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1- EG&G Technical Services and Science Applications International Corporation, (2002). Fuel
Cell Handbook, Sixth ed., US Department of Energy
2- Wang, X., Huang, B., Chen, T., Data-driven predictive control for solid oxide fuel cells
(2007). Journal of Process Control, 17 (2), pp. 103-114.
3- S.C. Singhal, K. Kendall,( 2003). High Temperature Solid Oxide Fuel Cells: Fundamentals,
Design and Applications, Elsevier Ltd., Oxford,
4- Stiller, C., Thorud, B., Bolland, O., Kandepu, R., Imsland, L., Control strategy for a solid
oxide fuel cell and gas turbine hybrid system(2006). Journal of Power Sources, 158, pp. 303
315.
5- Aguiar, P., Adjiman, C. S., Brandon, N. P., Anode-supported intermediate temperature direct
internal reforming solid oxide fuel cell. II. Model-based dynamic performance and control.
Journal of Power Sources, 138, 2004, pp. 136-147.
6- Jurado, F., Predictive control of solid oxide fuel cells using fuzzy Hammerstein
models(2006). Journal of Power Sources, 158, pp. 245253.
7- Chaisantikulwat, A., Diaz-Goano, C., Meadows, E. S., Dynamic modelling and control of
planar anode-supported solid oxide fuel cell(2008). Computers & Chemical Engineering, 32,
pp. 2365-2381.
8- Jiang, W., Fang, R., Khan, J., Dougal, R., Control Strategies for Start-Up and Part-Load
Operation of Solid Oxide Fuel Cell/Gas Turbine Hybrid System (2010). ASME Journal of
Fuel Cell Science and Technology, February, Vol. 7, p. 011016
9- R. J. Braun, (2002). Optimal design and operation of solid oxide fuel cell systems for small-
scale stationary applications, Ph.D. Thesis, University of Wisconsin Madison,
10- Campanari, S., Iora P., Definition and sensitivity analysis of a finite volume SOFC model for
a tubular cell geometry (2004). Journal of Power Sources, 132, pp. 113-126.

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14- Achenbach, E., Three-dimensional and time-dependent simulation of a planar solid oxide fuel
cell stack (1994). Journal of Power Sources, 49, pp. 333-348
15- Qi, Y., Huang, B., Chuang, K.T., Dynamic modelling of solid oxide fuel cell: The effect of
diffusion and inherent impedance (2005). Journal of Power Sources, 150, pp. 32-47.