STT Tn K hiu S liu n v

Nng sut yu cu 650000 tn/nm

Nhit phn ng t 441 0C
p sut p 137 bar
H2 65.92 % mol
N2 21.98 % mol
Thnh phn cu t u vo Ar 1.87 % mol
CH4 6.13 % mol
NH3 4.1 % mol
thnh phn cu t u ra H2 55.42 % mol
thnh phn cu t u ra N2 18.48 % mol
thnh phn cu t u ra Ar 2.1 % mol
thnh phn cu t u ra CH4 6.9 % mol
thnh phn cu t u ra NH3 17.1 % mol
Thnh phn kh nguyn liu sau khi tun hon H2 74.03 % mol
Thnh phn kh nguyn liu sau khi tun hon N2 24.67 % mol
Thnh phn kh nguyn liu sau khi tun hon Ar 0.3 % mol
Thnh phn kh nguyn liu sau khi tun hon CH4 1 % mol
Thnh phn kh nguyn liu sau khi tun hon NH3 0 % mol
Nguyn t khi H2 2 g/mol
Nguyn t khi N2 28 g/mol
Nguyn t khi Ar 40 g/mol
Nguyn t khi CH4 16 g/mol
Nguyn t khi NH3 17 g/mol
Thnh phn kh sau khi tch kh tr H2 63.17 % mol
Thnh phn kh sau khi tch kh tr N2 21.07 % mol
Thnh phn kh sau khi tch kh tr Ar 2.40 % mol
Thnh phn kh sau khi tch kh tr CH4 7.87 % mol
Thnh phn kh sau khi tch kh tr NH3 5.49 % mol
S mol N2 phn ng a 2389.97 kmol/h
S NH3 trong dng vo thp b 1756.11 kmol/h
khi lng cc cu t vo thp phn ng GH2 56759.06 Kg/h
khi lng cc cu t vo thp phn ng GN2 264955.97 Kg/h
khi lng cc cu t vo thp phn ng GAr 32202.50 Kg/h
khi lng cc cu t vo thp phn ng GCH4 42224.88 Kg/h
khi lng cc cu t vo thp phn ng GNH3 30006.87 Kg/h
khi lng cc cu t ra khi thp phn ng GH2 42420.75 Kg/h
khi lng cc cu t ra khi thp phn ng GN2 198034.95 Kg/h
khi lng cc cu t ra khi thp phn ng Gar 32148.53 Kg/h
khi lng cc cu t ra khi thp phn ng GCH4 42252.35 Kg/h
khi lng cc cu t ra khi thp phn ng GNH3 111256.88 Kg/h
khi lng cu t sau khi tun hon GH2 16137.22 Kg/h
khi lng cu t sau khi tun hon GN2 75286.67 Kg/h
khi lng cu t sau khi tun hon Gar 1307.89 Kg/h
khi lng cu t sau khi tun hon GCH4 1743.86 Kg/h
 khi lng cu t sau khi tun hon GNH3 0.00 Kg/h
khi lng cu t sau khi tch kh tr GH2 40621.84 Kg/h
khi lng cu t sau khi tch kh tr GN2 189669.30 Kg/h
khi lng cu t sau khi tch kh tr Gar 30894.61 Kg/h
khi lng cu t sau khi tch kh tr GCH4 40481.02 Kg/h
khi lng cu t sau khi tch kh tr GNH3 30006.87 Kg/h
khi lng cc cu t trong dng kh tr GH2 1787.85 Kg/h
khi lng cc cu t trong dng kh tr GN2 8347.73 Kg/h
khi lng cc cu t trong dng kh tr Gar 1359.73 Kg/h
khi lng cc cu t trong dng kh tr GCH4 1781.65 Kg/h
khi lng cc cu t trong dng kh tr GNH3 1320.66 Kg/h
Nhit dng nguyn liu i ngoi ng t1.vao -5 oC
Nhit dng nguyn liu i ngoi ng t1.ra 30 oC
Lng nhit cn trao i delta Q 9894.00 kw
Nhit dng sn phm i trong ng t2.vao 70.5 oC
Nhit dng sn phm i trong ng t2.ra 43.1 oC
Khi lng ring ca dng nguyn liu
nht ca dng nguyn liu
Trang Ti liu tham kho
STT Tn K hiu s liu
Tng lu lng mol cu t vo thp n1 43051.47
Tng lu lng mol cu t ra n2 38272.06
lu lng mol N2 phn ng a 2389.97
lu lng mol NH3 vo thp b 1765.11
1
2 Nng sut lm vic Ar 81259
H2 2
N2 28
Nguyn t khi Ar 40
CH4 16
3 NH3 17
GH2 56759.06
GN2 264955.97
Lu lng cc cu t vo thp GAr 32202.50
GCH4 42224.88
4 GNH3 30006.87
GH2 42420.75
GN2 198034.95
Lu lng cc cu t ra khi thp GAr 32148.53
GCH4 42252.35
5 GNH3 111256.88

K 2.95
6

lu lng mol kh nguyn liu n5

7 10899.1063291
8 Lu lng dng TH sau khi tch kh tr n4 32152.3636709
H2 0.6317
N2 0.2107
Thnh phn kh TH sau khi tch kh tr Ar 0.0240
CH4 0.0787
9 NH3 0.0549
GH2 16137.22
GN2 75286.67
Lu lng cu t dng kh nguyn liu GAr 1307.89
GCH4 1743.86
10 GNH3 0.00
GH2 40621.84

Lu lng dng TH sau khi tch kh tr

11
 GN2 189669.30
Lu lng dng TH sau khi tch kh tr GAr 30894.61
GCH4 40481.02
11 GNH3 30006.87
12 Tng mol dng kh tr thot ra n3 1415.09
GH2 1787.85
GN2 8347.73
Lu lng cc cu t trong dng kh tr GAr 1359.73
GCH4 1781.65
13 GNH3 1320.66
 Cng thc
{(/_1
=0,041@(2+)/_2
=0,171@_2=_12)

Gx=n1.x1x.Mx

Gx=n2.x2x.Mx

n4=k.n5

Gx=n5.x5x.Mx

Gx=n4.x4x.Mx
Gx=n4.x4x.Mx

Gx=n3.x3x.Mx
Thng s u vo pt
Nhit ( K) 408.34 H s
p sut ( Barg) 137 CH4
Tc dng (kmol/h) 32152.27 H2
Thnh phn kh vo (%Vol) N2
CH4 0.0787 NH3
H2 0.6317 Ar
N2 0.2107
NH3 0.0549
Ar 0.024
tng 1
Thng s u ra 32152.27
Nhit ( K) 303
p sut ( Barg) 137 Dng sn phm i trong ng vo
Tc dng (kmol/h) Nhit (K) 268.15
Thnh phn kh ra (%Vol) Cp( kJ/kmol.K) 29.37728907
CH4 0.0787 Q=G.Cp.T (kW) 70355.59778
H2 0.6317 delta(Q) 9894.24
N2 0.2107
NH3 0.0549
Ar 0.024
tng 1
 pt: Cp=a+bT+cT^2+dT^-2
a b c d H kj/kmol S kj/kmol
1.313551987 0.0992904207 -2.760368E-05 642858.9849
31.99958849 -0.0071480057 5.55277E-06 -135652.7335 0 130.68
27.05482428 0.0032151173 2.63174E-06 77927.82117 0 191.608
19.36121341 0.0504328233 -1.396731E-05 219908.3146 -45940 192.768
20.786 0 0 0

ra
303
29.65462255
80249.83877
9894.24
 ti nhit 268 Ti nhit 303
Cp(kJ/kmol.K) Cp(kCal/kmol.K) Cp(kJ/kmol.K) Cp(kCal/kmol.K)
34.8939168034 8.3362599272 35.8664179105 8.568593318
28.595549393 6.8315613247 28.8659832722 6.8961687783
29.1899612449 6.9735680742 29.1194259644 6.956716987
34.9388056139 8.3469839968 35.7553146903 8.5420504301
20.786 4.9658368771 20.786 4.9658368771
 pt: Cp=a+bT+cT^2+dT^-2
Nhit Cp
t1vao 268.15 CH4
t1ra 303 H2
t2vao 346.15 25.21845 N2
t2ra NH3
Ar

Thng s u vo
Nhit ( K) 408.34
p sut ( Barg) 137
Tc dng (kmol/h) 32152.27
Thnh phn kh vo (%Vol)
CH4 0.0787
H2 0.6317
N2 0.2107
NH3 0.0549
Ar 0.024
tng 1

Thng s u ra
Nhit ( K)
p sut ( Barg) 137
Tc dng (kmol/h) 38272.06
Thnh phn kh ra (%Vol)
CH4 0.069
H2 0.5542
N2 0.1848
NH3 0.171
Ar 0.021
tng 1
H s a b c
1.313551987 0.0992904207 -2.760368E-05
31.99958849 -0.007148006 5.55277E-06
27.05482428 0.0032151173 2.63174E-06
19.36121341 0.0504328233 -1.396731E-05
20.786 0 0

Nhit dung ring ca dng nguyn liu vo

Cp(kcal/kmol.K) 30.539759428 Dng tun hon
Nhit lng ca hn hp mang ra thp nhit (t)
Qr=Cp*Tr*Gr(Kcal/h) 369639168.52 Cp(kJ/kmol.K)
Qr(kW) 102677.54681 Qr=Cp*Tr*Gr(kW)

Nhit phn ng -106415.7654

Nhit lng phn ng
Qpu(kJ/h) 508599532.95 Dng tun hon
Qpu(kW) 141277.64804 nhit (t)
Nhit lng tn tht Cp(kJ/kmol.K)
Qtt=Qv+Qpu-Qr 38600.101229 Qr=Cp*Tr*Gr(kW)
Phn trm tiu hao delta(Q)
H=Qtt/(Qv+Qr)*100 27.322157301
Dng sn phm
nhit (t)
Cp(kJ/kmol.K)
Qr=Cp*Tr*Gr(kW)

Dng sn phm
Q2ra
T2(ra)
Cp2ra
lch
 ti nhit 268 Ti nhit t2 gi s
d H kj/kmol S kj/kmol Cp(kJ/kmol.K) Cp(kCal/kmol.K) Cp(kJ/kmol.K)
642858.9849 34.8939168034 8.3362599272 36.3810773186
-135652.7335 0 130.68 28.595549393 6.8315613247 28.9380501857
77927.82117 0 191.608 29.1899612449 6.9735680742 29.1139847761
219908.3146 -45940 192.768 34.9388056139 8.3469839968 36.1124403131
0 20.786 4.9658368771 20.786

vo
268.15
29.377289066
70355.597778

ra
303.15
29.655807589
80292.774898
9937.1771198

vo
343.65
30.825895077
112618.92621

ra
102681.74909
316.25
30.539759428
4.2022801931
Ti nhit t2 gi s ti nhit 303 ti nhit 343
Cp(kCal/kmol.K) Cp(kJ/kmolCp(kCal/kmol.K) Cp(kJ/kmolCp(kCal/kmol.K)
8.6915469728 35.87187 8.5698967978 37.6184 8.9871469421
6.9133857771 28.86688 6.8963824793 29.05026 6.94019327
6.9554170711 29.11931 6.956688743 29.13037 6.9593310076
8.6273687976 35.75924 8.5429881662 36.9051 8.8167386621
4.9658368771 20.786 4.9658368771 20.786 4.9658368771