1 As electcon moves freely along a straight Fine (in the \iirection) of length (F). being resiticted wo the range s = Oto x= # Hts ground state wave function 1s Ws) NEF san What as the probability of finding the electron at the mid-point of the line? aw b VF < 62 dove What is the ratio of the ground state energy af an electrort moving m Be’ Ww that of one moving in La (Presume that both betave Tike frydrogen atusn) a 43 bP © 16 doe CHEMISTRY Lot 1s 4 NaCland Myo Which one of the following lanthanides 1s colourtess ” aR b Ce & Sm a et 4 Two metal atoms ist a bin are on Seasis The om is sutable for which 9 a. a-hond overlap b. o-bond o3g 3 Match List-t with List- Il and selecigne coffect ansWer using the code gi al According to VSEPR theory, what are the the Tists ~ bond angles im NH: HO an SFp List UILPAC Symbod) | A Une B Usp @ © Ua O Uy | List if * | {Momigic 1 ow 3. | ode. I a AZ. BEC3 D4 b AR BS.C2. DF © ALIH.C3.DE dR BI.C2 Do 4 Which pair of sonic solids has the same Madelung constant” a. NaCl and CaCh } b. NaCl and CaF: ZnS and MgO respectively? BOT aR A? 27h bang 26°, 1078 8", UD ADM 27°, 10" 28 Bae 3 do ind 27° 2aTe AR Basu" 9 What as the yeometn. of nitrogen atom an NH, N(CHS3 and N(S(CH sh molecules 2 Trigonat planar in ali three cases, Trgonal pyramidat sn all Unree eases Triganal pyramidal in NH; wid NICH: while ingonal planar an NISit€!E To What is the E vatue at the equet alent point of wiration of Fe" against KMnO4 ABs. fan 77V and EF si vi Much less than 0.77 ¥ ‘Much greater than 52. Between 0 77 V and 152 ¥ Ws2¥ ‘oasider the following statements4 1s 6 rap as 1. Come, HINO, is a hase in cone, HS) a Ronty medium, 17 Solid erystatline PCI, has which of the 2 According te Lewis theory, SO, 1s falowing ? rather an acid-base adduct than an acid 4 Bicpyramidal moisticn 3. BRy' RF - RBF, can be regarded ay an ‘h. Cietahedral moietics avid-hase reaction. 2 Syuare-pyramidal moietios Which of the statements given shove are al Peatagonat moieties sorrecl? $8. What is the role of phosphate int a. aad 2 only detergent” Laud 3 only a. Wraduces the pli of the water, e. Qand only 1b. It increases the pit of the y Landa &. itremoves the Ca” and Which one af the following cosctions is ne water that cause hardy expected to ovcur at FISAB principle? A ncrcanes its soh a Nak HED > NaCl = HE 18 Which onc of the fall eactions will be Cath Pe CaF Cr a0 fe Ugcl 2B igh + CF a MgO = LO)» MgcOlT & i gar yor Ber, Which one of the following chemical Bgl or gtr 1, spceus can behave both as a Bronsted Tog 200» Ty Lowry seid and a base ? x» gre of the following sets of orbitals a Hay fm the hybridization to esplain & TICs ation uf the compounds of Xe? e NOY Ade Seo5p “sou bh SdeGu-Sp What it the trevzing point of heavy ati? &. Sd-SeSp are ad bore 21. Than oclahedtat comptes if Higands an one ere asis are dixplaced Tittle away toms their AE ideal positivns, the eeyxtal Held splitting of Boa is inoclectrypamggath hich one of orbitals tin dis complex is as giver the following below a. Re ay b AI, » 4 a Mol ¢ following statements The figands ane displaced om Which axis Structure of diborane GH.) 1 aver? ititar to that of ethane (Callas a xand y Boron nitride haw a graphite tike layer b vonty structure and is a lubricant < somly 3. The clectrical conductivity of boron d zomly nitride is sarme ax that of graphite 22. Which one of the following compounds has Which of the statements given aheve icone tetrahedral geametcy cuneet? a ENON & Lonly fe ENICLE & tand 3 2 [Pach «. Zand? ab (Pay20, ms Which one of the fitlowing bmtbanide ions fas the highest maynette nisment? a Dy" 6. Gah =. Sm! LTH Why dues aquevus Fe(HiE) ion develop intense red coloue when it reacts with SCN’ vn While FevfHt on dives not? a. Feit) jon Forms a charge transfer complex with SON fons 1b FotTHy is reduced to Feit) which is deep red un colowe & SEN jon oxidizes to CN ion sad that forms red complex with Perth ion. CN ian does not form any comptes with Ft) ion. The inteme blue colour of prussian blue salt arives from which one of the (ollowing” a. ded transition fh Inter vatonee electron wanster «Ligand to metal charge transfer xd Metal to tigand charge tramater Which one of the following is the coreg order of the wavelengths of absorpting £6 somplixes A> [Nith Oinf BINUNH nF, ao PNG tstef a ARC RB ACC oR A aod B iViaadlfnetic moments } iogpja square-planar and _ respectively? ate the eytivalent werghts of MCh in acidic and stkatine media respoctively, what is the value of ly-E3? a os b 6 e 18 a Which one af the following processes is used in the extraction of magnesium a. Self reduction a Buf AS b Thermite reds a Fused salt eectrofysia 4 Aqueous solution eletratysis fa which one of the following minerals, 16 aluminium aot present? x Coyote won b Miva s. Feldspar aL Fluorspar An impure metal is allowed wo arbi monoxide at $0" 4” am gives the metal of 03 the metal a fe hott e 2 ta AN, Cousidlye the Btlowing reoction Paste Sn fe masses: “H = 201441 aT OO3. tn = LO ames hat iv the energy released ie the nuclear reaction given above ? a 1676 Mev b 16.76 Mev «O18 Mev d 0.018 Mev The highest binding energy per nucleon five which of the fellowing? a. Nuclei with mass nurabers around 60 fy Nuclei with eran numbers below 20 4. Nuclei with mass numbers stich ahove 120, but below 200 AL Nucter with mass umbers shove 200 Which one of the fatlowing i the [EPAC name et RAFACN |? 4. Potassium ferrocyanide 'h. Pouresium hexaeyane terrate (IE) &. Tripotassium hexacyano ferrate aL. Potassium ferricyanide What is the comect TUPAC nase of the otpound {Ma f(CoHler: PCRRCHP CHa 1208 4. dit}, Zdipheny! phosphine cthane}bis (Winitsido) motybdcouns TY) be bis (1, 2eiphenyt phisphino ethane nd (dinitragsn) molybilenum W> R016:39, ay. Pads &. his (1, 2dipheny! phosphino ethane} 1. Phenwt bis (dinitrogen) molybdenum (0) 2. Benzene sulphonic acid d. bis (dinitrogen — his (1, 2-diphenyt 3. Benzoie acid phosphine ethane) matybdemam (0) 4. Ethyl aceto acetate How many stereoisomers are possible for 3. Acetylene the comples [PACH (Br) (E (NCh) (NI) Select the correct answer using the code (HOH? given below: als at dand 3 60 b. 24and 5 eR fe. Zand 3 only a6 To prepare: [PENH Ch} which pat 45 Consider the following cas of chemicals iy needed 1. Neopentyt " Beal b. [PUNE sj) and NACL tiie a. [PChap and NHACH hen Energy (CFSE) of a free Coll ion on forming the tewahedral chore complex, Sand 5 vay B PANT uP and KCI he Phenyt A UCHE and NA Whiet one 1i®ving is the correct Whit is the Crystal Field Stabitisation Aoi? [CoCLP fin the anits of Ao) 7 a 06 a af the toflow ing compounds: ede ® ald : “Minamata disease” is caused by apifel one of the following 2 1 8 a. Tetramethy Head b. Methy! thafliom Methane oe Methyl mereury Consider the follow shen below as Ll mom f cna HCH ye What is the comect sequence of the compounds given above in decreasing order of their Sat reactivity? yd a. beatin bo betel “ e Wetted stew 80. 4d, Consider the following species. Whar is the comect order of their dipole moments? i a. fete CHOW be Hlebothly i) OE VTE do Ale Here Which amongst the following are carbo acids?48. 46. 1. Sons What is the correct sequence uF the species fh AL BAC D3 given abowe in decreasing ander af © ALBLCL DS tucleaphiticity in an aqueaus solution? ad ANB3.C2 Da a Vetted vetl 48. Tenormin is 3 drag ased in the treatment uf fh LVAD high blood pressure. angina and abnormal Von DEW heart thy ths, do iVeUettaby What istite the produetts) for the following ; HN Cotten thot thy He reaction " 2 HS gu rm capes ¥ Pe aH ‘eM, ‘What is the correct order mmathed hydrogens oF in decreasing onder? oi om, a. b 8. € Fiqual amounts of (9) and tb) cm tly 7 se 1 J on “ d oH Peronidde eet is a very important foal af the chemistry of alkenes and comesgfte “nN elect dueinng the ad an oF se higkgan n Kt the following? on a HBr L b. BrOl 4 7] ro, HCL ai For the aleoholy give above, what Iy the Mate Listd with IfPIL gind select the increasing order uf reactivity towards comet answungising 1HMle given folow dehydration? the Fists a de Melt List bods the th eo Weibet dois tt $0. tlt (Function) chy i —0.{5)-NO, 4. Chain wanster agent V 2. Free-radical initiawor A. Plasticizer -0-€0)..00H, 4. Antioxidant 7 . Coe For the esters given abowe what is the BAR BRCL DH curtest order of decreasing reactivity tovwieds alkatine hydrolysis4 Wetted bean Ale Po neaan What are the products A und am the fob onsing reacuon? cH, fron ie Aor sisi i cH fe Ofs B. ene; b a cH, OTs cur, b Ht cH, A 4 A b A A ad cK, a » curt, § e2ON B HS CN cHcH, i Hy A, OTs B H-Ce 2 iH a CHG, eat, THC, BCH. TCHLGH, Loe H ° CH, iajor produc tiyT-3 -pemtano! imermedinie is weatl te The mayor product bas one stereoyenic wentre Which of the statements given above are correct? and 3 aunty and -t ony Vand $ enty Band 4 fonts Ts N “1 \ ay Oh QO Consider the abuve stdfeo-ssegers at that relahonship as gived following stareniens UPepresent mese Ff agfl 1H are diastereomers FY are enameomers shalotiemts give above ane F Stereorn 2 only be ating 3 onty 2and 3 only None of a. (bh te What is the correct order of the following dimethyleyelohexanes in decreasing order of thett relative stabutity om the bests of Faunatve gnuche interactions ? Scleet the comet answer using the cede given below a beReded bobstege? coDSR-det@ Qedeaed coon HBF Be ~ See cHOH “What is the absolute confignration of chiral eoutes 2 and 3 of the compound given above? @ IRR b 2B. 38 283K a 28.38 Match List with Listll and select the correct answer using the code given below the Bsts List-T {Newman Projection? ph Bs 4 i Br A CH, coo! HO, Ay ‘OH coo COOH HO goon We, -70H > H Lis (Fischer Projection) wo SS a. ALB3,C2,D4 & AR BLCLDS &. ALB3C4D2 a A3,B1.C4, D2 Cousider the hydrogen atoms labelled as Ha and He in the following molecules cH, Ae coon 4 on 4,—j;—On coon cH, ati Hy —peth cH,54 60. In which of the above are Hl, and Hy diastereotopic? a L2and3 bh. e Lands ab 2amda 58 To decide about the tapicity of hydropens mm the stereoisomers | and Ih. the hydrogen atoms were successively replaced by a substituent ¥ as shown betow a a 4 Hoa Mf Reece, ‘ A ne SP oe HO bY, 63 Jdeagens are homotopic m F and rereatopic it EE ‘The hydrogens are diastereotopic inf and enantrotopic int If The hydrugens are homotopic éa F sod — . ‘enantiotopic in Th Which of the statements given ahove ss eoreet”? a bony b. Zanty &. Sonly d. Nowe of the above avs Au SxZ renction af ant usyrametre: carbon of a compound ahways gives which one of the following’? a. An enantiomer of the substeate b. A produet with oppasite optical rotation €. A mixture of dtastereomers dA single stereoisomers Whictibne ogjhe thllowing sets of reagents Bye cH, +4 e ‘ R 5 Pap tale + where i edinte product. COOH te R-C--R 7 {i} ROH © ¥206 (it) HO b RCOOH ity OH (RMX iy a fi RL iy BO Which one of the Bllowing compoutds camnot he syfithesized fry the acetoacetie ester synthesis 7 8 3. Jedimethy!- 2-botanone 3 -methyt~ 2-penranone & 4-methyl~2-pentanone a Dhesanone Among the following. which one will have the highest dipole moment?4 6s 86 Mach List] with Listill and selec fae’ correct answer using the code given, bd the lists, Listel ® A NH, 8 CCL cH D Presonance jo inductive eect due to hyper conjugation due ta hyper reverse 2. BS. C1, D3 b AD. BSC3, OF & Ad B2.C3, DT d A482, C1, D3 When nitrobenzene is heated wath Zs dost, NHAC] in ethanol, what is the major product formed ” et 08, ar » et Nt Which one of the often would be produced Fopeds Maitro- b - with ntiuere anlinobenzettgaig, reacte the comect sequence of the ing compounds in the increasing rder of reactivity towards ring sitvation ? a Benzene bromobenzene nitrobenzene « toluene hh Toluene “benzene < fitrobenzene Nitrobenzene benzene * toluene d Nitroberzene foluene “ benzene Which one of the following composnds is # D-sugar giving an optically active pentitol on reduction 7 bromobenzene « bromobenzene < bromobenzene CHO CHOH a cue iL E » etyoH ©cKO Gon 70 Which one of the following is the ccsrect figure of B-D-elucopyraniose in Howarth projection? ne oy BO on a he} Me ogg 2 OH ao W Consider the following synthedc mathd 2) Rosenmund 3. Gabriel Amino acids cann sytihesized ny which of the above”: are b. t a d TR Whi the following orotecules is table by TR spectrum * CO: ‘Consider the following statements | > a™ transition is a fiwbiddon transition 1, 2-Diphenytethene absorbs UV fight at a shorter wavelength, thee its trans isomer R totes 3. In more polar solvents a -9 a transitions experience a red shift but x +R transitions show blue shitt Which of the statements given above is/are correct? 8 band only bh Zand 3 only € Fonly dt 2and3 Cortsider the following compound " * ut What fis thg “Correct sequence of the compelinds given shove in the decreasing Fc <= shuception frequency (in 4, The JR spectrum” >To Pema ce We ton a Heed Match List-l with Listll and setect the correct answermusing the code given below the fists List {Compound) : wooc-t-¢ 5 A an py CHCH OCH CH, Nc cow OH Cy CH, cH p CHPeH, Lisest {Number of PMR Signals} ' ' 3 4 C ‘ede76, 7 78, 74, a a A BEE bo AR ARCH D2 AL BLCL D2 a AS, BCH The 'I-nuciear magnetiy resonance spectrum of 1. 2. Strichiorepropane exhibits which of the thflowing a Tito signals, ¢ doublet and a quistel bo Fhree signals, tivo doublets and a quintet Two signals. a triplet and a doublet a. Five signals, tour doubters anil 2 quintet Om which method is the automatically programmed machine fer polypey synthesis hased a Van Styke method b. Sanger method &. Merrifield method a Hadimin degradation The virial equation of ste is written ts vol Which one of the fotlowing gives the expression far the constant DET) far a van der Waal gas ? a biey Pee QD fot A Bm Wo VE rey] ely. the ceitival point is & point ot oiled Won in the gas isutherm ? a0 b Gye ce dee, tee Which one of the following is correct a8 pet uccontpartied diagram ” at tails a. o™*8! plays a dominam rote in vieinity of eB only plays a dominant role T plays a dominsng plays 3 dominggitted while e™ =" plagh a do coe What will by oxygen ot 2f on} gen tant role as, calision nate of HP mean tree path of ven averuge speed af emains unchanged he average velociy of hydrogen at Standard! temperature and pressure (SIPS is 3.56810" emis and is mean free path is 1.78810" em, What would be the collision number per secand at STP? a 3x 1a" host ee Stu J 3x 10" Consider the foffow ing statements 1. More than one adiahatic proves. is possible between two fixed states of a selosed system 2. For closed system. af constant pressure, with rise of temperature thee energy (i) ‘af the system decreases, 3. For adiuhatie Gee expansion of fived. smiowor of pertvct ges, entepy change of the system is positive, Which of the statements given above isiare eorreet? a, Donly b, domly e, Dand} wo Cand Consider the entropy following statements for6, 7 #8 1 hk 3 stare fmetion 2. itv path independent tunetion, lt ie always positive quantity for random processes Which of the statements given above ane vorreet? a. Vand 2 only fh 2and 3 onty Land 3 onty ad. Lands Consider the tullowing statements Lo The work dune in the reversible isothermal expasion uf an ideal yas ia greater than thal for 8 vant der Waal 2 When am ides gis amdargocs expansion go under adiabatic condition im vacuum internal energy wreases gas. Which of the statements given above isare sonivet? a. Leaty & Zonty &. Both tard 2 Neither Vane? A bubble of 2 mol of monoatomic ideal sat expands lo 3 cestain ize whan submurggy in water at a eertain depth where wat well as the gas bobble un temperature increase of WC at pressure, How much heat i duriug the fen gas conslant B31 ask @ a Tiks 1 pax is expanded M, inate Ih) K} trom velume £2 dn’ don! and finally sttsins F quitibrum. Whot are the ange Gf the system amt that of Dedings respectively (R= 2 cal K? su Cand in hs 230357 146 calK and 4.6cal K? 4G cat“ and 18 eal KY e NSea and 46 0) Kt ARR GaP at 18 cal K7 fch Lael with LisTh ond setest the correut answer using the code piven below the fists (Fhe symbols have thelr usual meanings List taf 15 A. dl BooH eh Dd fast Valp~ Sd TS pd pa Sat Tas-Vap “de: 1 4 ‘ ; Oo n with HO fap0 tal mot | and WS. tyahPahny of Ace? & ALBA DI AL BAC3, DI For HO (lig) in eg fice) at 1 a, Seal iM iy provided with 100 em! of dey jor extracting the solute NX. fzom ita 130 em? aqueous solution. Ef the partition Snefficient of N betwen ether and water fv J. what finvtion of X is extracted when 160 ‘om’ dey other 4s axed in feo installments of equal volume? a 23 bo7 89 a13 Which of the following statements is are rot eorrect 1 the phase diagram of a substance shows the rvgions nf pressure and Lomperature af which the various phases are kinclivaily stable. The froczing point when the prossure is Char is called standard Iieezing point. 3. The normal and standard treezing points ate reg ligibly different for most ‘of the cases. Nelect the cofrect answer using the code given below a Tents fb 2and 3 & Vand # only“4 0 At 303 K, the vapour pressure of benzene is TS Torr atid that of eyelohexane is 122 Tort Assuming ideal behaviour. what will og he the vapour pressure of a sofution For which the mote faction of benzene is @ 25? U8 Tor 9 Torr e 20 Tor a 120 Tor Whot will he the number of phases, components and degrees of freedom og respectively of the azcolropic asixture af water and ethariel af 10 atin at equilibrium? a L2and2 ff f2and + . 2 2andtt qd 23andt What would be the vapour pressure of water at 38 C in 10% squenus solution of slucose (given vapour pressure of water at 409 38° Cis 31 8 nvay? a 324mm h 322mm c 318mm a 344mm ‘Calcium nitrate tonizes in wearer as 1 CaSO, & Ca?” + ZNOS against its normal molar a will be the degree of ipl nitrate” nw 028 bh 050 wr c O78 > a bo molarity of a solution S gof sodium hydroxide ia 250 on? 26 os 103 at What is the concentration of oxygen at 20°C and @ partial pressure of 021 atm applying Henry's taw equation” (Gaver that Henry's constant & © 138 x 1 motes L™ an) ios a 208 1y'M b 2ax 10TM Uses & 30x 107M dora tom The molar conductivity of O01 M CEACOOH(ac} at 298 K is E65 mS s’mot * What is the R of the actd 7 (Given A” 3011S nv mot") a bed x10" bf 84x tot e E84 s 10? Nome of the above What is the electrode potenti electrode in which concen ions is LOM [Giv electrode potential off logy, 2= 030101 8 DRY b 0349 ¢ O3KLY a 03 Whictlhsalt YF mercury (Hy) is used to Nigglled electrode ? ic nitrate bf Asireurie chloride ze Mereurous strate Mercurous chloride A gurrent of 3 A passing through silver nitrate solution for 20 minutes, deposits 4 x af silver What is the electrochemical equivalent of silver in um C17 a Fix? b tinxtot © fixie d bits io" The emf of the cell. Zeizn?” (0 1 My] Mz (0.1 Mi Mg is found ta increase by 0004 VK" if emf of this cell at 25°C is 1.6 V, Wat would be enthalpy of the ceft reaction” a -3603144 fy 3003145 © 251286) d 251286 5 in the hydleagen-ovygen fuel cell, whick catalyst is used int anode vessel * a Finely divided platinum 9 paltadiom b Mixture of CoO and platinum & Mixtare of CuO and palladiom No catalyst is required The rate equation on the hasis of following dava for a gaseous reaction Ay | 2B * TAB is105 196 wr 108, 109. Rate a ‘Concentration clisappearance fmol Gaol Esty Ay B Tinto wie pout 48x10" oi food Zino O20 DOE a. A )at~ k [An [BP b. -dfArvde k [AS}[B) ce -AAj dt k TAP BT dd fAz}dth [AT {87 fin a TL vesset at S00 K. it is Pound that ete specific reaction rate of ammonia sythesis is 0061 mol U's" What is the rate of formation of ammonia ? 6 01 mols" b. G01 mots" © BOOT mol s dt mols! A. fest order decomposition reaction completes its 50% ia 20 mimites: In what time daes it complete its 875% ? a 3S minutes b dv mutes 50 mites d._ 60 minotes She rate taw for a reaction 4 + produdlfes lat wa MAR For « given initial concentra at is the satio of the time fox ation pall to Ud to fall to SE to th centration to fall tw LP [Abs in a b © d is -hon-fadiative transition between th different spin angulat momenta 2 Internal conversion b intersystem crossing, 6. Fluorescence d Phosphiorescence When 2 substance “A is exposed to fight for [0 minutes, 0.001 mole of it is reacted fn the same time A absorbed 10 10° no ul Lots phous per second, What 3s the cquantunt yield of the reaction ? a bSx in? b fax io® © 29% 10" dé fox aa Consider the fatlowing statements | The free energy change (AG) 2 Inan enzyme catalyzed et Which of the statement carr a chemical reaction he presence of ¢ catalyst changes Kyo) the onder of reactiong eo? only b only «Both lay o jal initial rate és equal to one-half of the rate, then what ['$ Ky equal to? 8 {Sh b Sh, eal HS he dash, Mat corr ich Liste with fasted and select the ect answer using the cade given bean the fists List A a c b. List ' 3 4 of The catalyst is ia different phystcal hase fiom the reacts The phenomenon of ane of the products of a reaction itself acts as catalyst The phenomenon when a catalyst reduces the rate of the reaction Wheo the catalyst is in lhe same pase fs the reactants u Autocatalysis Negative catalysis Heterogeneous catalysis Homogeneous catalysis Code a b A AL Ag, 84,03, D1 BIL C2 Da BE.C3, Da3 4 115 116 uy dR 84,02, DF The coagulation of 100 ml of eutoidal sohtiant of gald is completely prevented by the addition of 0.24 g of X to it before addition of Um of 40% NaCl solution What is the gold qumber af a 028 b « a Assenion tA} poim than CC. Reason (RI There is a pend, ovesia between Cl and Si, thus making Si-Cl bond Fess polar 8 Both A and & are individually true and R is the correct explanation of 8 b Both A and R ate individually tue and Ris the correct explanation of A Aistrae but Ris fatse dA is False but R is trae Assertion (A) Dissolution of some secondary and tertiary alcohols ia vale eanctatrated H,SO, results im gradual separation of at insoluble fiquid of high; boiting point He SiCL, has lower boiling Ha Reason (R) Secondary and — tertiiey alcahols easily form alkenes whichfilgerd acid catalysed polymerisation toffor y boiting insoluble Fquids a Both A and R are in and Ris the correct explapati bh Both A and R jually true and Ris the correct cliglinayfin af A ie b Ais true biG. is fal 4 istue Assert -Amina acids show Rig jolubility in polar solvents melufiy points. Both A and R are individually true and Ris the comect explanation of A bh Both A and R ave individually true and Ris she correct explanation af A c. Ads true but R is false do Ais fatse bur R is true Assertion iA} The boiling point of 81 M Urea solution is less than that of © 1 MKCL solution. oes Reason (Ry Elevation aff boitmy point is inversely proportional to the rumbers of species present in the solution a Both A and R are individually ave and R is the correct explanation of A bb Hoth A und R are individually true and R is the correct explanation of A Ais true bud R is fiatse a Ais false but R is tue Assertion (A) Calomet electrode, reference electrode and con sparingly soluble salt of solution of a soluble satt af Reason (R) The reversible with resp fo the’ tion a Both A and R are Res the g rally tree and expigration of A sidividually true and planation of A is false Ehce of acid is a reaction of First orltPReheteas in presence of atkals, ts 2 action seccmd order Reason (RY Acid only acts ns a catalyst whereas alkali acts as one of the reactants a Both A and & are individually true and Ris the correct explanation of A b Hoth A and R are individually tue and Ris the correct explanation of A Ais rue bur R is false do Ais false but R is mse Assertion {A} For the _ following photuchernical decomposition of HE BO eT Helo +d Ped moh the quantum yield is ony 2 Reason (Ry atom is retatively unreactive and does not participate in the chain propagation step a Both A and R are nilivichally true ancl Ris the correct explanation of A b Both A and R are individually true and Ris the conect explanation of A ¢ Aistruebut Ris Ais false but R is tre