CNG N TP KIM TRA 1 TIT LN 2 NM HC 2016-2017

I.Kin thc
- Khi nim Amin, amino axit, peptit v protein, polime, cht do
-Tnh cht ha hc ca amin, amino axit, peptit
- Cc phuong php iu ch polime Nm c mt s vt liu polime
II.K nng
- Rn k nng gii ton ha hc nhanh, chnh xc ph hp vi cu hi trc nghim
- Rn k nng gii cc bi tp xc nh CTPT, tm CTCT
- Rn k nng gii cc bi ton hiu sut
- Rn k nng gii cc bi ton v tm khi lng cht, th tch kh c trong PTHH
- Rn k nng vit ng phn v gi tn
III. Mt s cu hi trc nghim
Cu 1: Cho 9 gam etylamin tc dng va vi dung dch HCl ,khi lng mui thu c l :
A.19,596 gam B.16,100 gam C.12,650 gam D.16,300 gam
Cu 2: Cho cc cht sau : NH3(1),CH3NH2(2), C6H5NH2(3). Trt t sp xp cc cht theo chiu tng dn tnh bazo l :
A.(3),(2),(1) B.(3),(1),(2) C.(1),(2),(3) D.(2),(1),(3)
Cu 3: Nh vi git nc brom vo ng nghim ng sn anilin ,thy trong ng nghim xut hin kt ta trng . CTPT ca
cht kt ta l :
A. C6H6Br3N B. C6H8B3N C. C6H4Br3N D. C6H2Br3N
Cu 4: Cht c nhiu trong cy thuc l gy hi cho sc khe con ngi , l mt cht c thn kinh rt mnh vi nh hng
r rt n cc loi cn trng, do vy trong qu kh c s dng rng ri nh l mt loi thuc tr su . Tn ca n l :
A.Cocain B.Nicotin C.Heroin D.Cafein
Cu 5: S ng phn amin bc 1 c cng thc phn t C5H13N l :
A. 4 B. 8 C. 5 D. 6
Cu 6: Cho 15 gam hn hp 3 amin n chc bc 1 tc dng va vi dung dch HCl 1,2M thu c 18,504 gam hn
hp mui .Th tch dung dch HCl dng l :
A.0,4 lit B.0,04 lit C.0,8 lit D.0,08 lit
Cu 7: Gii php thc t no sau y khng hp l?
A. Nhn bit amin bng mi khai B. Kh mi tanh ca c trc khi nu bng gim n.
C. Nhn bit metylamin v anilin bng dung dch brom D. Ra l ng anilin bng axit mnh sau ra li bng nc.
Cu 8: Cng thc chung ca amin no, n chc, mch h l :
A.CnH2n-5N (n 6) B.CnH2n-1N (n 2) C.CnH2n+1N (n 2) D.CnH2n+3N (n 1)
Cu 9: t chy hon ton mt amin no, n chc mch h ,sau phn ng thu c 1,0752 lt CO 2(ktc) v 1,296 gam
H2O. Khi lng ca amin em t l :
A. 1,224 gam B. 0,944 gam C. 3,408 gam D. 0,72 gam
Cu 10: Nhn nh no sau y khng ng?
A. Cng thc tng qut ca amin no,n chc, mch h l CnH2n+3N B. Metyl amin c tnh baz mnh hn anilin.
C. Cc amin u c tnh baz yu D. Tnh baz ca cc amin u mnh hn NH3.
Cu 11: Dy gm cc cht c xp theo chiu tnh baz gim dn t tri qua phi l
A. C6H5NH2, NH3, CH3NH2. B. CH3NH2, NH3, C6H5NH2. C. CH3NH2, C6H5NH2, NH3.D. NH3, CH3NH2, C6H5NH2.
Cu 12: Anilin tc dng vi dung dch no sau y thu c kt ta trng ?
A.dung dch HCl B.dung dch Br2 C.dung dch NaOH D.dung dch NaCl
Cu 13: Sau thc hnh th nghim xong, ra dng c thy tinh ng anilin ngi ta :
A.trng bng dung dch axit ri ra li bng nc B.trng bng dung dch brom ri ra li bng nc
C.ch cn ra bng nc D.trng bng dung dch kim ri ra li bng nc
Cu 14: Hn hp gm valin v Gly-Ala. Cho a mol X vo 100 ml dung dch H2SO4 0,5M thu c dung dch Y . Cho Y
phn ng va vi 100 ml dung dch gm NaOH 1M v KOH 1,75M un nng, thu c dung dch cha 30,725 gam
mui .Gi tr ca a l :
A,0,175 B.0,275 C.0,150 D.0,125
Cu 15: X l mt a -amino axit ch cha 1 nhm NH=2= v 1 nhm COOH .Cho 8,9 gam X tc dng vi HCl va
to ra 12,55 gam mui . Cng thc cu to ca X l :
A.CH3-CH(NH2)-COOH B.CH3-CH(NH2)-CH2-COOH C.H2N-CH2-COOH D.C3H7-CH(NH2)-COOH
Cu 16: chng minh alanin c tnh lng tnh ,ngi ta cho tc dng vi
A.HNO3,CH3COOH B.KOH, NH3 C.HCl,KOH D.CaCO3,HCl
Cu 17: phn bit 3 dung dch : CH3NH2, H2NCH2COOH v CH3COOH th cn dng mt thuc th l :
A.dung dch NaOH B.Cu(OH)2 C.dung dch Br2 D.qu tm
Cu 18: Pht biu no sau y khng ng ?
A.Axit glutamic l cht ch c tnh axit
B. iu kin thng cc aminoaxit u l cc cht rn kt tinh ,nhit nng chy cao, d tan trong nc
 C.t chy hon ton mt aminoaxit X thu c a mol CO 2,b mol H2O, c mol N2 nu b=a+c th X c mt nhm
COOH
D.T Gly v Ala c th to ra 2 ipeptit khc nhau c mt Gly v Ala
Cu 19: Hp cht hu c X c cng thc phn t CH 6O3N2 .Cho 3,29 gam X tc dng vi 21 ml dung dch NaOH 2M thu
c cht hu c n chc Y v cc cht v c .C cn dung dch thu c sau phn ng c m gam cht rn .Gi tr ca
m l :
A. 4,97 B. 3,255 C. 4,27 D. 2,975
Cu 20: Cht no sau y ng thi tc dng c vi dung dch HCl v dung dch NaOH: (1)C 2H3COOC2H5,
(2)CH3COONH4 ; (3)H2N-CH2-COOH
A. (2) B. (1) C. (1),(2) v 3 D. (3)
Cu 21: Cho protein c khi lng phn t l 100000vC. Khi thy phn 500 gam protein ny th thu c 164,65 gam
alanin .S mc xich alanin c trong phn t protein ny l :
A.250 B.237 C.370 D.439
Cu 22: Cho 13,23 gam axit glutamic phn ng vi 200 ml dung dch HCl 1M, thu c dung dch X. Cho 400 ml dung
dch NaOH 1M vo X thu c dung dch Y .C cn dung dch Y thu c m gam cht rn khan. Bit cc phn ng xy ra
hon ton , gi tr ca m l :
A.28,89 B.29,69 C.29,96 D.29,33
Cu 23: C cc dung dch : CH3NH2 (1), anilin(2),HOOCCH(NH2)-COOH (3), H2N-CH(COOH)-NH2 (4), axit glutamic
(5),lysin (6). S cht lm qu tm chuyn sang mu xanh l :
A.2 B.3 C.5 D.4
Cu 24: Nhn nh no sau y khng ng khi ni v aminoaxit?
A. Aminoaxit l hp cht tp chc m phn t cha ng thi nhm cacboxyl v nhm amino.
B. Cc aminoaxit l nhng cht rn, c nhit nng chy cao v d tan trong nc v chng tn ti dng ion lng
cc.
C. Aminoaxit ngoi dng phn t (H2NRCOOH) cn c dng ion lng cc H3N+RCOO-.
D. Aminoaxit l cc hp cht hu c a chc c cha ng thi nhm COOH v nhm NH 2
Cu 25: Cho 35,7513 gam mt a -aminoaxit c 1 nhm COOH v 1 nhm NH2 phn ng ht vi NaOH .Sau phn ng
thu c 43,3875 gam mui , aminoaxit l :
A. Axit 2-aminopropanoic B. Axit 2-aminobutanoic C. Axit 2-amino-3-metylbutanoic D. Axit 2-aminoetanoic
Cu 26: Glyxin khng phn ng vi :
A.NaCl B.H2SO4 long C.CH3OH/HCl D.CaCO3
Cu 27: Aminoaxit X phn ng vi NaOH cho ra mui c cng thc phn t l C 3H6O2NNa . Aminoaxit X l :
A. Lysin B. Glyxin C. Valin D. Alanin
Cu 28: Cht no sau y c dng lm bt ngt :
A. HOOC-CH2-CH2-CH(NH2)-COONa B. NaOOC-CH2-CH2-CH(NH2)-COONa
C. HOOC-CH(NH2)-COONa D. HOOC-CH2-CH2-CH(NH2)-COOH
Cu 29: Cho cc dung dch ln lt cha cc cht sau :
X1 : C6H5 - NH2 X2 : CH3 - NH2 X3 : NH2 - CH2 COOH
HOOC - CH2 - CH2 - CH - COOH H2 N - CH2 - CH2 - CH 2 - CH - COOH
X4 : | X5 : |
NH2 NH2
Dung dch no lm qu tm ha xanh ?
A. X1, X2, X5 B. X2, X5 C. X1, X3, X5 D. X2, X3, X4
Cu 30: Thy phn 1 mol peptit X thu c 1 mol H 2N-CH2-COOH v 2 mol H2N-CH(CH3)-COOH , X c cng thc phn
t l :
A. C5H10O3N2 B. C7H13O4N3 C. C8H19O6N3 D. C8H15O4N3
Cu 31: S nhm NH2 v nhm COOH c trong phn t lysin ln lt l :
A. 1;1 B. 2;1 C. 1;2 D. 2;2
Cu 32: ng vi cng thc phn t C4H9NO2 c bao nhiu a -aminoaxit l ng phn cu to ca nhau ?
A. 2 B. 3 C. 4 D. 5
Cu 33: Pht biu no sau y sai?
A.Protein phn ng vi Cu(OH)2/OH- to sn phm c mu tm
B.Peptit l hp cht c cha t 11 n 50 gc a -amino axit lin kt bng cc lin kt peptit
C.Trong phn t ipeptit mch h c mt lin kt peptit
D.Amino axit l hp cht hu c tp chc cha ng thi nhm amino (-NH 2) v nhm cacboxyl(-COOH)
Cu 34: Mt peptit X c phn trm khi lng ca N l 18,767% (X c to ra t aminoaxit no c 1 nhm NH 2 v 1 nhm
COOH) .t chy hon ton 5,222 gam peptit X thu c 4,704 lt CO 2 (ktc) ,H2O v N2 .Cho ton b sn phm chy
vo bnh ng dung dch Ca(OH)2 ly d ,khi lng bnh ng dung dch Ca(OH) 2 tng ln bao nhiu gam ?
 A. 12,983 gam B. 11,207 gam C. 12,642 gam D. 10,396 gam
Cu 35: Da nhn to (PVC) c iu ch t kh thin nhin (CH4). Nu hiu sut ca ton b qu trnh l 20% th iu
ch 1 tn PVC phi cn mt th tch metan l:
3 3 3
A. 5500m3 B. 3500m C. 3560m D. 3584m
Cu 36: Mt polime c cng thc:
CH3
CH2 C
n
COOCH3
tn gi ca polime ny l :
A. poli(mety propionat) B. poli(metyl axetat) C. poli(metyl metacrylat) D. poli(metyl crylat)
Cu 37: Trong cng nghip polietilen(PE) c iu ch t metan theo s :
H =80% H = 80% H =80%
CH 4 C2 H 2 C2 H 4 PE . tng hp 5,376 kg PE theo s trn cn V m3 kh thin
nhin (ktc, cha 75% kh metan theo th tch) .Gi tr ca V l
A.11,2 B.22,4 C.28,0 D.16,8
Cu 38: Loi t no di y thng dng dt vi may qun o m hoc bn thnh si len an o rt ?
A.T capron B.T nilon-6,6 C.T lapsan D.T nitron
Cu 39: Polime no sau y thc t khng s dng lm cht do ?
A. Cao su buna B. Poli(viny clorua ) C. Poli(metyl metacrilat) D. Poli(phenol fomandehit)
Cu 40: S kt hp cc phn t nh (monome) ging nhau hay tng t nhau thnh cc phn t ln (polime) c gi l :
A.s polime ha B.S trng ngng C.S trng hp D.S oxi ha
Cu 41: Cht no sau y dng iu ch poli (vinyl clorua) (PVC)?
A.etilen B.Vinyl clorua C.Stiren D.axetilen
Cu 42: Polime no sau y l polime thin nhin?
A.t nitron B.cao su buna C.t tm D.nilon-6,6
Cu 43: Polime X trong phn t ch cha C, H v c th c O. H s trng hp ca phn t X l 1800, phn t khi l
154800. X l
A. PE (polietilen) B. PVC (poli(vinyl clorua)) C. PVA (poli (vinyl axetat)) D. Cao su isopren
Cu 44: T visco l thuc loi:
A. T tng hp B. T thin nhin c ngun gc ng vt
C. T thin nhin c ngun gc thc vt D. T nhn to
Cu 45: Polime no sau y c tng hp bng phn ng trng hp ?
A. poli(hexxametylen aipanmit) B. poli(etylen terephtalat)
C. poli(metyl metacrylat) D. policaproamit
Cu 46: Kt lun no sau y cha chnh xc ?
A. Vt liu compozit c thnh phn chnh l polime B. Nilon-6,6 thuc loi t tng hp
C. T tm thuc loi t thin nhin D. Cao su l nhng polime c tnh n hi
Cu 47: Mt loi polietien c c phn t khi l 34580 vC. Vy h s trng hp ca n l :
A.1535 B.5415 C.1235 D.1545
Cu 48: Phn t khi trung bnh ca polietilen X l 420000. H s polime ho ca PE l
A. 17.000 B. 13.000 C. 12.000 D. 15.000
Cu 49: Loi t no sau y thuc loi t nhn to ?
A.T nitron B.nilon-6,6 C.t visco, t axetat D.T tm
Cu 50: Clo ho PVC thu c t clorin. Trung bnh 5 mt xch PVC th c mt nguyn t H b clo ho.
% khi lng clo trong t clorin l
A. 61,38%. B. 60,33%. C. 63,96%. D. 70,45%.
Cu 51: Khi thy phn n cng protein n gin ta thu c sn phm l :
A. a -amino axit B.peptit C.glucoz D. b -amino axit
Cu 52: Thu phn hon ton 1250 gam protein X thu c 425 gam alanin. Nu phn t khi ca X bng
100.000 vC th s mt xch alanin c trong phn t X l
A. 328. B. 453. C. 479. D. 382.
CH2 CH n
OOCCH3
Cu 53: Polime c tn l :
A. Poli (metyl acrylat) B. Poli (vinyl axetat) C. Poli acrilonitrin D. Poli (metyl metacrylat)
Cu 54: t chy hon ton 6,2g mt amin no, n chc, thu c 4,48 lt kh CO2 (ktc). Cng thc phn t ca
amin l:
 A. C2H5NH2 B. CH3NH2 C. C3H7NH2 D. C4H9NH2
Cu 55: ng trng hp imetyl buta-1,3-ien vi acrylonitrin theo t l tng ng x:y ,thu c mt loi polime.t chy
hon ton mt lng polime ny ,thu c hn hp kh v hi (CO 2,H2O,N2) trong c 57,69% CO2 v th tch .T l x/y
khi tham gia trng hp l :
A. 3/5 B. 3/2 C. 2/3 D. 1/3
Cu 56: t chy hon ton m gam mt amin X bng lng khng kh va , thu c 22,4 lt CO 2(ktc); 27 gam H2O v
7,25 mol N2. Gi s khng kh ch gm N2 v O2 trong N2 chim 80% th tch. Cng thc phn t ca X l
A. CH5N. B. C4H12N2. C. C2H7N D. C3H10N2.
Cu 57: X l a -amino axit ,phn t c cha 1 nhm COOH. Cho 0,1 mol X tc dng vi 200 ml dung dch
HCl 1M thu c dung dch Y . phn ng ht cc cht trong Y cn dng 300 ml dung dch NaOH 1M c dd
Z ,lm bay hi dd Z thu c 22,8 gam cht rn khan .Tm cng thc ca X?
A. CH3-CH(NH2)-COOH B. H2N -CH2-COOH
C. H2N-CH2-CH2-COOH D. H2N-CH2-CH2-CH(NH2)-COOH
Cu 58. Peptit X c CTCT l :
H2N-CH2-CO-NH-CH(CH3)-CO-NH-CH(COOH)-CH2CH2CH2CH2-NH2.
Tn gi ca X l :
A. Glyxin Alanin Lysin B. Glyxyl Alanyl Lysin
C. Glyxyl Alanyl Glutamin D. Alanyl Glyxyl Lysin
Cu 59: un nng hn hp gm 22,5 gam glyxin; 17,8 gam alanin; 11,7 gam valin vi xc tc thch hp, sau khi phn
ng hon ton thu c m gam hn hp X ch gm cc tripeptit. Gi tr ca m l
A. 41,2 gam B. 43 gam C. 44,8 gam D. 52 gam
Cu 60: Pht biu no sau y ng?
A. Trong mt phn t tetrapeptit mch h c 4 lin kt peptit.
B. Trong mi trng kim, ipeptit mch h tc dng c vi Cu(OH) 2 cho hp cht mu tm.
C. Cc hp cht peptit km bn trong mi trng baz nhng bn trong mi trng axit.
D. Amino axit l hp cht c tnh lng tnh.
Cu 61: Thy phn mt lng tetrapeptit X ch thu c 14,6 gam Ala-Gly; 7,3 gam Gly-Ala; 6,125 gam Gly-Ala-Val;
1,875 gam Gly; 8,775 gam Val; m gam hn hp gm Ala-Val v Ala. Gi tr ca m l
A. 29,006. B. 38,675. C. 34,375. D. 29,925.