Reactor R101 METHREC2

M-101

PURG E
METH METHREC

O UT
WAT ER

H2S O4 E-101

R-101
D-101

O UT2
O IL

QOut -
Element nIn,MIX3 Hin, nOut,S1 Hout, QIn QOut Qin
TG 156.91 2808.40 0 0 0
Methanol -238.97 -200.12 0 0 0
Sulfuric
Acid -813.58 -807.58 0 0 0
FAME 2.98 49.48 0 0 0
Glycerol -661.20 -648.60 0 0 0
-
HTotal 1553.86 1201.57 QTotal 0

Sample of Calculation

Methanol

Inlet
Ha
(25 C, 1 atm, Liquid) (28 C, 1 atm, Liquid)

H in H a

T2 T2

H a C pl (a bT )dT
T1 T1

28
(0.07586 0.0001683T )dT
25
 (0.0001683)
0.07586(28 - 25) (28 25) 2
2
0.2283 kJ/mol

H in H a 0.2283 kJ
mol

Outlet

(25 C, 1 atm, Liquid) (70 C, 1.01325 atm, Liquid)

Ha Hd
Hb Hc
(64 C, 1 atm, Liquid) (64 C, 1 atm, Liquid) (70 C, 1 atm, Liquid)

H in H a H b H c

T2 T2

H a C pl (a bT )dT
T1 T1

64
(0.07586 0.0001683T )dT
25

(0.0001683)
0.07586(64 - 25) (64 25) 2
2
= 3.0865 kJ/mol

H b H V 35.73 kJ
mol

T2 T2

H c C pG (a bT cT 2 dT 3 )dT
T1 T1
 70
(0.04293 0.000083T -0.0000000187T 2 -0.00000000000803T 3 )dT
64

(0.000083) (-0.0000000187) (-0.00000000000803)

0.04293(70 - 64) (70 64) 2 (70 64) 3 (70 64) 4
2 3 4
= 0.25907 kJ/mol

H d VP

1
( P2 P1 )
methanol

1 g 1kg mol.K J 1000 L 1kJ

(1.01325 1)atm 32.04 8.314
792 mol 1000 g 0.08206 L.atm mol.K 1m 3 1000 J

5.4308 10 5 kJ/mol

H out H a H b H c H d

H out (3.0865 35.73 0.25907 5.4308 10 5 ) kJ

mol

H out 39.0756 kJ
mol

H H f ( H out H in )

H [238.6 (39.0756 0.2283)] kJ

mol

H 199.7527 kJ
mol

D 101 ENERGY BALANCE SAMPLE OF CALCULATION

 METHREC2
M-101

PURG E
METH METHREC

FA ME
O UT
WAT ER
E-101

R-101
D-101

O UT2
NA OH
Element nIn,MIX3 Hin,MIX3 nOut,S1 Hout,S1 n outlet H outlet QIn QOut QOut - Qin
TG 0.15 2808.40 0 2389.48 0.15 4575.53 421.2602 686.3299 G265.0698
LY
Methanol 21.45 39.08 20.7207 38.83 0.7293 40.05 838.1729 833.7046 -4.4683
Sulfuric
Acid 0.03 6.42 0 5.57 8.55 9.67 0.192523 82.7105 82.51797
FAME 8.55 49.48 0 42.55 2.85 77.39 423.0366 220.5562 -202.48
Glycerol 2.85 21.00 0 19.26 0.03 27.61 59.85028 0.82825 -59.022
HTotal 2924.37 2495.69 4730.26 0 QTotal 81.61705

SAMPLE OF CALCULATION

Sulfuric acid

Inlet (OUT)

Ha
Ha HB
(25 C, 1 atm, Liquid) (70 C, 1 atm, Liquid) (70 C, 1.01325 atm, Liquid)

H in H a H B

T2 T2

H a C pl (a bT )dT
T1 T1

70
(0.1391 0.0001559T )dT
25

(0.0001559)
0.1391(70 - 25) (70 25) 2
2
= 6.4173 kJ/mol
H B VP

1
( P2 P1 )

1 g 1kg mol.K J 1000 L 1kJ
(1.01325 1)atm 98.08 8.314
1840 mol 1000 g 0.08206 L.atm mol.K 1m 3 1000 J

7.1558 10 5 kJ/mol

H in 6.4173 kJ 7.1558 10 5 kJ
mol mol

H in 6.4174 kJ
mol

Outlet (METHREC)
Ha
(25 C, 1 atm, Liquid) (64.21221 C, 1 atm, Liquid)

H out1 H a
T2 T2

H a C pl (a bT )dT
T1 T1

64.21221
(0.1391 0.0001559T )dT
25

(0.0001559)
0.1391(64.21221 - 25) (64.21221 25) 2
2

5.5743 kJ
mol

H out1 5.5743 kJ
mol

Outlet (OUT2)
Ha
(25 C, 1 atm, Liquid) (92.02806 C, 1 atm, Liquid)
H out 2 H a
T2 T2

H a C pl (a bT )dT
T1 T1

92.02806
(0.1391 0.0001559T )dT
25

(0.0001559)
0.1391(92.02806 - 25) (92.02806 25) 2
2

H out 2 9.6738 kJ
mol

H H out H in

H [(5.5743 9.6738) 6.4174] kJ

mol

H 8.8307 kJ
mol
 METHREC2 D-102
M-101 PUREF AME

PURG E
E101 ENERGY BALANCE SAMPLE OF CALCULATION
METHREC

BY PRO 2
FA ME
O UT
WAT ER
E-101

D-10
R-101
D-101
G LY2
O UT2
NA OH
R-102

G LY
E-102
O UT3

H
nIn,MI n inlet n outlet outle
Element X3 Hin, (Water) H inlet (FAME) t nOut,S1 Hout QIn QOut QOut - Qin
4575. 4259 4255 686.3 638.9
TG 0.15 53 0.15 .60 0 .74 301 393 -47.39086823
Methan 0.72 39.8 0.729 38.6 29.21 28.21
ol 93 40.05 0 9 3 9 03 644 -0.993858946
Sulfuric 0.290 0.273
Acid 0.03 9.67 0 9.12 0.03 9.12 214 481 -0.016733625
72.5 72.4 661.6 620.2
FAME 8.55 77.39 8.55 4 0 8 725 355 -41.43698053
26.5 26.4 78.68 75.48
Glycerol 2.85 27.61 0 0 2.85 9 399 881 -3.1951863
148.090 148.0 33.49 11.16
Water 3 0.23 0 4.78 903 0.08 803 601 -22.33201724
4730. 4412 4402
HTotal 26 0.23 .42 .59 QTotal -115.3656449

Glycerol

Inlet (OUT2) Ha
(0 C, 1 atm, Liquid) (92.02806 C, 1 atm, Liquid)

H in H a
T2 T2

H a C pl (a)dT
T1 T1

92.02806
(0.3)dT
0
 0.3(92.02806 - 0)

H in 27.6084 kJ
mol

Outlet (FAME)
Ha
(0 C, 1 atm, Liquid) (88.337 C, 1 atm, Liquid)

H out1 H a
T2 T2

H a C pl (a)dT
T1 T1

88.337
(0.3)dT
0

0.3(88.337 - 0)

H in 26.5011 kJ
mol

Outlet (GLY)
Ha
(0 C, 1 atm, Liquid) (88.291 C, 1 atm, Liquid)

H out 2 H a
T2 T2

H a C pl (a)dT
T1 T1

88.291
(0.3)dT
0

0.3(88.291 - 0)

H out 2 26.4873 kJ
mol

H H out H in
H [( 26.5011 26.4783) 27.6084] kJ
mol

H 25.371 kJ
mol