CBE 621: Problem Set #3 Due: February 12, 2016 (10:00 am) 1.) The Peng-Robinson equation of state has the following form: oir a) vob vive baby 5) where a= 045724 = a(n) b= 0.07780 a ee=[14 (037464 + 1542260 ~0.269920")1- JF) and T. and P, are the critical temperature and pressure, respectively, and « is the acentric factor. Given this equation of state, derive the following expression for the fugecity coefficient of a pure species, wf w(e-n-W(z- mn) a fete RT RT} 2 2bRT | Z+(1-V2]oP a 2.) Calculate the fugacity for each species in the following gases at 290 K. and 800 bar: a, Pure oxygen b. Pure nitrogen 3.) The coexistence (vapor-liquid) line of methylmercaptan is described by the following equation: 2338.3 7(K)-3 InP™ (men Hg) = 16.1909 ~ ‘a. What phase is methylmercaptan in at 273 K and 1 bar? What is the fugacity of methylmercaptan at 273 K and 1 bar? b. What phase is methylmercaptan in at 273 K and 0.5 bar? What is the fugacity of methylmercaptan at 273 K and 0.5 bar? 4.) Calculate the fugacity for each species in the following gases at 290 K and 800 bar: a. Oxygen and nitrogen in a 30 mol % Oz, 70 mol % No mixture using the Lewis- Randall Rule b. Oxygen and nitrogen in the mixture in part a using the Peng-Robinson equation of state for the mixture5) ‘At 35°C the vapor pressure of solid naphthalene is 2.80%10"* bar and its density is 1.145 g cm", Calculate the solubility of naphthalene in compressed ethylene at 35°C and at to- tal pressure of 30 bar: (a) Using the ideal-gas law. (b) Using the virial equation of state truncated after the second term For the second virial coefficient B use the van der Waals result, Bab-— RT Van der Waals constants a and 6 are related to the critical constants. For the gas mixture assume that a and b are a quadratic and a linear function of the mole fraction, respec- tively,le e = — 4 ules) bGr-b) _ (62) ae = Pe rkTleD) ead) = [ ar [de “0th +e) apt nr Lut aa a - “or de 1 (a dr (BE a PJ Rrhy vs zr | vdves) +6004) efe —Me + 1) Aff) - Ae) ee ul ie Sy erty) v hee +@-l\ Ai MOH Faas aK deed) 6004) thoy whee + Gt) 46) = Co ~Afatetl] - 2 [Ae ue hy veers) blo 4€)- co Le 4) ieee& Got) Cnbive. 46 = Gt) he (- Mer) “et \a nea) ee [Ed ayMk) a) +6) nse Peng Robasn BS b calcalale pure eouporeat Aegac Hes self) @-)nte(et be [et Cre beet er ~ Dor 3 RT Z tC) RT See neat sheet, Excel prrtratad. Tee "308" ad 180 sToase ovittoa vasa bcos aaxteoe "Meta Pepe a "oaks ee ok 0 220707 eacoriaas asiites 2aabtos asics fee) PDS; naa) Pony Het REDS) isieet "Reieoom’ Seas “Gaccvae 1st cassia osretbone 7Iss3—3 Pongian regioon vine riegsinen poy memprmOs | Sedat /TEiel” ate “Gaereos’ ase 260era1 szomiasee costae, oe aby we ad, 2 ao er36 2) tigecily oF molkylucrciptr € SIZE + I bac! LP = le, (204 = 2339.8 TH 3hy Case da PPP = (0.190% — 2339-38 2 ps 223-3644 LP? = 354 PP = oxy (6.381) = S45.2 nay (@e 4 bar = 760 mae My PoP? —s thes no legued plase ‘ (et fiz pw

Lhed cord hes +l pe Le pp2. B ') hgecty @ IBE + 0.5 ber? pis S29 nuh Gat a) P=0S br PR = 380 un th p Sito “Thus, the oaximum moisture content, y,0+is elven by Sip = Sitgo