Chemistry 322
Inorganic Chemistry
Spring 2007
Problem Set 1
In solving the problems for this class, encourage you to work together using whatever
resources you need. Please answer the questions fully; use prose, calculations, figures and
references as appropriate to communicate your understanding. The organization and
comprehensibility of your answer is one basis for its evaluation, As always, the written work
that you hand in should be your own.
2, For trans-1,2-dibromo-1,2-dichloroethylene, of C2» symmetry,
Determine the symmetry elements and assign the point group of the following molecules or
ions. You will need to consult a general chemistry textbook if you do not remember how to
use VSEPR to obtain the correct structure of the molecules.
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a. List all the symmetry operations for the molecule. :
b. Write a set of transformation matrices that describe the effect of each symmetry operation
in the C2, point group on a set of coordinates x, y, z for a point. (Your answer should
consist of four 3 x 3 matrices.)
c. Using the terms along the diagonal, obtain as many irreducible representations as
possible from the transformation matrices. (You should be able to obtain three
irreducible representations in this way, but two will be duplicates.)
4. Using the Cz, character table, verify that the irreducible representations are mutually
orthogonal
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