Series :SMA/I err 56/1/1 mae (LT TTT Candidates must write the Code on! the title page of the answer-book. pen ate wr a fis ee eto a afr yes serena Ff ee? ener at ate feo 1 ate tear et oe See afar ae pren atter wee ef fi rer weer 30 wee BY pr res er sere fener ape ees A eet, See eT ees orev fer | a weer wh el ae fee 5 free a ey fear ner ewes ae Pare qaler 10.15 4 fran wrt 1 10.15 wt 10.30 wa ee ee ewer rere bt ste ee safe hes & oer. pfs ac td ere set Fert © Please check that this question paper contains 11 printed pages. © Code number given on the right hand side of the question paper should be written on the title page of the answer-book by the candidate, * Please check that this question paper contains 30 questions. * Please write down the Serial Number of the question before attempting it. ¢ 15 minutes time has been allotted to read this question paper. The question paper will be distributed at 10.15 a.m. From 10.15 a.m, to 10.30 am., the students will only read the question paper and will not write any answer on the answer script during this period. Tare faa aan) CHEMISTRY (Theory) Predfer ore : 3 ed (SRR Ae : 70 Time allowed : 3 hours | {[ Maximum marks : 70 amar Prt; (i) wei ver sift Fy (ii) Wete meT art sie Te Te (iii) Rear La 8 rR aif ore aeT & | meter er & Fae aie es (iv) wecaear9 a 18 aa ong-setta wer Fi ade wer S fer 2 aire (y)) Wega 19 327 aad apamia wet i ards ea S fered aie (vi) weer 28 330 theories Fares Sis ee (vid) atrereeresenrpene eater Sereah er Wratten S TVePT we TA TT 56/1 1 [F-T.0.‘General Instructions : Sor (i) All. questions are compulsory. (ij) Marks for each question are indicated against it. (iii) Question numbers 1 to 8 are very short-answer questions and carry I mark etch. fiv) Question numbers 9 to 18 are short-answer questions and carry 2 marks each. {¥) Question numbers 19 to 27 are also shori-answer questions and carry 3 marks each (vi) Question numbers 28 to 30 are long-answer questions and carry $ marks each. (vii) Use Log Tables, if necessary. Use of calculators is nat allowed. oe abearerer i myorent i eieet oF (ii), MnO; +NO; +H? > Complete the following chemical equations : @ COP +H +r (ii) MnO; + NO; + H* > Lea, yee ay fies Feeafenftaen en spar erreaet & (i) Shere forte (ii) mat Fe (biocatalyst) ? 2 ‘What is meant by (i) peptide linkage (ii) biocatalysts ? 17. seen SUE caffe wi fetta Prva caret vepera aroy wi age dren ere ai i m \ 2 ‘Write any two reactions of glucose which cannot be explained by the open chain structure of glucose molecule, 18, referrer migerent ar srt camer wt izwer otf wife : 2 (i) Fee 6 (i) Wehr Draw the structure of the monomer for each of the following polymers : (i) Nylon6 (ii) Polypropene 19, 2Rea wae Bae ware ase ae A fasion wien #1 aie qise Get I ST ATE 316.5 pm & at deer remy] aa ren ser er? eT APT 286.65 pm Set Aree & are aaa Seo wits ae Sat ren et ae ae ee 7.874 gem te Se ee Ge et der at sii ST (Fe 4, Zam = $5,845 u) 3 Tungsten crystallizes in bgdy centred cubic unit cell. If the edge of the unit cell is 316.5 pm, what is the radius of tungsten atom ? oR Iron has a body centred eubic unit cell with a cell dimension of 286.65 pm. The density of iron is 7.874 g em. Use this information to calculate Avogadro's number, (At. mass of Fe = 55.845 u) Sei 5 [P.T.0,20. 21. Ker ah 33 srr on ofcrers Sitar fart Se 1 kg eT A sre ae ot fae a sree 2K ‘RT et ore | (K, Bret a fev = 1.86 K kg mol!) Calculate the amount of KCI which must be added to 1 kg of water so that the Freezing point is depressed by 2K. (K, for water = 1.86 K kg mol") ‘fare afafiear INO jg) + Clay) FZ NOCH) a Ferd Presfeation otter wend Parte anit avy 263. K ve fet me: mid. bem Noa METTICA] Cl, Barger at es (wt) et (M/min) t O1s OS 0.60 2 OS 0.30 1.20 3 0.30 O15 2.40 4 0.25 0.25 z (a) x Pree wr alone feted (b) or Perches et arr afters wine atte arr ere aif Co) a aH CH, & area at wh merase we? For the reaction INO gy + Clacy > 2 NOCK the following data were collected. All the measurements were taken at 263 K : — Initial (NO} OM) itil [Cl] (4) “ee 1 ous Os 0.60 2 ous 030 1.20 3 0,30 O15 2.40 4 0.25 0.25 2 v (a) Write the expression for rate law, (b) Calculate the value of rate constant and specif its units. (¢) What is the initial rate of disappearance of Cl, in exp. 4? 622, Pretetian st oma are 88 qu fet ere eT? (aga ee we sicvent died wae as aaa Gi) Howrey erat ast gets (Say Aoi St erste Beant eee set oat Aer (4d) St aedaadt art ace aE ii) Aste pe: +3 ae wart &, wafie Wiestos a oiftal 9 ger afeier rere +4 ar + 6 ree ae Se fagtoren cet How would you account for the following ? (i) Many of the transition elements are known to form interstitial compounds. (ii) ‘The metallic radii of the third (5d) series of transition metals are virtually the same as those of the corresponding group members of the second (4d) series. (iii) Lanthanoids form primarily +3 ions, while the actinoids usually have higher oxidation states in their compounds, +4 or even + 6 being typical. 23, Preafeeftaer srrearefedtory godt wrt ts ape ffi: (i) Col saret & w Cr, ee NH, 20] athe et rceelra fects crea (en) are] saree ti Gi) Ni2* sre a et oer ary ate et ett se TE enter srapdaior errenait 4 webs dear sty qerets eae feta (2. # Co=27, Ni = 28) Give the formula of each of the following coordination entities : (i) Co** ion is bound to one Ci’, one NH, molecule and two bidentate ethylene diamine (en) molecules. (ii) Ni? ion is bound to two water molecules and two oxalate ions. Write the name and magnetic behaviour of each of the above coordination entities. (At nos, Co = 27, Ni= 28) mw. ae ein eta strate ees are ant & oe Fer vit ae eciagifeiees ecw aie aaftieansit 4 are. du.Peee tien hi are sitar te sat Although chlorine is an electron withdrawing group, yet it is ortho-, para-directing in electrophilic aromatic substitution reactions. Explain why it is so ? Sort 7 [P.1.0.25. 27. 28, aan Prafaten tesieiei =i stectes fear oie # ot ora seme & ay ait gaat aaa dime ae ares sis at atacberee at oer arfues St svetr sy are ae Es (i) CH,CH,CH,CH,OH Gi) 2-3ter ii) 2-8feee Laer J ‘Draw the structure and name the product formed if the following alcohols are ‘oxidized, Assume that an excess of oxidizing agent is used. CHyCH,CH,CH,OH 2-butenol 2-methyl-1-propanol Paeaieattan Saierentt 3 cravat aaeiteeor ferfiane ; 3 (i) aregtaetis ht Sites ore (i) fener weirs ara (iii) fret eh afiorer cerita Write chemical equations for the following conversions : (i) Nitrobenzene to benzoic acid. (ii) Benzyl chloride to 2-phenylethanamine, (iii) Aniline to benzyl alcohol. ‘Preafafoey ver 9 sat A rete eer were aererer efor: 3 (i) Prevage (Tranquilizers) i) wre oftzer# (Food preservatives) (iii) "BET sreHTFaF (Synthetic detergents) What are the following substances ? Give one example of each one of them. (i) Tranquilizers (ii) Food preservatives (iii) Synthetic detergents (a) ts eite ded few war ot aed? te ita deft Fee 84 we ett Tite, ‘tears ve ot affect at afte gee Prerec eet creh safttiner at fafa 1 (6) Bares ey a awh ary ered fat a mee mea er A res aftr wet Bag + AGO + H;0 pp -> Zap5i) +2 Agiy +2 OH, . aT Wa afitfieen & fra Eo atte AG? at amet sifare | (Rea RT : B® ytigg = + 0.80V, E*p,2+;2, =—0.76V) SorI/L &29. (a) (b) @ (b) (@) b) () tere area 3 feats wifey six aren sitar fe ay a wee fags ares ‘ford store area wizer ara Sat tales viet F 2 0,001 M KCI facet aret areaar det er aface 298 K wt 1500 0 F 1 dae fete aa tafe 298 K 40.001 M KCI 3 area 0.146 x 1078 cor! #2 ‘What type of a battery is the lead storage battery ? Write the anode and the cathode reactions and the overall reaction occurring in a lead storage battery when current is drawn from it, In the button cell, widely used in watches, the following reaction takes place Eingy + ABO + HO > 2nd) +2 ABiy +2 OH.) Determine E° and AG® for the reaction. (piven: B,.+7,4 "+ O.80V, B%p, 2125" ~0.76V) OR Define molar conductivity of a solution and explain how molar conductivity changes with change in concentration of solution for a weak and a strong electrolyte. ‘The resistance of a conductivity cell containing 0.001 M KCY solution at 298 K. is 1500 ©. What is the cell constant if the conductivity of 0.001 M KCI ‘solution at 298 K is 0.146 x 1073 em! ? Freafeian sietivarsl we) qo sire: @ Py+S0,Ch > Gi) XeF,+H,O> Fea ng atm (90° ar aif aT omy afte sree a Fer a ete st eee sia @ so} sia 0-s-o (i) CHF, attest F-CI-F (iii) XeF, att ett F- Xe-F 23 9 PTO.30. @) (b) (@ (b) @) (b) @) oe) ‘fre cara aeeer a pt aT: i HH + Ci, 0 eae (i) XeF,+0,F, > fret angst at trent ant aie (HPO, ) Hy 8,0, (iti) XeOF, Complete the following chemical reaction equations ; (i) P,+S0,CI, + (ii) XeF, + HO > Predict the shape and the asked angle (90° or more or less) in each of the following cases : (i) SO% and the angle O-S-0 (ii) CiF, and the angle F = Ci (iii) XeF, and the angle F - Xe -F OR Complete the following chemical equat (i) NaOH +Ci, > (hot and cone.) Gi) XeF,+O,F, + Draw the structures of the following molecules ; @) HPO, ii) Hy 8,0, XeOF, Sa Sere tT Paes order ae wt seer wt evita sha ; @ FR ae (ii) Bret steed siferent aati fret at ea eciatte att? @ 0 Guewreans st wastes ee (i) RRL -2iter ST peste ae Gi) tee are at aie aE | 2,3 awa(a) ) fa) (b) (a) (by wate fed aap gene ta ge Peieiien aiid ef seein sia: @ wets oer Gi) SepraifeprteT aifral & Fra gral a aie era & fry anereot airei at Ga: @) s2.9m oft 3-3 Gi) Fires ott td a Gi) Ste ste aaitee aes a Illustrate the following name reactions giving suitable example in each case : @— Clemmensen reduction (ii) Hell-Vothard-Zetinsky reaction ‘How are the following conversions carried out ? (i) Ethylcyanide to ethanoic acid (ii) Butan-l-ol to butanoie acid (iii) Benzoic acid to m-bromobenzoic acid OR lustrate the following reactions giving a suitable example for each. (J) Cross aldol condensation (ii) Decarboxylation Give simple tests to distinguish between the following pairs of compounds (@ Pentan-2-one and Pentan-3-one (ii) Benzaldchyde and Acetophenone (iii) Phenol and Benzoic acid