Litton Core Lab 03-3-005-07 Reservoir Fluid Study HOCOL, 8.A. San Francisco 41 Well San Francisco Field Colombia RFL 270335Litton Core Lab ee cL-87-501 July 20, 1987 HOCOL, S.A. Bogota, Colombia Atention: Mr. Eduardo Pardo Subiect: Reservoir Fluid study San Francisco 41 Well San Francisco Field RFL 270335, Gentlemen: Two subsurface samples of reservoir fluid were collected from the subject well and delivered to our laboratory for use in a reservoir fluid study. The results of the subsequent study are presented in this report. As a quality check, the room temperature saturation pressure of the samples were initially determined. At 69°F, both samples were found to have a bubble point pressure of 260 psig. The hydrocarbon composition of the fluid was measured using flash/chromatographic techniques. This analysis is reported on page two together with the physical properties of the heptanes plus fraction. A portion of the fluid was charged to a high pressure visual cell and thermally expanded to the reported reservoir temperature of 135°F. During a subsequent constant composition expansion, a bubble point of 466 psig was observed. The results of the pressure-volume relation measurements are summarized on page three and detailed on page four. When subjected to a differential vaporization at the reservoir temperature of 135°F, the fluid liberated 80 cubic feet of gas at 14.7 psia and 60°F per barrel of residual oil at 60°F, The resulting relative oil volume factor was 1.065 barrels of saturated fluid per barrel of residual oil at 60°F. The oil density and the properties of the liberatedHOCOL, S.A. CL-87-501 San Francisco 41 Well Page Two gases were measured at each point during the differential vaporization and these data are reported on page five and presented graphically on pages ten through thirteen. The viscosity of the reservoir fluid was measured over a wide range of pressures in a rolling ball viscosimeter at reservoir temperature. The viscosity of the fluid was found to vary from a minimum of 6.945 centipoise at the bubble point pressure to a maximum of 10.787 centipoise at atmospheric pressure. These results are tabulated on page six and presented graphically on pages fourteen and fifteen. Four single-stage separator tests were performed at laboratory temperature to determine the effects of separator pressure upon gas-oil ratio, stock tank oil gravity and formation volume factor. The results of these separator tests are tabulated on page seven. The separator gas from each of the four tests was collected and analyzed by routine gas chromatography. The results of these separator gas analyses are tabulated on page eight. Also, the differential vaporization data was adjusted to the optimum separator conditions as reported on page nine. We would like to thank HOCOL, S.A. for the opportunity to perform this reservoir fluid study. If you have any questions or if we may be of further assistance, please feel free to call upon us. Truly yours, WESTERN GEOPHYSICAL CORE LAB DIVISION hott Lucidio 0. caflizales Supervisor Reservoir Fluid Analysis Loc/co/it 7 cc: AddresseeCORE LABORATORIES, INC. Petroleum Reservoir Engineering Page—!__of _15__ Fite__RFL_270335 Company__HOCOL, S.A. Date Sampled. 1/05 /8; Wel SAN FRANCISCO 41 Country. COLOMBIA Field. |AN_ERANCISCO State. Formation Name FORMATION CHARACTERISTICS (yppen Date First Well Completed » 19 Original Reservoir Pressure 1050 PSIG @—___ Ft. Original Produced Gas-Oil Ratio aoe Production Rate Bbl/Day Separator Pressure and Temperature PSIG._____F. Oil Gravity at 60° F. $25 eons AY Datum Ft, Subsea Original Gas Cap ———————— WELL CHARACTERISTICS Elevation Ft, Total Depth 3584 Ft. Producing Interval 3051 - 3132 Fe Tubing Size and Depth 21/8 __in, to____Ft. Productivity Index BbI/D/PSI @——Bbl/Day Last Reservoir Pressure PSIG @ Ft. Date ie Reservoir Temperature 135___»F. @_2980____Ft. Status of Well Pressure Gauge Normal Production Rate BbI/Day Gas-Oil Ratio ‘SCF/BbI Separator Pressure and Temperature ae PSIG,. oF. Base Pressure PSIA Well Making Water % Cut. SAMPLING CONDITIONS ‘Sampled at 2980 Ft. Status of Well Gas-Oil Ratio scr Separator Pressure and Temperature PSIG,___°F. Tubing Pressure 299 es Casing Pressure PSIG ‘Sampled by “CORE LABORATORIES Type Sampler —WOEFORD —_ REMARKS:CORE LABORATORIES, INC Petroleum Reservoir Engineering Page_2._ of _15__ Company HOCOL, S.A. Well_____SAN FRANCISCO 41 Field____SAN_ FRANCISCO State. ae HYDROCARBON ANALYSIS OF_RESERVOIR FLUID _SAMPLE cone | [ sm | Sees [: wae. | esse Hydrogen Sulfide 0.00 0.00 Carbon Dioxide 2.60 0,50 Nitrogen 0.00 0.00 Methane 10.43 0.73 Ethane 1.53 0.20 Propane 0.69 0.13 iso-Butane 0,50 0.13 n-Butane 0.59 0.15 iso-Pentane, 0.73 0.23 n-Pentane 0.55 0.18 Hexanes 2.25 0.83 Heptanes plus 80.13 96.92 0.9070 24.4 276 100.00 100.00CORE LABORATORIES, Inc. Petroleum Reservoir Eagineering Page_3__ of __15___ File__RFL_270335 ‘Well__SAN FRI 4 VOLUMETRIC DATA OF_RESERVOIR FLUID SAMPLE Saturation pre Specific volume at saturation pressure: ft 1b ooess _@ 135 °F. Thermal expansion of saturated oil @ 3000 __ PSI = 4G RE =_ 1.02601 Compressibility of saturated oil @ reservoir temperature: Vol/Vol/PSI: ure (bubble-point pressure) 466 _ PSIG @_135_ °F. From _3000 _ PSIto__2500_ PSI=__4,82 x 10°6 From _ 2509 PSIto__2000 PSI = __5.00 x 10°® From _2000__ PSIto_1500_ PSt=__5.29 x 10° From _1500__PSIto 1000 PSt=__5,67 x 10° From _1000__PSIto__466_ PSI=__5.73 x 1076CORE LABORATORIES, Inc. Petroleum Reservoir Engineering Page 4 of 15 File 335, ‘Well__SAN FRANCISCO 41 Pressure-Volume Relations at_135 °F. Presaure Relative ¥ PSIG Volume (1. Function (2; 3000 0.9866 2500 0.9890 2000 0.9915 1500 0.9941 1000 0.9969 800 0.9981 700 0.9987 600 0.9992 500 0.9999 466" 1.0000 445 1,0044 410 1.0168 7.850 380 1,0359 6.061 350 1.0653 4.866 320 1.1045 4.172 290 1.1633 3.533 260 1,2330 3.215 230 1.3400 2,833 205 1.4537 2.615 180 1.6346 2.311 140 2.1070 1.900 110 2.8003 1,582 *Bubble Point Pressure. (1) Relative Volume: V/Vsat is barrels at indicated pressure per barrel at saturation pressure. (2) ¥ Function = E (Pabs) (V/Veat-1)1 SPO RATOOLES, INC Petroleum Reservoir Engineering Differential Vaporization at_135_°F. Page—2_— of 8. Fite _RFL_270335 Went SAN FRANCISCO. 4i,_ Solution Relative Relative oun Deviation Gas Formation _ Incremental Pressure Gas/Oil ou Total Density Factor Volume Gas PSIG Ratio (1) Volume (2) Volume (3) _gm/cc Zz Factor (4) Gravity 466 80 1,065 1.065 0.8641 300 56 1.058 1.271 0.8659 0.957 0.05108 0.753 200 39 1.052 1.607 0.8687 0.972 0.07604 0.759 100 23 1.044 2.504 0.8726 0.983 0.14378 0.845 0 0 1,031 0.8770 1.233 At 60°F = 1,000 Gravity of residual oi] = 24.8° API at 60°F. Density of residual of] = 0.9044 gm/cc at 60°F. (1) Cubic feet of gas at_14,7 _psia and 60°F. per barrel of residual oil at 60°F. (2) Barrels of oi! at indicated pressure and temperature per barrel of residual oil at 60°F. (3) Barrels of oil plus liberated gas at indicated pressure and temperature per barrel of residual oil at 60°F. (4) Cubic feet of gas at indicated pressure and temperature per cubic foot at_14,7 psia and 60°F.CORE LABORATORIES, Inc. Petrolewm Reservoir Engineering Page__6_of. 15 File__RFL_270335 Well__SAN_ FRANCISCO Viscosity Data at_135__° Calculated 0i1/Gas Pressure Oil Viscosity Gas Viscosity Viscosity PSIG Centipoise Centipoise * Ratio 1500 7.750 1000 7.350 800 7.194 600 7.040 466+ 6.945 300 7.600 0.0119 638.7 200 8.050 0.0117 688.0 100 8.639 0.0112 ™.3 0 10.787 **Bubble Point Pressure. *Calculated from correlation of Lee, A.L., Gonzalez, M.H., and Eakin, B.E., The Viscosity of Natural Gases", Journal of Petroleum Technology, August, 1966, pp. 997-1000. EBs cs, them, an for rhea so dent Betteser eLearn ‘ ‘ie Be sSapmee oC bate iia Ree TAT Sree SP Rae!CORE LABORATORIES, Inc. Petroleum Reservor Engineering Page. File _RFL_270335 Welt SAN FRANCISCO 41 SEPARATOR TESTS OF_RESERVOIR FL SAMPLE eee per ence “F SSmET, | Tcron | racron | rCisheo one wo fen 3 ‘a 30 69 63 63 1,006 0.779" to 0 69 6 6 25.7 1.061 1,004 0.915 Rsfb = 69 60 69 56 57 1.009 0.753* to 0 69 un i 25.8 1.060 1.004 0.919 Rsfb = 68 90 69 52 53 1.012 0.736" to 0 69 45 15 2.7 1.060 1,004 0.916 Rsfb = 68 120 69 48 49 1,014 0.718* to 0 69 20 20 25.6 1,061 1,004 0.901 Rsfb = 69 *Ggas collected and analized in the laboratory. (1) Gas Oi! Ratio in cubic feet of gas @ 60° F.and 14.7. PSI absolute per barrel of oil @ indicated pres- sure und temperature. (2) Ga, On Ratio incubie feet of gas @ 60° Peand_ 14-7 pst absolute per barrel of stuck tank oil vs 605 F (3) Feemation Volume Factor ss burrels of saturated eit @ 446 Psi gauge and 135 .* F. per burrel of stork oil @ 60° F. (4) Suunentor Volume Fuctor is barrels of oil @ indicated pressure and temperature per barrel of stack tank oil @ 60° F.CORE LAGURATO RIS, 1 Petroleum Reservoir Engineering Page 8 of__15 File___RFL_ 270335 Separator Conditions: 30 PSIG and 69°F. 60 PSIG and 69°F. 90 PSIG and _69°F. 120 PSIG and_69 *! Component Mol Percent GPM Mol Percent _GPM_ ‘Mol Percent GPM Moll Percent = _GPM. Hydrogen Sulfide 0.00 0.00 0.00 0.00 Carbon Dioxide 14.50 14.26 13,72 12.58 Nitrogen 0.02 0.04 0.06 0.08 Methane 75.39 77,83 79.59 81.67 Ethane 6.63 1.769 5.56 1,484 4.85 1,294 4.2. 1.124 Propane 1.48 0.407 1,03 0.283 0.82 0.225 0.67 0.184 iso-Butane 0.56 0.183 0.37 0.121 0.28 0.091 0.23 0.075 n-Butane 0.45 0.142 0.30 0.094 0.22 0.069 0.18 0.057 iso-Pentane 0.24 0.088 0.16 0.058 0.12 0.044 0.10 0.037 n-Pentane ons 0.054 0.10 0.036 0.07 0.025 0.06 0.022 Hexanes 0.18 0.070 ou 0.043 0.08 0.031 0.07 0.027 Heptanes plus 0.40 0.177 0.26 0.115 0.19 0.084 0.15 0.066 100.00 2.890 100.00 2,234 100.00 1,863 100.00 1.592 Calculated gas Gravity (Air = 1.000) 0.779 0.753 0.736 0,718 Calculated gross heating value per cubic foot of dry gas at 14.7 psia and 60°F, 996 963 949 948 pisemesatm lis ie reaCORE LABORATORIES, INC. Petroleum Reservoir Engineering Page, of__15 File__pet 270335 Well___SAN FRANCISCO 41 DIFFERENTIAL VAPORIZATION DATA ADJUSTED TO SEPARATOR CONDITIONS OF 69 PSIG AT 69 TO 0 PSIG _AT 69 Solution Formation Gas Gas/0i1 Volume Formation Pressure Ratio, Factor, Volume Factor, Psig Rs (1) Bo (2) 8g (3) 1500 68 1.054 1000 68 1,057 800 68 1.058 600 68 1,059 466 Bubble Point 68. 1.060 Pressure 300 44 1.053 0.00810 200 27 1,047 0.01354 100 nu 1.039 0.02561 0 0 1.031 At 60°F = 1.000 Gravity of the stock tank oil = 25.8 °API at 60°F. (1) Cubic feet of gas at 14.7 psia and 60°F per barrel of stock tank of] at 60°F. (2) Barrels of ofl at 466 psig and _135 °F per barrel of stock tank of] at 60°F. (3) Barrels of gas at indicated pressure and 135 °F per cubic foot at _14.7 psia and 60°F,SOLUTION GOR, STANOARD CUBIC FEET PEA BBL OF RESIOUAL OIL AT 60 F Page 10 of 15 File AFL 270335 Well SAN FCO-44 SOLUTION GAS/OIL RATIO DURING DIFFERENTIAL VAPORIZATION AT 135 F 100 200 300 400 500 600 PRESSURE, PSIGRELATIVE OIL VOLUME, BBLS PEA BBL OF RESIDUAL OIL AT 60 F Page 11 of 15 File AFL 270335 Well SAN FCO-41 RELATIVE OIL VOLUME DURING DIFFERENTIAL VAPORIZATION AT 135 F iB iS 100 200 300 400 500 600 PRESSURE, PSIGRELATIVE TOTAL VOLUME, BBLS PER BBL OF RESIDUAL OIL AT 60 F Page 120f 45 File RFL 270335 Well SAN FCO-44 RELATIVE TOTAL VOLUME DURING DIFFERENTIAL VAPORIZATION AT 135 F e = S &: 3 100 200 300 400 500 600 PRESSURE, PSIGGAS FORMATION VOLUME FACTOR, CUBIC FEET PER STANDARD CUBIC FOOT X 10-3 Page 43 of 15 File AFL 270335 Well SAN FCO-44 GAS FORMATION VOLUME FACTOR QURING DIFFERENTIAL VAPORIZATION AT 135 F 450 0 400 200 300 400 PRESSURE, PSIGVISCOSITY, CENTIPOISE Page 14 of 15 File AFL 270335 Well SAN FCO-44 VISCOSITY OF RESERVOIR FLUID AT 135 F 250 Z| 500 750 1000 1250 1500 PRESSURE, PSIGOIL/GAS VISCOSITY RATIO Page 15 of 45 File AFL 270335 Well SAN FCO-44 QIL/GAS VISCOSITY RATIO AT 135 F 50 100 450 200 250 300 350 PRESSURE, PSIG