* Hemegenss Seb < A cofatast is a substance that accelerates a reaction bub undergoes? no net chemical chonge - The coctatysh Lowers the cee! energ EE the reaction iS ovrdaney On altepetive path thot nee he slow, ~+ok Ae re ave, St the uncottatysed yeaction. ae 4 EaConcobotyse) bh Ente seal) Pehoped sa Conia. \ae os Reoutror Co-wrdiel Let w consider a enerol cotalytic mechanism invelui Da substhate 3 id z "0 g CS se K+Y eo Wipes Where 6. Catalyst S = substrate Mo = Catalyst -Substate complex Pe Product Y and tnfore some subshonce formect m additra, Tn mest cores Y amd W ave non-existot The veverse reach From Produc is considered megkigible bored on the assumption that the Pprodic ave Tm Oo very Pio eneiqy Level. Z < nrlemler formed after decampasitn of * 4 eC Tt & Surly the x nee OsTwo possibilities ovise from the above yeactos k the conibube of the second -ceorkdon (with ks) - Con be es a Gece the Gea ea vation Concentsatens et on (MAGA = iy, Kean ees aes a {cel and (3) oe witial cmcentrat ma f (€) owl (s) seapectively aos cai Liu unsteee hee) xe) Cha eo eae woith above eons , et (a 69) (B- #1) Two specials Corer onise for the above er © Gy Pas.) > 1.) then Ta] — (ea {6-4 : €q» @ com be covtien EG, ce (CaP) EA > pisses K(sa+N) Tn covperating (0 from obsve eqn overall Tote of the reaction » AS. ovieg qe IG oe ae Kel +f) KOI on KLSI [s.) Ceo] com (i) et, emen. set equal to G)-fR] @ then Kk. (OI (4) (sa -GD ee \, K a ( 0 Since [x] te small the term (CK)? con be ee ae Sar k, aga k fe.) +k +k, f)~%f9 ond the Overall vate of the reactor 4 Telit ke fe] (STON ae b (co «(s+ I+ BOW This ean. mdreater that at Jeo conc + (E.) eral (35 the vote vores Lineow with the concentrecdia, of eoch of thete and that at higher Cencentvodtias ¢ ether ,the rote will betome mdependent of that Concembratior® . : Tn cov s, Woamal ¥ ove usually nen existent the vote luo become =2., eee de i (fee) + Sa) + Rs F@" Reactions on Saliel Suecfaces The cotalysis b sunfaces invelves specific Chemicod mnteadin between the sunface ond the react eo molenmles, hich must beeme adserbal on the sr before veaetion Com ocwuyr The extent of adsorption The ectent sf surface Coverage 7S normalli expressed as the fractional SoBe, bs 5 @ = number of actsoxption sites Occupied Number of adsorption alt Rr ao neal soln AW--X ond in Ndsegh prcead Censideving tive Limiting cares of eqn. © we have Poy epee eA kKp We can alto uwwte above Sqn. ws ip Shee k*. kK Using the dinky ond din m8 onal obeve "d a ae ere — we have elo a lilakes Alix AT aT “dt =: ihe Cee ge” ait Where Cae APparent enerss of athvaty mn Mee G2 true ones ya athvetion atl fi \ L ee WY. | Pdsorbed rent eae Reaction Co-ordinate