SPM Trial 2013 Chemistry Qa SBP PDF

SULIT 4541/1
Kimia
Kertas 1
Ogos
2013
1 jam
BAHAGIAN PENGURUSAN SEKOLAH BERASRAMA PENUH

DAN SEKOLAH KECEMERLANGAN
PENDIDIKANMALAYSIA
KEMENTERIAN PELAJARAN MALAYSIA
PENTAKSIRAN DIAGNOSTIK AKADEMIK SBP 2013

SIJIL PELAJARAN MALAYSIA
KIMIA
Kertas 1
1 jam 15 minit
JANGAN BUKA KERTAS SOALAN INI SEHINGGA DIBERITAHU
Arahan:
1. Kertas ini mengandungi 50 soalan.
2. Jawab semua soalan.
3. Rajah yang mengiringi soalan tidak dilukis mengikut skala kecuali dinyatakan.
4. Anda dibenarkan menggunakan kalkulator saintifik yang tidak boleh diprogramkan.
5. Tiap-tiap soalan diikuti oleh empat pilihan jawapan A , B , C dan D .

Pilih satu jawapan yang terbaik bagi setiap soalan dan hitamkan ruangan yang sepadan
pada kertas jawapan objektif anda.
Kertas ini mengandungi 27 halaman bercetak
4541/1 2013 Hak Cipta BPSBPSK [Lihat Halaman Sebelah

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SULIT 2 4541/1
1 Sublimation is a process when the solid change to gas.

Which substance undergoes sublimation?
Pemejalwapan adalah satu proses apabila pepejal bertukar kepada gas.
Bahan manakah mengalami pemejalwapan?
A Iodine
Iodin
B Carbon
Karbon
C Sulphur
Sulfur
D Bromine
Bromin
2 Which substance contains 6.02 x 1023 atoms?

Bahan manakah mengandungi 6.02x1023 atom?
A 1.0 mol of carbon dioxide gas

1.0 mol gas karbon dioksida
B 1.0 mol of hydrogen gas
1.0 mol gas hidrogen
C 1.0 mol of oxygen gas
1.0 mol gas oksigen
D 1.0 mol of helium gas
1.0 mol gas helium
3 Which elements are located in Group 1 in the Periodic Table of Elements?

Unsur-unsur manakah terletak dalam Kumpulan 1 dalam Jadual Berkala Unsur?
A Sodium and caesium

Natrium dan sesium
B Lithium and barium
Litium dan barium
C Potassium and calcium
Kalium dan kalsium
D Magnesium and sodium
Magnesium dan natrium
4541/1 2013 Hak Cipta BPSBPSK SULIT

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SULIT 3 4541/1
4 Which substance is an ionic compound?

Bahan manakah adalah sebatian ion?
A Ethanol
Etanol
B Ammonia
Ammonia
C Sodium oxide
Natrium oksida
D Sulphur dioxide
Sulfur dioksida
5 Diagram 1 shows the set-up of apparatus of a chemical cell.

Rajah 1 menunjukkan susunan radas bagi satu sel kimia.
Y electrode Zinc electrode

Elektrod Y Elektrod zink
Electrolyte
Elektrolit
Diagram 1
Rajah 1
Electrode Y is the negative terminal of the cell.

What is Y?
Elektrod Y adalah negatif terminal bagi sel itu.
Apakah Y?
A Iron
Ferum
B Lead
Plumbum
C Copper
Kuprum
D Aluminium
Aluminium

SULIT 4 4541/1
6 Which of the following is a diprotic acid?

Antara berikut yang manakah asid diprotik?
A Nitric acid
Asid nitrik
B Ethanoic acid
Asid etanoik
C Sulphuric acid
Asid sulfurik
D Hydrochloric acid
Asid hidroklorik
7 Which salt is insoluble in water?

Garam manakah tidak larut dalam air?
A Lead(II) nitrate
Plumbum(II) nitrat
B Iron(II) chloride
Ferum(II) klorida
C Barium sulphate
Barium sulfat
D Sodium carbonate
Natrium karbonat
8 Trophy and medal are normally made up of bronze.

What is the composition of bronze?
Piala dan pingat biasanya diperbuat daripada gangsa.
Apakah komposisi gangsa?
A Copper and tin

Kuprum dan stanum
B Copper and zinc
Kuprum dan zink
C Tin, copper and antimony
Stanum, kuprum dan antimony
D Iron, carbon and chromium
Ferum, karbon dan kromium

SULIT 5 4541/1
9 Which reaction has the lowest rate of reaction?

Tindak balas manakah mempunyai kadar paling rendah?
A Precipitation of salt
Pemendakan garam
B Combustion of alcohol
Pembakaran alkohol
C Fermentation of glucose
Penapaian glukosa
D Neutralisation of acid and alkali
Peneutralan asid dan alkali
10 Diagram 2 shows the particles arrangement for the change of state of matter.
Rajah 2 menunjukkan susunan zarah bagi pertukaran keadaan jirim.
Process X
Proses X
Diagram 2
Rajah 2
Which of the following is process X?
Antara berikut yang manakah adalah proses X?
A Condensation
Kondensasi
B Evaporation
Penyejatan
C Sublimation
Pemejalwapan
D Freezing
Pembekuan

SULIT 6 4541/1
11 Which statement is incorrect about unsaturated hydrocarbons?

Pernyataan manakah yang tidak betul mengenai hidrokarbon tak tepu?
A Soluble in water
Larut dalam air
B Cannot conduct electricity at any state
Tidak mengkonduksi elektrik dalam sebarang keadaan
C Contain only carbon and hydrogen atoms
Mengandungi hanya atom karbon dan atom hidrogen
D Contain at least one double bond between carbon atoms
Mengandungi sekurang-kurangnya satu ikatan ganda dua antara atom-atom
karbon
12 Which statement defines oxidation?

Pernyataan manakah mendefinisikan pengoksidaan?
A Increase in oxidation number

Penambahan nombor pengoksidaan
B Gain of hydrogen
Penerimaan hydrogen
C Loss of oxygen
Kehilangan oksigen
D Gain of electron
Penerimaan electron
13 The reaction between silver nitrate solution and hydrochloric acid is an exothermic
reaction.
Which statement is correct about the reaction?
Tindak balas antara larutan argentum nitrat dengan asid hidroklorik adalah tindak balas
eksotermik.
Pernyataan manakah betul tentang tindak balas itu?
A Heat is absorbed from surroundings

Haba diserap daripada persekitaran
B The products formed are more stable than reactants
Hasil tindak balas lebih stabil daripada bahan tindak balas
C The surroundings temperature increases during the reaction
Suhu persekitaran meningkat semasa tindak balas
D The energy content of reactants is lower than the energy content of products
Kandungan tenaga bahan tindak balas lebih rendah daripada kandungan tenaga
hasil indak balas

SULIT 7 4541/1
14 Diagram 3 shows a decorative glass which is used in the house. The glass has the
following properties.
Rajah 3 menunjukkan satu kaca perhiasan yang digunakan di rumah. Kaca itu mempunyai
ciri-ciri berikut.
Optically transparent
Lutsinar secara optik
High refractive index

Indeks biasan yang
High density tinggi
Ketumpatan yang tinggi
Diagram 3
Rajah 3
Which of the following glass has the above properties?

Kaca manakah mempunyai ciri-ciri seperti di atas?
A Fused glass
Kaca silika terlakur
B Soda-lime glass
Kaca soda kapur
C Borosilicate glass
Kaca borosilikat
D Lead crystal glass
Kaca plumbum Kristal
15 What is the function of aspartame?

Apakah fungsi aspartam?
A Stabiliser
Penstabil
B Flavouring
Perisa
C Preservative
Pengawet
D Antioxidant
Antipengoksida

SULIT 8 4541/1
16 Diagram 4 shows the set-up of apparatus for an experiment to determine the empirical
formula of magnesium oxide.
Rajah 4 menunjukkan susunan radas bagi satu eksperiment untuk menentukan formula
empirik magnesium oksida.
Tongs to remove lid

Penyepit untuk mengangkat penutup
Magnesium ribbon
Pita magnesium
Pipe clay triangle
Segitiga tanah liat
Tripod stand
Tungku kaki tiga
Heat
Panaskan
Diagram 4
Rajah 4
The lid of crucible must be lifted at intervals during the heating process.
What is the reason for this action?
Penutup mangkuk pijar perlu diangkat sekali sekala semasa proses pemanasan.
Apakah sebab tindakan ini diambil?
A To get the accurate mass of magnesium oxide

Untuk mendapatkan jisim yang tepat bagi magnesium oksida
B To allow oxygen enter into the crucible and react with magnesium
Untuk membenarkan oksigen masuk ke dalam mangkuk pijar dan bertindak
balas dengan magnesium
C To ensure the complete reaction of magnesium to form magnesium oxide
Untuk memastikan tindak balas lengkap magnesium untuk membentuk
magnesium oksida
D To release the white fumes that produce from combustion to the surroundings
Untuk membebaskan wasap putih yang terhasil daripada pembakaran ke
persekitaran

SULIT 9 4541/1
17 Which isotope is used in radiotherapy for the treatment of cancer?

Isotop manakah digunakan dalam radioterapi untuk mengubati penyakit kanser?
A Cobalt-60
Kobalt-60
B Sodium-24
Natrium-24
C Carbon-14
Karbon-14
D Phosphorus-32
Fosforus-32
18 Element M forms two different chlorides, MCl2 and MCl3.

What is M ?
Unsur M membentuk dua jenis klorida, MCl2 dan MCl3 .
Apakah M?
A Iron
Ferum
B Zinc
Zink
C Copper
Kuprum
D Lead
Plumbum
19 Which substance is an electrolyte?

Bahan manakah adalah elektrolit?
A Glucose
Glukosa
B Naphthalene
Naftalena
C Ethanoic acid
Asid etanoik
D Ethyl ethanoate
Etil etanoat

SULIT 10 4541/1
20 Diagram 5 shows the set-up of apparatus to investigate the electrical conductivity of

substance P.
Rajah 5 menunjukkan susunan radas untuk mengkaji kekonduksian elektrik bagi bahan P.
Diagram 5
Rajah 5
Substance P lights up the bulb because

Bahan P menyalakan mentol kerana
A soluble in water.
larut dalam air.
B has high melting point.
mempunyai takat lebur yang tinggi.
C has free moving ions.
mengandungi ion-ion yang bebas bergerak.
D has strong electrostatic forces between ions.
mempunyai daya elektrostatik yang kuat antara ion-ion.
21 Which of the following is correct about weak alkalis?

Antara berikut yang manakah betul mengenai alkali lemah?
A Unable to neutralise acid
Tidak boleh meneutralkan asid
B The pH value is less than 7
Nilai pH kurang daripada 7
C Able to change blue litmus paper to red
Boleh menukarkan kertas litmus biru ke merah
D Ionise partially in water to produce hydroxide ion
Mengion separa dalam air untuk menghasilkan ion hidroksida

SULIT 11 4541/1
22 Which reactants are suitable to prepare copper(II) sulphate?

Bahan manakah sesuai untuk menyediakan kuprum(II) sulfat?
A Copper and sulphuric acid

Kuprum dan asid sulfurik
B Copper(II) carbonate and sulphuric acid
Kuprum(II) karbonat dan asid sulfurik
C Copper(II) oxide and sodium sulphate
Kuprum(II) oksida dan natrium sulfat
D Copper(II) nitrate and sodium sulphate
Kuprum(II) nitrat dan natrium sulfat
23 A substance has the following properties:

Satu bahan mempunyai ciri-ciri berikut:
Hard and opaque

Keras dan legap
Inert towards chemicals
Lengai terhadap bahan kimia
Good insulator of heat and electricity
Penebat haba dan elektrik yang baik
Which substance has the above properties?

Bahan manakah mempunyai ciri-ciri di atas?
A Ceramic
Seramik
B Polymer
Polimer
C Metal
Logam
D Glass
Kaca

SULIT 12 4541/1
24 The higher the concentration of reactant, the higher the rate of reaction.
Which statement explains why the rate of reaction increases?
Apabila kepekatan bahan tindak balas meningkat, kadar tindak balas meningkat.
Pernyataan manakah menerangkan mengapa kadar tindak balas meningkat?
A Kinetic energy of the particles increases

Tenaga kinetik zarah-zarah bertambah
B The total surface area of the particles increases
Jumlah luas permukaan zarah-zarah bertambah
C The number of particles per unit volume increases
Bilangan zarah-zarah per unit isi padu bertambah
D More particles are able to achieve lower activation energy
Lebih banyak zarah-zarah berupaya untuk mencapai tenaga pengaktifan yang
lebih rendah
25 Diagram 6 shows the structural formula of substance X.

Rajah 6 menunjukkan formula struktur bagi bahan X.
Diagram 6
Rajah 6
Which of the following are properties of substance X?
Antara berikut yang manakah sifat-sifat bahan X?
I Reacts with copper to produce hydrogen gas
Bertindak balas dengan kuprum menghasilkan gas hidrogen
II Colourless liquid at room temperature
Cecair tidak berwarna pada suhu bilik
III Reacts with alcohol to form an ester
Bertindak balas dengan alkohol menghasilkan sejenis ester
IV Does not dissolve in water
Tidak larut di dalam air
A I and II
I dan II
B I and IV
I dan IV
C II and III
II dan III
D III and IV
III dan IV
SULIT 13 4541/1
26 Which substance accepts electron?

Bahan manakah menerima elektron?
A Dehydrating agent
Agen pengontangan
B Emulsifying agent
Agen pengemulsian
C Oxidising agent
Agen pengoksidaan
D Reducing agent
Agen penurunan
27 The thermochemical equation represents the neutralisation between hydrochloric acid,

HCl and sodium hydroxide, NaOH solution.
Persamaan termokimia mewakili tindak balas peneutralan antara asid hidroklorik, HCl
dan larutan natrium hidroksida, NaOH.
HCl + NaOH NaCl + H2O H = -57 kJ mol-1
Which substance is suitable to replace hydrochloric acid to obtain the same H value?
Bahan manakah yang sesuai menggantikan asid hidroklorik untuk memperoleh nilai H
yang sama?
A Nitric acid
Asid nitric
B Ethanoic acid
Asid etanoik
C Carbonic acid
Asid karbonik
D Phosphoric acid
Asid fosforik

SULIT 14 4541/1
28 Diagram 7 shows the elements in Period 3 of the Periodic Table of the Elements.
Rajah 7 menunjukkan unsur-unsur dalam Kala 3 Jadual Berkala Unsur.
Na Mg Al Si P S Cl Ar
Diagram 7
Rajah 7
Which of the following statement is correct?

Antara pernyataan berikut yang manakah betul?
A Argon is denser than magnesium

Argon lebih tumpat daripada magnesium
B Chlorine is more electronegative than sulphur
Klorin lebih elektronegatif daripada sulfur
C Sodium has smaller atomic size than aluminium
Natrium mempunyai saiz atom lebih kecil daripada aluminium
D Magnesium has lower melting point than phosphorus
Magnesium mempunyai takat lebur lebih rendah daripada fosforus
29 Which equations represent a neutralisation reaction?

Persamaan manakah mewakili tindak balas peneutralan?
I MgO + 2HCl MgCl2 + H2O

II CH3COOH + KOH CH3COOK + H2O
III Mg + 2AgNO3 Mg(NO3)2 + 2Ag
IV BaCl2 + H2SO4 BaSO4 + 2HCl
A I and II
I dan II
B II and III
II dan III
C I and IV
I dan IV
D III and IV
III dan IV

SULIT 15 4541/1
30 Diagram 8 shows a cut apple turns brown after 20 minutes.

Rajah 8 menunjukkan sepotong epal yang bertukar perang selepas 20 minit.
Brown colour
Warna perang
perang
Diagram 8
Rajah 8
Which of the following is the reason why the cut apple turns brown and the type of
food additive used to prevent it?
Antara berikut yang manakah sebab mengapa epal yang dipotong itu bertukar
perang dan jenis bahan tambah makanan yang digunakan untuk mengelakkannya?
Reason Food additive

Sebab Bahan tambah makanan
A The growth of microorganisms Preservative
Pembiakan mikroorganisma Pengawet
B Oxidation occur Antioxidant
Pengoksidaan berlaku Antipengoksida
C Concentration of salt is high Flavouring
Kepekatan garam adalah tinggi Perisa
D Azo compound presents in the apple Colouring
Sebatian azo wujud dalam epal Pewarna
31 A woman is always sad and anxious.

Which medicine is suitable to treat this patient?
Seorang wanita selalu sedih dan gelisah.
Ubat manakah paling sesuai untuk mengubati pesakit itu?
A Chlorpromazine
Klorpromazin
B Tranquilizer
Trankuilizer
C Penicillin
Penisilin
D Aspirin
Aspirin

SULIT 16 4541/1
32 Diagram 9 shows the the electron arrangement of a compound formed between carbon, C and
element Y. The letter Y is not the actual symbol of the element.
Rajah 9 menunjukkan susunan elektron bagi sebatian yang terbentuk antara karbon, C dan
unsur Y. Huruf Y bukan simbol sebenar unsur itu.
x
x x
Y x C
X x Y
x
Diagram 9
Rajah 9
What is the formula of the compound formed when lithium reacts with Y?
Apakah formula bagi sebatian yang terbentuk apabila litium bertindak balas dengan Y?
A LiY
B LiY2
C LiY4
D Li2Y
33 Atoms X and Y are isotopes. The nucleon number of atom Y is 37 and it has 20 neutrons.
What is the electron arrangement of atom X?
Atom X dan Y adalah isotop. Nombor nukleon atom Y adalah 37 dan ia mempunyai 20
neutron.
Apakah susunan elektron atom X?
A 2.7
B 2.8.7
C 2.8.2
D 2.8.8.2

SULIT 17 4541/1
34 Diagram 10 shows an energy profile, X for one of the stage in the production of sulphuric
acid through Contact Process.
Rajah 10 menunjukkan profil tenaga, X bagi salah satu peringkat dalam penghasilan asid
sulfurik melalui Proses Sentuh.
Energy
Tenaga
X
Y
2SO3
2SO2 + O2
Diagram 10
Rajah 10
What is the change needed to be done to obtain curve Y?

Apakah perubahan yang perlu dilakukan untuk mendapat lengkung Y?
A Heat the reactants at 450oC

Panaskan bahan tindak balas pada suhu 450oC
B Compress the reactants at 1 atm
Mampatkan bahan tindak balas pada tekanan 1 atm
C Increase the concentration of reactants
Tingkatkan kepekatan bahan tindak balas
D Heat the reactants with the presence of vanadium(V) oxide
Panaskan bahan tindak balas dengan kehadiran vanadium(V) oksida

SULIT 18 4541/1
35 Diagram 11 shows the apparatus set-up for the electrolysis of sodium nitrate solution,
NaNO3 using carbon electrodes.
Rajah 11 menunjukkan susunan radas bagi elektrolisis larutan natrium nitrat, NaNO3
menggunakan elektrod-elektrod karbon.
Electrode X Electrode Y
Elektrod X Elektrod Y
Sodium nitrate solution
Larutan natrium nitrat
Diagram 11
larutan natrium nitrat
Rajah 11
What are the products at electrodes X and Y?
Apakah hasil tindak balas pada elektrod X dan Y?
X Y
A Oxygen gas Sodium
Gas oksigen Natrium
B Hydrogen gas Oxygen gas
Gas hidrogen Gas oksigen
C Nitrogen gas Sodium
Gas nitrogen Natrium
D Oxygen gas Hydrogen gas
Gas oksigen Gas hidrogen
36 Copper(II) sulphate solution is electrolysed using carbon electrodes.

Which half-equations represent the reactions at the anode and the cathode?
Larutan kuprum(II) sulfat dielektrolisiskan menggunakan elektrod-elektrod karbon.
Setengah persamaan manakah mewakili tindak balas di anod dan di katod?
Anode Cathode
Anod Katod
A Cu2+ + 2e Cu 4OH 2H2O + O2 + 4e
B 4OH 2H2O + O2 + 4e 2H+ + 2e H2
C 4OH 2H2O + O2 + 4e Cu2+ + 2e Cu
D 2H+ + 2e H2 4OH 2H2O + O2 + 4e

SULIT 19 4541/1
37 Diagram12 shows the set-up of apparatus for the decomposition of compound Q.

Rajah 12 menunjukkan susunan radas bagi penguraian sebatian Q.
Q
Heat
Panaskan Lime water
Air kapur
Diagram 12
Rajah 12
When Q is heated, the lime water turns milky.

What is compound Q?
Apabila Q dipanaskan, air kapur bertukar keruh.
Apakah sebatian Q?
A Ammonium carbonate
Ammonium karbonat
B Potassium carbonate
Kalium karbonat
C Sodium carbonate
Natrium karbonat
D Zinc carbonate
Zink karbonat
38 A farmer discovered that his plants were not growing well because the soil was acidic.
Which substance is used to overcome the problem?
Seorang petani mendapati tanamannya tidak tumbuh dengan subur kerana tanahnya
berasid.
Bahan manakah digunakan untuk mengatasi masalah tersebut?
A Zinc oxide
Zink oksida
B Calcium oxide
Kalsium oksida
C Potassium hydroxide
Kalium hidroksida
D Magnesium hydroxide
Magnesium hidroksida

SULIT 20 4541/1
39 Diagram 13 shows curve I in a graph of volume of gas released against time for the reaction
between excess zinc powder and 100 cm3 of 1.0 mol dm-3 hydrochloric acid, HCl.
Which of the following conditions represents curve II?
Rajah 13 menunjukkan lengkung I dalam graf isi padu gas terbebas melawan masa bagi tindak
balas antara serbuk zink berlebihan dengan 100 cm3 asid hidroklorik, HCl 1.0 mol dm-3.
Antara berikut keadaan manakah mewakili lengkung II?
Volume of gas (cm3)

Isi padu gas (cm3)
II
Time (s)
Masa (s)
Diagram 13
Rajah 13
Concentration of HCl (mol dm-3) Volume of HCl (cm3)

Kepekatan HCl ( mol dm-3) Isi padu HCl (cm3)
A 0.5 100
B 1.0 50
C 2.0 50
D 2.0 25

SULIT 21 4541/1
40 Which of the following shows the structural formula for 2-methylbut-2-ene.

Antara berikut yang manakah menunjukkan formula struktur bagi 2-metilbut-2-ena.

SULIT 22 4541/1
41 Diagram 14 shows two experiments to investigate the effect of metals X and Y on the
rusting of iron.
Rajah 14 menunjukkan dua eksperimen untuk mengkaji kesan logam X dan Y terhadap
pengaratan besi.
Experiment Observation
Eksperimen Pemerhatian
Jelly solution + potassium
hexacyanoferrate(III)
Larutan agar + kalium No change
heksasianoferat(III) Tiada perubahan
air nail and metal X
Iron
Paku besi dan logam X

hexacyanoferrate(III)
Larutan agar + kalium Blue spot formed
heksasianoferat(III) Tompok biru terbentuk
air nail and metal Y
Iron
Paku besi dan logam Y
Diagram 14
Rajah 14
Arrange X, Y and iron in order of increasing tendency to release electrons.

Susun X, Y dan besi dalam urutan pertambahan kecenderungan melepaskan elektron.
A Iron , X , Y
Besi , X , Y
B X , iron , Y
X , besi , Y
C X , Y , iron
X , Y , besi
D Y , iron , X
Y , besi , X

SULIT 23 4541/1
42 Table 1 shows temperature change obtained for two set of experiments.

Jadual 1 menunjukkan perubahan suhu yang didapati bagi dua set eksperimen.
Set Reactants Temperature change ( oC)

Set Bahan tindak balas Perubahan suhu ( oC)
Magnesium powder + 25 cm3 of 0.2 mol dm-3
copper(II) sulphate solution
I Serbuk magnesium + 25 cm3 larutan kuprum(II)
sulfat 0.2 mol dm-3
Magnesium powder + 25 cm3 of copper(II) x

sulphate solution 0.4 mol dm-3
II Serbuk magnesium + 25 cm3 larutan kuprum(II)
sulfat 0.4 mol dm-3
Table 1
Jadual 1
What is the value of x?

Apakah nilai x?
A
B 2
C 0.5
D 0.25
43 Element X is located below potassium in the Periodic Table of Elements.

X is not the actual symbol of the element.
Which statement is correct about element X?
Unsur X berada di bawah kalium dalam Jadual Berkala Unsur.
X bukan simbol sebenar unsur itu.
Pernyataan manakah betul tentang unsur X?
A X is less dense than potassium

X kurang tumpat daripada kalium
B X is less reactive than potassium
X kurang reaktif daripada kalium
C X atom is smaller than potassium atom
Atom X lebih kecil daripada atom kalium
D X is more electropositive than potassium
X lebih elektropositif daripada kalium

SULIT 24 4541/1
44 Table 2 shows the proton number of four atoms of elements.

Jadual 2 menunjukkan nombor proton bagi empat atom unsur.
Atom W X Y Z
Atom
Proton number 12 8 18 17
Nombor proton
Table 2
Jadual 2
Which elements react to form an ionic compound?
Unsur-unsur manakah bertindak balas untuk membentuk sebatian ion?
I W and X
W dan X
II W and Z
W dan Z
III X and Y
X dan Y
IV X and Z
X dan Z
A I and II
I dan II
B I and III
I dan III
C II and IV
II dan IV
D III and IV
III dan IV
45 What is the number of atoms in 8.5 g of ammonia gas, NH3?

[Molar mass of NH3 = 17 ; Avogadro constant = 6.02 x 1023 mol-1]
Berapakah bilangan atom dalam 8.5 g ammonia gas, NH3?
[Jisim molar NH3 = 17 ; Pemalar Avogadro = 6.02 x 1023 mol-1]
A 0.5 x 6.02 x 1023

B 0.5 x 4 x 6.02 x 1023
C 8.5 x 6.02 x 1023
D 8.5 x 4 x 6.02 x 1023

SULIT 25 4541/1
46 The equation represents the reaction between sulphuric acid and sodium hydroxide.
Persamaan mewakili tindak balas antara asid sulfurik dan natrium hidroksida.
H2SO4 + 2NaOH K2SO4 + 2H2O
What is the volume of 1.0 mol dm-3 sodium hydroxide solution needed to neutralise
25.0 cm3 of 1.0 mol dm-3 sulphuric acid?
Berapakah isipadu larutan natrium hidroksida 1.0 mol dm-3 yang diperlukan untuk
meneutralkan 25.0 cm3 asid sulfurik 1.0 mol dm-3?
A 12.5 cm3
B 25.0 cm3
C 50.0 cm3
D 75.0 cm3
47 Table 3 shows the volume of oxygen gas collected in the decomposition of hydrogen
peroxide.
Jadual 3 menunjukkan isi padu gas oksigen terkumpul dalam penguraian hidrogen
peroksida.
Time (s) 0 30 60 90 120 150 180 210

Masa (s)
Volume of oxygen (cm3) 0.0 7.0 14.5 20.5 26.2 30.5 30.5 30.5
Isi padu oksigen (cm3)
Table 3
Jadual 3
What is the average rate of reaction in the second minute?

Berapakah kadar tindak balas purata dalam minit ke-2?
A 0.254 cm3 s-1

B 0.218 cm3 s-1
C 0.203 cm3 s-1
D 0.195 cm3 s-1

SULIT 26 4541/1
48 Diagram 15 shows a structural formula of an ester propyl ethanoate.

Rajah 15 menunjukkan formula struktur bagi satu ester propil etanoat.
H O H H H
H C C O C C C H
H H H H
Diagram 15
Rajah 15
What are the structural formula of alcohol and carboxylic acid used to prepare the ester?
Apakah formula struktur alkohol dan asid karbosilik yang digunakan untuk menyediakan
ester itu?
Alcohol Carboxylic acid

Alkohol Asid karbosilik
A CH3CH2OH CH3COOH
B CH3CH2CH2OH CH3COOH
C CH3CH2 CH2OH CH3CH2COOH
D CH3CH2 OH CH3CH2COOH
49 R is located between aluminium and iron in the reactivity series of metals.

Which oxide is not reduced by R?
R terletak antara magnesium dan ferum dalam siri kereaktifan logam.
Oksida manakah tidak diturunkan oleh R?
A Copper(II) oxide
Kuprum(II) oksida
B Magnesium oxide
Magnesium oksida
C Silver oxide
Argentum oksida
D Tin(II) oxide
Stanum(II) oksida

SULIT 27 4541/1
50 The thermochemical equation represents the combustion of methanol, CH3OH.

Persamaan termokimia mewakili pembakaran methanol, CH3OH.
CH3OH + 3/2 O2 CO2 + 2H2O H = -728 kJ mol-1
What is the mass of methanol needed to raise the temperature of 250 cm3 of water by
27.8C?
[Molar mass of CH3OH = 32; Specific heat capacity of water = 4.2 J g-1 C-1;
Density of water = 1 g cm-3]
Berapakah jisim metanol yang diperlukan untuk menaikkan suhu 250 cm3 air sebanyak
27.8 C?
[Jisim molar CH3OH = 32; Muatan haba tentu air =4.2 J g-1 C-1;
Ketumpatan air = 1 g cm-3]
A 2.56 g
B 1.88 g
C 1.28 g
D 0.79 g
END OF QUESTION PAPER

KERTAS SOALAN TAMAT

SULIT 4541/2
Chemistry
Kertas 2
Ogos
2013 NAMA: TINGKATAN:
2 JAM
BAHAGIAN PENGURUSAN SEKOLAH BERASRAMA PENUH

KEMENTERIAN
KEMENTERIANPENDIDIKAN
PELAJARAN MALAYSIA
MALAYSIA

CHEMISTRY
KERTAS 2
2 JAM 30 MINIT
Arahan:
1. Tuliskan Nama dan Tingkatan pada ruang Untuk Kegunaan Pemeriksa
yang disediakan. Bahagian Soalan Markah Markah
penuh diperoleh
2. Jawab semua soalan daripada Bahagian A. 1 9
Tuliskan jawapan anda dalam ruang yang
disediakan. 2 9
3 10
3. Jawab satu soalan daripada Bahagian B dan
satu soalan daripada Bahagian C A 4 10
4. Anda diminta menjawab dengan lebih 5 11

terperinci untuk Bahagian B dan Bahagian
C. Jawapan mestilah jelas dan logik. 6 11
Persamaan, gambar rajah, jadual, graf dan
cara lain yang sesuai untuk menjelaskan 7 20
jawapan anda boleh digunakan. B
8 20
5. Penggunaan kalkulator saintifik yang tidak 9 20

boleh diprogramkan adalah dibenarkan. C
10 20
Jumlah
4541/2 2013 Hak Cipta BPSBPSK [Lihat Halaman Sebelah

http://www.chngtuition.blogspot.com SULIT
SULIT 2 4541/2
Section A
Bahagian A
[60 marks]
[60 markah]
Answer all questions in this section

Jawab semua soalan dalam bahagian ini.
1. (a) Diagram 1 shows the set-up of the apparatus an experiment to study Process I.
Rajah 1 menunjukkan susunan radas bagi satu eksperimen bagi mengkaji Proses I.
Solid agar
_ Agar-agar pejal _
_ _ Whole agar
_ _ turns purple.
Solid potassium
- _ Seluruh agar
manganate(VII)
- - menjadi ungu
Pepejal kalium
- manganat(VII) -
-
-
-
Diagram 1.1
Rajah 1.1
(i) Name the process involved in this experiment?

Namakan proses yang terlibat?
..
[1 mark]
(ii) State the type of particles present in potassium manganate(VII).

Nyatakan jenis zarah dalam kalium manganat(VII).
..
[1 mark]
(iii) Explain the observation in this experiment based on the kinetic theory
of matter.
Terangkan pemerhatian dalam eksperimen ini berdasarkan teori kinetik
jirim.
..
.
[3 marks]

SULIT 3 4541/2
(b) Diagram 1.2 shows the symbols for three atoms of carbon.
Rajah 1.2 menunjukkan simbol bagi tiga atom karbon.
Atom Proton number Nucleon number

Atom Nombor proton Nombor nukleon
12
6C 6 12
13
6
C 6 13
14
C
6 6 14
Diagram 1.2
Rajah 1.2
(i) Name one subatomic particles present in the nucleus of carbon atom.
Namakan satu zarah subatom yang terdapat dalam nukleus atom karbon.
..
[1 mark]
12 13 14
(ii) , 6 C and 6 C are isotopes.
6C
What is meant by isotope?
13
12
, 6 C dan 6 C adalah isotop.
6C
14
Apakah yang dimaksudkan dengan isotop?
..
[1 mark]
14
(iii) Determine the number of neutrons for the isotope of carbon-14, C.
6
14
Tentukan bilangan neutron bagi isotop karbon-14, C.
6
..
[1 mark]
14
(iv) State one use of carbon-14, C
6
14
Nyatakan satu kegunaan karbon-14, C.
6
..
[1 mark]

SULIT 4 4541/2
2 Diagram 2 shows the symbol of atoms of magnesium, aluminium and chlorine.

Rajah 2 menunjukkan simbol atom-atom bagi magnesium, aluminium dan klorin.
24 27 35.5
Mg Al Cl
12 13 17
Diagram 2
Rajah 2
(a) (i) Write the electron arrangement of magnesium atom.

Tuliskan susunan elektron bagi atom magnesium.
..
[1 mark]
(ii) State the position of magnesium in the Periodic Table of Elements.

Nyatakan kedudukan magnesium dalam Jadual Berkala Unsur.
.
[1 mark]
(b) What is the physical state of chlorine at room condition?

Apakah keadaan fizik bagi klorin pada keadaan bilik?

[1 mark]
(c) Which element forms an acidic oxide?

Unsur manakah membentuk oksida yang bersifat asid?
..
[1 mark]
(d) Aluminium reacts with oxygen to form aluminium oxide.

Aluminium bertindak balas dengan oksigen membentuk aluminium oksida.
(i) Write the chemical formula of aluminium oxide.

Tuliskan formula kimia bagi aluminium oksida.
..
[1 mark]
(ii) State the type of bond in aluminium oxide.
Nyatakan jenis ikatan di dalam aluminium oksida.
.
[1 mark]

SULIT 5 4541/2
(e) 2.4 g magnesium reacts with chlorine to form 9.5 g magnesium chloride.
Determine the empirical formula of magnesium chloride.
2.4 g magnesium bertindak balas dengan klorin membentuk 9.5 g magnesium klorida.
Tentukan formula empirik bagi magnesium klorida.
[Relative atomic mass : Mg = 24, Cl = 35.5]

[Jisim atom relatif : Mg = 24, Cl = 35.5]
[3 marks]
3 Diagram 3 shows the series of reactions that involve copper(II) nitrate.

Rajah 3 menunjukkan siri tindak balas yang melibatkan kuprum(II) nitrat.
Reaction I
Tindak balas I
Copper(II) nitrate Solid X Colourless Brown
Kuprum(II) nitrat Pepejal X + +
Gas Y Gas Z
Heat Gas Y yang Gas Z yang
Panaskan tidak berwarna
berwarna perang
Reaction II
Tindak balas II
+ Hydrochloric acid
Asid hidroklorik
Solution R
Larutan R
Diagram 3
Rajah 3

SULIT 6 4541/2
(a) Copper(II) nitrate is a salt.

Kuprum(II) nitrat adalah sejenis garam.
(i) State the meaning of salt.

Nyatakan maksud garam.
....
[1 mark]
(ii) State the colour of copper(II) nitrate.

Nyatakan warna kuprum(II) nitrat.

[1 mark]
(b) In Reaction I, copper(II) nitrate is heated strongly to form solid X, gas Y and gas
Z.
Dalam tindak balas I, kuprum(II) nitrat dipanaskan dengan kuat untuk menghasilkan
pepejal X, gas Y dan gas Z.
(i) Name gas Y.

Namakan gas Y.
....................
[1 marks]
(ii) Write the chemical formula of gas Z.

Tuliskan formula kimia bagi gas Z.
................
[1 mark]
(iii) Write the chemical formula of solid X.

Tuliskan formula kimia bagi pepejal X.
................
[1 mark]

SULIT 7 4541/2
(c) In Reaction II, solid X is added into a test tube containing hydrochloric acid to
form solution R.
Dalam Tindak balas II, pepejal X ditambah ke dalam sebuah tabung uji yang
mengandungi asid hidroklorik untuk membentuk larutan R.
The equation represents the reaction.

Persamaan mewakili tindak balas itu.
X + 2HCl R + H2O
(i) Name the cation in solution R.
Namakan kation dalam larutan R.

[1 mark]
(ii) State another substance that can be used to replace solid X to produce
solution R.
Nyatakan bahan lain yang boleh digunakan untk menggantikan pepejal X untuk
menghasilkan larutan R.

[1 mark]
(iii) 20 cm3 of 0.5 mol dm-3 hydrochloric acid reacts with excess solid X.
Calculate the number of molecules of water produced.
[ Avogadro constant = 6.02 x 1023 mol-1]
20 cm3 asid hidroklorik 0.5 mol dm-3 bertindak balas dengan pepejal X berlebihan.
Hitung bilangan molekul air yang terbentuk.
[Pemalar Avogadro = 6.02 x 1023 mol-1]
[3 marks]

SULIT 8 4541/2
4 Diagram 4 shows the apparatus set-up for an experiment to determine the heat of
displacement.
Rajah 4 menunjukkan susunan radas bagi satu eksperimen untuk menentukan haba
penyesaran.
Excess zinc powder

Serbuk zink berlebihan
Polystyrene cup
Cawan polistirena
50 cm3 of 0.2 mol dm-3copper (II) sulphate

50 cm3kuprum(II) sulfat 0.2 mol dm-3
Diagram 4
Rajah 4
Based on the experiment,
(a) State the meaning of heat of displacement.

Nyatakan maksud haba penyesaran.
..
..
[1 mark]
(b) Give one reason why polystyrene cup is used in the experiment.
Berikan satu sebab mengapa cawan polistirena digunakan dalam eksperimen ini.

[1 mark]

SULIT 9 4541/2
(c) The thermochemical equation below represents the displacement reaction.

Persamaan termokimia di bawah mewakili tindak balas penyesaran itu.
Zn + CuSO4 ZnSO4 + Cu H = 210 kJ mol-1
Calculate:
Hitung:
(i) the number of moles of copper(II) ion.

bilangan mol ion kuprum.
[1 mark]
(ii) the heat released during the reaction.

haba yang dibebaskan semasa tindak balas.
[2 marks]
(iii) the change of temperature in the experiment.

[Specific heat capacity of solution = 4.2 J g-1 oC-1;
Density of solution = 1 g cm-3]
perubahan suhu dalam eksperimen ini.
[Muatan haba tentu larutan = 4.2 J g-1 oC-1;
Ketumpatan larutan =1 g cm-3]
[1 mark]

SULIT 10 4541/2
(d) The experiment is repeated using magnesium powder to replace zinc powder.
The volume and concentration of copper (II) sulphate used is remained the
same.
Eksperimen diulang dengan menggunakan serbuk magnesium menggantikan serbuk
zink. Isi padu dan larutan kuprum(II) sulfat yang digunakan adalah sama.
(i) Predict the heat of displacement for the reaction.

Ramalkan haba penyesaran bagi tindak balas itu.
..
[1 mark]
(ii) Give a reason for your answer in 4(d)(i).

Beri sebab bagi jawapan di 4(d(i).
.
[1 mark]
(e) Draw the energy level diagram for the reaction.

Lukis gambar rajah aras tenaga bagi tindak balas ini.
[2 marks]

SULIT 11 4541/2
5 Diagram 5.1 and Diagram 5.2 shows the apparatus set-up to investigate the factor that
affects the rate of reaction.
Rajah 5.1 dan 5.2 menunjukkan susunan radas bagi mengkaji faktor yang mempengaruhi
kadar tindak balas.
Experiment I
Eksperimen I
Gas Y
Dilute hydrochloric acid

Asid hidroklorik cair
Zinc granules
Water
Ketulan zink
Air
z Diagram 5.1
Rajah 5.1
Table 5.1 shows the result obtained for Experiment I.

Jadual 5.1 menunjukkan keputusan yang diperolehi bagi Eksperimen I.
Time (s) 0 20 40 60 80 100 120 140 160 180

Masa (s)
Volume of gas 0.00 6.50 12.50 17.80 23.50 27.20 31.80 35.00 35.00 35.00
released (cm3)
Isi padu gas
terbebas (cm3)
Table 5.1
Jadual 5.1
Experiment II
Eksperimen II
Gas Y
Dilute hydrochloric acid

Asid hidroklorik cair
Zinc powder
Serbuk zink Water
Air
z Diagram 5.2
Rajah 5.2

SULIT 12 4541/2
Table 5.2 shows the result obtained for Experiment II.

Jadual 5.2 menunjukkan keputusan yang diperolehi bagi Eksperimen II.
Time (s) 0 20 40 60 80 100 120 140 160 180

Masa (s)
Volume of gas 0.00 8.50 15.50 21.00 26.80 31.50 35.00 35.00 35.00 35.00
released (cm3)
Isi padu gas
terbebas (cm3)
Table 5.2
Jadual 5.2
(a) (i) Name gas Y.

Namakan gas Y.

[1 mark]
(ii) Describe a chemical test to verify gas Y.

Jelaskan satu ujian kimia untuk mengesahkan gas Y.
..
[2 marks]
(b) (i) Calculate the average rate of reactions for Experiment I and Experiment II.
Hitung kadar tindak balas purata untuk tindak balas bagi Eksperimen I dan
Eksperimen II.
Experiment 1:
Eskperimen I:
Experiment II:
Eksperimen I1:
[2 marks]

SULIT 13 4541/2
(ii) Compare the rate of reaction of Experiment I and Experiment II.

Bandingkan kadar tindak balas bagi Eksperimen I dan Ekesperimen II.
...
..
[1 mark]
(iii) Explain the answer in 5(b)(ii) with reference to the collision theory.
Terangkan jawapan di 5(b)(ii) dengan merujuk kepada teori perlanggaran.
..

[3marks]
(c) Sketch the graph of volume of gas Y produced against time for both experiments
on the same axes.
Lakar graf isipadu gas Y yang dihasilkan melawan masa bagi kedua-dua eksperimen.
Volume of gas Y (cm3)

Isi padu gas Y (cm 3)
Time ( s)
Masa (s)
[2marks]

SULIT 14 4541/2
6 (a) Diagram 6 shows the apparatus set-up to study the displacement of halogen between
bromine water and potassium iodide solution.
Rajah 6 menunjukkan susunan radas untuk mengkaji tindak balas penyesaran halogen di
antara air bromin dan larutan kalium iodida.
Bromine water
Air bromin
Potassium iodide solution

Larutan kalium iodida
Diagram 6
Rajah 6
1,1,1-trichloroethane is added into the mixture and shaken thoroughly.

1,1,1-trikloroetana ditambah ke dalam campuran itu dan digoncang lagi dengan sempurna.
(i) State the function of bromine water.

Nyatakan fungsi air bromin.
..
[1 mark]
(ii) State one observation after 1,1,1-trichloroethane is added to the mixture.

Nyatakan satu pemerhatian setelah 1,1,1-trichloroetana ditambah kepada campuran.
..
[1 mark]
(iii) Write the ionic equation for the reaction.

Tuliskan persamaan ion bagi tindak balas ini.
..
[2 marks]
(iv) State the change in the oxidation number of iodine.

Nyatakan perubahan nombor pengoksidaan bagi iodin.
..
[1 mark]

SULIT 15 4541/2
(v) Name another reagent that can replace bromine water.

Namakan reagen lain yang boleh menggantikan air bromin.
..
[1 mark]
(b) An experiment is carried out to study the reactivity of metals with oxygen.
Satu eksperimen telah dijalankan untuk mengkaji kereaktifan logam terhadap oksigen.
Table 6 shows the observations and the colour of the residue for each metal.
Jadual 6 menunjukkan pemerhatian dan warna baki pemanasan bagi setiap logam itu.
Metal Observation Colour of Residue

Logam Pemerhatian Warna Baki
Yellow when hot

Glow brightly white when cold
W Membara terang Kuning semasa panas
putih semasa sejuk
Glow faintly Black

X Membara malap Hitam
Burn brightly White

Y Menyala terang Putih
Table 6
Jadual 6
(i) Draw the diagram of the apparatus set-up for the experiment.
Lukiskan diagram bagi susunan radas bagi eksperimen ini.
[2 marks]

SULIT 16 4541/2
(ii) Suggest metal W.

Cadangkan logam W.
..
[1 mark]
(iii) Based on your answer in 6(b)(ii),

Write the chemical equation for the reaction between metal W and oxygen.
Berdasarkan jawapan anda dalam 6(b)(ii),
Tuliskan persamaan kimia bagi tindak balas antara metal W dan oksigen.
..
[1 mark]
(iv) Based on the observations, arrange metals W, X and Y in descending order of

the reactivity towards oxygen.
Berdasarkan kepada pemerhatian, susunkan logam-logam W, X and Y mengikut
tertib menurun dalam kereaktifan terhadap oksigen.
..
[1 mark]

SULIT 17 4541/2
Section B
Bahagian B
[20 marks]
[20 markah]
Answer any one questions from this section.

Jawab mana-mana satu soalan daripada bahagian ini
7. (a) Diagram 7.1 shows a frying pan and a water pipe.

Rajah 7.1 menunjukkan sebuah kuali dan sebatang paip air.
Glass lid Water pipe

Penutup kaca Paip air
Diagram 7.1
Rajah 7.1
State the type of glass and polymer to make the glass lid and the water pipe.
Give a reason to each of your answer based on the property of each material.
Nyatakan jenis kaca dan polimer untuk membuat penutup kaca dan paip air itu.
Berikan satu sebab bagi setiap jawapan anda berdasarkan sifat setiap bahan itu.
[4 marks]

SULIT 18 4541/2
(b) Sulphuric acid is manufactured in industry through Contact Process. The process
consists of three stages.
Asid sulfurik dihasilkan dalam industri melalui Proses Sentuh. Proses itu terdiri daripada
tiga peringkat.
Stage 1 Molten sulphur is burnt in dry air to produce sulphur dioxide.

Peringkat 1 Leburan sulfur dibakar dalam udara untuk menghasilkan sulfur dioksida.
S + O2 SO2
Stage 2 Sulphur dioxide and excess oxygen gas are reacted to produce sulphur
Peringkat 2 trioxide.
Sulfur dioksida dan gas oksigen berlebihan bertindak balas untuk
menghasilkan sulfur trioksida.
2SO2 + O2 2SO3
Stage 3 Sulphur trioxide is first reacted with concentrated sulphurid acid to

Peringkat 3 form oleum. The oleum is then diluted with water to produce sulphuric
acid.
Sulfur trioksida pada mulanya bertindak balas dengan asid sulfurik pekat
untuk membentuk oleum. Kemudian oleum itu dicairkan dengan air untuk
menghasilkan asid sulfurik.
Table 7.1
Jadual 7.1
(i) 8 g of sulphur is burnt completely in Stage 1. Calculate the volume of sulphur

dioxide produced.
[Relative atomic mass: S = 32 ; Molar volume = 24 dm3 mol-1 at room condition]
8 g sulfur dibakar dengan lengkap dalam Peringkat 1. Hitungkan isi padu sulfur dioksida
yang dihasilkan.
[Jisim atom relatif: S = 32 ; Isi padu molar = 24 dm3 mol-1 pada keadaan bilik]
[2 marks]
(ii) Describe how sulphur dioxide gas can cause environmental pollution and state
two effects of pollution cause by sulphur dioxide gas.
Huraikan bagaimana gas sulfur dioksida boleh menyebabkan pencemaran alam sekitar
dan nyatakan dua kesan pencemaran yang disebabkan oleh gas sulfur dioksida.
[3 marks]
(iii)Write the chemical equation for the formation of oleum in Stage 3.

Tuliskan persamaan kimia bagi pembentukan oleum dalam Peringkat 3.
[1 mark ]

SULIT 19 4541/2
(c) Diagram 7.2 shows two experiments to investigate the effectiveness of the cleansing
action between cleaning agents X and Y.
Rajah 7.2 menunjukkan dua eksperimen untuk mengkaji keberkesanan tindakan pencucian
antara agen pencuci X dan agen pencuci Y.
Experiment I II
Eksperimen
Cleaning agent
X Y
Agen pencuci
Chemical formula
CH3(CH2)14COO-K+ CH3(CH2)11OSO3-K+
Formula kimia
Hard water + cleaning agent X Hard water + cleaning agent Y

Air liat + agen pencuci X Air liat + agen pencuci Y
Oil stain on a Oil stain on a

handkerchief handkerchief
Kotoran bergris pada Kotoran bergris pada
Cleaning in hard sehelai sapu tangan sehelai sapu tangan
water
Pencucian dalam air liat
Observation Oil stain remains Oil stain is removed

Pemerhatian Kesan minyak kekal Kesan minyak hilang
Diagram 7.2
Rajah 7.2
(i) Based on Diagram 7.2, compare and contrast the effectiveness of the cleansing
action between cleaning agent X and cleaning agent Y in hard water. Explain your
answer.
Berdasarkan Rajah 7.2, banding dan bezakan keberkesanan tindakan pencucian antara
agen pencuci X dan agen pencuci Y dalam air liat. Terangkan jawapan anda.
[5 marks]

SULIT 20 4541/2
(ii) Diagram 7.3 shows the structure of a particle of agent Y.

Rajah 7.3 menunjukkan struktur bagi suatu zarah agen Y.
Part P Part Q
Bahagian P Bahagian Q
Diagram 7.3
Rajah 7.3
State the name of part P and part Q. Explain the role of part P and part Q in the
cleansing action.
Nyatakan nama bahagian P dan bahagian Q. Terangkan peranan bahagian P
dan bahagian Q dalam tindakan pencucian.
[5 marks]

SULIT 21 4541/2
8 (a) Diagram 8.1 shows a chemical cell and an electrolytic cell. Metal P is situated below
zinc in the electrochemical series.
Rajah 8.1 menunjukkan satu sel kimia dan satu sel elektrolisis. Logam P terletak di bawah
zink dalam siri elektrokimia.
Zinc electrode P electrode

Elektrod zink Elektrod P Magnesium
P nitrate solution electrode
Larutan P nitrat Elektrod
magnesium
Chemical cell
Electrolytic cell
Sel kimia
Sel elektrolisis
Diagram 8.1
Rajah 8.1
Based on Diagram 8.1, state:

Berdasarkan Rajah 8.1, nyatakan:
the negative terminal for chemical cell and electrolytic cell.

terminal negatif untuk sel kimia dan sel elektrolisis tersebut.
the flow of direction of electron for the chemical cell and electrolytic cell.
arah pengaliran elektron bagi sel kimia dan sel elektrolisis tersebut.
[ 4 marks]

SULIT 22 4541/2
(b) A student wants to electroplate iron spoon with silver metal to make it more shining
and attractive. The following are materials that used in the electroplating process.
Seorang pelajar ingin menyadur sudu besi dengan logam argentum agar kelihatan berkilat
dan menarik. Berikut adalah bahan-bahan yang digunakan dalam proses penyaduran
tersebut.
Silver plate
Kepingan argentum
Iron spoon
Sudu besi
Silver sulphate solution
Larutan argentum sulfat
Referring to the above materials, plan one laboratory experiment to electroplate the
iron spoon. Your answer should include the following :
Merujuk pada bahan-bahan di atas, rancangkan satu eksperimen makmal bagi proses
penyaduran sudu besi tersebut. Jawapan anda perlu mengandungi perkara berikut:
A labelled diagram showing the apparatus set-up.

Gambar rajah berlabel menunjukkan susunan radas.
Procedure of experiment
Prosedur eksperimen
The half-equations for the reaction at cathode or anode.

Setengah persamaan bagi tindak balas yang berlaku di katod atau di anod.
[6 marks]

SULIT 23 4541/2
(c) Diagram 8.2 shows the set-up of apparatus for a chemical cell. Metal Q is placed
above copper in the electrochemical series and act as a positive terminal in the
chemical cell.
Rajah 8.2 menunjukkan susunan radas bagi satu sel kimia. Logam Q terletak di atas
kuprum dalam siri elektrokimia dan berfungsi sebagai terminal positif dalam sel kimia itu.
Aluminium plate Metal Q

Kepingan aluminium Logam Q
Porous Pot
Aluminium nitrate solution Pasu berliang
Larutan aluminium nitrat
Q solution
Larutan Q
Diagram 8.2
Rajah 8.2
Describe how the set-up of apparatus can be function as a chemical cell. Your
answer should include :
Terangkan bagaimana susunan radas itu boleh berfungsi sebagai sel kimia. Jawapan anda
haruslah mengandungi:
the suitable name of metal Q and Q solution

nama logam Q dan larutan Q yang sesuai
the direction of flow of electrons

arah pengaliran elektron
the half equations for the reaction at positive and negative terminals
setengah persamaan tindak balas yang berlaku di terminal positif dan negatif
an ionic equation for the reaction

persamaan ion bagi tindak balas
the function of porous pot

fungsi pasu berliang
the observations after 30 minutes the reaction occur

pemerhatian selepas 30 minit tindak balas berlaku
[10 marks]

SULIT 24 4541/2
9. (a) By using suitable examples, state two applications of neutralisation in daily life .
Dengan menggunakan contoh yang sesuai, nyatakan dua aplikasi peneutralan dalam
kehidupan harian.
[4 marks]
(b) Diagram 9 shows the pH values for solutions of alkali Q and alkali R which have same
concentration.
Rajah 9 menunjukkan nilai pH bagi alkali Q dan alkali R yang mempunyai kepekatan
yang sama.
10 14
Alkali Q Alkali R
Diagram 9
Rajah 9
By using one named example for each alkali, explain why the pH values of the alkalis
are different.
Dengan menamakan satu contoh bagi setiap alkali, terangkan mengapa nilai pH bagi setiap
alkali itu berbeza.
[ 6 marks]
(c) Solution X and solution Y are used to prepare barium carbonate salt.
Describe the preparation of barium carbonate salt in the laboratory.
In your description, include the chemical equation involved.
Larutan X dan larutan Y digunakan untuk menyediakan garam barium karbonat.
Huraikan penyediaan garam barium karbonat dalam makmal.
Dalam huraian anda, sertakan persamaan kimia yang terlibat.
[ 10 marks]

SULIT 25 4541/2
10(a) Diagram 10.1 shows the structural formulae of compound A and compound B.
Rajah 10.1 menunjukkan formula struktur bagi sebatian A dan sebatian B.
Compound A Compound B
Sebatian A Sebatian B
Diagram 10.1
Rajah 10.1
Compound A and compound B are burnt completely in oxygen to produce carbon

dioxide gas and water.
Sebatian A dan sebatian B terbakar lengkap dalam oksigen menghasilkan gas karbon
dioksida dan air.
(i) Name compound B.

Namakan sebatian B.
(ii) Compound B produced more soot than compound A when burnt in oxygen.
Explain why.
Sebatian B menghasilkan lebih jelaga daripada sebatian A apabila terbakar dalam
oksigen. Terangkan mengapa.
[Relative molecular mass of: A = 86, B = 84]
[Jisim molekul relatif: A = 86, B = 84]
[4 marks]

SULIT 26 4541/2
(b) Diagram 10.2 shows the structural formulae of compound J and compound K.
Rajah 10.2 menunjukkan formula struktur bagi sebatian J dan sebatian K.
Compound J Compound K
Sebatian J Sebatian K
Diagram 10.2
Rajah 10.2
State one physical property of compound K . Describe briefly a chemical test to

differentiate between compound J and compound K.
Nyatakan satu sifat fizik Sebatian K. Huraikan secara ringkas satu ujian kimia untuk
membezakan antara sebatian J dan sebatian K.
[6 marks]
(c) Alcohols undergo dehydration reaction to produce alkenes and water.

Describe how to prepare an alkene from a named alcohol through dehydration
process. In your description, include the diagram of the apparatus set-up and
balanced chemical equation for the reaction.
Alkohol mengalami tindak balas pendehidratan untuk menghasilkan alkena dan air.
Huraikan bagaimana satu alkena disediakan daripada alkohol yang dinamakan melalui
proses pendehidratan. Dalam huraian anda, sertakan gambar rajah bagi susunan radas dan
persamaan kimia seimbang bagi tindak balas itu.
[10 marks]

KERTAS SOALAN TAMAT

Nama: . Tingkatan:
SULIT
4541/3
Chemistry
Kertas 3
Ogos
2013
1 jam
BAHAGIAN PENGURUSANSEKOLAH BERASRAMA PENUH

KEMENTERIAN
KEMENTERIANPENDIDIKAN
PELAJARAN MALAYSIA

CHEMISTRY
Kertas 3
Satu jam tiga puluh minit
1. Tuliskan nama dan tingkatan pada ruang yang

Untuk Kegunaan Pemeriksa
disediakan di atas.
Soalan Markah Markah
2. Kertas soalan ini adalah dalam dwibahasa. Penuh Diperoleh
3. Soalan dalam bahasa Inggeris mendahului

1 15
soalan yang sepadan dalam Bahasa Melayu.
4. Calon dibenarkan menjawab keseluruhan atau 2 18

sebahagian soalan sama ada dalam Bahasa
3 17
Inggeris atau Bahasa Melayu.
5. Calon dikehendaki membaca maklumat di Jumlah 50

halaman belakang kertas soalan ini.
4541/3 2013 Hak Cipta BPSBPSK [Lihat sebelah

SULIT
2
Answer all questions

Jawab semua soalan
1. Diagram 1.1 shows the apparatus set-up for an experiment to determine the For examiners
melting point of naphthalene. The temperature reading of naphthalene is recorded use
at one minute intervals until the temperature is above its melting point.
Rajah 1.1 menunjukkan susunan radas bagi satu eksperimen untuk menentukan
takat lebur naftalena. Bacaan suhu direkodkan pada sela masa satu minit
sehingga melebihi takat lebur naftalena.
Thermometer
Termometer
Boiling tube
Tabung didih
Water
Air
Naphthalene
Naftalena
Diagram 1.1
Rajah 1.1
3
Diagram 1.2 shows the recorded thermometer readings at one minute intervals. For
Rajah 1.2 menunjukkan bacaan termometer yang direkodkan pada sela masa examiners
satu minit. use
Temperature at Temperature at Temperature at

Suhu pada Suhu pada Suhu pada
0 min: .. 1 min: .. 2 min:
Temperature at Temperature at Temperature at

Suhu pada Suhu pada Suhu pada
3 min: 4 min: . 5 min:
Temperature at Temperature at
Suhu pada Suhu pada
6 min: .. 7 min: .
Diagram 1.2
Rajah 1.2
4
(a) Record all the temperatures in the spaces provided in Diagram 1.2 For examiners
Rekodkan suhu pada ruang yang disediakan dalam Rajah 1.2. use
[3 marks] 1(a)
[3 markah]
(b) On the graph paper provided, plot a graph of temperature against time for the
heating of naphthalene. 1(b)
Pada kertas graf yang disediakan, plot satu graf suhu melawan masa bagi
pemanasan naftalena.
[3 marks]
[3 markah]
(c) Based on the graph in (b);

Berdasarkan graf di (b);
(i) Determine the melting point of naphthalene.

Show on the graph how you determine this melting point.
Berdasarkan graf di (b), tentukan takat lebur naftalena.
Tunjukkan pada graf bagaimana anda menentukan takat lebur tersebut. 1(c)(i)
..
[3 marks]
[3 markah]
(ii) How does graph in 1(b) shows the melting point of naphthalene?
Bagaimanakah graf di 1(b) dapat menunjukkan takat lebur naftalena?
.. 1(c)(ii)
..
[3 marks]
[3 markah]
5
Graph of temperature against time.

Graf suhu melawan masa
6
(d) The temperature of naphthalene did not change from the 2nd minute until 4th For examiners
minute during the heating process. use
Explain why?
Suhu naftalena tidak berubah dari minit ke-2 sehingga minit ke-4 semasa
proses pemanasan naftalena.
Terangkan mengapa?
...
.. 1(d)
..
[3 marks]
[3 markah]
TOTAL
7
2. Diagram 2.1 shows the apparatus set-up of the experiment to investigate the For examiners
effect of other metal on rusting of iron. A mixture of jelly solution, potassium use
hexacyanoferrate (III), K3Fe(CN)6 solution and phenolphthalein were used as
medium in each test tube. The observation was recorded after one day.
Rajah 2.1 menunjukkan susunan radas bagi eksperimen untuk mengkaji kesan
logam lain terhadap pengaratan besi. Medium yang digunakan di dalam
setiap tabung uji adalah campuran larutan agar-agar, larutan kalium
heksasianoferat (III), K3Fe(CN)6 dan fenolftalein. Pemerhatian direkodkan
selepas satu hari.
Test tube Set-up of apparatus

hexacyanoferrate(III) +
phenolphthalein
larutan agar-agar, larutan Iron nail coiled with
A kalium heksasianoferat magnesium ribbon
(III) + fenolftalein Paku besi dililit dengan
pita magnesium

B phenolphthalein Iron nail coiled with
larutan agar-agar, larutan copper strip
kalium heksasianoferat(III) Paku besi dililit dengan
+ fenolftalein kepingan kuprum

phenolphthalein Iron nail coiled with
larutan agar-agar, larutan zinc strip
C kalium heksasianoferat(III) Paku besi dililit dengan
+ fenolftalein kepingan zink

D phenolphthalein
larutan agar-agar, larutan Iron nail
kalium heksasianoferat(III) Paku besi
+ fenolftalein
Diagram 2.1
Rajah 2.1
8
For examiners
(a) Table 2.1 shows the result of the experiment. use
State the inference for each test tube.
Jadual 2.1 menunjukkan keputusan eksperimen tersebut.
Nyatakan inferens untuk setiap tabung uji.
Test tube A B C D
Intensity of
blue colour None High None Low
Keamatan Tiada Sangat tinggi Tiada Rendah
warna biru
Pink
colouration
Warna Present Present Present Present
merah Ada Ada Ada Ada
jambu
Inference
Inferens
Table 2.1 2(a)

Jadual 2.1
[3 marks]
[3 markah]
(b) State the hypothesis for the experiment.

Nyatakan hipotesis bagi eksperimen tersebut.
...
...
.. 2(b)
..
[3 marks]
[3 markah]
9
(c) State the variables for this experiment. For

Nyatakan pembolehubah bagi eksperimen ini. examiners use
(i) The manipulated variable:

Pembolehubah dimanipulasikan:
.....
(ii) The responding variable:

Pembolehubah bergerak balas:
(iii) The constant variable:

Pembolehubah dimalarkan: 2(c)

[3 marks]
[3 markah]
(d) State the operational definition for the rusting of iron.

Nyatakan definisi secara operasi bagi pengaratan besi.
2(d)

[3 marks]
[3 markah]
10
(e) Based on the experiment, classify the metals that can provide sacrificial
protection and metals that cannot provide sacrificial protection to iron.
Berdasarkan eksperimen ini, kelaskan logam-logam tersebut kepada logam
yang boleh menyediakan perlindungan korban dan logam yang tidak boleh
menyediakan perlindungan korban.
2(e)
[3 marks]
[3 markah]
(f) Metal Y is placed below copper in Electrochemical Series. For
Predict one observation when metal Y is coiled with iron nail and dipped into examiners use
the mixture of jelly solution, potassium hexacyanoferrate(III), K3Fe(CN)6
solution and phenolphthalein.
Logam Y terletak di bawah kuprum dalam Siri Elektrokimia.
Ramalkan satu pemerhatian apabila logam Y dililitkan pada paku besi dan
dicelupkan ke dalam campuran larutan agar-agar, larutan kalium
heksasianoferat(III) K3Fe(CN)6 dan fenolftalein. 2(f)

[3 marks]
[3 markah]
TOTAL
11
3 Diagram 3.1 shows the production of ammonia, NH3 through Haber process. The mixture
of nitrogen and hydrogen gases is passed over iron, Fe. Iron acts as the catalyst to increase
the rate of the production of ammonia gas.
Rajah 3.1 menunjukkan penghasilan ammonia, NH3 melalui proses Haber. Campuran gas
nitrogen dan gas hidrogen dialirkan melalui serbuk besi. Besi bertindak sebagai mangkin
yang meningkatkan kadar penghasilan gas ammonia.
Iron, Fe
450oC
Diagram 3.1
Rajah 3.1
Based on this idea, plan one laboratory experiment to investigate the effect of the
presence of catalyst on the rate of decomposition of hydrogen peroxide, H2O2.
Berdasarkan idea ini, rancangkan satu eksperimen makmal untuk mengkaji kesan
kehadiran mangkin ke atas kadar penguraian hidrogen peroksida, H2O2.
Your planning should include the following aspects:

Perancangan anda hendaklah mengandungi aspek-aspek berikut:
(a) Problem statement

Penyataan masalah
(b) All the variables

Semua pemboleh ubah
(c) Statement of the hypothesis

Pernyataan hipotesis
(d) List of substances and apparatus

Senarai bahan dan radas
(e) Procedure for the experiment

Prosedur eksperimen
(f) Tabulation of data

Penjadualan data
[17 marks]
[17 markah]
KERTAS SOALAN TAMAT
INFORMATION FOR CANDIDATES
MAKLUMAT KEPADA CALON
1. This question paper consists of three questions. Question 1, Question 2 and Question 3.
Kertas soalan ini mengandungi tiga soalan: Soalan 1, Soalan 2 dan Soalan 3.
2. Answer all questions. Write your s answer for Question 1 and Question 2 in the spaces
provided in this question paper.
Jawab semua soalan. Tuliskan jawapan bagi Soalan 1 dan Soalan 2 pada ruang yang
disediakan dalam kertas soalan.
3. Write your answers for question 3 on the addition answer sheets provided by invigilators. You
may use equations, diagrams, tables, graph and other methods to explain your answer.
Tulis jawapan anda bagi Soalan 3 di dalam helaian tambahan yang dibekalkan oleh
pengawas peperiksaan.Anda boleh menggunakan persamaan, gambar rajah, jadual, graf dan
cara lain yang sesuai untuk menjelaskan jawapan anda.
4. The diagram in the questions is not drawn to scale unless stated.

Rajah yang mengiringi soalan tidak dilukiskan mengikut skala kecuali dinyatakan.
5. The marks allocated for each question or sub-part of a question is shown in brackets.
Markah yang diperuntukkan bagi setiap jawapan atau ceraian soalan ditunjukkan
dalam kurungan.
6. Show your working, it may help you to get marks.

Tunjukkan kerja mengira. Ini membantu anda mendapatkan markah,
7. If you wish to change your answer, cross out the answer that you have done. Then
write down the new answer.
Sekiranya anda hendak menukar jawapan, batalkan jawapan yang telah dibuat,kemudian
tulis jawapan yang baru.
8. You may use a non-programmable scientific calculator.

Anda dibenarkan menggunakan kalkulator saintifik yang tidak diprogramkan.
9. Tie the addition answer sheets together with this question paper and hand in at the end of the
examination.
Ikat semua kertas jawapan anda bersama-sama soalan ini di akhir peperiksaan.
Marks awarded:
Mark Description
3 Excellent : The best response
2 Satisfactory : An average response
1 Weak : An inaccurate response
0 No response or wrong response
4541/3 2013 Hak Cipta BPSBPSK [Lihat sebelah

SULIT
1

CHEMISTRY
SKEMA JAWAPAN KERTAS 1
1 A 11 A 21 D 31 B 41 D
2 D 12 A 22 B 32 D 42 B
3 A 13 C 23 A 33 B 43 D
4 C 14 D 24 C 34 D 44 A
5 D 15 B 25 C 35 D 45 B
6 C 16 B 26 C 36 C 46 C
7 C 17 A 27 A 37 D 47 D
8 A 18 A 28 B 38 B 48 B
9 C 19 C 29 A 39 D 49 B
10 D 20 C 30 B 40 A 50 C
2
KERTAS 2
SECTION A
No Rubric Mark
1(a) (i) Diffusion r. diffuse 1
(ii) Ion 1
(iii) 1. Potassium manganate(VII) is made of tiny and discrete 1

particles/ions
2. The particles are constantly moving/vibrate and rotate 1
3. The particles move into spaces between agar particles//
there are spaces between agar particles// the particles
move from high concentration area to low 1
concentration region
(b) (i) Proton // neutron r. p/n 1
(ii) Atoms that have the same proton number but difference
nucleon number. 1
(iii) 8 1
(v) To estimate the age of fossil 1
TOTAL 9
3
No Rubric Mark
2 (a)(i) 2.8.2 1
(ii) Group 2, Period 3 1
(b) Gas 1
(c ) Chlorine/ Cl 1
(d) (i) Al2O3 1

(ii) Ionic r: ionic compound 1
(e) Mass Mg Cl
2.4 g 7.1 g 1
Mol 0.1 0.2 1
Ratio 1 2
Formula : MgCl2 1
TOTAL 9
4
No Rubric Mark
3 (a) (i) ionic compound formed when the hydrogen ion from an acid is 1
replaced by a metal ion or ammonium ion
(ii) Blue 1
(b) (i) Oxygen 1
(ii) NO2 1
(iii) CuO 1
(c) (i) Copper(II) ion 1
(ii) Copper(II) carbonate / CuCO3 1
(d) 1. Mol of HCl = 0.5 x 20 /1000// 0.01 mol 1
2. Mol of H2O= 0.005 1
3. No. of H2O molecules = 0.005 x 6.02 x 10 23 // 3.01 x 10 21 1
TOTAL 10
5
No Rubric Mark
4 (a) Heat change / released when one mole of copper is displaced from/ 1
copper(II) sulphate solution by zinc
(b) Polystyrene is a heat insulator / / to reduce heat loss to surroundings 1

r: to prevent
(c) (i) No of moles of Copper(II) ion = 0.2 x 50 // 0.01 mol 1

1000
(ii) 1. 1 mol of Cu is displaced produce 210 kJ heat 1
2. 0.01 mol of Cu = 0.01 x 210 kJ
// 2.1 kJ / 2100 J 1
(iii) 2100 J = 50 x 4.2 x // = 10oC 1
(d) (i) More than -210 kJ mol-1 / Higher / Increases 1
(ii) Magnesium is more electropositive than zinc // magnesium is higher 1

than zinc in electrochemical series // distance between Mg Cu is
further than Zn-Cu in electrochemical series
(e) 1. Label energy and diagram has 2 different energy levels 1

for exothermic reaction
1
2. Balanced chemical / ionic equation, H is written
Energy
Zn + CuSO4 /
Zn + Cu2+
H = -210 kJ mol-1
ZnSO4 + Cu /
Zn2+ + Cu
TOTAL 10
6
No Rubric Mark
5(a) (i) Hydrogen 1
(ii) Place/ insert a lighted splinter into a test tube 1

Produce pop sound 1
(b)(i) Experiment 1:
Average rate of reaction:
= 35/ 140 cm3s-1 or 0.25 cm3s-1 1
Experiment II:
Average rate of reaction: 1
= 35/120 cm3s-1 or 0.29 cm3s-1
(ii) Rate of reaction in Experiment II is higher 1
b(iii) In Experiment II , 1
1. Size of zinc in is smaller// Total surface area of zinc in
Experiment II is bigger
2. Frequency of collision between zinc atom and hydrogen ion is
higher 1
3. Frequency of effective collisions between zinc atom and
hydrogen ion is higher 1
(c ) Volume of gas Y (cm3)
Experiment II
Experiment I
Time ( s)
1. Correct shape of graf and smooth 1
2. Label the curve correctly 1
Total 11
7
No. Rubric Marks
6(a)(i) oxidizing agent / to oxidize iodide ion 1
(ii) Purple layer formed 1

(iii) Br2 + 2I- 2Br + I2
1. First mark for correct formulae of reactants and products 1

2. Balanced the equation 1
(iii) 1 0 1
(iv) Chlorine r: Fluorine 1
(b)(i)
Glass wool Metal powder
Wul kaca Serbuk logam
Potassium
manganate(VII)
Kalium
manganat(VII) Heat Heat
Panaskan Panaskan
1. Functional diagram 1
2. Label; Potassium manganate(VII), glass wool, metal 1
(ii) Zinc / Zn 1
(iii) 2Zn + O2 2ZnO 1
(iv) Y, W , X 1
Total 11
8
SECTION B
No Mark scheme Mark Mark

P1: Borosilicate glass 1
P2: It has a lower thermal expansion coefficient
7(a) // high resistant to heat// more resistant to chemical attack. 1 4
P3: Polyvinyl chloride 1
P4: It does not rust a: Light 1
Number of moles of sulphur = 832 // 0.25 mol

Volume of sulphur dioxide = 0.25 24 = 6 dm3 // 6000 cm3
1
7(b)(i) 2
3 3
1
[unit mol and dm / cm must be stated]
P1: Sulphur dioxide dissolves in water/ rain water to produce 1

acid solution/acid rain.
Any two correct answers: 1

7(b)(ii) P2: Acid rain can corrode buildings /metal structures 1 3
P3: Lake and river become acidic
P4: pH of soil decreases
P5: Destroys trees/forest
7(b)(iii SO3 + H2SO4 H2S2O7 1 1

)
P1: Y is more effective than X in hard water. 1
P2: Hard water contains magnesium or calcium ions. 1
P3: X form scum/insoluble salt with magnesium /calcium ion 1
7(c)(i)
P4: Y does not form scum/insoluble salt. 1
P5: Amount of agent X is reduced// amount of agent Y is 1 5
remains
P1: Part P = Hydrophobic 1
P2: Part Q = Hydrophilic 1
P3: Hydrophobic part dissolves in the grease/ oil 1
7(c)(ii) P4: Hydrophilic part dissolves in the water 1
P5: This reduces the surface tension// Increase the wetting ability 1 5
of water
r: Like / dislike
Total 20
9
Total
No Answer Mark
Mark
8 (a)
Voltaic cell Electrolytic cell
Negative terminal Zinc P 1+1
The flow of electron Zinc to P through Magnesium to P 4
external circuit through external 1+1
circuit
r: showing the answer in the diagram
(b)
Iron spoon Silver plate

Silver sulphate solution
Functional diagram (not include rheostat)

1
Silver plate is connect to positive terminal and iron spoon
1
connect to negative terminal.
Procedure:
1. Iron spoon is cleaned with sand paper
1
2. a beaker is half fulled with silver sulphate solution
1
3. iron spoon and silver plate are dipped into the silver
1
sulphate solution
4. iron spoon is connected to the negative terminal and silver
1
plate is connected to the positive terminal.
5. half equation:
Anode/ Silver plate : Ag Ag+ + e //
1
Cathode/ Iron spoon : Ag+ + e Ag
Max 6
[Anode/silver plate or cathode/Iron spoon must be stated]
10
(c) 1. metal Q : eg: Zinc [Zn/Fe/Sn/Pb] 1

2. Q solution: eg: zinc nitrate 1
3. Flow of electron : Aluminium plate to zinc plate through 1
connecting wire/ external circuit
4. Negative terminal : Al Al3+ + 3e 1
5. Positive terminal : 2H+ + 2e H2 1
6. Ionic equation: 2Al + 6H+ 2Al3+ 3H2 1+1
7. Function of porous pot : to allow the movement of ions // to
balance the total charges between solution 1 10
8. Observations:
Aluminium plate become thinner// Mass decreases// 1
size become smaller
Colourless bubble gas produce 1
TOTAL 20
SECTION C
NO RUBRIC MARK MARK
9 (a) Daily application of neutralisation

1. Ammonia : neutralize organic acid produced by
bacteria// to prevent latex from coagulate/remain as 1+1
liquid
2. Antacid/ health salt/ sodium hydrogen carbonate : 1+1
neutralised acid in stomach of gastric patients
3. Lime /quick lime (calcium oxide)/ slaked lime
(calcium hydroxide), chalk (calcium carbonate) :
neutralised acidic soil
4. Magnesium hydroxide / toothpaste: neutralised acid
produced by bacteria in our mouth
[Accept other suitable examples and usage]
Any 2 4
(b) 1. Example of R ; sodium hydroxide solution/ litium hydroxide 1
solution/ potassium hydroxide solution
2. R ionised completely in water and produced high 1+1
concentration of OH- ions
3. Exampleof Q : ammonia aqueous / solution 1
4. Q ionised partially in water and produce low concentration
of OH- ions 1+1
5. the concentartion of OH ions in R is higher than Q 1 Max 6
11
(c) 1. Solution 1 : barium nitrate /barium chloride solution 1

2. Solution 2 : sodium carbonate/ potassium
carbonate/lithium carbonate solution/ H2CO3 1
[Any pair of solution above]
3. Procedure :
1. Pour solution 1 into a beaker 1
2. Add solution 2 into the beaker/solution 1 1
3. Stir the mixture using glass rod 1
4. Filter the mixture 1
5. Rinse the residue with distilled water 1
6. Dry the precipitate/solid/salt/residue in between 1
sheet of filter papers to dry
4. Equation
Sample answer:
Ba(NO3) 2 + Na2CO3 BaCO3 + 2NaNO3
// BaCl2 + Na2CO3 BaCO3 + 2NaCl
Correct reactant & product

Balanced 1
1
10
Total 20
No Explanation Mark mark

10
(a)(i) Hex-1-ene 1
r: hexene
1
(ii) 1. Percentage of carbon in compound B is higher 1
2. Percentage carbon in compound A = 72/86 x 100 % / 83.72% 1

Percentage carbon in compound B = 72/84 x 100 % /85.71% 1
12
(b) Soluble in water/ miscible in water

Low melting point/ volatile
Colourless liquid
Cannot conduct electricity 1
Any 1
1. Pour compound J and K into two different test tubes 1

2.Put magnesium ribbon / calcium carbonate / any suitable 1
metal/carbonate metal into both test tubes
3. Place a lighted wooden splinter into the test tube// gas release 1
is pass through the lime water
4. If pop sound produced// lime water turns cloudy shows the
compound is J 1
5. If no change the compound is K 1
6
(d) Sample answer:
1. Name of alcohol 1
2. Place glass wool in a boiling tube 1
3. Add a few drops of alcohol to the glass wool 1
4. Clamp the boiling tube horizontally 1
5. Place a porcelain chips in the middle of the boiling tube 1
6. Heat the porcelain chips strongly 1
7. Heat the alcohol/glass wool 1
8. Collect the gas produced in a test tube 1
9. Functional diagram 1
10. Label : Glass wool damped with alcohol, porcelain chips, 1
water, heat
11. Equation: C2H5OH C2H4 + H2O 1
10
Total 20
13
KERTAS 3
No. Mark scheme Score

1(a) Able to record all readings accurately to one decimal point with correct unit. 3
Answer :
70.0 oC, 77.0 oC, 83.0 oC, 83.0 oC, 83.0 oC, 84.0 oC, 89.0 oC, 95.0 oC
Able to record all readings without unit and no decimal point 2

Able to record at least 6 readings. 1
No response / wrong response 0
1(b) Able to plot a graph correctly which fulfills the following criteria.
Answer :
Temperature 3
Time, t (s)
1. both axes are labeled and with correct units

Y axis : temperature, (oC)
X axis : time, min
2. uniform scale
3. all points are transferred correctly
4. smooth and correct curve
5. the size of the graph must 50% of the graph paper.
Able to plot a graph at least fulfill three of the criteria. 2
Able to have an idea to plot a graph 1

Example answer:
1. graph axis
2. a curve
14

1(c)(i) Able to state all 3 criteria correctly
1. mark on the graph to show melting point
2. label the melting point on the graph and 3
3. state the melting point, 83.0 o C
Answer:
Temperature
1.
83
Time, t (s)
2. show 83.0 o C / write the melting point on the graph

3. 83.0 o C
Able to state at least two criteria correctly 2
Able to state at least one criteria correctly 1

(c)(ii) Able to state the meaning of melting point based on the heating graph correctly. 3
1. The temperature is constant in 2nd minute to 4th minute

2. at 83.0 o C
3. Where solid becomes liquid.
Sample answer:
1. The temperature which doesnt change / constant within a certain period of
time / 2nd to 4th minute
2. at 83.0 o C
3. Where solid becomes liquid.
Able to state any two criteria correctly. 2
Able to state any one criteria correctly or an idea of melting point. 1
15

(d) Able to explain why the temperature of naphthalene from 2nd minute to 4th minute 3
did not change during the heating process correctly.
Answer :
1.Heat energy absorbed by the particles /molecules, is
2. Used to overcome the forces between particles / molecules.
Able to explain why the temperature of naphthalene did not change from 2nd 2
minute to 4th minute during the heating process.
Sample answer:
1. Heat absorbed.
2. Used to overcome the forces between particles / molecules.
Able to an idea of why the temperature does not change during the heating 1
process.
Example :
Heat is absorbed//
Solid become liquid//
Q Mark scheme Score

2(a) Able to state all inferences correctly
Test tube A B C D
Inference Iron nail does Iron nail rust Iron nail does Iron nail rust
not rust // Fe2+ // Fe2+ present not rust // Fe2+ // Fe2+ present 3
does not / formed does not / formed
present present
Able to state 3 inferences correctly 2

Able to state any one inference correctly 1
16
Q Mark scheme Score

2(b) Able to state the hypothesis correctly
Sample answer:
When a more electropositive metal / higher than iron in Electrochemical series is

in contact with iron, iron (nail) does not rust.
When a less electropositive metal / lower than iron in Electrochemical series is in 3
contact with iron, iron (nail) rust.
Able to state the hypothesis less correctly 2

Sample answer:
When a more electropositive metal / higher than iron in Electrochemical series is
in contact with iron, iron (nail) does not rust. or
When a less electropositive metal / lower than iron in Electrochemical series is in

contact with iron, iron rust. or
The rusting of iron is faster/slower, if a less /more electropositive metal is in

contact with iron/Fe.
Able to give an idea of hypothesis 1

Sample answer:
Iron rust when in contact with other metal // other metal affect the rusting of iron.
Q Answer Score
2(c) Able to state all the variables in this experiment correctly 3
Sample answer:
Manipulated variable: Type / different metal
Responding variable: Rusting // presence of blue spot
Constant variable: Type of nail iron // iron// medium in which the iron are
kept
Able to state any two of the variables in this experiment correctly 2
Able to state any one of the variables in this experiment correctly 1
17
Q Answer Score
2(d) Able to state all 3 criteria correctly 3
Sample answer:
1. Rusting of iron is the formation of blue spot / colouration
2. When iron nail is coiled / in contact with a less electropositive metal (copper) /
metal located below iron in Electrochemical series.
3. Immersed / dipped / placed / put in a mixture of jelly solution, potassium
hexacyanoferrate(III) and phenolphthalein.
Able to state at least two criteria correctly 2
Sample answer:
1. Rusting of iron is the formation of blue spot / colouration
2. When iron nail is coiled / in contact with a less electropositive metal
Able to state any one criteria correctly 1
Sample answer:
1. Rusting of iron is the formation of blue spot / colouration or
2. When iron nail is coiled / in contact with a less electropositive metal
Q Answer Score
2(e) Able to classify the metals into metal that can provide sacrificial protection and 3
metal that cannot provide sacrificial protection correctly.
Answer:
Metal that can provide sacrificial protection: magnesium /Mg and zinc /Zn
Metal that cannot provide sacrificial protection : copper/Cu
Able to classify any two metals correctly 2
Able to classify one metals correctly 1
Q Answer Score
2(f) Able to predict the observation correctly. 3
Answer :
The intensity of blue spot/colouration is very high // higher than test tube B.
Able to predict the observation 2

Answer:
Blue spot/ colouration formed
Able to state idea of observation 1
Answer:
18
Blue
Q Answer Score
3(a) Able to state the problem statement of the experiment correctly.
How does the presence of catalyst / manganese (IV) oxide affect on the rate of
decomposition of hydrogen peroxide? 3
How does the presence of catalyst affect the rate of reaction? 2
To investigate the effect/ presence of catalyst. 1
Students give a wrong response. 0
3(b)
Sample answer:
Manipulated variable: The presence of catalyst/ manganese (IV) oxide

Responding variable: rate of reaction// rate of decomposition of hydrogen
peroxide
Constant variable: Concentration and temperature of hydrogen peroxide.
Students able to write all 3 variables correctly 3
Students able to write 2 variables correctly 2
Students able to write 1 variable correctly 1
3(c) Able to state the relationship between the manipulated variable and the
responding variable and state the direction.
Sample answer:
When catalyst/ manganese (IV) oxide presents, the rate of decomposition of

hydrogen peroxide increases 3
When catalyst presents, the rate of reaction increases. 2
Catalyst affects the rate of reaction. 1
19
Q Answer Score
3(d) Able to give complete list of substances and apparatus
Method 1:
Substances:
Hydrogen peroxide, manganese (IV) oxide powder 3
Apparatus:
Test tube, measuring cylinder, spatula, wooden splinter.
Students able to list down substances and improperly apparatus

Substances:
Hydrogen peroxide, manganese (IV) oxide powder
Apparatus: 2
Test tube, spatula
Students able to list one of the substance and suitable container

Substances:
Hydrogen peroxide and manganese (IV) oxide powder 1
Apparatus:
Beaker
3(d) Method 2:
Able to give complete list of substances and apparatus

Substances:
Hydrogen peroxide, manganese (IV) oxide powder
Apparatus:
Conical flask, delivery tube and stopper, burette, basin/ water trough, retort stand
with clamp, stopwatch, measuring cylinder, spatula. 3
Students able to list down substances and improperly apparatus

Substances:
Hydrogen peroxide, manganese (IV) oxide powder 2
Apparatus:
Conical flask, delivery tube and stopper, burette, basin/ water trough, retort stand
with clamp, stopwatch.
Students able to list one of the substance and suitable container

Substances:
Hydrogen peroxide, manganese(IV) oxide powder 1
Apparatus:
Conical flask, delivery tube and stopper, burette, basin/ water trough
Students give a wrong response.
20
Q Answer Score
3(e) Method 1:
Able to list all the steps correctly 3
Procedure:
1. Measure and pour (2 - 5) cm3 of hydrogen peroxide in a test tube.
2. Add 1 spatula of manganese (IV) powder into the test tube
3. Put a glowing splinter into the test tube.
4. Observe and record the changes on the glowing splinter.
5. Repeat steps 1 to 4 without adding manganese (IV) oxide/ catalyst.
Able to write steps 1, 2, 4, 5 improperly. 2
Able to write steps 1&2 less correctly. 1
No response / wrong response. 0

3(e) Method 2:
Able to list all the steps correctly
Procedure: 3
1. Fill a basin/ water trough with water.
2. Fulfill a burette with water and invert it in onto water in a basin/ water
trough.
3. Clamp the burette by using a retort stand. Record the initial burette
reading.
4. Measure and pour (20 - 100) cm3 of hydrogen peroxide in a conical flask.
5. Add 1 spatula of manganese (IV) powder into the conical flask.
6. Close the conical with a stopper which attached to a delivery tube.
Immediately start the stopwatch.
7. Observe and record the burette reading at every 30 seconds interval time.
8. Repeat steps 1 to 7 without adding manganese(IV) oxide/ catalyst.
Able to write 7 steps improperly.

2. Fulfill a burette with water and invert it in onto water in a basin/ water 2
trough.
3. Clamp the burette by using a retort stand. Record the initial burette
reading.
4. Measure and pour of hydrogen peroxide in a conical flask.
5. Add 1 spatula of manganese(IV) powder into the conical flask.
6. Close the conical with a stopper which attached to a delivery tube. Start
the stopwatch.
7. Observe and record the burette reading
21
Able to write at least 6 steps improperly.

2. Fulfill a burette with water and invert it in onto water in a basin/ water 1
trough.
3. Measure and pour of hydrogen peroxide in a conical flask.
4. Add 1 spatula of manganese (IV) powder into the conical flask.
5. Close the conical with a stopper which attached to a delivery tube.
6. Observe and record the burette reading
No response / wrong response.
0
3(f) Method 1:
Able to tabulate the data with the following aspects
Sample answer:
Set Observation
Hydrogen peroxide + manganese(IV) oxide 2
Hydrogen peroxide only

Sample answer:
Set
With catalyst 1
Without catalyst
3(f) Method 2:
Set 1: With catalyst/ manganese(IV) oxide
Time (s) 0 30 60 90 120

Volume of gas (cm3) 2
Set 2: Without catalyst/ manganese(IV) oxide
Time (s) 0 30 60 90 120

Volume of gas (cm3)
1
22
Able to tabulate the data with the following aspects 0
Set Volume
With catalyst/ manganese(IV) oxide
Without catalyst
Students give a wrong response.
END OF MARKING SCHEME

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SULIT 4541/1

BAHAGIAN PENGURUSAN SEKOLAH BERASRAMA PENUH

PENTAKSIRAN DIAGNOSTIK AKADEMIK SBP 2013

JANGAN BUKA KERTAS SOALAN INI SEHINGGA DIBERITAHU

1. Kertas ini mengandungi 50 soalan.

2. Jawab semua soalan.

4. Anda dibenarkan menggunakan kalkulator saintifik yang tidak boleh diprogramkan.

5. Tiap-tiap soalan diikuti oleh empat pilihan jawapan A , B , C dan D .

Kertas ini mengandungi 27 halaman bercetak

4541/1 2013 Hak Cipta BPSBPSK [Lihat Halaman Sebelah

1 Sublimation is a process when the solid change to gas.

2 Which substance contains 6.02 x 1023 atoms?

A 1.0 mol of carbon dioxide gas

3 Which elements are located in Group 1 in the Periodic Table of Elements?

A Sodium and caesium

4541/1 2013 Hak Cipta BPSBPSK SULIT

4 Which substance is an ionic compound?

5 Diagram 1 shows the set-up of apparatus of a chemical cell.

Y electrode Zinc electrode

Electrode Y is the negative terminal of the cell.

4541/1 2013 Hak Cipta BPSBPSK SULIT

6 Which of the following is a diprotic acid?

7 Which salt is insoluble in water?

8 Trophy and medal are normally made up of bronze.

A Copper and tin

4541/1 2013 Hak Cipta BPSBPSK SULIT

9 Which reaction has the lowest rate of reaction?

4541/1 2013 Hak Cipta BPSBPSK SULIT

11 Which statement is incorrect about unsaturated hydrocarbons?

12 Which statement defines oxidation?

A Increase in oxidation number

A Heat is absorbed from surroundings

4541/1 2013 Hak Cipta BPSBPSK SULIT

High refractive index

Which of the following glass has the above properties?

15 What is the function of aspartame?

4541/1 2013 Hak Cipta BPSBPSK SULIT

Tongs to remove lid

A To get the accurate mass of magnesium oxide

4541/1 2013 Hak Cipta BPSBPSK SULIT

17 Which isotope is used in radiotherapy for the treatment of cancer?

18 Element M forms two different chlorides, MCl2 and MCl3.

19 Which substance is an electrolyte?

4541/1 2013 Hak Cipta BPSBPSK SULIT

20 Diagram 5 shows the set-up of apparatus to investigate the electrical conductivity of

Substance P lights up the bulb because

21 Which of the following is correct about weak alkalis?

4541/1 2013 Hak Cipta BPSBPSK SULIT

22 Which reactants are suitable to prepare copper(II) sulphate?

A Copper and sulphuric acid

23 A substance has the following properties:

Hard and opaque

Which substance has the above properties?

4541/1 2013 Hak Cipta BPSBPSK SULIT

A Kinetic energy of the particles increases

25 Diagram 6 shows the structural formula of substance X.

26 Which substance accepts electron?

27 The thermochemical equation represents the neutralisation between hydrochloric acid,

HCl + NaOH NaCl + H2O H = -57 kJ mol-1

4541/1 2013 Hak Cipta BPSBPSK SULIT

Which of the following statement is correct?

A Argon is denser than magnesium

29 Which equations represent a neutralisation reaction?