Professional Documents
Culture Documents
MIT6 007S11 Lec41 PDF
MIT6 007S11 Lec41 PDF
at a Potential Step
Outline
1
Schrodinger: A Wave Equation for Electrons
E = = j px = k = j
t x
p2
E= (free-particle)
2m
2 2
j = (free-particle)
t 2m x2
2 2 (x)
E(x) = 2
+ V (x)(x)
2m x
The quantity | |2 dx is interpreted as the probability that the particle can be
found at a particular point x (within interval dx)
2 ||2
P (x) = || dx
n=3
0 L x
Dr. Akira Tonomura, Hitachi, Ltd., Japan. All rights reserved. This content is
excluded from our Creative Commons license. For more information, see
http://ocw.mit.edu/fairuse.
3
Schrodinger Equation and Particle in a Box
2 2 (x)
E(x) = 2
+ V (x)(x)
2m x
2 n x
2
(x) = sin P (x) = |(x)| dx
L L
EIGENENERGIES for EIGENSTATES for PROBABILITY
1-D BOX 1-D BOX DENSITIES
3
x x
2
x x
1
x x
0 L 0 L
4
Semiconductor Nanoparticles
(aka: Quantum Dots)
Determining QD energy
Core Shell
using the Schrdinger Equation
Core
Quantum 2 2 k12 2 2
Dot E1 = n E 1 E1 = =
2m 2mL2
9E1B
Red: bigger dots!
Blue: smaller dots!
9E1R
4E1B
4E1R
E1B E1R
3KRWRE\-+DOSHUW&RXUWHV\RI0%DZHQGL*URXS&KHPLVWU\0,7
LBLUE QD LRED QD
5
Solutions to Schrodingers Equation
2 2
2
= (E V (x))
2m x
6
The Wavefunction
2
|| dx corresponds to a physically meaningful quantity
- the probability of finding the particle near x
d
dx is related to the momentum probability density -
dx - the probability of finding a particle with a particular momentum
(a) 7
(b) 8 x
(c) 9
V(x) V(x)
V(x)
(a) (b) (c)
E E E
L L L
8
WHICH WAVEFUNCTION CORRESPONDS TO WHICH POTENTIAL WELL ?
(A)
(1)
(B)
(2)
(C)
(3)
NOTICE THAT FOR FINITE POTENTIAL WELLS WAVEFUNCTIONS ARE NOT ZERO AT THE WELL BOUNDARY
9
A = Aejk1 x C = Cejk1 x
A Simple
Potential Step B = Bejk1 x
E = Eo
V
CASE I : Eo > V
E=0
Region 1 Region 2
x
x=0
2 2 2mEo
In Region 1: Eo = k12 =
2m x2 2
2 2 2m (Eo V )
In Region 2: (Eo V ) = k22 =
2m x2 2
10
A = Aejk1 x C = Cejk1 x
A Simple
Potential Step B = Bejk1 x
E = Eo
V
CASE I : Eo > V
E=0
Region 1 Region 2
x
x=0
is continuous: k2
(0) = 2 (0) AB = C
x x x k1
11
A = Aejk1 x C = Cejk1 x
A Simple
Potential Step B = Bejk1 x
E = Eo
V
CASE I : Eo > V
E=0
Region 1 Region 2
x
x=0
A+B =C
B 1 k2 /k1 C 2
= =
A 1 + k2 /k1 A 1 + k2 /k1
k2
k1 k 2 2k1 AB = C
= = k1
k1 + k2 k1 + k2
12
Example from: http://phet.colorado.edu/en/get-phet/one-at-a-time
13
Quantum Electron Currents
2
J = v = q || (k/m)
14
A = Aejk1 x C = Cejk1 x
A Simple
Potential Step B = Bejk1 x
E = Eo
V
CASE I : Eo > V
E=0
Region 1 Region 2
x
x=0
2
Jref lected JB |B | (k1 /m) B
2
Reection = R = = = 2
=
Jincident JA |A | (k1 /m) A
2
Jtransmitted JC |C | (k2 /m) C k2
2
Transmission = T = = = 2
=
Jincident JA |A | (k1 /m) A k1
B 1 k2 /k1 C 2
= =
A 1 + k2 /k1 A 1 + k2 /k1
15
A = Aejk1 x C = Cejk1 x
A Simple
Potential Step B = Bejk1 x
E = Eo
V
CASE I : Eo > V
E=0
Region 1 Region 2
x
x=0
2 2
B k1 k2
Reection = R = =
1
A k1 + k2
T
Transmission = T = 1 R
T +R=1
4k1 k2
= 2
R |k1 + k2 |
1
k2 V
= 1
Eo = V Eo = k1 Eo
16
IBM Almaden STM of Copper
IBM Corporation. All rights reserved. This content is excluded from our Creative Commons
license. For more information, see http://ocw.mit.edu/fairuse.
17
IBM Almaden
Image originally created by the IBM Corporation.
IBM Corporation. All rights reserved. This content is excluded from our Creative Commons
license. For more information, see http://ocw.mit.edu/fairuse.
18
IBM Almaden
Image originally created by the IBM Corporation.
IBM Corporation. All rights reserved. This content is excluded from our Creative Commons
license. For more information, see http://ocw.mit.edu/fairuse.
19
A = Aejk1 x C = Cex
A Simple
Potential Step B = Bejk1 x
V
CASE II : Eo < V E = Eo
E=0
Region 1 Region 2
x
x=0
2 2 2mEo
In Region 1: Eo = k12 =
2m x2 2
2 2 2 2m (Eo V )
In Region 2: (Eo V ) = =
2m x2 2
20
A = Aejk1 x C = Cex
A Simple
Potential Step B = Bejk1 x
V
CASE II : Eo < V E = Eo
E=0
Region 1 Region 2
x
x=0
1 = Ae jk1 x
+ Be jk1 x 2 = Cex
is continuous:
(0) = 2 (0) A B = j C
x x x k1
21
A = Aejk1 x C = Cex
A Simple
Potential Step B = Bejk1 x
V
CASE II : Eo < V E = Eo
E=0
Region 1 Region 2
x
x=0
A+B =C
B 1 + j/k1 C 2
= =
A 1 j/k1 A 1 j/k1
A B = j C
2 k1
B
R = = 1 T =0
A
Total reflection Transmission must be zero
22
Quantum Tunneling Through a Thin Potential Barrier
R=1 T =0
T = 0
23
KEY TAKEAWAYS CASE I : Eo > V
2
B k 1 k 2 2
Ref lection = R = =
A k1 + k2
Region 1 Region 2
4 k1 k2
T ransmission = T = 1 R = 2
|k1 + k2 |
PARTIAL REFLECTION
CASE II : Eo < V
Region 1 Region 2
TOTAL REFLECTION
24
A = Aejk1 x C = Cex F = F ejk1 x
A Rectangular
Potential Step B = Bejk1 x D = Dex
V
CASE II : Eo < V E = Eo
E=0
a 0 a
Region 1 Region 2 Region 3
2 2 2mEo
In Regions 1 and 3: Eo = k12 =
2m x2 2
2 2 2 2m(V Eo )
In Region 2: (Eo V ) = =
2m x2 2
2
F 1
for Eo < V : T = =
A 1+ 1 V2
4 Eo (V Eo ) sinh2 (2a)
25
A Rectangular
Potential Step
E U
for Eo < V :
2
F 1
T = =
A 1+ 1 V2
4 Eo (V Eo ) sinh2 (2a)
2
2a
2a 2
sinh (2a) = e e e4a
2
F 1
T = 2 e 4a
A 1 + 14 Eo (VV Eo )
26
Flash Memory
Stored
Electrons
Erased Programmed
1 0
SOURCE DRAIN
CHANNEL
Channel
x
Substrate
V (x)
Control Gate
Conducting Channel
Semiconductor
,PDJHFRXUWHV\RI-+R\W*URXS((&60,7
3KRWRE\/*RPH]
,PDJHFRXUWHV\RI-+R\W*URXS((&60,7
3KRWRE\/*RPH]
UNPROGRAMMED PROGRAMMED
SILICON
2me 2me 6eV 1
= (V Eo ) = 2 (V Eo ) = 2 12.6 nm
2 h 2
1.505eV-nm2
Sodium atoms
on metal:
E0 V
Single walled
carbon nanotube:
STM images
Image originally created
by IBM Corporation
IBM Corporation. All rights reserved. This content is excluded from our Creative
Commons license. For more information, see http://ocw.mit.edu/fairuse. Image is in the public domain
32
MIT OpenCourseWare
http://ocw.mit.edu
For information about citing these materials or our Terms of Use, visit: http://ocw.mit.edu/terms.