Problema 12.

63 Valoracin de un cido dbil con base fuerte a) Ca=20mM Cb=100mM

Cb= pH [H+] [OH-] Alfa (A-) Fi Vb (mL)

1.00E-01 3 0.001 1.00E-11 9.99E-04 -4.85E-02 -4.85E-01
Ca= 3.86 0.00013804 7.24E-11 7.19E-03 2.90E-04 2.90E-03
2.00E-02 4 0.0001 1.00E-10 9.90E-03 4.90E-03 4.90E-02
Va= 5 0.00001 1.00E-09 9.09E-02 9.04E-02 9.04E-01
50 6.15 7.0795E-07 1.41E-08 5.85E-01 5.85E-01 5.85E+00
Ka= 7 0.0000001 1.00E-07 9.09E-01 9.09E-01 9.09E+00
1.00E-06 8 0.00000001 1.00E-06 9.90E-01 9.90E-01 9.90E+00
Kw= 9.18 6.6069E-10 1.51E-05 9.99E-01 1.00E+00 1.00E+01
1.00E-14 10 1E-10 1.00E-04 1.00E+00 1.01E+00 1.01E+01
11 1E-11 1.00E-03 1.00E+00 1.06E+00 1.06E+01
12 1E-12 1.00E-02 1.00E+00 1.67E+00 1.67E+01

C4 = 10^-B4
D4=$A$12/C4
E4=$A$10/(C4+$A$10)
F4=(E4-(C4-D4)/$A$6)/(1+(C4-D4)/$A$4)
G4= F4*$A$6*$A$8/$A$4)

Vb Vb pH
-4.85E-01 3
2.90E-03 3.86
14 4.90E-02 4
12 9.04E-01 5
10 5.85E+00 6.15
pH
9.09E+00 7
8
9.90E+00 8
pH

6 1.00E+01 9.18
4 1.01E+01 10
2 1.06E+01 11
0
1.67E+01 12
-5.00E+00 0.00E+00 5.00E+00 1.00E+01 1.50E+01 2.00E+01
Problema 12.63 Valoracin de un cido dbil con base fuerte b) Ca=2mM Cb=10mM

Cb= pH [H+] [OH-] Alfa (A-) Fi Vb (mL)

1.00E-02 3 0.001 1.00E-11 9.99E-04 -4.54E-01 -4.54E+00
Ca= 3.94 0.00011482 8.71E-11 8.63E-03 -4.82E-02 -4.82E-01
2.00E-03 4 0.0001 1.00E-10 9.90E-03 -3.97E-02 -3.97E-01
Va= 4.4 3.9811E-05 2.51E-10 2.45E-02 4.58E-03 4.58E-02
50 6.15 7.0795E-07 1.41E-08 5.85E-01 5.85E-01 5.85E+00
Ka= 7 0.0000001 1.00E-07 9.09E-01 9.09E-01 9.09E+00
1.00E-06 8 0.00000001 1.00E-06 9.90E-01 9.91E-01 9.91E+00
Kw= 9.18 6.6069E-10 1.51E-05 9.99E-01 1.01E+00 1.01E+01
1.00E-14 10 1E-10 1.00E-04 1.00E+00 1.06E+00 1.06E+01
10.5 3.1623E-11 3.16E-04 1.00E+00 1.20E+00 1.20E+01
12 1E-12 1.00E-02 1.00E+00 6.00E+10 6.00E+11

C4 = 10^-B4
D4=$A$12/C4
E4=$A$10/(C4+$A$10)
F4=(E4-(C4-D4)/$A$6)/(1+(C4-D4)/$A$4)
G4= F4*$A$6*$A$8/$A$4)

pH vs Vb
12
10
8
pH vs Vb
6
4
2
0
0.00E+00 5.00E+00 1.00E+01 1.50E+01
Problema 12.63 Valoracin de un cido dbil con base fuerte c) Ca=.2mM Cb=1mM

Cb= pH [H+] [OH-] Alfa (A-) Fi Vb (mL)

1.00E-03 3 0.001 1.00E-11 9.99E-04 -2.50E+00 -2.50E+01
Ca= 3.93 0.00011749 8.51E-11 8.44E-03 -5.18E-01 -5.18E+00
2.00E-04 4 0.0001 1.00E-10 9.90E-03 -4.46E-01 -4.46E+00
Va= 4.87 1.349E-05 7.41E-10 6.90E-02 1.55E-03 1.55E-02
50 5 0.00001 1.00E-09 9.09E-02 4.05E-02 4.05E-01
Ka= 5.5 3.1623E-06 3.16E-09 2.40E-01 2.24E-01 2.24E+00
1.00E-06 5.8 1.5849E-06 6.31E-09 3.87E-01 3.78E-01 3.78E+00
Kw= 6.15 7.0795E-07 1.41E-08 5.85E-01 5.82E-01 5.82E+00
1.00E-14 7 0.0000001 1.00E-07 9.09E-01 9.09E-01 9.09E+00
8 0.00000001 1.00E-06 9.90E-01 9.96E-01 9.96E+00
9 1E-09 1.00E-05 9.99E-01 1.06E+00 1.06E+01
10 1E-10 1.00E-04 1.00E+00 1.67E+00 1.67E+01
11 1E-11 1.00E-03 1.00E+00 6.00E+08 6.00E+09
12 1E-12 1.00E-02 1.00E+00 -5.67E+00 -5.67E+01
C4 = 10^-B4
D4=$A$12/C4 12
E4=$A$10/(C4+$A$10)
10
F4=(E4-(C4-D4)/$A$6)/(1+(C4-D4)/$A$4)
G4= F4*$A$6*$A$8/$A$4) 8

6
Column B
4

0
0.00E+00 1.00E+01 2.00E+01
Problema 12.64 Influencia del pKb en la valoracinde una base dbil con un cido fuerte. Kb=-2

Ca= pH [H+] [OH-] Alfa (BH+) Fi Va (mL)

1.00E-01 2 0.01 1.00E-12 1.00E-04 5.56E-01 5.56E+00
Cb= 2.9 0.00125893 7.94E-12 1.26E-05 6.38E-02 6.38E-01
2.00E-02 3.5 0.00031623 3.16E-11 3.16E-06 1.59E-02 1.59E-01
Vb= 4 0.0001 1.00E-10 1.00E-06 5.01E-03 5.01E-02
50 4.5 3.1623E-05 3.16E-10 3.16E-07 1.58E-03 1.58E-02
K(BH+)= 5 0.00001 1.00E-09 1.00E-07 5.00E-04 5.00E-03
1.00E+02 6 0.000001 1.00E-08 1.00E-08 4.95E-05 4.95E-04
Kw= 7 0.0000001 1.00E-07 1.00E-09 1.00E-09 1.00E-08
1.00E-14 1 0.1 1.00E-13 9.99E-04 5.00E+12 5.00E+13

C4 = 10^-B4
D4=$A$12/C4
E4=$A$10/(C4+$A$10)
F4=(E4-(C4-D4)/$A$6)/(1+(C4-D4)/$A$4)
G4= F4*$A$6*$A$8/$A$4)

Ph vs Va
8
7
6
5
Ph vs Va
4
3
2
1
0
0.00E+001.00E+002.00E+003.00E+004.00E+005.00E+006.00E+00
Problema 12.64 Influencia del pKb en la valoracinde una base dbil con un cido fuerte. Pkb=2

Ca= pH [H+] [OH-] Alfa (BH+) Fi Va (mL)

1.00E-01 2 0.01 1.00E-12 5.00E-01 1.11E+00 1.11E+01
Cb= 2.9 0.00125893 7.94E-12 1.12E-01 1.77E-01 1.77E+00
2.00E-02 3.5 0.00031623 3.16E-11 3.07E-02 4.66E-02 4.66E-01
Vb= 4 0.0001 1.00E-10 9.90E-03 1.49E-02 1.49E-01
50 4.5 3.1623E-05 3.16E-10 3.15E-03 4.73E-03 4.73E-02
K(BH+)= 6 0.000001 1.00E-08 1.00E-04 1.49E-04 1.49E-03
1.00E-02 7.2 6.3096E-08 1.58E-07 6.31E-06 1.54E-06 1.54E-05
Kw=
1.00E-14 8
7
6
5
4
Column B
3
2
1
0
0.00E+00 5.00E+00 1.00E+01 1.50E+01
Problema 12.64 Influencia del pKb en la valoracinde una base dbil con un cido fuerte. Pkb=6

Ca= pH [H+] [OH-] Alfa (BH+) Fi Va (mL)

1.00E-01 2 0.01 1.00E-12 1.00E+00 1.67E+00 1.67E+01
Cb= 2.5 0.00316228 3.16E-12 1.00E+00 1.20E+00 1.20E+01
2.00E-02 2.9 0.00125893 7.94E-12 9.99E-01 1.08E+00 1.08E+01
Vb= 3.5 0.00031623 3.16E-11 9.97E-01 1.02E+00 1.02E+01
50 4 0.0001 1.00E-10 9.90E-01 9.96E-01 9.96E+00
K(BH+)= 4.5 3.1623E-05 3.16E-10 9.69E-01 9.71E-01 9.71E+00
1.00E-06 5 0.00001 1.00E-09 9.09E-01 9.10E-01 9.10E+00
Kw= 5.5 3.1623E-06 3.16E-09 7.60E-01 7.60E-01 7.60E+00
1.00E-14 6 0.000001 1.00E-08 5.00E-01 5.00E-01 5.00E+00
6.5 3.1623E-07 3.16E-08 2.40E-01 2.40E-01 2.40E+00
7 0.0000001 1.00E-07 9.09E-02 9.09E-02 9.09E-01
8 0.00000001 1.00E-06 9.90E-03 9.85E-03 9.85E-02
8.15 7.0795E-09 1.41E-06 7.03E-03 6.96E-03 6.96E-02
9.15 7.0795E-10 1.41E-05 7.07E-04 1.21E-06 1.21E-05

9
8
7
6
5
4 Column B
3
2
1
0
0.00E+00 5.00E+00 1.00E+01 1.50E+01
Problema 12.64 Influencia del pKb en la valoracinde una base dbil con un cido fuerte. Pkb=4

Ca= pH [H+] [OH-] Alfa (BH+) Fi Va (mL)

1.00E-01 2 0.01 1.00E-12 9.90E-01 1.66E+00 1.66E+01
Cb= 2.9 0.00125893 7.94E-12 9.26E-01 1.00E+00 1.00E+01
2.00E-02 3.5 0.00031623 3.16E-11 7.60E-01 7.78E-01 7.78E+00
Vb= 4 0.0001 1.00E-10 5.00E-01 5.06E-01 5.06E+00
50 4.5 3.1623E-05 3.16E-10 2.40E-01 2.42E-01 2.42E+00
K(BH+)= 5 0.00001 1.00E-09 9.09E-02 9.14E-02 9.14E-01
1.00E-04 6 0.000001 1.00E-08 9.90E-03 9.95E-03 9.95E-02
Kw= 8.15 7.0795E-09 1.41E-06 7.08E-05 5.17E-07 5.17E-06
1.00E-14 9 1E-09 1.00E-05 1.00E-05 -4.90E-04 -4.90E-03
7 0.0000001 1.00E-07 9.99E-04 9.99E-04 9.99E-03
10
9
8
7
6
5
Column B
4
3
2
1
0
-5.00E+000.00E+005.00E+001.00E+011.50E+01
Problema 12.64 Influencia del pKb en la valoracinde una base dbil con un cido fuerte. Pkb=8

Ca= pH [H+] [OH-] Alfa (BH+) Fi Va (mL)

1.00E-01 2 0.01 1.00E-12 1.00E+00 1.67E+00 1.67E+01
Cb= 2.9 0.00125893 7.94E-12 1.00E+00 1.08E+00 1.08E+01
2.00E-02 3.5 0.00031623 3.16E-11 1.00E+00 1.02E+00 1.02E+01
Vb= 4 0.0001 1.00E-10 1.00E+00 1.01E+00 1.01E+01
50 4.5 3.1623E-05 3.16E-10 1.00E+00 1.00E+00 1.00E+01
K(BH+)= 6 0.000001 1.00E-08 9.90E-01 9.90E-01 9.90E+00
1.00E-08 7 0.0000001 1.00E-07 9.09E-01 9.09E-01 9.09E+00
Kw= 8 0.00000001 1.00E-06 5.00E-01 5.00E-01 5.00E+00
1.00E-14 8.15 7.0795E-09 1.41E-06 4.15E-01 4.14E-01 4.14E+00
9 1E-09 1.00E-05 9.09E-02 9.04E-02 9.04E-01
9.5 3.1623E-10 3.16E-05 3.07E-02 2.91E-02 2.91E-01
10.14 7.2444E-11 1.38E-04 7.19E-03 2.90E-04 2.90E-03
12
10
8
6
Column B
4
2
0
0.00E+00 5.00E+00 1.00E+01 1.50E+01
Problema 12.64 Influencia del pKb en la valoracinde una base dbil con un cido fuerte. Pkb=10

Ca= pH [H+] [OH-] Alfa (BH+) Fi Va (mL)

1.00E-01 1.8 0.01584893 6.31E-13 1.00E+00 2.13E+00 2.129959305E+01
Cb= 2 0.01 1.00E-12 1.00E+00 1.67E+00 1.666555567E+01
2.00E-02 2.2 0.00630957 1.58E-12 1.00E+00 1.40E+00 1.403900330E+01
Vb= 2.4 0.00398107 2.51E-12 1.00E+00 1.25E+00 1.248506394E+01
50 2.6 0.00251189 3.98E-12 1.00E+00 1.15E+00 1.154188271E+01
K(BH+)= 2.8 0.00158489 6.31E-12 9.99E-01 1.10E+00 1.095984280E+01
1.00E-06 3 0.001 1.00E-11 9.99E-01 1.06E+00 1.059596968E+01
Kw= 3.2 0.00063096 1.58E-11 9.98E-01 1.04E+00 1.036505388E+01
1.00E-14 3.4 0.00039811 2.51E-11 9.97E-01 1.02E+00 1.021466295E+01
3.6 0.00025119 3.98E-11 9.96E-01 1.01E+00 1.011133998E+01
3.8 0.00015849 6.31E-11 9.94E-01 1.00E+00 1.003244485E+01
4 0.0001 1.00E-10 9.90E-01 9.96E-01 9.960950990E+00
4.2 6.3096E-05 1.58E-10 9.84E-01 9.88E-01 9.881766123E+00
4.4 3.9811E-05 2.51E-10 9.75E-01 9.78E-01 9.778764529E+00
4.6 2.5119E-05 3.98E-10 9.62E-01 9.63E-01 9.632113633E+00
4.8 1.5849E-05 6.31E-10 9.41E-01 9.42E-01 9.415906981E+00
5 0.00001 1.00E-09 9.09E-01 9.10E-01 9.096818182E+00
5.2 6.3096E-06 1.58E-09 8.63E-01 8.64E-01 8.635629843E+00
5.4 3.9811E-06 2.51E-09 7.99E-01 7.99E-01 7.994707265E+00
5.6 2.5119E-06 3.98E-09 7.15E-01 7.15E-01 7.153960878E+00
5.8 1.5849E-06 6.31E-09 6.13E-01 6.13E-01 6.132254296E+00
6 0.000001 1.00E-08 5.00E-01 5.00E-01 5.000544505E+00
6.2 6.3096E-07 1.58E-08 3.87E-01 3.87E-01 3.868963151E+00
6.4 3.9811E-07 2.51E-08 2.85E-01 2.85E-01 2.847669605E+00
6.6 2.5119E-07 3.98E-08 2.01E-01 2.01E-01 2.007710022E+00
6.8 1.5849E-07 6.31E-08 1.37E-01 1.37E-01 1.368117888E+00
7 0.0000001 1.00E-07 9.09E-02 9.09E-02 9.090909091E-01
7.2 6.3096E-08 1.58E-07 5.94E-02 5.93E-02 5.934611681E-01
7.4 3.9811E-08 2.51E-07 3.83E-02 3.83E-02 3.827585408E-01
7.6 2.5119E-08 3.98E-07 2.45E-02 2.45E-02 2.448462681E-01
7.8 1.5849E-08 6.31E-07 1.56E-02 1.56E-02 1.557081104E-01
8 0.00000001 1.00E-06 9.90E-03 9.85E-03 9.851392570E-02
8.2 6.3096E-09 1.58E-06 6.27E-03 6.19E-03 6.190985431E-02
8.4 3.9811E-09 2.51E-06 3.97E-03 3.84E-03 3.839794053E-02
8.6 2.5119E-09 3.98E-06 2.51E-03 2.31E-03 2.306572908E-02
8.8 1.5849E-09 6.31E-06 1.58E-03 1.27E-03 1.266905937E-02
9 1E-09 1.00E-05 9.99E-04 4.99E-04 4.990011039E-03

10
Colu
8 mn B
6
4
2
0
0.0E+00 1.0E+01 2.0E+01 3.0E+01
4
2
0
0.0E+00 1.0E+01 2.0E+01 3.0E+01
Problema 12.66 Valoracin de un cido dbil con base fuerte H2A=.200 M NaOH=0.100 M
a) pk1=4, pk2=8
Cb= pH [H+] [OH-] Alfa (HA-) Alfa (A-2) Phi
1.00E-01 2.865 0.00136458 7.33E-12 6.83E-02 5.00E-07 4.99E-05
Ca= 4 0.0001 1.00E-10 5.00E-01 5.00E-05 4.95E-01
2.00E-02 5 0.00001 1.00E-09 9.08E-01 9.08E-04 9.09E-01
Va= 6 0.000001 1.00E-08 9.80E-01 9.80E-03 1.00E+00
50 7 0.0000001 1.00E-07 9.08E-01 9.08E-02 1.09E+00
Kw= 7.5 3.1623E-08 3.16E-07 7.60E-01 2.40E-01 1.24E+00
1.00E-14 8 0.00000001 1.00E-06 5.00E-01 5.00E-01 1.50E+00
K1= 9 1E-09 1.00E-05 9.09E-02 9.09E-01 1.91E+00
1.00E-04 9.5 3.1623E-10 3.16E-05 3.07E-02 9.69E-01 1.97E+00
K2= 10 1E-10 1.00E-04 9.90E-03 9.90E-01 2.00E+00
1.00E-08 11 1E-11 1.00E-03 9.99E-04 9.99E-01 2.07E+00
12 1E-12 1.00E-02 1.00E-04 1.00E+00 2.78E+00
Vb(mL)
C4=10^-B4 4.99E-04
D4= =$A$10/C4 4.95E+00
E4==C4*$A$12/(C4^2+C4*$A$12+$A$12*$A$14) 9.09E+00
F4=$A$12*$A$14/(C4^2+C4*$A$12+$A$12*$A$14) 1.00E+01
G4=(E4+2*F4-(C4-D4)/$A$6)/(1+(C4-D4)/$A$4) 1.09E+01
H4==G4*$A$6*$A$8/$A$4 1.24E+01
1.50E+01
14
1.91E+01
12 1.97E+01
10
2.00E+01
2.07E+01
8 2.78E+01
6 Column B

0
0.00E+00 1.00E+01 2.00E+01 3.00E+01
Problema 12.66 Valoracin de un cido dbil con base fuerte H2A=.200 M NaOH=0.100 M
b) pk1=4, pk2=6
Cb= pH [H+] [OH-] Alfa (HA-) Alfa (A-2)
1.00E-01 2.865 0.00136458 7.33E-12 6.83E-02 5.00E-05
Ca= 4 0.0001 1.00E-10 4.98E-01 4.98E-03
2.00E-02 6 0.000001 1.00E-08 4.98E-01 4.98E-01
Va= 8 0.00000001 1.00E-06 9.90E-03 9.90E-01
50 10 1E-10 1.00E-04 1.00E-04 1.00E+00
Kw= 12 1E-12 1.00E-02 1.00E-06 1.00E+00
1.00E-14 Phi Vb(mL)
K1= 1.44E-04 1.44E-03
1.00E-04 5.02E-01 5.02E+00
K2= 1.49E+00 1.49E+01
1.00E-06 1.99E+00 1.99E+01
2.01E+00 2.01E+01
2.78E+00 2.78E+01

14

12

10

8
Column B
6

0
0.00E+00 1.00E+01 2.00E+01 3.00E+01
Problema 12.66 Valoracin de un cido dbil con base fuerte H2A=.200 M NaOH=0.100 M
c) pk1=4, pk2=5
Cb= pH [H+] [OH-] Alfa (HA-) Alfa (A-2) Phi
1.00E-01 2.862 0.00137404 7.28E-12 6.78E-02 4.93E-04 9.08E-05
Ca= 4 0.0001 1.00E-10 4.76E-01 4.76E-02 5.66E-01
2.00E-02 5 0.00001 1.00E-09 4.76E-01 4.76E-01 1.43E+00
Va= 6 0.000001 1.00E-08 9.08E-02 9.08E-01 1.91E+00
50 8 0.00000001 1.00E-06 9.99E-04 9.99E-01 2.00E+00
Kw= 10 1E-10 1.00E-04 1.00E-05 1.00E+00 2.01E+00
1.00E-14 12 1E-12 1.00E-02 1.00E-07 1.00E+00 2.78E+00
K1= Vb(mL)
1.00E-04 9.08E-04
K2= 5.66E+00
1.00E-05 1.43E+01
1.91E+01
2.00E+01
2.01E+01
2.78E+01

pH vs Vb
14
12
10
pH vs Vb
8
6
4
2
0
0.00E+00 1.00E+01 2.00E+01 3.00E+01
Problema 7.32 Valoracin de 100 mL de (C2O4)-2 0.100 M con La 3+ 0.100M

Kps La2(C2O4)3= pLa+3 [La+3] [C2O4]-2 Vm

1.00E-25 11 1E-11 0.1 0.000000006
Vo 10.9 1.2589E-11 0.08576959 6.03572758
100 10.5 3.1623E-11 0.04641589 27.28094564
Co(C2O4) 10 1E-10 0.02154435 45.73491038
0.1 8 0.00000001 0.001 65.56293035
Co(La) 7 0.0000001 0.00021544 66.42779455
0.1 6 0.000001 4.6416E-05 66.61677506
5.1 7.9433E-06 1.1659E-05 66.66695087
4 0.0001 2.1544E-06 66.83110159
2.9 0.00125893 3.9811E-07 68.79117366
2.5 0.00316228 2.1544E-07 72.1089834
2.4 0.00398107 1.8478E-07 73.57666431
2 0.01 0.0000001 85.18504801
1.9 0.01258925 8.577E-08 90.67055882
1.8 0.01584893 7.3564E-08 98.05639233

C4= =10^-B4
D4= =(($A$4)/C4^2)^(1/3)
E4==$A$6*(2*$A$8+3*C4-2*D4)/(3*$A$10-3*C4+2*D4)

pH vs Vm
12
10
8
Axis Title 6 Vm
4
2
0
0 20 40 60 80 100 120
Axis Title
Problema 12.35 Preparar un grfico de segunda derivada para hallar el punto final de la valoracin cuyo
Datos datos se indican a continuacin.
mL NaOH pH 1era derivada 2da derivada
10.679 7.643 mL pH/mL mL (pH/mL)/mL)
10.6875 -11.529412
10.696 7.447 10.696 -553.6332179931
10.7045 -20.941176
10.713 7.091 10.71075 -2234.7058823526
10.717 -48.875
10.721 6.7 10.72 -11770.833333336
10.723 -119.5
10.725 6.222 10.725 -21374.9999999952
10.727 -205
10.729 5.402 10.729 25687.500000017
10.731 -102.25
10.733 4.993 10.73325 12411.111111101
10.7355 -46.4
10.738 4.761 10.73975 2350.9803921582
10.744 -26.416667
10.75 4.444 10.75075 885.1851851851
10.7575 -14.466667
10.765 4.227

C5= (A6+A4)/2 E6=(C7+C5)/2

D5=(B6-B4)/(A6-A4) F6=(D7-D5)/(C7-C5)

(pH/mL)/mL)
30000
20000
10000 (pH/mL)/mL)
Axis Title 0 Moving average
10.68 10.7 10.72 10.74 10.76 ((pH/mL)/mL))
-10000
-20000
-30000
Axis Title