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Solvents By-Products
Mass Chemical
Mass
Plant Effluents
Catalysts
(Enterprise)
Material for Utilities Spent Materials
(Water, Coal)
Heating Power Pressure
Cooling
Energy
Mass Integration (Mass Exchange Network MEN)
Energy Integration (Heat Exchange Network HEN)
Hot Streams In
Heat
Exchanger
Network
Cold Streams In
Plant Products
Raw Materials & A
Unit Operations By-Products
Table 1*
Stream Q available
No. Condition FCp, BTU/(hroF) Tin Tout 103 BTU/hr
Therefore, 10x103 BTU/hr must be supplied from utilities (if there are no restrictions on temperature driving force)
How can we check driving force restrictions? Second Law Analysis (You can not transfer heat from a lower
temperature to a higher temperature)
5
*Ref. Douglas, 1988, Conceptual Design of Chemical Processes, McGraw-Hill Publishers, p. 218.
Shifted Temperature Scales (using Table 1 data):
Hot Temperature Scale Cold Temperature Scale
250 240
200 190
150 140
100 90
Sources Sinks
250 240
200 190
160 150
140 130
120 110
100 90
1 50
200 190
2 -40
160 150
3 -80
140 130
120
4 110 40
100 5 90 20
Total = -10
Qi = [ ( FCp) hot ,i ]
( FCp ) cold ,i Ti
Therefore,
Q1 = (1000)(250 200) = 50 x103
Q2 = (1000 + 4000 6000)(200 160) = 40 x103
Q3 = (1000 + 4000 3000 6000)(160 140) = 80 x103
250 240
50
200 190
120
40 110
100 20 90
250 240
50
200 50 190
Since FCp values are constant, we could have replaced the calculation for H2, H3, H4 with a single expression:
H2,3,4=(1000+4000)(200-120)=400,000
Temperature
(oF) Plot Becomes the Hot Composite Curve
270
250
230
Temperature (deg F)
210
190
170
150
130
110
90
0 100 200 300 400 500 600
Enthalpy, 1000 BTU/hr
Temperature
(oF) Plot Becomes the Cold Composite Curve
*Ref. Douglas, 1988, Conceptual Design of Chemical Processes, McGraw-Hill Publishers, p. 218.
210
190
Temperature (deg F)
170
150
130
110
90
0 100 200 300 400 500 600 700
Enthalpy, 1000 BTU/hr
270
250
Temperature, deg F
230
210
190
170
150
130
110
90
0 200 400 600
Enthalpy, 1000 BTU/hr
Computer Aided process Engineering - Lecture 11 (R. Gani) 15
Hot Composite Stream
Cold Composite Stream at 10 deg F
Composite Curves minimum temperature driving force
Cold Composite Stream at 20 deg F
minimum temperature driving force
270
250
Temperature, deg F
230
210
190
170
150
130
110
90
0 200 400 600
Enthalpy, 1000 BTU/hr
Computer Aided process Engineering - Lecture 11 (R. Gani) 16
Composite Pinch Diagram
Pinch or
Tminimum
Process to Process
Heat Integration
Enthalpy
Computer Aided process Engineering - Lecture 11 (R. Gani) 17