UIT JEEI (b) 4.010% (@) 4.0x10° (@) 125M the total number of moles of H,SO, needed to ¢ 5.0 L of a 2,0 M solution of H;80,? (UP SEE) 25 (b) 5.0 ©) 10 (a) 20 "How many grams of NaOH will be required to prepare 500 g solution containing 10% ~ NaOH solution ? we [ey cen) 100g (>) 50g (6) 05g (@ 50g 2008 16. 10cm? of 0.1N monobasic acid requires 1Sem? of sodium hydroxide solution whose normality is. [KCE} @) 15N (b) 0.15N (©) 0.066 N (@) 0.66N AT. What s the molality of pure water? (0JEE) ay (b) 18 FO) 555 (@) None of these 2.N HCI solution will have same molar concentration asa (WB JEE} (@) 40N H,SO, (b) 05 H,SO, (c) 1NH,SO, (@) 2NH,SO, 19. The volume of water to be added to 100cm’ of 0.5N H3S0, to get decinormal concentration is (BCECE} (a) 400cm* () 4500m* (@) 100cm? concentration factors is affected rate of 298 Kans am | 2 SPY om of enperature and B contains 1M and Im aquegy, |. Two bottles ph (Manipal ion of sulphuric acid respectively = mt more concentrated thn 3 {b) Bis more concentrated than A {3 concentration of Ais equal to concentration ofp {@ itis not possible to compare the concentrations 22. Molarity is expressed as (MP Pen, UL. = (@) Umol Ab) mol (©) mol/1000 ¢ @ gl 24, Which one of the following concentration unity : f (sex cen, (@) Normality (b) Molarity (e) Molality (@) ppm 2007 24. The density (in g mL“) of a 3.60 M sulphuric agg solution that is 29% HSO, (molar mass =98 g mot) by mass will be U G@) 164 (b) 188) 1.22 (@) 145 25. 40% by weight solution will contain how much massof = the solute in IL solution, density of the solution i2gmL? ce) ~(@) 40g (0) 48g (©) 38E (A) 380g 26. Which one is correct ? Dey — (a) Molality changes with temperature. > Ab) Molality does not chang (©) Molarity does not ch (@) Normality does not chat 27, Molarity of a given orthophosphoric acid solution is e with temperature, with temperature. with temperature. 3M. It’s normality is IKCET] va) 9N (6) 03N ()3N IN 28. The volume of 10 Nand 4 N HCI required to make ILof 7N HCI are (Kcen (a) 0.50 L of 10 N HCI and 0.50 L of 4N HCI (b) 0.60 L of 10 N HCL and 0.40 L of 4N HCI (c) 0.80 L of 10 N HC} and 0.20 L of 4N HCL (d) 0.75 L of 10 N HCI and 0.25 L of 4N HCL Volume of 0.6 M NaOH required to neutralise 30cm? of 0.4 M HClis [AMU (a) 20em3 (b) 40cm? (©) 45cm* (@) 30cm? 30,_138 g of ethyl alcohol is mixed with 72 g of water Te ratio of mole fraction of aleohol to water is (EAMCET v@3:4 bl. @1L4 @H 31. To neutralise completely 20 mL of 0.1 M aques 7 solution of phosphorous acid (HPO;), the volume of 0.1 M aqueous KOH solution required is 29. [Jamia Millia Islami se(@) 10 mL. (b) 20 mL. (6) 40mL > (@) 60 mL{@) 1000 g of solution of water to be added to HCI prepare (RPET) (b) 100cm* (@) 400em? "$4. 6.02% 10°? molecules of urea are present in 100 mL of its solution. The concentration of urea solution is “(Avogadro constant, Ny =6.02% 10°" mol!) (AIEEE) (@) 0.001 M (b) 0.01M (©) 002M @ o1M 55. x grams of water is mixed in 69 g of ethanol. Mole -— fraction of ethanol in the resultant solution 1s 0.6. What isthe value of x in grams ? [BAMCET] (a) 54 (b) 36 (©) 180 +@ 18 _56 Mole faction of a solute in benzene is 0.2 then find molality of solute [BCECE] + @ 32 (b) 2 4 (d) 3.6 57. What amount of water is added in 40 mL. of NaOH 4 (G1) which is neutralised by 50 mL of HCI (0.2 N)? [BCECE] (a) 80mL + (b) 60: mL. (c) 40 mL (d) 90 mL 58. Thenormality of mixture obtained by mixing 100 mL of 0.2MH,SO; +100ml of 0.2 M NaOH is [BCECE] (@) 0.2 (b) 0.01 (©) 0.1 « (d) 03 59. The solubility of gas in liquid depends upon [BCECE] (a) the nature of gas (b) the temperature (©) the nature of the solvent = (d) Allof the above 60. The unit of molality is @ molL* (c) mol Lt ec [Jamia Millia Islamia) (b) mol kg - (4) molL 61. Volume of 0.1 M_ KzCrg07 required © oxidise 35 mL of 0.5 M FeSO, solution is (8K cen (@) 29.2 mL (b) 17.5 mL (©) 175 mL (@) 145 mL 62, 100 ce of 0.6 N H,S0, and 200 ce of 0.3 N HCI were ‘mixed together. The normality of the solution will be eK @02N ()04N (©) OSN (6) 0.6N 2003 163. What is the molarity of HySO, solution if 25 mL ig exactly neutralised with 32.63 mL of 0.164 M NaOH 7 * ‘mek (a) 0.107 M (b) 0.126M (©) 0.214M (@) -0.428M 64, Volume of water needed to mix with 10 mL. 10N HNO, to get 0.1 NHNOs is (UP SEE} (a) 1000 mL (b) 990 mL. (©) 1010 mL (@) 10mL 65. If 117 g NaCl is dissolved in 1000 of water the concentration of the solution is said to be (Kerala CEE} (a) 2 molar (b) 2 molal (©) 1 normal (@) 1 molal (e) 2normal 66. How much K,Cr,0; (Mol. wt. = 294.19) is required to. prepare one litre of 0.1 N solution ? (OJEE} (a) 9.8063 ¢ (b) 7.3548 (c) 3.6774. g (@) 4.903 g ‘The ionic strength of a solution containing 0.1 molkg of KCI and 0.2 mol/kg of CuSO, is (O3EE} (a) 03 (b) 0.6 (©) 09 (a) 0.2 1 kg of NaOH solution contains 4 g of NaOH. The approximate concentration of the solution is [Manipal] (a) about 0.1N (b) decinormal <(c) 0.1 molal (d) 0.1molar 69. How much of 0.1 M HSQ, solution is required to ~ neutralise 50 mL. of 0.2 M NaOH solution? (Manipall ®(a) S0mL (b) 5.0 mL (c) 0.50 mL (a) 100 mL 70. What is molality of a solution in which / (8 g glucose mol. wt. =180) is dissolved in 500 g of water ? (MP PET, @) Im (b) 05m 4(c) 02m (a) 2m ZA. An aqueous solution of 6.3 g oxalic acid dihydrate is made up to 250 mL. The volume of 0.1 N sodium hydroxide required to completely neutralise 10 mL of this solution is (eK CEN (@) 40mL (6) 20 mL (@) 4m 72. Normality of MH,S0, is [g&KCET ()2N — (b) 4N o% 67. 68. eA (©) 10mL, N © =* zn % 0), Migy S01E 7 gy ay |g. A solution of 10 Tiguids boils at a temperature more 8101 | ant alison’ of hehe tae bay ution shows NG Be tet tevieton Gem raat sie N\ positive deviation from Raoult's law Sy, J (6) no deviation from Raoult’s law Nig | (@ positive oF negative deviation from Raoul’ tw en depending upon the composition sist Zag 2010 Ing, 2 Onmixin, heptane and octane form an ideal solution, At 373 K, the vapour pressures of the two liquid components (heptane and octane) are 105 kPa and 45KPa respectively. Vapour pressure of the solution obiained by mixing 25 g of heptane and 35 g of octane will be (molar mass of heptane = 100 g mol! and of octane = 114 g mol). (AIBEE} (@) 720 kPa () 36.1 kPa (6) 962 kPa (@) 144.5 kPa 4. The vapour pressure of a pure liquid 4 is 40 mm Hg at (310K. The vapour pressure of this liquid in a solution gui with liquid 2 is 32 mm Hg, What is the mole fraction of tiny, in the solution if it obeys the Raoult’s law ? a (Punjab CET) S @ os ) 0.6 (©) 0.7 (@) 08 “= 2009 @& 4 Two liquids X and ¥ form an ideal solution at 300 K, ‘vapour pressure of the solution containing | mol of X and3, mol of Ys 550 mmHg. At the same temperature, i if mol of Y'is further added to this solution, vapour fF pressure of the solution increases by 10 mmHg. Vapour 4) pressure (in mmHg) of X and Yin their pure states will be, respectively [AIEEE] (b) 300 and 400 * —(@) 200 and 300 (@) 500 and 600 (©) 400 and 600 ; 5. binary liquid solution is prepared by mixing ¥ mheptane and ethanol. Which one of the following statements is correct regarding the behaviour of the | solution 2 [AIEEE] (a) The solution formed is an ideal solution i (b) The solution is non-ideal, showing positive deviation from Raoult’s law 77. The vapour pressure of to liquid Topic 2 ‘\ oN Vapour Pressure of Li (Raoult’s Law) Ideal and Non-ideal Solutions Solutions (©) The solution is non-ideal, showing negative deviation from Raoult’s law (@) heptane shows positive deviation while ethanol show negative deviation from Rauoult’s lay ‘One component of solution follows Raoult's law over the entire range < x) <1. The second component must follow Raoult law in the range when xy is (AMU) () close to 2010 (b) close to 1 (© 0x 505 (@) 05x <1 anil ¥ are 80 and (60 Torr respectively. The total vapour pressure of the {deal solution obtained by mixing 3 moles of X and 2 moles of ¥ would be [Kerala CRE] (a) 68 Torr (b) 140 Torr (©) 48 Torr +(@) 72 Torr (©) 54 Torr 8. Vapour pressure of pure ‘A’ is 70 mm of Hg at 25°C, tt forms an ideal solution with ‘B° in which mole fraction, of 4 is 0.8. If the vapour pressure of the solution is ‘84 mm of Hg at 25°C, the vapour pressure of pure *B? at 25°C is {Manipal} @ 28mm (6) S6mm (©) 70mm. (®) 140mm 2008 9 At 80°C, the vapour pressure of pure liquid “4° is, 520 mm Hg and that of pure liquid °B” ig 1000 mm Hg, Ifa mixture solution of ‘a’ and *B° boils at 80°C and 1 atm pressure, the amount of “4” in the mixture is (1 atm = 760mm Hg) [AIEEE] (a) $2:mole per cent (b) 34 mole per cent (©) 48 mole per cent (a) 50 mole per cent Two liquids X and ¥ form an ideal solution. The mixture has a vapour pressure of 400 mm at 300 K when mixed in the molar ratio of 1:1 and a vapour pressure of 350mm when mixed in the molar ratio of: atthe same temperature. The vapour pressures of the two pure liquids X and Y respectively are [Kerala CER) (a) 250mm, 350mm —_(b) 350 mm, 450. mm (©) 350mm, 700mm ——_(d)_ $00 mm, $00. mm v(e) 550mm, 250. mm. 10.and oxygen are mixed in an ‘The fraction of the total is [AIEEE] ‘of 290 mm at 300 K. The vapour "of propyl alcohol is 200 mm. If the mole ‘of ethyl aleohot is 0.6, its vapour pressure thesame temperature will be [ALBEE (@) 300 (©) 700 (a) 360 _ Formation of a solution from two components can be ‘considered as (1) pure solvent — separated solvent molecules, AF, (2) pure solute —» separated solute molecules, AH |G) separated solvent and solute molecules —> solution, Hs ‘Solution so formed will be ideal if (UP SEE} hrs 15, On a humid day in summer, the mole fraction of ‘gaseous HO (water vapour) in the airat 25°C can be as ‘high as 0.0287, Assuming a total pressure of 0.977 atm ‘What isthe partial pressure of dry air? (Kerala CEE] (a) 94.9 atm. (b) 0.949 atm © 949 atm (@) 0.648 atm \ (e) 1.248 atm 16. Which one of the following is not correct for an ideal solution? [Jamia Millia Islamia] (a) Itmust obey Raoult’s law (b) AH =0 (©) AV=0 © (d) AH=AV 20 “At25°C, the total pressure of an ideal solution obtained ixing 3 moles of “4° and 2 moles of B’, is 184 tore. i ‘pressure (in tort) of pure ‘B” at the 2 (Vapour pressure of pure ‘4° at (J&K CET) (@) 180, (6) 160 () 16d) 100 2005, : 48, Benzene and toluene form neatly ideal Solution, 20°C, the vapour pressure of benzene is 75 torr and! of toluene is 22 tort. The partial vapour pressige fngene at 20°C Tor a solution containing Ty's benzene and 46 g of toluene in torr is ae (a) 53.5 (b) 37.5 i (©) 25 @) 50 49, A and Bare ideal gases. The molecular weightsof Jang B ate in the ratio of 1:4. The pressure of a gas mings containing equal weights of A and B is p stm. Wau, the partial pressure (in atm) of B inthe mixture? : TEAMEn ) Or 3p @ >? 20, Ina mixture of A and B, components show negate deviation when (Jamia Miia Islami, (a) A—B interaction is stronger than A— 4'ang BB interaction (b) 4—B interaction is weaker than A—4 yj B— B interaction (©) AV pix >, AS pun > 0 (€) AV yun =0, ASyuy 0 2004 21, Which of the following liquid pairs shows a posite deviation from Raoult’s law ? TAIEER) (a) Water-hydrochloric acid ¥ (b) Benzene-methanol (©) Water-nitric acid i (@) Acetone-chloroform _ 22. A non-ideal solution was prepared by mixing 30 nl 7 chloroform and $0 mL acetone. The volume of mistee will be (Jamia Millia Islami (a) >80mL ¥ (b) <80mL 4 (©) =80mL (@) = 80mL > Aesowropie misture of HCL and water has (aKce (a) 48% HCL a 7 0) 22.2% HCL eI (©) 36% HCI : Y @ 20.2% HCI q 2003 24, If liquids 4 and B form an ideal solution, the (AM + (a) enthalpy of mixing is zero (b) entropy of mixing is zero (6) free energy of mixing is zero (@) free energy as well as the entropy of mixing each zero a"fe mixture oF Wo liquids has Mian eltherof hem, whens re pot shows positive deviation fiom Raoutt’s law a shows no deviation from Raoul Cert 2011 The fcezing point (in °C) of solution containing 0.1 g AF Ks[Fe(CN)s ] (mol. wt, 329) in 100 g of water (&; =186K kg mol!) is ees, ( -23x107 (b) =5.7%107 (5.7107 (@) -12«10" 4, Ethylene glycol is used as an antifreeze in a cold climate. Mass of ethylene glycol which should be added {04 kg of water to prevent it from freezing at ~6°C will be (Ky for water = 1.86 K ky mol and molar mass of ethylene glycol = 62 z mol") (a) 804.32 2 (b) 20430 (@) 400.00 g (@) 304.608 4. A 5% solution of cane. sugar (molar mass 342) is V isotonic with 1% of a solution of an unknown solute. The molar mass of unknown solute in g/mol is [AIEEEL [AIEEE] (@) 136.2 (b) 171.2 0) 84 (¢) 342 4. Asolution containing 1.8 g of a compound (empirical formula CH.,0) in 40 g of water is observed to freeze at = 465°C. The molecular formula of the compound is (K, of water =1.86 ke K mol ') [Kerala CEE} (@ CsHi0> (b) ©3405 (9) CyHs04 (@) CsHi0Os (©) CoH;206 §, At25°C a 5% aqueous solution of glucose (molecular Weight = 180 g mol™!) is isotonic with 2% aqueous Solution containing an unknown solute, What is the molecular weight of the unknown solute. [Kerala CEE] (@) 60 (b) 80 © 72 @) 63 (d) 98 6 The empirical formula of a nonelectrolyte is CH;0. A solution containinig 3 g of the compound exerts the Mets «negative deviation ory Raoul’ secre! deviation ftom the Raoul’ aw 7 26. Whi of lowing mists doc nt show postive (a) Benzene + acetone Pere (8) Acton aan (6) Acstoneelersixm {@) Waters eat ve Dopie3 Colligative Properties and Determination of Molar Mass same osmotic pressure as that of 0.05 M glucose solution, The molecular formula of the compound is (KCET] (a) CHO (b) CsH402 (©) CaH\O,, (@) CsH40) 7. Choose the correct statement. +” When concentration of a salt solution is increased (Gy cen) 4 (a) Boiling point increases while vapour pressure decreases, (b) Boiling point decreases while vapour pressure increases. (©) Freezing point decreases while vapour pressure increases, (@) Freezing point increases while vapour pressure decreases, 2010 8. The empirical formula of a non-electrolyte is CHO. A solution containing 6g of the compound exerts the same osmotic pressure as that of 0.05 M glucose solution at the same temperature, The molecular formula of the compound is {KCET) (a) CyH,02 (©) CyH,O5 (©) CsHy9s (@) CyHyOu 9, The relative lowering of vapour pressure of a dilute Y aqueous solution containing non-volatile solute is 0.0128. The molality of the solution is about (Manipal) * (a) 0.70 (b) 0.50 (©) 0.90 (a) 0.80 10, At 25°C, the highest osmotic pressure is exhibited by 0.1 M solution of (Manipal) (a) urea (b) glucose (c) KC (a) CaCl,| temperature, which of the following hhave the maximum vapour NaCl = 58.5, H,S0, = 98.0-mol~) * wee (Guj CET) ‘ ) Vmolal NaCI (ag) (b) 1 molar NaCl (ag) -molal HO, (ag) (4) 1 molar H;S0, (az) ive | ies of a solution depends upon cae er pana CET) (a) nature of both solvent and solute (b) nature of solute only (c) number of solvent particles . ‘the number of solute particles 2009 15. A 5% solution of sugarcane (mol. wt. = 342) is isotonic with 1% solution of X under similar conditions. The molecular weight of X is [DCE] (a) 136.2 (b) 689.4 (c) 34.2 (d) 171.2 16. If0.1 M solutions of each electrolyte are taken and if all electrolytes are completely dissociated, then whose boiling point will be highest? (Indraprastha CET] (a) Glucose (b) KCI (©) BaCl, (@) K,{Fe(CN) 4] _J7- Which of the following is nota colligative property ? (UP SEE] 9 (a) Optical activity (b) Osmotic pressure (c) Depression of freezing point (d) Elevation of boiling point 18. An 1% solution of KCI (1), NaCl (1), BaCl, (If) and urea (IV) have their osmotic pressure at the same temperature in the ascending order (molar masses of NaCl, KCl, BaCl, and urea are respectively 58.5, 74.5, 208.4 and 60g. mol '), Assume 100% ionisation of the electrolytes at this temperature [Kerala CEE] (a) [ (b) 0.25 (@) 0.15me 7. Osmotic pressure of a solution Ne a ata given 1 Sy) e(@) imereases with concentration (b) decreases with concentration (6) remains same (qd) initially increases and then decreases 28, The osmotic pressure (At27°C) of an aqueous solution (200 mL) containing 6 g of a protein is 210" atm. If R=0.080 L atm mol 'K~', the molecular weight of protein is (UP SEE] (a) 7.2105 (b) 3.6105 (6) 1.8%10° (4) 1.0%10° 29, On adding 1 g arsenic to 80 g benzene, the freezing {/ point of benzene is lowered by 0. 19°C. The formula of arsenic is [UP SEE} @ As) As, ©) As; (@) Asa 30, Which of the following can be measured by the of Ostwald-Walker dynamic method” IKCET! (@) Relative lowering of vapour pressure si (6) Lowering of vapour pressure ky (©) Vapour pressure ofthe solvent OT ig 3 (d) All of the above ‘iy 31. The relative lowering of vapour pressure of an aqueous r solution containing non-volatile solute is 0.0125. The % a ag of! molality of the solution is [Kerala CEE) not (a) 0.70 (b) 0.50 (c) 0.60 (d) 0.80 (© 040 32, Isotonic solutions have equal (0388) $m ~7 (a) vapour pressure (b) osmotic pressure bth (c) boiling point (d) freezing point Hg 33, Highest boiling points found in [OJEE} Cy (a) 0.1 M NaCl « (b) 0.1 MB: ue (©) 0.1 M sucrose (@) 0.1MKCL tH 34, The freezing point of water is depressed by 0.37°C in a el 0.01 mol NaCl solution. The freezing point of ae) 0.02 molal solution of urea is depressed by (WB JE] 1 @) 037°C (b) 0.74°C (@) 0.185°C (A) 0°C 436,, Blood cells do not shrink in blood because blood is So (BCECE] ssi) hypotonic # (b) isotonic (©) equimolar (@ hypertonic va 36 The mass of glucose that shouldbe dissolved in 30 g of water in order to produce the same lowering of vapour e® pressure as is produced by dissolving 1 g of urea in the WD same quantity of water is [Jamia Millia Islamia} @lg 1) 38 () 6g @ Be 31. Solutions A, B, C and D are respectively 0.1 M glucose, % 0,05 MNaCl, 0.05 M BaCl, and 0.1 M AICI. Which — oneof the following pairs is isotonic? © [MHT CET) W (a) Aand B (b) Band C (©) Aand D @ AandC 640 mm of Hg. at veighing 2.17 ‘certain tomperature ‘A non-volatile and non-electrolyie : added. 39.08 pofbenine Pressure of the Solution RerHe Blectlarweighot dst ot oath, oe mace, Ceti oe 39, Which of the followinijso!vrions will have ti 7 boiling point? (mncr c @ 0.1 MFecl, ©) 0.1 MBacl, (6) 0.1 MNact (4) 0.1 Murea (NH,CONH,) 40, Which snot coltignve propery in the following,” (MP PET) * (a) pH ofa buffer solution (b) Boiling point elevation (©) Freezing point depression (@) Vapour pressure lowering 41. Maximum lowering of vapour pressure is observed in. the case of, (aK CET] (@) 0.1 M glucose () 0.1 MBaCl, (©) 0.1 MMs80, (@) 0.1 Nach 42. A solution containing 4 g of polyvinyl chloride polymer in one litre of dioxane was found to have an osmotic pressure of 4.1% 10"* atm at 27°C. The approximate molecular weight of the polymer is, [38K CET] (a) 15x10? (b) 2.4108 (©) 1.0104 (@ 2x10" 43. Consider the following aqueous sofutions and as 100% ionisation in electrolytes 10.1 murea 1 0.04 m Aly (SO4)3 TIL. 0.05 mCaCly TY. 0.005 m NaC ‘The correct statement regarding the above solution is 3 [Guj CET] (a) freezing point will be lowest for solution 1 (b) freezing point will be highest for solution IV (©) boiling point will be highest for solution IV (4) vapour pressure will be highest for soution TL 2007 44, A 5.25% solution of a substance is isotonic with a 1.5% solution of urea (molar mass =60 g mot” ')in the same solvent. Ifthe densities of both the solutions are assumed to be equal to 1,0 gem”, molar mass of the substance will be _ (AIEEE (a) 90.0 g mol (b) 115.0 gol (©) 105.0 gml” (@) 210.0 g mol ama oe (Molar mass =342 g/mol) is pressure mol!) at 273K? (b) 4.48 atm (d) 29.4 atm ‘the following aqueous solutions will i [UP SEE} (BITSAT] The relative lowering of vapour pressure of a dilute i solution containing non-volatile solute is 0.0125. The molality of the solution is about (Kerala CEE] (b) 0.50 (d) 0.80 49. If the elevation in boiling point of a solution of 10 g of solute (mol. wt. =100) in 100 g of water is A7;, the ebullioscopic constant of water is [Kerala CEE] (a) 10 (b) 1007, © an, ( Ah. (© 107, Which one is a colligative property ? [OsEE} (a) Boiling point (b) Vapour pressure 2 (c) Osmotic pressure (d) Freezing point 51. Which one of the following statements is false ? (Jamia Millia Islamia) (a) Raoult’s law states that the vapour pressure of a component over a solution is proportional to its mole fraction (b) The osmotic pressure (n) of a solution is given by the equation x= MRT, where, M is the molarity of the solution (c) The correct order of osmotic pressure for 0.01 M aqueous solution of each compound is BaCl, > KCI>CH;COOH> sucrose 9 (d) Two sucrose solutions of same molality prepared in different solvents will have the same freezing point 7 (a) hypertonic solution 2 moal aqueous solution of sweat nc a tapes of fonisation i 03. Taking aking for wera Mer orig pomcettoasceton wl be next, " headin: * (a) —0.480°C (©) -0.260°C (dy +0. 400°C 153. The osmotic pressure is expressed in te us og o aK (@) MeV (b) cal (Cy ems (4) ctey 2006 54, 18 gof glucose (C,Hy20 Jis added 10 17824 of vg, ‘The vapour pressure of water for this aquecis shang at 100°C is ‘steep (a) 759.00 torr (©) 7.60 torr , (©) 76.00 torr (B) 752.40 tore 55. Depression in freezing point is 6 K for N20 sohision ¢ ky for water is 186 Kikg: mol, amount of wg samc ka (@) 342) 162 (ey 3284) 17 56. Osmotic pressure of 0.4% urea solution is 1.64 sm iag that of 3.42% cane sugar is 2.46 atm. When the zim two solutions are mixed, the osmotic pressure of resulting solution is 0 sez, (a) 0.82 atm (b) 2.46 atm (c) 1.64 atm (4) 4.10 amy 57. Atcertain temperature 2 5.12% solution of cane sigs isotonic with a 0.9% solution of an unkrows siute The molar mass of solute is Kerate Cem: (a) 60 (by 46.17 (c) 120 (d) 9 (e) 92.34 58. By dissolving Sg substance im SO ¢ of water tir decrease in freezing point is 12°C. The gram mid depression is 1.85°C. The molecular weight f substance is (we an (@) 1054 (by 1182 (©) 1372 (a 1542 59. The vapour pressure will be lowest for (WEI & (a) 0.1 M sugar solution (b) 0.1 M KCI solution (c) 0.1 MCu(NO; )> solution (4) 0.1 M AgNO; solution 60, Blood cells will remain 2s such in (wea (b) hypotonic solution + (©) isotonic solution (@) None of the above 61. Which has the minimum freezing point ? 4 (Jamia Millia Salas (a) One molal NaC! aqueous solution + (b) One molal CaCl; aqueous solution (©) One molal KCl aqueous solution (4) One molal urea aqueous solutionrere om steno Mati (@) below OC fof urea to be dissolved in $00 ce of water .$6°C) to produce a depression of 0.186°C in Sint s one @) 6e @ 3g (g7 Relative lowering of vapour pressure of dilute solution is 0.2. What is the mole fraction of the aoa-volatile solute ? (J&K CET) @es 0s (@ 02 2005 (6% Equimolar solution in the same solvent have [AIEEE] {@) different boiling and different freezing points {(@) same boiling and same freezing points {e) same freezing point but different boiling point {@) same boiling point but different freezing point @. X is dissolved in water. Maximum boiling point is © 03 observed when X is... (0.1 M each) (DcE} (@) CaSO, (b) BaCl, (¢) NaCl (d) urea 70. Which has minimum osmotic pressure ? (DcE} (2) 200 mL of 2 M NaCl solution (6) 200 mL of I M glucose solution (©) 200ml of 2 Murea solution (@) All have same osmotic pressure 71. Solution A contains 7 g/L of MgCl; and solution B contains 7 g/l of NaCl. At room temperature, the ‘osmotic of [DCE] (a) solution a is greater than B (b) both have same osmotic pressure (€) solution B is greater than 4 (@ cannot be determine Fee ee etre ne 190 g of water and then through pure water. The — of solution is 2.5. and that of pure 0.05 g, Calculate the molecular weight of the < ‘(Kerala OBE] Fabia ~~ @) 50 (b) 180 (e) 102 (a) 28 (St 73. In an osmotic pressure measurement experiment, 5% solution oF compound “X° is found tobe isotonie with a 2% acetic acid solution, The gram molecular mass of Sxtis IAMU} @ 24) 60) 150A) 300 74. The vapour pressure of water at 23°Cis 19.8 mm. 0.1 mole of glucose is dissolved in 178.2 g of water, What is, the vapour pressure (in mm) ofthe resultant solution ? (FAMCEN (a) 190 (b) 19.602) 19.402 (a) 19.202 75. Calculate the molal depression constant of a solvent which has freezing point 16.6°C and latent heat of fusion 180.75 Je. {osEE) (@) 268 (b) 3.86 (6) 4.68 (A) 2.86 76. Which of the following shows maximum depression in freezing point ? UBCECE] (@) KySOq (b) NaCl (c) Urea (a) Glucose 77. For an aqueous solution, freezing point is ~0.186°C, Elevation of the boiling point of the same solution is (kp =1.86°mol”! kg and &,, =0.512° mol ‘kg) (Gamia Millia Tslamial {a) 0.186 (b) 0.0512° (©) 1.86° (A) 5.12" 78. The molar freezing point constant for water is 1,86°C/mol, If 342 g of cane sugar (CigHy2011) is dissolved in 1000 gof water, the solution will freeze at [Manipal (@) -1.86°C (w) 186°C (©) -3.92°C (@) 2.42 79, The movement of solvent molecules through a semipermeable membrane is called (Manipall {a) electrolysis (b) electrophoresis (©) osmosis (@) cataphoresis 80. The osmotic pressure of 0.2 molar solution of urea at 27°C (R =0.082L atm mol 'K”') is (MP PET) (a) 492atm (b) Latm (6) 0.2 atm (@) 27 atm $1. Which of the following is incorrect? W&K CET) (a) Relative lowering of vapour pressure is independent of the nature of the solute and the solvent, (b) The relative lowering of vapour pressure is a colligative property. (©) Vapour pressure of a solution is lower than the vapour pressure of the solvent. (@) The relative lowering of vapour pressure is directly proportional to the original pressure,(®) 0.1 murea a @) 0.1 m glucose ‘relative lowering of the seureis equal totheratioof the molesofthesole oy | number of the moles in the solution” refers to 4 a (Kerala CEE] ©) Bes ay odes ie R Jaw (@) Charles’ law (©) Boyle’s law 4. Ethylene glycol is added to wate as antieeze. twill 1 (Kerala CEE} (@) decrease the freezing point of water in the winter and increase the boiling point of water in the summer (b) only decrease the freezing point of water (€) only increase the boiling point of water (d) be used for cleaning the radiator in a car (©) prevent corrosion of automobile parts 85. The molal elevation constant for water is 0.52. What will be the boiling point of 2 molar sucrose solution at 1 atm pressure ? (Assume bp. of pure water is 100°C) [AMU] (@) 101.04°¢ (b) 100.26°C (©) 100.52°C (a) 99.74°C 86. After adding a solute freezing point of solution decreases to ~0.186. Calculate AT, if ky =1.86 and ky =0.521 [OJEE} (a) 0.521 (b) 0.0521 © 1.36 (@) 0.0186 For determination of molar mass of colloids, polymers and protein, which property is used? [OJEE} (@) Diffusion pressure (6) Atmospheric pressure (c) Osmotic pressure (d) Turgor pressure 88. The freezing point depression constant for water is 1.86 K kg mol’. If 45 g of ethylene glycol is mixed with 600 g of water, the freezing point of the solution is (BCECE} (a) 22K (b) 270.95 K (©) 273K (@) 275.35K 89. Fora dilute solution Raoult’s law states that (MP PET] (@) the relative lowering of vapour pressure is equal to mole fraction of solute (b) the lowering of vapour pressure is equal to the mole fraction of solute (©) the vapour pressure of the solution is equal to mole fraction of the solvent (@) the relative lowering of vapour pressure is Proportional to amount of solute in solution a 90. Which of the following solutions will have the i, boiling point ? taxon (@) O1MFeCl, (b) 0.1 MBacl, (©) 0.1 MNacl (d) 0.1. M urea 91, Maximum freezing point falls in tax, (a) camphor: (b) naphthatene PU (©) benzene (a) water 92. Vapour pressure of dilute aqueous solution of g 730 mm of mercury at 373 K. The mole freien solute is ; ar, 1 1 es ot @t eee age 9) 2003 93. The relationship between the values of osmotic f0.1 Msolutions of KNO, (p, JandCH;COOK(p, 5 dis (egy @ — (©) p> pr A+P2 P+Pr © p> ri @ n=r 94. What is the freezing point of a solution contin 8.1 g HBr in 100 g water assuming the acid 90% ionised? (ky for water=1.86K mol"') poy (@) 0.85°C (b) -3.53°C © oc @ -0.35°C 95. On adding a solute to a solvent having vapour pres 0.80 atm, vapour pressure reduces to 0.60 atm, Mog fraction of solute is (UP seq) (a) 025) 0.75) 050 (a) 033 96. A solution of 4.5 g of a pure non-electrolyte in 100 gif water was found to freeze at 0.465°C. The molec weight of the solute is closest to (k , =1.86) (Kerala ceg (a) 135.0 (b) 172.0 (©) 90.0 (@) 86.2 (©) 180.0 97. Which of the following solution has highest boilag point ? (aN, (@) 0.1 Murea (b) 0.1 M sucrose (©) 0.1MNaNO, (@) 0.1 MAINO); 98. Which of the following statement is true? [OH (@) The relative lowering of vapour pressure of! solution is equal to the mole fraction of the soit present in the solution, (b) Passage of solute molecules towards solution sit through semipermeable membrane is osmosis. (c) The boiling point of a solution is always lower the solvent. (d) The boiling point of a liquid is the temperatut®! which its vapour pressure becomes equi! * 260 mm.isu 10 @ 1.001 NaCl> sucrose (b) NaCl> Bal, >secros (©) sero > NaCl> BoC (@) BaCh, >serose > NaCl OP PET ‘non-volatile substance 3 is mixed in 4. then its vapour pressure becomes 0.6 atm. The mole faction of Bin Be solution is Dr ren & 025 (@) 075, @ 015 (©) 050 De highest for (@ CcH.NHCl (SEE CET) () La (@) CaN05)2 4. van" Hoff factor of ag, K,SO, af infinite dilution bes value equal to (ae @1 2 ©3 (@) between 2 and 3 2008 5. van't Hoff factor of CANO )> 18 (BCECE! (@) one ©) two (©) three @ four 6 Osmotic pressure observed when benzoic acid is dissolved in benzene is less than thet expected from theoretical considerations. This is because (Jamia Molla Islamia} (a) benzoic acid is an organic solute {(b) benzoic acid has higher molar mass than benzene (©) benzoic acid gets associated in benzene (@) benzoic acid gets dissociated in benzene 7. van't Hoff factor more than unity indicates that the solute in solution has (Manipall (@) dissociated (b) associated (©) Both (a) and (b) (@) cannot say anything 8 Abnormal colligative properties are observed only ‘when the dissolved non-volatile solute in a given dilute solution (38K CET] (@ isanon-clectrolyte“ye «hy 0.08 Wn (dy 02 An IF ats the dayree of dimociation of NA,80,, y, |The yan't Holt (rn eoneentration bi (Key (a) 49 (b) 69 " pa Hor ager (o) #9 (@) 98 Loum (@) 100 2004 Degree of dissociation of NaySOy is Lore seg, (a) 75% (by 50 colligative property assuming normal (©) 25% (a) 85% Wispiven by waKkenr) — 2003 () 1 Mpg Met (A) ie Tom weight of [Manipal Tat (a) 61 (b) 244 (c) 366 (a) 12 12. The elevation in boiling point of a solution of 13.44 g of ‘CuCl, in 1 kg of water using the following information 2.74, Ths dogroe of dissoclation (8K CET) will be (molecular weight of CuCl, «134.4 and (a) 91.3% (b) 87%. ky =0.52 Km!) prams (c) 100% (d) 74% Topic 5 Distribution Law 2011 2006 1. One gram of silver gets distributed between 10m of 2. Distribution law was given by 1WB EE) and 100 em’ of molten lead at 800°C. The (a) Henry of silver still left in the lead layer in (b) van't Hoff ly (KCET] (c) Nemst’s (b) 5 3 @t (a) Ostwald ‘van't Hott factor (4) used for ealoulating the moe i) sa A tte @ Indo (b) 12. m wie Wve 14. The van't Hoff thetor of RuCl; At0.01 M concent, Js 1.98, The porwentage of dissociation of Bac, qe, 15, 0,004 M NaySO, Is isotonic with 0.01 M glucose 16, Henzoic acid dissolved in benzene shows 4 molecule 17. The van't Hoff factor for 0,1 M Ba(NO )> solution's2) ~ 19.(@) 20. @) 29. (0) 30. (a) 39.(<) 40. (0) : es tie, 54. (b) 59. (4) 60. (b) 64. (0) 69.(2) 70. ©) : Vapour Pressure of Liquid Solutions (Raoult’s Law) Ideal and Non-ideal Solutions hs 38 go 28 0 28 28 38 88 (o) 22. (b) 23. (a) 24. (a) 25. (c) 2 ti opie 3 : Colligative Properties and Determination of Molar Mass de 2@ 320 40 56 66) 72) ® a 12) 13) 14) 15.) 6). @) © oe 2) 23.) 2H.() 5. (6) 28.) 27.3) 2B.) B@) 32) 33-0) 34.) 35.) 3K.) 37.) © BO 420 40) aa 46.(0) 47. @) @ @ 52.2) 53. (4) 54. a) HO) 620) 63.) 6a. a) @ 72) 73.) 74. (b) @ 82) BB. (c)—BA. (a) @) 56.(c) 57.) 5B.) 66.(0) 67GB.) 76.(0) 77.0) 7G) 86.0) 87.) BB.) 96.(0) 97.) 98.) 92. (2) 93. (b) 94. (b) (@) 102, (a) 103. (c) 108. (c) ‘Topic 4: Abnormal Molar Masses L@ _2.(0) 3. (a) 4. (0) 5. (6. @) 7.) a © 9.) 10. @) W@ 12) «18 (148 5.) 168.) ‘Topic 5 ; Distribution Law 16 20