HA - CH BIN DU KH

NGHIN CU CH TO CHT KH NH TCH NC KHI DU TH

NHM M BO YU CU V CHT LNG DU TH
TRONG QU TRNH KHAI THC
ThS. L Thi Sn1, ThS. Trn Thanh Phng1, ThS. V An1, ThS. Trn Hng Sn1
ThS. T Quang Minh1, ThS. Phan Trng Hiu1, KS. Cao Huy Hip1, ThS.V Ngc Don2
1
Vin Du kh Vit Nam
2
Hc Vin k thut Qun s
Email: sonlt@vpi.pvn.vn
Tm tt

Trong nghin cu ny, cht kh nh cho nh tng t nhin gin MSP801-819 Bch H c tng hp t polymer
keo t, dung mi v cht xc tin. Da trn kt qu thc nghim, nhm tc gi la chn ra cc thnh phn ti u
cho cht kh nh. Nhm tc gi xc nh tnh nng ca cht kh nh da trn quy trnh hng dn th nghim ca
Lin doanh Vit - Nga Vietsovpetro (I-VC-03 VSP) v so snh, nh gi hiu qu ph nh vi cht kh nh thng
mi ang c s dng. Kt qu nh gi cho thy, cht kh nh ch to tng hp tt vi ha phm deoiler v c
hiu qu ph nh tng ng vi ha phm thng mi nng th nghim 100ppm.
T kha: Cht kh nh, cng thc cht kh nh, cht kh nh tan trong du.

1. Gii thiu kt qu v bn nh, nng gii hn ca nh tng,

Nh tng nc trong du th hnh thnh trong qu
trnh khai thc, gy n mn ng ng, thit b v tng chi
ph cho qu trnh vn chuyn, ch bin. Phng php ch
yu kh nh tng nc trong du th l s dng ha
cht [1 - 4], nh cc cht kh nh loi anion, cation, nonion
hoc cc hp cht lng tnh [5]. Cc hp cht anion c gi
thnh sn xut thp v d ch to, song rt nhy vi s thay
i pH v thnh phn mui khong c mt trong du th.
Cc cht kh nh noion c cn bng a nc - a du c
s dng ph bin hn do khng b tc ng bi s thay i
pH v thnh phn mui khong ca mi trng. Cc loi
hp cht polymer c cha ng thi nhm a c v a
du i t phn ng ngng t ca ethylene oxide (a nc)
v propylene oxide (a du) c s dng ch yu lm cht
kh nh trong cng nghip du kh t sau chin tranh th
gii th 2. Hin nay, cc hp cht polymer hot ng b
mt i t dn xut alcoxylate l loi cht kh nh tng
nc trong du tt nht [4, 5, 14 - 19]. Ty thuc vo bn
cht du th tng ni, cc polymer ny c th s dng
kt hp vi mt s loi hp cht anion hoc cation theo t
l nht nh t c hiu qu kh nh cao nht. phenolalkyl ethoxylate formaldehyde, copolymer EO/PO,
Theo d bo sn lng khai thc ca Vietsovpetro,
nhu cu s dng ha phm kh nh ca n v ny trong
thi gian ti khong trn 500 tn/nm. Hin nay, loi ha
phm kh nh ny ang c nhp khu t nc ngoi
vi gi thnh cao. C mt s cng trnh nghin cu trong
nc v phng php tch nh tng nc trong du cho
thnh phn to nh tng t nhin nh hng n
bn nh v mt s kt qu nh gi hiu qu tnh nng
ca cht kh nh i vi du th Bch H Tuy nhin, t
l s dng ha phm kh nh x l du th Bch H
trong cc nghin cu ny rt ln so vi ha phm kh nh
thng mi hin nay (khong 25 - 40g/tn).
Trn thc t, s thay i t l nc, mui trong du
th dn n s thay i tnh cht v thnh phn nh
tng. Do , c tnh ca cc cht kh nh cn phi thay
i cho ph hp. V vy, nhm tc gi tp trung nghin
cu t hp cht kh nh p ng c cc yu cu k
thut, c hiu qu tng ng sn phm thng mi
ang s dng v cnh tranh v gi thnh. Da trn
xut ca nghin cu trc y, dng cht kh nh s
dng ph bin hin nay trn th gii, cc thnh phn
c bn trong cng thc kh nh tng thng mi
ang s dng ti cc gin khai thc trong nc v tnh
kinh t - k thut ca cc ha phm, nhm tc gi tp
trung ch to, nh gi cht kh nh da trn cc thnh
phn sau: Hp cht c tnh nng keo t (nh polymer
ethylene diamine alcoxylate); hp cht c hot tnh pha
lin din cao, khuch tn nhanh (nh sodium dodecyl
sulfate, sodium lauryl ether sulfonate) v cc loi dung
mi dn (nh xylene/methanol, xylene/propanol-2;
xylene/butanol-2, naphtha aromatic/methanol, naphtha
aromatic/propanol-2, naptha aromatic/butanol-2).

32 DU KH - S 12/2014

2. Thc nghim
Nhm tc gi xy dng tiu ch nh gi, la chn
thnh phn trong cht kh nh:
Polymer keo t: Khi lng phn t, ch s tan tng
i (RSN), h s phn b du - nc, sc cng b mt phn
chia du nc, tnh lu bin b mt phn chia du-nc,
tc khuch tn, kh nng ph nh theo Quy trnh
hng dn th nghim I-VC-03 VSP ca Vietsovpetro;
Cht xc tin: Ch s tan tng i (RSN), h s phn
b du - nc, sc cng b mt phn chia du nc, tnh
lu bin b mt phn chia du - nc, tc khuch tn,
kh nng cng hng ca cht xc tin ln tnh nng ca
polymer keo t;
Dung mi dn: Tc khuch tn khi dung mi c
ha tan vo cc thnh phn polymer keo t v cht xc
tin la chn.
Sau khi la chn c cc thnh phn polymer keo
t, cht xc tin v dung mi dn, nhm tc gi tin hnh
ti u ha t l cc thnh phn bng phng php quy
hoch thc nghim.
2.1. Cc phng php xc nh tnh cht cc thnh phn
trong cht kh nh
2.1.1. Xc nh khi lng phn t polymer
Khi lng phn t polymer c xc nh da trn
phng php phn tch sc k loi tr kch thc (GPC/
SEC). Thit b GPC/SEC s dng xc nh khi lng
phn t l h thng Viscotek TDAmax. Trc khi phn tch,
nhm tc gi tin hnh lp ng chun xc nh
s phn b khi lng phn t theo thi gian lu da trn
cht bit di khi lng phn t, sau phn tch mu
thc t. Da trn thi gian lu thc t ca mu phn tch
p theo ng chun lp xc nh khi lng phn
t thc t ca mu. Cc thng tin c th nhn bit c
t qu trnh phn tch gm: s khi lng mol trung bnh
Nghin cu la Nghin cu
chn polymer t
la chn cht
keo t xc tin
Cht
kh nh
Hnh 1. S nghin cu ch to cht kh nh
PETROVIETNAM
(Mn), khi lng mol trung bnh khi lng (Mm), khi
lng mol trung bnh (Mz).
2.1.2. Ch s tan tng i
Cho 1g sn phm cht kh nh ha tan trong 30ml
hn hp dung mi chun (dung mi cha 2,6% toluen v
97,4% EGDE). Cho t t nc vo hn hp dung mi ny
ging nh qu trnh chun v im cui m dung
dch xut hin im c. Gi tr RSN l th tch nc cn
to im c trong hn hp. V vy, khi ch s RSN cng
cao tnh a nc ca sn phm cng tng. Cc cht kh
nh a nc khng c khuyn khch s dng bi chng
s di chuyn vo pha nc trong sut qu trnh tch pha
v vy i hi phi c qu trnh x l nc tip theo.
2.1.3. Xc nh sc cng b mt phn chia du - nc
Sc cng b mt giao din hai pha l s o nng lng
tip xc b mt to ra t s mt cn bng lc gia cc phn
t b mt tip xc, c xc nh bng phng trnh:
(1)
: Sc cng b mt hai pha;
: H s hnh dng;
: S khc nhau gia t trng hai cht lng;
g: Hng s hp dn;
Ro: Bn knh cong ca git cht lng;
H s hnh dng c th c xc nh t phng trnh
Young - Laplace:
(2)
(3)
(4)
Nghin cu
la chn dung
mi dn
Hnh 2. Thit b o sc cng b mt phn chia du - nc
DU KH - S 12/2014 33
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Thit b o sc cng b mt giao din hai pha nc v
mi trng du c th hin trong Hnh 2.
2.1.4. o tnh lu bin b mt phn chia du - nc
Thit b gm mt xilanh hnh tr c th iu chnh
chnh xc kch thc git, ng knh trong ca u kim
7,1mm. Mt thit b knh hin vi in t nm ngang vi
phng i ln c s dng o kch thc v bn knh
cong (R) ca mng du bt k thi im no (Hnh 2).
Nu lp mng khng qu mng, sc cng mng du
() bng hai ln sc cng pha lin din mng du.
= 2
Sc cng mng du tnh theo p sut mao qun v
bn knh mng du:
Trc khi th nghim, lm sch hon ton xilanh bng
xylene, heptan loi b tp cht hu c. S c mt ca
tp cht c kim tra bng cch o sc cng b mt lin
quan gia nc loi ion v dodecane. Sau khi lm sch,
dung dch nc mui (nc khai thc) c a vo trong
xilanh mc thch hp v c t vo v tr thit k
sn ca thit b o. u kim ca xilanh sau c nhng
vo cuvet thch anh c cha pha du v cht kh nh.
Git nc u kim xilanh c to ra bng cch nn
p lc vo piston sao cho chng chuyn ng t trn
xung theo tng vch chia trn xilanh. Lp mng du
bao quanh git nc c gin n tc khng i,
bn knh lp mng c gim st, sc cng ng hc lp
mng c tnh ton nh l hm ca thi gian. n
hi mng ng hc (E) c tnh thng qua o sc cng
ng hc v ng cong ln(A/Ao):
Trong :
A: Din tch lp mng thi im tc thi;
Ao: Din tch lp mng thi im ban u.
Lp th biu din mi tng quan gia sc cng
b mt hai pha v gi tr ln(A/Ao), E l h s gc ca ng
thng c thit lp t s tng quan ca hai bin.
2.1.5. Xc nh tc khuch tn ca cht kh nh
T s liu sc cng b mt pha lin din ng hc (gi
tt l sc cng b mt ng hc) theo thi gian to git c
th c s dng nghin cu ng hc hp ph cht kh
nh v tc khuch tn. Phng trnh biu din sc cng
b mt ng hc v thi gian c tnh theo cng thc:
34 DU KH - S 12/2014
(8)
Trong :
: Nng b mt giao din;
Co: Nng cht kh nh pha lin tc;
e: Sc cng b mt tnh;
d: Sc cng b mt ng hc;
D: Tc khuch tn;
t: Thi gian hp ph.
(5) Gi tr G c tnh t dc ca ng thng tng
quan gia sc cng b mt tnh v gi tr lnCo theo phng
trnh:
(6) (9)
Lp ng thng biu din mi tng quan gia d
v t-1/2, t tnh xc nh h s gc ca ng thng ny.
T gi tr h s gc ca ng thng v da vo phng
trnh (9), tnh gi tr D tng ng.
2.1.6. Xc nh h s phn b ca cht kh nh
H s phn b l t l cn bng ca nng cht kh
nh (t l polymer keo t) trong pha du (Co) v pha nc
(Cw) v c th hin bng biu thc:
(10)
2.2. Xc nh kh nng ph nh theo Hng dn th
nghim I-VC-03 VSP
Mu th nghim l hn hp mu nh tng t nhin
MSP801-819 Bch H. Gia nhit mu n nhit 50 -
60C, lc mnh ng nht mu. Chun b dung dch
(7) 10% ha phm kh nh vi dung mi xylene. Cho mi
mu du phn tch (100ml/mu) vo tng ng thy tinh
(hnh cn c vch chia ) v chuyn vo b n nhit, duy
tr nhit 60C trong khong 15 pht. Bm ha phm
kh nh vi cc nh lng 50ppm, 100ppm, 150ppm vo
cc ng nghim cha mu du cn tch nc. mt ng
nghim cha mu trng (khng c ha phm) nh
gi bn nh ca mu. Vn cht cc nt ng nghim v
lc u trong khong 3 pht. Nhng cc ng nghim tr
li b n nhit v duy tr nhit 60C.
- Theo di, xc nh v ghi chp lng nc tch ra
trong cc ng nghim sau cc khong thi gian nht nh;
- Thi gian th nghim kt thc khi lng nc tch
ra khng c s thay i;

- Sau khi kt thc th nghim, tin hnh xc nh
hm lng nc cn li;
- Rt dung mi xylene vi mc 50% vo cc ng
thy tinh ca my ly tm;
- Dng xilanh ly 50% phn mu du cch b mt
phn chia du - nc 10 - 15mm cho vo cc ng nghim
trn. Cho thm 1 git nh cht kh nh F46, lc u cc
ng thy tinh trn;
- t cc ng thy tinh vo my quay ly tm, cho
my quay vi vn tc 2.000 vng/pht trong 10 pht;
- c v ghi li hm lng nc cn li.
Hoc dng xilanh ly khong 30 - 40ml phn mu du
cch b mt phn chia du - nc t 0 - 15mm vo bnh
cu ba c 500ml. Cho thm 300ml xylene v tin hnh
chng ct xc nh hm lng nc (ASTM D4006).
2.3. So snh nh hng ca cht kh nh ch to vi ha
phm deoiler
Nc tch ra sau qu trnh kh nh nc/du bng
ha phm demulsifier vn cha mt lng du nht nh
dng nh tng du trong nc. Ha phm s dng
cho qu trnh x l nh tng du/nc trong nc thi
nhim du c gi l deoiler. Kt qu th nghim ti cc
gin CTP-2 v CTP-3 ca Vietsovpetro cho thy, cc ha
phm deoiler sau khi s dng c hiu qu tch du trong
nc thi t tiu chun cho php.
V vy, i vi ha phm kh nh ch to, cn phi th
nghim nh gi tnh tng thch vi ha phm deoiler
ang c th nghim cng nghip ti mt s gin khai
thc ca Vietsovpetro. Quy trnh nh gi mc tng
thch gia ha phm kh nh ch to (CT-1 v CT-2) vi
ha phm deoiler (RBW-517) nh sau:
- Chun b nc thi nhim du: Mu du hn hp
Bng 1. Khi lng phn t v h s phn b cc loi polymer keo t
Khi lng
Loi polymer
(g/mol)
10.000
Alkylphenol alcoxylate formaldehyde 80.000
120.000
10.000
EO/PO block copolymer 80.000
120.000
10.000
Ethylene diamine alcoxylate 80.000
120.000
PETROVIETNAM
801 - 819 c s dng lm i tng th nghim. Nc
c tch khi du th bng cc loi ha phm kh nh
l CT-1, CT-2 v ha phm thng mi DMO 86318 cng
nng 100ppm trong 2 gi. Kt qu thu c 3 mu
nc thi, sau xc nh tng lng du trong 3 mu
bng phng php hp th UV.
- X l nc thi nhim du bng ha phm deoiler:
Cho thm 10ppm ha phm deoiler vo tng mu nc
thi ( c ng trong 3 bnh khc nhau), lc u. Sau
20 pht, ly phn nc gia bnh v xc nh hm lng
du cn li. T nh gi v so snh nh hng ca ha
phm kh nh ch to, ha phm kh nh thng mi
n hiu qu x l ca ha phm deoiler.
3. Kt qu tho lun
3.1. Kt qu nh gi la chn polymer keo t
Trong cht kh nh tng thng mi, polymer khi
lng phn t ln hay polymer keo t c cho l thnh
phn c tnh nng quan trng nht. Cc polymer ny khi
phn tn trong du th c tc dng lm thay i sc cng
b mt gia cc git nc v lm mt n nh h thng
nh tng nc/du bng cch thm t v ph v lp
mng bao quanh cc ht nh tng. Mt yu t rt quan
trng ca cc loi polymer ny l vai tr keo t. Nh lc
tng tc phn t (lc ht gia cc i phn t polymer)
cc git nc s tin li gn nhau hn to hin tng keo
t Cc loi polymer s dng trong nghin cu kh nng
kh nh nc/du (Bng 1).
Qu trnh la chn ny da trn cc dng cht polymer
trong cc cng thc kh nh tng thng mi s dng
ph bin hin nay. Cc polymer ny a phn l cc hp
cht khng ion i t dn xut alcoxylate. Theo nghin cu
[4, 5, 8, 9], cc loi polymer khng ion c kh nng n nh
cao trong mi trng c hm lng mui khong ln, kh
Ch s RSN H s Kp K hiu
11 1 PA1
9,7 1 PA2
7,9 1 PA3
12 1 EP1
10,3 1 EP2
9,5 1 EP3
13 1 ED1
11,5 1 ED2
10,8 1 ED3
DU KH - S 12/2014 35
HA - CH BIN DU KH

nng kh nh hiu qu i vi ht nh tng c phn

5,00 Log khi lng phn t vs. Th tch lu
tn cao. Tuy nhin, hiu qu tch nh ca cc loi polymer
ph thuc nhiu vo khi lng phn t. nghin cu 4,70
nh hng ny, nhm tc gi xc nh khi lng phn
4,40
t polymer keo t da trn phng php phn tch sc k
loi tr kch thc. Hnh 3 v 4 l kt qu phn tch khi 4,10
lng phn t ca PA1.
3,80
Kt qu xc nh khi lng phn t trung bnh Mz
3,50
ca cc polymer keo t c th hin trong Bng 1, cc
loi polymer s dng trong nghin cu l 3 loi khc nhau 3,20

i t dn xut alcoxylate. Mi loi polymer kho st u 2,90

c di phn t lng phn b rng t 10.000 - 120.000g/
2,60
mol v cho php nh gi nh hng ca khi lng
phn t n kh nng keo t. Mt yu t khc xc nh 2,30
ng thi vi khi lng phn t l kh nng phn tn
2,00
ca polymer trong pha du. Mc phn tn hay kh
13,0 14,0 15,0 16,0 17,0 18,0 19,0
nng tng hp trong mi trng du hoc nc ca cc
loi polymer trong cht kh nh c xc nh thng qua
WF/dLog M vs. Log khi lng phn t
1,30
o ch s tan tng i. Bng 1 cho thy cc loi polymer
trn c ch s tan tng i thp trong khong t 7,5 - 1,17
11,5, do tng hp tt vi du th hay tan hon ton
1,04
trong pha du.
0,91
Hiu qu polymer keo t trong vai tr kt t tch
pha nc th hin qua mi lin quan gia cc yu t: 0,78
kh nng tch pha nc (thi gian tch, hm lng s
0,65

0,52
6
15,5
Tn hiu ch s khc x (mV)

41,0
0,0
0,39
-41,0
0,26
-82,0
-123,0
0,13
-164,0
-205,0 Mn Mw Mz
0,00

0,0 4,0 8,0 12,0 16,0 20,0 24,0 28,0 32,0 36,0 40,0 2,0 3,0 4,0 5,0
Th tch lu (ml)
Hnh 4. ng chun v kt qu xc nh
Hnh 3. Thi gian lu ca PA1 khi lng phn t PA1
Bng 2. Mt s tnh cht ca nh tng t nhin MSP801-819 Bch H
TT Cc ch tiu Phng php Kt qu
1 Hm lng nha, asphaltene (%kl) Chit dung mi 1,4
2 Hm lng paraffin (%kl) Sc k kh 21,2
3 Hm lng nc (%V) ASTM D4006 16,0
4 nht 50oC (cSt) ASTM D445 -
5 T trng, d204 ASTM D1289 0,9124
6 Ca2+ (mg/l) trong pha nc Chun 1.643
7 Na+ (mg/l) trong pha nc AAS 7.300
8 Mg2+ (mg/l) trong pha nc Chun 24,4
9 Fe2+ (mg/l) trong pha nc Chun 3,04
10 Cl- (mg/l) trong pha nc Chun 19.596
11 SO4 2- (mg/l) trong pha nc Chun 216
12 Tng mui (mg/l) trong pha nc Tng cht rn ha tan 25.448

36 DU KH - S 12/2014
 PETROVIETNAM

dng, % pha nc tch ra) vi tc khuch tn ca Kt qu ny cho thy quy lut v tc tch pha ca
phn t polymer ti b mt phn chia nc/du hay ti cc dng polymer PA lun cao hn cc dng EP v ED. V
lp mng du; tnh lu bin mng du hay kh nng ph vy dng polymer keo t PA c di phn t lng khc
v lp mng cng nh kh nng lm thay i sc cng nhau c s dng phi trn nhm mc tiu to ra
b mt phn chia nc/du [6 - 13]. Phng php nh t hp polymer c tc v hiu qu tch pha ln nht.
gi hiu qu kh nh nc/du c thc hin theo Quy Bng 3 th hin mt s tnh cht ca polymer t hp.
trnh hng dn th nghim I-VC-03-VSP. y l phng
Cht kh nh nc/du t hiu qu phi tan hon
php nh gi hiu qu kh nh theo nng cht kh
ton trong pha du, th hin ch s RSN thp (< 13); c
nh, v cho kt qu trc quan v hiu qu kh nh ca
tc khuch tn cao tc l c kh nng di chuyn nhanh
polymer th hin qua tc tch pha theo thi gian,
ti b mt phn chia du nc; c kh nng lm suy gim
mc phn pha v hm lng s dng. V vy, nhm
mnh sc cng b mt ca git nc trong pha du v
tc gi s dng phng php ny trc tin nhm xc
c bit phi c tnh lu bin b mt phn chia thp, tc
nh hiu qu kh nh ca cc dng sn phm polymer
l kh nng lm gim mnh n hi ca lp mng du
i t dn xut alcoxylate; t la chn c dng kh
bao quanh cc git nc. Bng 3 cho thy tc khuch
nh tt nht. Nh tng s dng nh gi kh nng
ph nh l loi nh tng t nhin hn hp MSP801-819 tn ca PA3 ln nht tng ng 42 x 10-4cm2/s; PA1 c
Bch H c tnh cht nh Bng 2. tc khuch tn nh nht 1,20 x 10-4cm2/s. Tuy nhin,
kh nng gim n hi mng du hay tnh lu bin
Kt qu nh gi kh nng kh nh ca cc loi mng du ca PA3 li tng i cao. PA2 c tnh lu bin
polymer keo t c th hin Hnh 5 v 6. mng du thp nht nhng tc khuch tn l 4,10 x
Hnh 5 v 6 th hin tc tch pha nc ca cc 10-4 cm2/s thp hn PA3 v cao hn PA1. V vy, c th la
dng polymer keo t trn i tng nh tng t nhin chn t l phi trn gia PA1, PA2 v PA3 to ra mt
MSP801-819 nng 50ppm v 100ppm, nhit th t l ti u xt trn ch tiu tc khuch tn v tnh lu
nghim 60C. Kt qu so snh cho thy tc tch pha bin mng du. V tc khuch tn ca PA1 l ln nht,
ca cc dng polymer keo t PA > EP > ED. do t l phi trn gia cc loi polymer c xc nh

Nh tng t nhin: Du th MSP8 01 - 819, 16% nc, Nh tng t nhin: Du th MSP8 01- 819, 16%nc,
Hm lng nc tch pha, ml

nng cht kh nh 50ppm, t = 60C nng cht kh nh 100ppm, t = 60C

16
16
Hm lng nc tch pha, ml

14 PA1
PA2
14 PA1
PA2
12
PA3 12 PA3
10 EP1 10 EP1
EP2 EP2
8
EP3
8
EP3
6 ED1 6 ED1
4 ED2 4 ED2
ED3 ED3
2 2
0 0
5 10 15 30 45 60 90 120 5 10 15 30 45 60 90 120
Thi gian, pht Thi gian, pht

Hnh 5. Tc kh nh ca cc loi polymer keo t s dng nh tng t nhin Hnh 6. Tc kh nh ca cc loi polymer keo t s dng nh tng t nhin
MSP801-819: nhit 60C, nng 50ppm MSP801-819: nhit 60C, nng 100ppm

Bng 3. Tnh cht c bn ca cc loi polymer keo t dng PA ring l v t hp

Sc cng Tnh lu bin Tc khuch tn

Loi polymer RSN
b mt (dyn/cm) (E, dyn/cm) (D, cm2/s)
PA1 8,97 10,520 1,20 x 10-4 11
-4
PA2 7,56 7,095 4,10 x 10 9,7
PA3 4,09 9,738 42,00 x 10-4 7,9
PA4 (50% PA3 + 40% PA2 + 10% PA1) 5,966 8,759 22,76 x 10-4 8,93
-4
PA5 (50% PA3 + 30% PA2 + 20% PA1) 6,107 9,101 22,47 x 10 9,06
PA6 (50% PA3 + 10% PA2 + 40% PA1) 6,248 9,444 22,18 x 10-4 9,19
-4
PA7 (70% PA3 + 20% PA2 + 10% PA1) 5,272 9,287 30,34 x 10 9,32
-4
PA8 (70% PA3 + 10% PA2 + 20% PA1) 5,413 9,630 30,5 x 10 8,57

DU KH - S 12/2014 37
HA - CH BIN DU KH

da trn t l PA1. Cc t l phi trn v kt qu o tnh

Du th Bch H MSP801- 819,
lu bin mng du cng nh tc khuch tn ca hn
nng cht kh nh 5 0ppm, t = 60oC
16 hp c ch ra trong Bng 3. Kt qu cho thy PA4 c tnh
Hm lng nc tch pha, ml

14 lu bin mng du nh nht v tc khuch tn tng

12 PA3
i cao so vi cc hn hp PA5, PA6, PA7 v PA8. Do vy,
10 PA4
hn hp polymer keo t PA4 c s dng nh l thnh
8 PA5
6 phn chnh cho cht kh nh ch to.
PA6
4
PA7 Bng 3 cho thy quy lut tnh cht ca thnh phn cht
2
PA8 kh nh ph thuc vo t l phi trn. Khi tng t l PA1,
0
5 10 15 30 45 60 90 120 150 tnh lu bin mng du tng ln theo mt t l nht nh.
Thi gian, pht
t l PA1 di 50%V, tc khuch tn tng i nh,
do vy nhm tc gi khng kho st. Kt qu thc nghim
Hnh 7. Tc kh nh ca t hp polymer keo t s dng nh tng t nhin o tnh lu bin mng du v tc khuch tn cho thy
MSP801-819: nhit 60oC, nng 50ppm
PA4 t hiu qu tt nht. Tuy nhin, hiu qu ca cc t l
phi trn cn phi c kim chng bng hiu qu tch
Du th Bch H MSP801 - 819, pha cui cng cng nh tc tch pha. V vy, nhm tc
nng cht kh nh 100ppm, t = 60oC gi tin hnh th nghim hiu qu ph nh ca PA4, PA5,
16
Hm lng nc tch pha, ml

PA6, PA7 v PA8; ng thi so snh vi PA3 trn mu nh

14
12 PA3 tng MSP801-819 Bch H. Tc kh nh ca cc t hp
10 PA4 polymer keo t c th hin qua cc Hnh 7 v 8.
8 PA5
6 PA6
Hnh 7 v 8 cho thy, hiu qu ph nh cui cng ca
4
PA7 cc dng polymer keo t trn i tng nh tng t nhin
2 MSP801-819 nng 50ppm v 100ppm nh sau: PA4 >
PA8
0
5 10 15 30 45 60 90 120 150 PA5 > PA6 > PA7 > PA8. Nh vy, PA4 l t hp polymer keo
Thi gian, pht t c tnh nng tt nht trong qu trnh kho st.

3.2. Kt qu nh gi la chn cht xc tin

Hnh 8. Tc kh nh ca t hp polymer keo t s dng nh tng t nhin
MSP801-819: nhit 60oC, nng 100ppm Cc cht hot ng b mt khi lng phn t thp
Bng 4. Tnh cht c bn ca cht xc tin
(cht xc tin) c kh nng di chuyn nhanh n b mt
phn chia nc/du, thm t v thay i n nh ca
Tn thnh phn
mng du to iu kin cho cc polymer keo t xc tin
Sodium Sodium
Tnh nng nhanh hn qu trnh ph v mng du. V bn cht, cht
dodecyl lauryl ether
sulfate sulfate xc tin phi l cc phn t hot ng b mt c kh nng
(SDS) (SLES) phn tn trong pha du mt mc nht nh v c kh
Sc cng b mt (dyn/cm) 5,21 5,67 nng thm nhp vo cc git nc lm thay i tnh cht
Tnh lu bin b mt (dyn/cm) 20,405 22,643 ti b mt tng tc hai pha du - nc. V vy, tiu ch
Tc khuch tn (cm2/s) 34 x 10-4 29 x 10-4 nh gi hiu qu ca cht xc tin l kh nng khuch
Ch s tan tng i 15 15,5 tn nhanh ti b mt phn chia, kh nng lm suy gim
H s phn b Kp 0,02 0,015 sc cng b mt mng du cng nh c kh nng chng
li n hi ca lp mng phn chia. Hai cht hot ng
Bng 5. Tc ng cng hng ca cht xc tin ln tnh nng b mt c kh nng p ng cc yu cu ca cht xc tin
ca polymer keo t c la chn l sodium dodecyl sulfate (SDS) v sodium
Tn thnh phn lauryl ether sulfate (SLES). y l cc cht hot ng b
Tnh nng 99,7% PA4 + 99,7% PA4 + mt anion, v vy c kh nng bo mn lp mng du cao
0,3% SDS 0,3% SLES do u a nc c cha nhiu in tch (Bng 4).
Sc cng b mt (dyn/cm) 5,52 5,87
Bng 4 cho thy cc cht xc tin c la chn c
Tnh lu bin b mt (dyn/cm) 8,238 8,571
kh nng suy gim sc cng b mt hai pha, do vy c kh
Tc khuch tn (cm2/s) 23,12 x 10-4 22,97 x 10-4
nng y nhanh qu trnh bt n nh lp mng du bao

38 DU KH - S 12/2014
 PETROVIETNAM

quanh cc git nh tng - ni c cha cc phn t hot methanol t l 20/1 v naphtha aromatic/methanol t l
ng b mt t nhin nh nha v asphaltene. Kt qu 20/1 ha tan hn ch thnh phn cht kh nh, cc dung
cng cho thy tc khuch tn ca hai phn t ny cao mi cn li c kh nng ha tan hon ton thnh phn
hn so vi tc khuch tn ca PA4; do , khi kt hp hot tnh. nh gi tc dng ca dung mi n tc
vi cc loi polymer keo t c kh nng to ra hiu ng ph nh, nhm tc gi tin hnh xc nh tc khuch
kt hp lm tng tc khuch tn ca cht kh nh. Kt tn ca thnh phn cht kh nh khi ha tan trong dung
qu nh gi tc ng cng hng ca cht xc tin v t mi (Bng 7).
hp polymer keo t PA4 c th hin trong Bng 5.
Kt qu xc nh tc khuch tn ca cc thnh
So snh kt qu nh gi tc ng cng hng ca phn hot tnh khi pha dung mi cho thy t l dung
cht xc tin ln tnh nng ca t hp polymer keo t vi mi thm/ru bc nht trong khong 50/1 tc
tnh cht ca cht xc tin cho thy tc khuch tn ca khuch tn cc thnh phn hot tnh ln nht. C th,
t hp polymer PA4 cao hn so vi PA4 v tnh lu bin t l dung mi xylene/propanol-2 v naphtha aromatic/
mng du ca hn hp cng gim hn so vi khi s dng propanol-2 cho tc khuch tn ln nht tng ng
PA4 mt cch ring r. Nh vy, cc cht xc tin c tc 24,6 x 10-4 v 24,7 x 10-4cm2/s.
ng ci tin tnh nng ca t hp polymer PA4. SDS c
Qua thc nghim, nhm tc gi la chn cc
la chn l thnh phn xc tin trong cht kh nh, do c
thnh phn trong cht kh nh tng vi tc tch pha
hiu qu cao hn cht xc tin SLES.
v hiu qu ph nh cui cng. Cc thnh phn trong
3.3. Kt qu nh gi la chn dung mi dn cht kh nh nh sau: Thnh phn c tnh nng keo t
l dng polymer alkylphenol alcoxylate formaldehyde
Dung mi c tc dng ng nht tt c thnh phn c di phn t lng khc nhau. C th thnh phn keo
trong cht kh nh, gip cc thnh phn hot ng trong t gm: 50% loi alkylphenol alcoxylate formaldehyde
cht kh nh phn tn hiu qu trong pha du. Mi dng (PA) vi khi lng phn t 10.000g/mol, 30% PA vi
cht kh nh tng nc/du cn phi la chn dung khi lng phn t khong 80.000g/mol v 20% PA vi
mi phn tn ph hp. Thnh phn ca PA4 ch yu l cc khi lng phn t khong 120.000g/mol; cht xc tin
loi polymer cha cc nhm alkyl, EO, PO v vng thm, l hp cht sodium dodecyl sulfate; dung mi dn l
cho nn dung mi ph hp nht l cc loi hydrocarbon xylene/propanol-2.
thm nh xylene hay naphtha aromatic. Theo nghin cu
Bng 6. Kt qu xc nh ng nht cc phn t hot tnh
[19 - 25], cc dung mi l cc phn t ru n chc mch
ngn c s dng nh mt thnh phn lm tng T l hn hp dung mi 20/1 50/1 100/1
phn tn ca cc phn t polymer cng nh tng cng Xylene/methanol - + +
hiu qu kh nh nh kh nng khuch tn vo bn trong Xylene/propanol-2 + + +
cc ht nh tng nc/du, lm y nhanh qu trnh keo Xylene/butanol-2 + + +
t, tch pha ca cc git nc. Tuy nhin, cc loi ru Naphtha aromatic/methanol - + +
n chc ch c s dng mt t l nht nh do c Naphtha aromatic/propanol-2 + + +
bn cht dung mi khc vi cc loi dung mi thm. V Naphtha aromatic/butanol-2 + + +
vy phi tin hnh kho st t l gia cc dung mi thm
Bng 7. Xc nh tc khuch tn ca thnh phn cht kh nh khi ha tan
v ru n chc tm ra t l s dng ti u. Bng 6
trong dung mi
l kt qu xc nh ng nht ca cc loi dung mi
Loi dung mi Tc khuch tn (D, cm2/s)
thm v ru bc nht khi pha cc phn t hot tnh cc
T l 20/1 50/1 100/1
t l khc nhau.
-4 -4
Xylene/methanol 23,1 x 10 23,7 x 10 23,3 x 10-4
Bng 6 cho thy cc t l dung mi c nh du + Xylene/propanol-2 24,1 x 10-4 24,6 x 10-4 24,4 x 10-4
l cc dung mi c kh nng ha tan tt cc thnh phn Xylene/butanol-2 23,2 x 10 -4
23,8 x 10 -4
23,6 x 10-4
hot tnh trong cht kh nh tng, cc t l dung mi
Naphtha
c nh du - l cc dung mi ha tan hn ch cc 23,3 x 10-4 6,9 x 10-4 6,6 x 10-4
aromatic/methanol
thnh phn hot tnh. T kt qu xc nh ng nht Naphtha
24,3 x 10-4 24,7 x 10-4 24,4 x 10-4
cc phn t hot tnh cho thy t l dung mi thm/ru aromatic/propanol-2
bc nht cng cao kh nng ha tan cc thnh phn hot Naphtha 23,3 x 10-4 23,5 x 10-4 23,4 x 10-4
aromatic/butanol-2
tnh cng ln. Trong cc dung mi kho st ch c xylene/

DU KH - S 12/2014 39
HA - CH BIN DU KH

3.4. Ti u ha cc thnh phn trong cht kh nh Hm lng cht keo t: Z1 = 70 - 75% khi lng;

Trc khi ti u ha, nhm tc gi kho st cc hm
lng cht keo t, cht xc tin v dung mi dn xc
nh vng ti u cho hiu qu tch pha cui cng.
T kt qu kho st nh hng ca cc thnh phn
trong cht kh nh n hiu qu ph nh theo quy trnh
th nghim cho thy vng ti u thit lp cc t l
thnh phn trong cht kh nh nh sau:
Hm lng cht keo t: 70 - 75% khi lng;
Hm lng cht xc tin: 0,1 - 0,5% khi lng;
Dung mi dn: 24,5 - 29,9% khi lng.
Ti u ha thc nghim xc nh t l ti u cho
cc thnh phn trong cht kh nh tng cho i tng
nh tng MSP801-819 Bch H.
La chn cc yu t kho st:
Hm lng cht xc tin: Z2 = 0,1 - 0,5% khi lng;
Hm lng dung mi dn: Z3 = 24,5 - 29,9% khi lng.
La chn hm mc tiu:
Y (%V): Lng nc tch pha sau 180 pht th nghim
La chn kiu mu thit k:
Bi ton c m hnh ha theo thc nghim bc
2 tm xoay, tin hnh trn c s xy dng ma trn quy
hoch ha thc nghim bc 2 tm xoay. Vi 3 nhn s
kho st nn s thc nghim gc l 8, s thc nghim
im sao l 6 (vi khong cch t tm n im sao
d = 1,682) v tin hnh 2 th nghim tm. Nh vy quy
hoch thc hin 16 th nghim.
Dng tng qut ca phng trnh hi qui bc 2 c 3
nhn t nh sau:

Bng 8. Kt qu kho st nh hng ca t l thnh phn n hiu qu ph nh Y = bo + b1x1 + b2x2 + b3x3 + b12x1x2 + b23x2x3
(13)
(nhit th nghim 60oC, nng cht kh nh 100ppm, + b13x1x3 + b11x12 + b22x22 + b33x32
thi gian th nghim 180 pht)
Trong :
Thnh phn cht kh nh (% kl) Lng nc
TT
PA4 SDS Xylene/propanol-2 cn lai (%V) bo: H s t do;
1 60 0,05 39,95 4
2 60 0,1 39,9 4 b1, b2, b3: H s tuyn tnh;
3 60 0,3 39,7 4 b12, b23, b13: H s tng tc i.
4 60 0,5 39,5 4
5 60 0,55 39,45 5 Kt qu mu ti u ton phn thu c sau khi chy
6 70 0,05 29,95 0,5 phn mm l:
7 70 0,1 29,9 0,1
8 70 0,3 29,7 0,3 - Hm lng cht keo t: Z1 = 72%
9 70 0,5 29,5 0,4
10 70 0,55 29,45 0,5 - Hm lng cht xc tin: Z2 = 0,15%
11 75 0,05 24,95 0,5 - Hm lng dung mi dn: Z3 = 27,85%
12 75 0,1 24,9 0,5
13 75 0,3 24,7 0,4 3.5. nh gi hiu qu kh nh ca cng thc ch to
14 75 0,5 24,5 0,4
15 75 0,55 24,45 0,5 Kt qu nh gi hiu qu ca cng thc ch to trn
16 80 0,05 19,95 3,5
mu nh tng MSP801-819 nhit th nghim 60oC
17 80 0,1 19,9 3,5
18 80 0,3 19,7 0,4 c th hin trn Bng 10.
19 80 0,5 19,5 0,3 Kt qu cho thy nng 100ppm, hiu qu tch
20 80 0,55 19,45 4
pha nc ca cng thc ch to tng ng vi sn
Bng 9. iu kin th nghim ti u ha phm cht kh nh thng mi DMO 086318.
Cc yu t nh hng
3.6. nh gi kh nng tng thch ca cng thc cht
Hm lng Hm lng Hm lng
Cc mc kh nh ch to (demulsifiers) vi ha phm deoiler
cht keo t cht xc dung mi
Z1 (%) tin Z2 (%) dn Z3 (%) Cng thc cht kh nh ch to l ha phm s dng
Mc trn (+1) 75 0,5 29,9 tch nc khi du th. Sau qu trnh tch nc, cc
Mc c s (0) 72,5 0,3 27,2
ha phm ny s theo dng du. Tuy nhin, cc thnh
Mc di (-1) 70 0,1 24,5
phn chnh trong cng thc cht kh nh ch to l cc
Khong bin thin 2,5 0,2 2,7
cht hot ng b mt khi lng phn t ln v cc cht

40 DU KH - S 12/2014
 PETROVIETNAM

Bng 10. Kt qu nh gi trong phng th nghim

Lng nc tch ra theo thi gian (pht), ml Nc

Hm lng
Ha phm cn li
(ppm) 5 10 15 30 45 60 90 120 150 180 (%V)
Cng thc 50 2 4 4 4 6 8 10 12 12 12 4
ch to 100 3 5 7 7 7 9 12 16 16 16 0,3
DMO 50 6 9 12 14 14 14 14 14 14 14 2
086318 100 8 10 11 13 16 16 16 16 16 16 0,5
Blank 0 0 0 0 0 0 0 0 0 0 16

Bng 11. Kt qu th nghim kh nng tng thch ca ha phm kh nh ch to vi deoiler

Hm lng du cn li (ppm)
Tn ha phm
Khng x l bng deoiler X l bng deoiler
Cng thc ch to 110 31
DMO 86318 110 30

Bng 12. Kt qu so snh hiu qu kh nh ca cng thc ch to v sn phm thng mi trn mu hn hp 801-819 gin 8 m Bch H

Hm Lng nc tch ra theo thi gian (pht), ml Nc

Ha
lng cn li
phm (ppm) 5 10 15 30 45 60 90 120 150 180 (%V)
Cng thc 50 0,5 1 1 1 1,5 1,5 1,5 2 2 2 7
ch to 100 1 4 4 6 7 8 11 14 14 14 0,2
DMO 50 6 6 7 7 7 7 7 7 7 7 1
086318 100 7 8 8 8 8 9 9 9 9 9 0,3
Blank 0 0 0 0 0 0 0 0 0 0 14

xc tin c kh nng phn tn mt phn trong pha nc.
Trong nc thi c th cn mt lng nh thnh phn
ca cht kh nh, nh hng n hot tnh ca ha phm
deoiler. V vy, cn nh gi kh nng tng thch ca ha
phm kh nh ch to v ha phm deoiler.
Bng 11 cho thy lng du cn li trong pha nc
sau khi du c x l bng 2 loi ha phm demulsifier
cao hn tiu chun cho php (< 40ppm). Tuy nhin, sau
khi c x l bng ha phm deoiler, hm lng du
trong pha nc ca cc mu u t tiu chun cho php.
Kt qu ny khng nh ha phm kh nh ch to c
kh nng tng thch vi ha phm deoiler ang c
th nghim cng nghip ti Vietsovpetro.
3.7. So snh kt qu th nghim trong phng th nghim
v th nghim ti Vietsovpetro trn mu nh tng hn
hp 801-819 gin 8 m Bch H
Quy trnh tch nc khi du th ti cc m ca
Vietsovpetro c thc hin nh sau: Nh tng t cc
gin MSP v BK c a v gin cng ngh trung tm.
Ti y, du th c bm ha phm tch nc, sau gia
nhit n nhit 60 - 65C. Du i vo bnh tch 3 pha, ri
i vo bnh tch tnh in, bnh tch 2 pha ri gom v bnh
200m3 bm sang tu. tu, du s c gi nhit
45 - 50C, lu tank cng ngh v tank hng t 5 - 6 ngy
ri xut bn. Trong quy trnh trn, nh tng v gin cng
ngh c hm lng nc t 40 - 50%, du bm i tu c
hm lng nc t 0,5 - 2%. Qu trnh tch tnh in l qu
trnh quyt nh. Du xut bn c hm lng nc < 0,5%.
Theo quy trnh trn, ha phm tch nc phi t cc
yu cu sau: c kh nng tch nc nhanh (khong 40 -
50% hm lng nc trong nh vi thi gian ngn < 60
pht), gim lng nc trc khi vo bnh tch tnh
in; c tc dng nhit thp, nc vn tch ra khi
du lu tu.
Hiu qu kh nh ca mu th nghim c nh gi
da theo Quy trnh hng dn th nghim I-VC-03-VSP.
Theo , mu nh tng t nhin (loi mu nh mi hoc
c) c s dng nh gi hiu qu ph nh v liu
lng ha phm s dng l 50ppm v 100ppm. Vic s
dng di nng cht kh nh nhm nh gi xu hng
hiu qu ph nh. Kt qu nh gi so snh hiu qu ph
nh ca 2 t hp ch to v ha phm thng mi DMO
08618 trn mu nh tng hn hp 801-819 gin 8 m
Bch H ti Vin Nghin cu Khoa hc v Thit k Du kh
bin (NIPI), Vietsovpetro c th hin trong Bng 12.

DU KH - S 12/2014 41
HA - CH BIN DU KH
Kt qu nh gi th nghim cho thy t hp cht
kh nh ch to u c tc dng ph nh mt mc A.A.Fada, A.A.Abdel-Rahman. Preparation and application
nht nh, hiu qu tch pha thp hn, song vi nng
100ppm th hiu qu ph nh cui cng tng ng
ha phm ang s dng ti Vietsovpetro.
4. Kt lun
Nhm tc gi la chn c cc thnh phn trong
cht kh nh cho i tng nh tng MSP801-819 Bch
H. Cc thnh phn c la chn trong cht kh nh
bao gm: thnh phn keo t l alkylphenol alcoxylate
formaldehyde (PA) vi di phn t lng khc nhau;
cht xc tin l sodium dodecyl sulfate v dung mi dn
l xylene/propanol-2 vi t l khi lng tng ng l
72; 0,15 v 27,85.
Kt qu nh gi ti Phng th nghim trn cc mu
nh tng hn hp 801-819 gin 8 m Bch H cho thy
nng 100ppm cc cng thc ch to cho hiu qu ph
nh cui cng tng ng vi sn phm DMO 086318 -
l mt trong cc sn phm ang c s dng ph bin
ti cc gin khai thc trong nc.
Kt qu nh gi lab test i chng do Vin Nghin
cu Khoa hc v Thit k du kh bin vi mu nh tng
hn hp 801-819 gin 8 m Bch H cho thy cc cng
thc t hp cho hiu qu ph nh nht nh. nng
50ppm, cng thc ch to v cht kh nh thng mi
u c lng nc tch pha sau th nghim ln hn
0,5%V. nng cht kh nh 100ppm, hiu qu ph
nh cui cng ca cht kh nh ch to v ha phm
ang s dng ti Vietsovpetro tng ng vi lng
nc cn li sau th nghim < 0,5%V.
Ti liu tham kho
1. inh Th Qunh Nh, Phm Th Ngc Bch, Trng
nh Hi, Nguyn Th Cc, ng Quc Dng, Nguyn
Phan Tr, Bi nh Huy. Nghin cu tnh cht h nh nc
trong du th m Rng v phng php kh nh bng gia
nhit v ph gia ha phm. Vin Du kh Vit Nam. 1998.
2. Nguyn Th Cc, Phm Vn Lm, Nguyn Linh
Giang, Phm Vn Khang, Phm Th Ngc Bch, H Vn Bch.
Nghin cu tnh cht nh nc trong du, du trong nc
ca du th Bch H v phng php kh nh bng nhit
ha. Vin Du kh Vit Nam. 1993.
3. V Cng Thng, Nguyn Vn Thng, L Xun Ba,
Nguyn Thu H, Trn Vn Tn, V Vn Trng, Trnh Kin
Quc, H Xun Linh, Mai Th Ho. Nghin cu s to nh
trong du, nh du trong nc v phng php tch nh.
Vin Du kh Vit Nam. 1992.
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4. Atta M.Ayman, H.S.Ismail, A.M.Elsaeed, R.R.Fouad,
of nonionic polypropylene oxide-graft-polyethylene glycol
copolymer surfactants as demulsifier for petroleum crude oil
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5. Ahmed M.Al-Sabagh, Nadia G.Kandile, Mahmoud
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6. Ahmed M.Al-Sabagh, Nadia G. Kandile, Rasha
A.El-Ghazawy Mahmoud R.Noor El-Din. Synthesis and
evaluation of some new demulsifiers based on bisphenols for
treating water-in-crude oil emulsions. Egyptian Petroleum
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7. Alexandre Goldszal, Maurice Bourrel.
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Eugenio A.Flores, Flavio Vazquez. Demulsifying super-
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Christopher. Chemical interactions and demulsifier
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11. Feng Jie, Fang Hong-Bo, Zong Hua Zhang Lei,
Liu Xue-Peng, Zhang Lu, Zhao Sui, Yu Jia-Yong. Effect of
demulsifiers on dilatational properties of crude oil-water
interfaces. Journal of Dispersion Science and Technology.
2012; 33: p. 24 - 31.
12. Gabriel Cendejas, Felipe Arreguin, Laura V.Castro,
Eugenio A.Flores, Flavio Vazquez. Demulsifying super-
heavy crude oil with bifunctionalized block copolymers.
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emulsions. Petroleum Engineering Handbook. 1989.
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15. Johannes Fink. Petroleum engineers guide
 PETROVIETNAM

to oil field chemicals and fluids. Gulf Professional
Publishing. 2011.
16. Ishpinder Kailey, Xianhua Feng. Influence of
structural variations of demulsifiers on their performance.
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Study on manufacturing demulsifier to separate water

from crude oil to ensure quality requirements during
production operations
Le Thai Son1, Tran Thanh Phuong1, Vu An1, Tran Hung Son1
Ta Quang Minh1, Phan Trong Hieu1, Cao Huy Hiep1, Vu Ngoc Doan2
1
Vietnam Petroleum Institute
2
Military Technical Academy

Summary
In this study, demulsifier for crude oil emulsion from Bach Ho MSP801-819 is prepared by mixing polymers acting as
flocculants, solvents and promoter. Based on the experimental results, the authors have selected the optimal chemi-
cal components for the demulsifier.
The properties of demulsifier was determined based on the testing standard of Vietsovpetro (I-VC-03 VSP), while the
authors compared and evaluated the efficiency of the prepared demulsifier with commercial demulsifier. The result
shows that the prepared demulsifier has good compatibility with deoiler and the same efficiency of water separation
in comparison with commercial demulsifier at concentration of 100ppm.
Key words: Demulsifier, formulation for demulsifier, oil-soluble demulsifier.

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