co+Cu+Fe+Zr) Sm 0.65~0.85
Sm(CobalFeCuZr)z Br z iHc
z Sm(CobalFeCuZr)z (BH)max z

FeCuSm
Fe Fe
Fe Fe

Fe 1:5 Cu
Cu
Cu Cu
Sm
Sm
2:17 SmCo
2:17R
1:5 Zr Z Zr
Zr FeCoCu Fe
2:17 Cu 2:17 1:5 Z
Z
1


Z 2:17 SmCo
Sm Cu Fe

Zr /
Zr Sm
Cu 1:5 2:17
Fe
1:5 2:17 CuZr 2:17 1:5

Sm(CoFe0.12Cu0.08Zr0.33)7.2

1.2
2:17 SmCo 2
2

2:17 SmCo
8.4g/cm3 2:17 SmCo

1
234

1.3

:, Br 0.8T iHc=1.2T
(BH)max 120kJ/m3

[1]WalmerMS,ChenCH,WalmerMH.AnewclassofSm-TMmagnetsforoperatingtempera
turesupto550/spldeg/C[J].IEEETransactionsonMagnetics,2000,36(5):3376-3381.

[2]TangW,ZhangY,GollD,etal.NewSm(Co,Fe,Cu,Zr)zmagnetswithbettertemperaturest
ability[J].JournalofMagnetism&MagneticMaterials,2001,226(00):1365-1366.

[3] , , . SmCo [J].

3


,2014,35(10):2794-2801.

2.1
WS-4

100Pa
10-3Pa

1
2
1000#3

99.9% SmCoFeCu Zr

Sm
Sm2O3
Sm

Sm CoFeZr
Cu
5100Pa 10-3Pa
0.1
3

100~200A

2.2

80
Spex-8000

2.3
2:17 SmCo
3~5m

5T

( 300MPa)
200 MPa 1h

2.4

8.3g/cm3

310-3Pa
310-3Pa 700
Sm 4~5h
20

310-3Pa
310-3Pa 700
6


810 24h 0.5/min

10h

3.1

99.9% SmCoFeCu Zr
Sm(CoFe0.12Cu0.08Zr0.33)7.2 Sm
Sm 4wt% 30g

Sm Co Fe Cu Zr

/g 5.317 14.427 1.641 1.245 7.370

0.1mg BSA224S

1mg

3.2

WS-4
310-3Pa Ar Ar
Sm CoFeZr
Cu

100~200A 4
150A100A150 180A 20
Sm
Sm z

3.3

80 Spex-8000
7


Spex-8000

10:1 9mm
5mm 1:1

2~3min

3~5m

3.4
2:17 SmCo
3~5m
5.5g/cm3 10mm10mm

5T 3
3

230MPa 1h

3.4

50%~70% 50%~30%

2:17

310-3Pa 310-3Pa 700

8


Sm 4~5h
20
310-3Pa 310-3Pa
700 810 24h 0.5/min
400 10h

3.5
3.5.1

20 0.789~0.791g/mL
0.0001 :8.15g/cm3

3.5.2

Br Hcb Hic
(BH)max
JDAW-2000C
(VSM) NIM-500C
10T

Br Hcb Hic
(BH)max Br=7.935kGs0.793T
9


Hc 26.05kOe wm=116.4kJ/m3

Sm2(CoFe)17 Cu Sm(CoCu)5
Cu 2:17 1:5
2:17
1:5 c Zr
500 810
50~100nm 5~10nm FeCu
600~400
FeCu FeCu 2:17
1:5

2:17

Sm(Co0.784Fe0.100Cu0.088Zr0.028)7.19
1210 1h 1186 4h800
24h 0.5/min 400 10h

Sm(CoFe0.12Cu0.08Zr0.33)7.2 Zr
Br=11.28kGs 1.128T wm=234.5kJ/m3
Hc=26.07kOe Zr c
Zr Zr Cu
1:5

[1]WalmerMS,ChenCH,WalmerMH.AnewclassofSm-TMmagnetsforoperatingtempera
turesupto550/spldeg/C[J].IEEETransactionsonMagnetics,2000,36(5):3376-3381.

[2]TangW,ZhangY,GollD,etal.NewSm(Co,Fe,Cu,Zr)zmagnetswithbettertemperaturest
ability[J].JournalofMagnetism&MagneticMaterials,2001,226(00):1365-1366.

[3] , , . SmCo [J].

10


,2014,35(10):2794-2801.

[4].2:17 [D].,2015.

[5],,,.
[J].,2014,38(6):1017-1021.

[6],.2:17 SmCo [J].

,2004,33(4):337-342.

[6],,,.Sm2Co17 [J].
,2015,34(11):789-795.

[7]Xiao-dong,Ying,CHANG,etal.PreparationofNanoscaleSm2Co17FlakesbyBallMilli
nginMagneticField[J].(),2014,21(5):517-520.

[8]JeffriesJR,VeigaLSI,FabbrisG,etal.Robustferromagnetisminthecompressedpermane
ntmagnetSm2Co17[J].Phys.rev.b,2014,90(10).

11