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SIJIL TINGGI PERSEKOLAHAN MALAYSIA

Instructions to candidates:

DO NOT OPEN THIS QUESTION PAPER UNTIL YOU ARE TOLD TO

DO SO.
Thereqre fifty questionsin this paper. eaghquestion,four suggestedanswersare given.
lor
Choose one correct answer and indicate ii on the muhipie-choice"answeisheetprovided.

Readall instructions on the multiple-choice answer sheetvery cmefully.

Answer all questions.Marks will not be deductedfor wrong anEwers.

This questionpaperconsistsof 37 printed pages.

STPM962lr
*This questionpaperis GONtr'IDENTIAL until
theexaminationis over. CONIIDENTIAL*

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 CONFIDENTIAL*

SectionA
Four suggesfedanswerslabeledA, B, C and D are givenfor eachquestion.Choose
one conect answer.

1. Forwhichof the followingwouldthe latticeenergybe expectedto havethe greatest

numerical
value(thegreatestmagnitude,
disregarding
sign)?
A NaCl
BK I
c Pbso4
D MgO

2 Which of the followingis the correct trend of the electricalconductivityof the elements
Na, Mg, Si and P?

A M g tNa>S i>P .
B N a>Mg>S i>P .
C M gtNa>P >S i.
D P>S i>Na>Mg.

E
{
g
=
ut
at,
E
o-

?6 product

Whichof thefollowing
reactions
at a constant
temperature
canbe explained
bythegraph
above?
A X (g) + 2Y(g) e+ 2z(g)
B X (g) + Y(g) r- 2Z(s)
C X (g) + 2Y0)F=+ 22$
D x (g) F- 2z(g)

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CONFIDENTIAL*

BahagianA
EmpatcadanganjawapanyangberlabelA, B, C dan D dibeikanbagi setiapsoalan.
Pilih satujawapanyang betul.

1. Antarayangberikutmanakahdijangkamempunyainilaitenagakekisiyangterbesar
(magnitud
nilaiangkanya terbesar,tanpamengambil
kiratandanya)?
A NaCl
BK I
c Pbso4
D MgO

2 Antarayangberikutapakahturutanyangbetultentangkekonduksian
elektrikbagi
unsur-unsur
Na,Mg,Si danP?

A M g t N a >S i >P .
B N a > Mg >S i >P .
G M g t Na >P >S i .
D P> S i >N a >Mg .

E
(E
c.
(o
E
(g
.Y
(l'
F

Tohasil

olehgraf di ataspadasuhu
Yangmanakahantaratindakbalasberikutbolehditerangkan
malar?
A X(g) + 2Y(g)
B X (g )+Y (g )- z(g )
c X (g) + 2Y(l) .---: 2z(t')
D X (g) t===+ 2Z(g)

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CONFIDENTIAL* 4

4 Arrangethe followingcompoundsin ascendingorderof theirboilingpoints.

1 (CH3)3CH
2 CH3CH2CH2OH
3 CH3CH2CH2SH
4 CH3CH2CHzCH'

A 14 32 B 3241

c 41 3 2 D 142 3

5. The half-lifeof a firstorderreactionis 5.00hours.The rateconstant,in unitsecond-1,

for thisreactionis

A 3 .8 5 x 105
B 2 .0 0x 1 03
C 1.25x 10-3
D 9.63x 10{

6 The standardelectrodepotentialsare givenbelow.

Zn2*(aq)+ ls F:: Zn(s); f = - 0.76V

Ag.(aq) +e i^ Ag(s); f =+O.8OV

Whatis the e.m.fof the cellthat consistsof the halfcellsof zinc andsilver?

A [0.80+ (-0.76)]V
B [0.80- (-0.76)lv
c [(2x 0.80)+ (-0.76)]
V
D [(2x 0.80)- (-0.76)lV

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CONFIDENTIAL*

4 Susunsebatian-sebatian
berikutdalamtertibmenaikmengikut
takatdidihnya.

1 (CH3)3CH
2 CH3CH2CH2OH
3 CH3CH2CH2SH
4 CH3CH2CH2CH3

A 14 32 B 3241

c 4 13 2 D 142 3

5. Setengahhayatbagisuatutindakbalastertibpertamaialah5.00jam. pemalarkadar,
dalamunitsaafl, untuktindakbalasiniialah

A. 3.85x 10-5
B. 2.00x 103
C.1 .2 5x 1 0 3
D. 9.63x 10{

6 Keupayaan
elektrodpiawaizinkdanargentum
adalahsepertiberikut.
Zn2.1ak\+ 2e i=: Zn(p); E - - 0.76V
Ag *( ak )+e + A g(p); F = + O . B O V

Apakahnilaid.g.eyangterhasildaripada
setengah
selzinkdanargentum?

A [0.80+ (-0.76)]v
B [0.80- (-0.76)]V
c [(2x 0.80)+ (-0.76)]V
D [(2x 0.80)- (-0.76)lv

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CONFIDENTIAL* 6

7 fne { for ammoniagasis ploftedagainstp at constanttemperature.

Whichof thefollowing
p
graphsis mostlikelyto be conect?[d = densityof ammonia;
p = pressure]
Ailp

c D

8 Thefollowingseriesof linesis formedin thevisiblelightregionof the emissionspectrumof

the hydrogen
atom:

Whichof thefollowingstatements
is not true?
A LineP hasthe longestwavelength.

B LineP hasthe highestcolourintensity.

C LineP is violetwhilelineQ is redin colour.

D Theseriesis calledthe Balmerseries.

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CONFIDENTIAL* 8

is passthroughmoltenaluminium
9 When8 A of electricity oxideusinginertelectrodes
for
100minutes,whatis the closestvolumeof gasreleasedat s.t.p?
[1 mofeof gasat s.t,poccupies
22.4dm3;Faraday constant = 9.65x 104C mofl]

A 2.8 dm3 B 5.6 dm3 C 8.4 dm3 D 11.2 dm3

10 Theboilingpoint- composition
graphfortwomiscible
liquidsP andQ is shownbelow:

Temperature

100YoP 100%Q

Whatis the composition

of the distillates
if a mixtureof composition
X is fractionaldistilled?
A Pan d Q B P andZ
C Qa n d Z D Zonly

11. X andY aretwo miscibleliquidswhichobeyRaoult'slawAt 2s'c, the vapour

pressureof X is 3.20kPa. Whatis the partialpressureof X in a mixtureof 45 g X and
253g Y? [Relativemolecularmass:X = 18,Y = 461
A 2.80kPa B 2.00kPa C 1.75kPa D 1.00kPa

12 Which of the followingmixturewould experiencethe smallestchange in pH when one drop

of dilute hydrochloricacid is added to it?

A 100cm3NH30.1 moldm-3+ 100cm3HCl0.1 moldm-3.

B 100cm3NH30.1 moldm-3+ 100cm3HCt0.2moldm-3.
C 100 cm3NaOH0.2 moldm-3+ 100cm3CH3COOH
0.1 moldm-3.
D 100 cm3NaOH 0.1 mol dm'3+ 100 cm3CH3COOH0.2 mol dm-3.

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CONFIDENTIAL* 9

9 Apabila8 A aruselektrikdialirkan
melaluileburanaluminium
okidadenganmenggunakan
elektrodlengaiselama100minit,apakahisipadugasyangterbebaspada s.t.p?
[ 1 molgaspadas.t.pmenempati22.4dm3,PemalarFaraday= 9.65x 104C mol-1]
A 2.8 dm3 B 5.6 dm3 C 8.4 dm3 D 1 1 . 2d m3

10 Graftakatdidih- komposisi
bagiduacecairP danQ yangterlarutcampur
adalah
ditunjukkan
sepertidi bawah.

100o/oP X Z 100o/oQ

Apakahkomposisihasil-hasil jika satucampuran

sulingan dengankomposisi
X disuling
secaraberperingkat?

A Pd a nQ B P danZ
C Q d a nZ D Zsahaja

11. X danY adalahduacecairterlarutcampur

yangTematuhihukumRaoult.Tekanan
wapX ialah3.20kPa. ApakahtekananseparaX dalamsuatucampuran
45 g X dan253
g Y? [Jisimmolekulrelatif:X = 18,Y = 461
A. 2.80kPa B .2 .0 0kP a C. 1 . 7 5k P a D. 1.00kPa

12 Manasatu campuranberikutakanmengalamiperubahanpH yang patingkecil

apabilasetitisasid hidroklorikcair ditambahkanke dalamnya

A 100cm3NH30.1 moldm-3+ 100cmt HCl0.1moldm'3.

B 10 0cm 3NH30.1 moldm'3+ 100cm3HCl0 . 2mo ld m-3 .
C 100 cm3NaOH0.2 mol dm-3+ 100 cm3CH3COOH0.1 moldm-3.
D 100cm3NaOH0.1 moldm-3+ 100cm3CH3COOH
0.2 moldm-3.

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CONFIDENTIAL* 10

13. lf the radiusof a metalatomis 125pm,determine

thevolumeof one unitcellthat
formface-centredcubic.[1pm= 10'12m]
A 5.52x 10-2acm3 B 4.42x 1O-23
cm3
C 1.95x 10-2acm3 D 1 . 5 6x 1 0 2 3 c m3

14 Theenthalpychangeof solutionof sodiumhydroxide is - 44.4kJ mol-1.

Whena sampleof
sodiumhydroxide dissolvesin 250cm3of water,thetemperature of waterchangesby 14 K.
whatis the massof sodiumhydroxideusedin theexperiment?
tR.A.M:Na=2!O = 16;H = 1;assumingdensityof solution= l gcm-3;
specificheatcapacity
= 4.12Jg'tKtl
of sotution
A 0.85g
B 2.75g
C 1 0 . 8 0g
D 1 2 . 9 9g

15 Thegraphbelowshowsthe variationof pHwhen10 cm3of 0.1 moldm'3aqueousalkaliis

titratedagainst0.1 moldm'3ethanoicacid.

20
Volumeof CHgCOOH
/ cm3

is not conect?
Whichof thefollowingstatements

A Thealkaliusedcouldbe Ba(OH)2.
B Phenolphthalein for the reaction.
is a suitableindicator
c A buffersolutionis formedat pointX.
D Thesaltformedis alkaline.

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CONFIDENTIAL* tt

13.Jikajejariatomsuatulogamialah125pm,tentukanisipadusatusel unityang
membentuk kiubberpusatmuka.[1pm= 10'12m]
A. 5.52x 10-2acm3 B. 4.42x 1023cm3
C. 1.95x 10-2acm3 D. 1.56x 10'23cm3

'14 Perubahanentalpibagilarutansodiumhidroksidaialah - 44.4kJmol-l.Apabilasatusampet

natriumhidroksida
dilarutkandi dalam250cm3air,suhularutantersebutberubahsebanyak14
K.Apakahjisimnatriumhidroksida yangdigunakandi dalameksperimen tersebut?
I J . A. R : N a = 2 3 ;O=1 6H
; =1 ;A n g g a p kanketumpatanlar utan= 1.0gcm' 3;
muatanhabaten tu
larutan = 412JgtKtl
A 0.85g
B 2.75g
C 1 0 . 8 0g
D 12.99g

15 Grafdi bawahmenunjukkan
perubahanpHapabila10 cm3 0.1 moldm-3suatularutan
akueusberalkalidititratkan
dengan0.1 moldm'3asidetanoik.

20
lsipaduCH3COOH/ crna

yangmanakahyangtidak benar?
Penyataan
A AlkaliyangdigunakanmungkinBa(OH)2.
B adalahpenunjuk
Fenolftalein yangsesuaibagitindakbalasini.
C Suatularutanpenimbalterbentuk
padatitikX.
D Garamyangterbentukbersifatalkali.

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CONFIDENTIAL'T L2

reactswithiodinein thepresence
16 Propanone of an acid.
t*
cH3cocHs*lz , cH3 co cH2 l+ Hl

Itsmechanism thefollowing
involved steps:

CH3COCH,4 a,f.? = CHz slow

5t
= CHz + lz ----) CH3?l- CH2l fasf
"T '?t l
OH OH

CH3?l- CH2l -=-> CH3COCHzl + Hl fasf

I
OH

Whichconclusion
cannotbe drawnfromthe aboveinformation?
A lodineis notinvolvedin the ratedetermining
step.
B Thereaction
is unimolecular.
C Theoverallorderof reactionis 3.
D Therateof reactionis notaffectedby a changein the iodineconcentration.

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CONFIDENTIAL* 13

16 Propanon
bertindak
balasdenganiodindengankehadiran
suatuasid.
H*
* lz
CH3COCHa > + Hl
CH3COCH2I

Mekanismenya
melibatkan yangberikut:
langkah-langkah

CH3COCH.-g aX.9 = CHz perlahan

I
OH

an.9 = CHz + lz -) CH39l- CH2l cePat

Ir
OH OH

CH39l- CH2l --------> CH3COCHzl + Hl cepat

I
OH

Manakahataraberikutadalahtidak benarmengenaikesimpulan
berdasarkan
maklumat
di atas?

A lodintidakterlibatdalamlangkahpenentukadar.
B Tindakbalasituadalahunimolekul.

C Tertibkeseluruhan
bagitindakbalasitu ialah3.
D Kadartindakbalastidakdipengaruhi
olehperubahan
kepekataniodin.

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 CONFIDENTIAI* t4

17 The diagramrepresents the meltingpointsof fourconsecutive

elementsin the third
periodof the PeriodicTable.

Y
g
o
CL
o)
c
E
=

Protonnumber

Thesketchesbelowrepresentanothertwo properties
of the elements.

Protonnumber Protonnumber

Whatarethe propertiesM and N ?

Property M Property N

A Thirdionisationenergy Electronegativity

B Numberof valenceelectrons Boilingpoint

c lonicradius Effectivenuclearcharge

D Electricalconductivity Atomicradius

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CONFIDENTIAL'} 15

17 Rajahdi bawahmewakilitakat
leburbagiempatunsureyangberturutan
dalamkala
ketigadidalamJadualBerkala.

Y
L
5
-o
o
o
.Y
(U
F

Nomborproton

Lakaran-lakaran
di bawahmewakilidua
lagisifatunsur-unsur
ini.

z
E
U'

Nomborproton Nomborproton

Apakahsifat-sifatM dan N ?

Sifat M Sifat N

A Tenagapengionanketiga Keelektronegatifan

B Bilangan
elektronvalens Takatdidih

c Jejariion Casnuklearberkesan

D Kekonduksian
elektrik Jejariatom

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CONFIDENTIAL* T5

ToC,NOz(g) dissociates
18 Whenheatedto a temperature intoN2(g)and Oz(g).

2NOz(g)i+ Nz(9)+ 2Or(g)

A mixtureof 0.76mol NOz(g)and 0.26molN2(g)was heatedto a temperature ToCin a 1.0dm3

flask.lf 0.52mol NOz(g)is presentat equilibrium,
whatis the equilibrium
constant,I for the
abovereaction?

A 0.04moldm-3 C 0.18moldm-3

B 0.08moldm'3 D 0.27moldm-3

19. Thefollowingdiagramshowsthe structuralformula

of a compound.
CHS H CHE CHg
\./\./
C=C C=C
/\/\ - cH2cH3
H' -cH r-
Whatis the totalnumberof geometrical
isomers(cis-trans)
in this molecule?
A2 83 C4 D8

thetransitionmetalsis correct?
20.Whichstatementconcerning
A Theyare the onlymetalswhichhavemorethanonevalency(oxidation state).
B Theyarethe onlymetalswhichgivecolouredionsin an aqueoussolution.
C Theyare the onlymetalswhichthe anhydrous
chlorideshavecovalentbonds.
D Theyare the onlymetalswitha complete4s orbitalin theiratoms.

21 Whichpropertyof a group14elementin the PeriodicTabledecreaseswhenthe relative

atomicmassincreases?
A Basicpropertyof the oxides.
B lonicpropertyof its compounds.
C Firstionisationenergy.
D of itstetrahalides.
Easeof hydrolysis

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 CONFIDENTIAL'} L7

18 Apabiladipanaskan
kepadasuhuToc, Noz(g)berceraikepadaNz(g)dan oz(g)

2NOz(g) i:* Nz(g) + 2Oz@)

Suatucampuran0.76mol NOz(g)dan 0.26molN2(g)dipanaskan

kepadasuatusuhu
T'C dalamsatukelalang1.0dm3.Jika0.52molNOzhadirpadakeseimbangan,
apakah
pemalarkeseimbangan,
K" untuktindakbalasdi atas?

A 0.04moldm-3 C 0.18moldm-3

B 0.08moldm-3 D 0.27moldm'3

19.Gambarrajahberikutmenunjukkan
strukturformutabagisuatusebatian.
CH. H CH. CH.
t
\=c/
H/ "="'\"rrl -arr"H.
Apakahjumlahbilanganisomergeometri(cis-trans)dalammolekulini?
A2 83 c4 D8

20. Penyataan
yangmanakahbenarmengenailogamJogam
peralihan?
A Hanyalogamperalihansahajayangmempunyailebihdaripadasatuvalensi
(keadaanpengoksidaan).
B Hanyalogamperalihansahajayangmemberiion-ionberwarnadidalamsuatu
larutanakueus.
c Hanyalogamperalihansahajayangmanakloridakontangnyamempunyai
ikatan-ikatan
kovalen.
D Hanyalogamperalihan sahajamempunyai
orbital4syangpenuhdalamatom-
atomnya.

21 Manakahsifatunsurkumpulan14 dalamJadualBerkalaberkurangan
apabilajisim
atomrelatifnyabertambah?
A Sifatbes oksida-oksidanya.
B Sifation sebatian-sebatiannya.
C Tenagapengionanpertama.
D Tahaphidrolisistetrahalida-tetrahatidanya.

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CONFIDENTIAL* 18

22 Whichof thefollowingis not disproportionation?

A Cl2+ 21t139H -+ NaCl + NaOCI+ HzO
B Hg2Cl2+ HgCl2+ Hg
C 2SiO -+ SiO2 + Si
D 2KC|O3+ 2KCl + 3Oz

23 Which of the followingis not a propertyof nitrogengas?

A lt is inert.
B lts meltingpoint is high becauseof the triple bond betweennitrogenatoms.
C lt has a high bonddissociation
energy.
D lt is colourlessand odourless.

24 Whichstatement
cannotbe explained bythe polarizing
powerof aluminium
ions?
A Thehighboilingpointfor aluminium
fluoride.
B Theamphoteric
natureof aluminium
hydroxide.
C Thecovalentnatureof aluminium
chloride.
D Theacidicproperty
of aqueousaluminiumsalts.

25 Whichfactorshelpto explainthe increasein thermalstabilityof the carbonates

of
Group2 metalsfrommagnesium
to barium?

Chargedensityof cation Relativepolarisability

of carbonate
andoxideions
A Increases COg'-less than Oz'
B Increases O'-lessthanCOaz-
c Decreases COr'- lessthan 02-
D Decreases O'-lessthanCOs'-

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 CONFIDENTIAL'} 19

22 Antaraberikutyangberikutadalahbukanpenyahkad
aran?
+
A Cl2 211sgH + NaCl + NaOCI+ HzO
B Hg2Cl2 -+ HgCl2 + Hg
C 2SiO + SiO, + Si
D 2KC|O3-+ 2KCl + 3Oz

23 Manakahantaraberikutbukansifat-sifat
gasnitrogen?
A la adalahlengai.
B Takatleburnyaadalahtinggikeranawujudnyaikatangandatigadi antara
atom nitrogen.
C Tenagapenguraian ikatannyatinggi.
D la bersifattidakbenlrrarna
dantidakberbau.

24 Penyataanmanakahyangtidak dapatditerangkan
melaluikuasapengutuban
ion
aluminium?
A Takatdidihyangtinggibagialuminiumfluorida.
B Sifatamfoterikbagialuminiumhidroksida.
c Sifatkovalenbagialuminiumklorida.
D Sifatasid bagilarutanakueusgaramaluminium.

25 Faktor-faktor
yangmanakahbolehmenerangkan
pertambahan
dalamkestabilan
termakarbonat-karbonat
logamKumpulan2 danpada
magnesiumkepadabarium?
Ketumpatan
caskation Kekutuban
relatifion{onka?bonat

Bertambah COr'-kurangderipaG
Bertambah kurangdaripadaCO3
Berkurang COa'-kurangdaripad-
Berkurang kurangdaripadaCO3

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CONFIDENTIAL'T 20

does not exhibitcis-transisomerism.The shapeof

26 The complexion [M(NH3)2C12]*
the complexis most likely
A squareplanar B tetrahedral
C linear D trigonalbipyramidal

27 Whichof the followingis not true aboutkaoliniteandmontmorillonite?

A Bothareclay.
B Botharelayeredstructures.
C Bothcanabsorbcations.
D BothhaveformulaCagAlzOe.

28 2.30g of methylbenzene reactswithchlorineto givea compound of X

X. Hydrolysis
of aqueoussilvernitrateyields7.18g of silverchlorideas white
in the presence
accordingto the followingreactionscheme.
precipitate

CHs Clz AgNOs/HNOg

+ \/
.4. AgCl
Boiling

X couldbe
Compound
atomicmass:C= 12;H = 1;Ag = 108,Cl = 35.5iN = 14]
[Refative

cH2cl cHct2

c D

o(:"'
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CONFIDENTIAL* 2L

26 lon kompleks tidakmenunjukkan

[M(NH3)rClr]. keisomeran Bentukyang
cis-trans.
mungkinbagiionkompleksini ialah
A segiempatsesatah B tetrahedral
C linear D bipiramid
trigon
27 Manayangberikutadalahtidak benarmengenai
kaolinitdanmontmorillonit?
A adalahtanahliat.
Kedua-duanya
mempunyai
B Kedua-duanya strukturberlapis.
bolehmenyerapkation.
C Kedua-duanya
D Kedua-duanya
mempunyaiformulaCagAlzOo.

28 2.30g metilbenzena balasdenganklorinuntukmenghasilkan

bertindak suatu
sebatian Xdengankehadiran
X. Hidrolisis larutanakueusargentumnitratmenghasilkan
7.18g argentum kloridasebagaimendakanputihsepertiyangditunjukkan
dalamskema
tindakbalasberikut.

CHa Clz AgNOg/HNOr

x AgCl
Didih

Sebatian
X mungkinialah
C= 12;H= 1;Ag= 108,Cl = 35.5;N = 14]
[Jisimatomrelatif:

A cHzcl

c D

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CONFIDENTIAL* 22
29 Whattypeof reactiondoescyclohexene
undergo?

A Freeradicalsubstitution B Electrophilic
addition

c Nucleophilic
addition D Nucreophilic
substitution

30 Experiments
arecarriedouton threecompounds
P: CHoCHzCH2CI
Q: CHgCHzCOCI,
and
R: CeHsCl
To 0.010molsamplesof eachof P, Q andR, 10cm3of wateris addedandthe
samplesareshakenandkeptat a fixedtemperature
for 24 hours.
An excessof aqueoussilvernitrateis thenaddedto eachsampleandthe silver
chlorideproducedis filteredoff,washed,driedandweighed.Thethreesamplesof silver
chloride
weighed0.000g, 0.014g and1.430g.
Whichsequenceof compounds matchestheseresults?
0.000g 0 . 0 1 4g 1.430g
A P o R
B o R P
c R P o
D R o P

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CONFIDENTIAL* 23
29 Apakahjenistindakbalasyangtelibatolehsikloheksena?

A Penukargantian
radikalbebas B penambahan
elektrofilik

c Penambahan
nukleofilik D penukargantian
nukleofilik

30 Eksperimen
dijalankan
ke atastigasebatian
P: CHgCHzCHzCI
Q: CHgCH2COCI,
dan
R: CeHsCl
kepada0.010molbagisetiapsampelp, e danR dan
10cm3alrditambahkan
sampel-sampel
digoncang padasuatusuhutetapselama24 jam.
danditinggalkan
Suatuakueusargentumnitratberlebihankemudiannya
ditambahkankepadasetiap
sampeldanargentum
kloridaterbentukdituraskan,
dibasuh,
dikeringkan
danditimbang.
Tigasampelargentumkloridaberjisim
0.000g, 0.014g dan1.430g.
Manakahantaraturutansebatian-sebatian
berpadanan dengankeputusan-keputusan
ini?
0.000g 0.014g 1.430g
A P o R
B o R P
c R P o
D R o P

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CONFIDENTIAL'} 24
31 Aspartame usedby diabeticpatients.
is an artificialsweetener Thestructure
of
is givenbelow.
aspartame
HO H o
Hz N-9
lll -?- I il
CHs
I
CHt
c-
iH CO-

?H'
I
cooH ,

Whichof thefollowingis trueof aspartame?

A lt formsthreedifferentaminoacidswhenhydrolysedcompletely.
B lt reactswithaqueoussodiumhydroxide to givemethanolas oneof the
products.
C lt is opticallyinactive.
D lt is a polyamide.

32 Whichof thefollowingreagentscanreactwithallthethreebromocompounds
below?
CeHsBr,
C2HsBr
andCeHsCH2Bt?

A Magnesium B Potassium
cyanide
C Alcoholicsilvernitrate D Ammonia

33 Compound
A, CaHTNO is neutralandreactswithnitrousacidto producecompound
B,
CsHeOz Whatcouldcompounds
andnitrogen. A andB be?

CompoundA B
Compound
A CH3CONHCH3 cH3coocH3
B CH3CH2CONH2 cH3cH2cooH
c cH3coNHcH3 CHgCHzCOOH
D CH3CH2CONH2 cH3coocH3

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CONFIDENTIAI* 25

31 'Aspaftame'ialahsatupemanisbuatanyangdigunakan
untukpesakitdiabetis.
Strukturbagi'aspartame'
diberisepertiyangberikut.
HOHO
llllll
H , N-C b- N -g - c o- c Hs
l -l l
cHz H 9Ht
lr
cooH ra
\./

Manakahantaraberikutadalahbenarbagi'aspartame'?
A la membentuk tigaasidaminoyangberlainan
apabiladihidrolisis
sepenuhnya.
B la bertindakbalasdenganlarutanakueusnatriumhidroksida
untuk
menghasilkan metanolsebagaisalahsatudaripada
hasil-hasilnya.
C la tidakaktifsecaraoptik.
D la adalahsatupoliamida.

32 Manakahantarareagenberikutbertindakbalasdenganketiga-tiga
sebatianbromo
di bawah?
CeHsBr
, CzHsBr
andCoHsCH2Br
?

A Magnesium B Kaliumsianida
C Argentumnitratberalkohol D Ammonia

33 SebatianA, CaHTNO bersifatneutraldan bertindakbalasdenganasidnitrusuntuk

menghasilkansebatianB, CaHoOz dan nitrogen.
Apakahsebatian-sebatianA danB yang
mungkin?
SebatianA SebatianB
A CH3CONHCH3 cH3coocH3
B CH3CH2CONH2 cH3cH2cooH
c cH3coNHcH3 cH3cH2cooH
D CH3CH2CONH2 cH3coocH3

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CONFIDENTIAL{' 26

MIBKis usedas a solventfor a few typesof glue.The molecular

34 4-methylpentan-2-one,
structureof MIBKis
(cH3)2cHcH2cocH3
Whichof the followingis a particulartest that is performedin MIBK?

A lt will form an orangeprecipitate

whenheatedwith Fehling'ssolution.
B solutionandthe colourof potassium
lt is oxidisedby potassiumdichromate(Vl)
dichromate(Vl) solutionchangesto green.
C lt formsa yellowprecipitate
whenheatedwith an alkalineiodinesolution
D lt producesa scentwhen heatedwith benzoicacid

35 Whichof the followingmechanismsis mostlikelyexperiencedby the carbonatoms

labefedx, y andz?

Yz
cH.<.oF cHr- 9- - 61
CH2
x \-/ ll
o
x Y z
A Freeradicalsubstitution Electrophilic
addition Nucleophilic
addition
B ilic substitution
Electroph addition
Nucleophilic Electrophilic
substitution
c Freeradicalsubstitution addition
Nucleophilic Nucleophilic
substitution
D substitution Nucleophilic
Electrophilic addition Freeradicalsubstitution

36 Whichone of the followingreagentscan be usedto distinguishbetweenphenol

andphenylmethanol?

A Aqueousbromine B Ethanoylchloride

C Dilutehydrochloric
acid D Fehling'ssolution

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CONFIDENTIAL'* 27
34 4-metilpentan-2-on,
MIBKdigunakan
sebagaipelarutuntukbeberapa
jenisgam.
Struktur
molekulMIBKialah
(cH3)2cHcH2cocH3
Manakah di antaraberikutadalahujiankhasyangditunjukkandalamMIBK?
A la akanmembentuk suatumendakan jinggaapabiladipanaskan
denganlarutan
Fehling.
B la dioksidakan
olehlarutankaliumdikromat(Vl)danwarnalarutankalium
dikromat(Vl) bertukarkepadahijau.
C la membentuk mendakankuningapabiladipanaskan
dengansuatularutaniodin
beralkali.
D la menghasilkan
suatubauwangiapabiladipanaskan
denganasidbenzoik.

35 Apakahmekanisme-mekanisme berikutadalahpalingmungkindialamiolehatom-
atomkarbonyangtelahdilabelkan
I y danz?

cH,{+- cHz- [-Z^,- cl

x\-Jil
o
x v z
A Penukargantian
radikal Penambahan
elektrofi
lik Penambahannukleofilik
bebas
B Penukargantian
elektrofilik Penambahan
nukleofilik Penukargantian
elektrofi
lik
c Penukargantian
radikal Penambahan
nukleofilik Penukargantian
nukleofi
lik
bebas
D Penukargantian
elektrofi
|ik Penambahan
nukleofilik Penukargantian
radikal
bebas

36 Reagenmanakahantaraberikutbolehdigunakan
untukmembezakan
antarafenot
danfenilmetanol?

A Akueusbromin B Etanoilklorida

C Asidhidroklorik
cair D LarutanFehling

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CONFIDENTIAL

d.
7 - bagigasammonia
telahdiplotkan p padasuhuyangmatar.Graf
berlawanan
yangmanasatukahadalahbenar?[d = ketumpatan p = tekanan]
bagiammonia;

A B

c D

garisdi bawahterbentukdalamkawasancahayanampakbagispektrum
I Beberapa
pemancaran
atomhidrogen.
P

Penyataan
yangmanakahyangtidak benar?

A GarisP mempunyai
nilaipanjang
gelombang
yangpalingtinggi.

B GarisP mempunyai
keamatan
cahayayangpalingtinggi.

c GarisP berwarnaungumanakala
garise berwarnamerah.

D Siriinidipanggil
SiriBalmer.

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CONFIDENTIAL{' 28
37 Whichof the followingpolymersis producedby condensation
polymerisation?
A Poly(ethene) B Polyamide
C Syntheticrubber D Perspex

38 The chlorination
of methaneoccursthrougha seriesof steps.Whichof the
followingis not true ?
A The initiation
stepis endothermic.
B Ghlorinefree radicalsareformedin the initiationstep.
C One of the productsis ethane.
D The reactionwill onlystopwhenall the hydrogenatomsin the methane
moleculehas beenreplacedby chlorineatoms.

39 Whichof the followingis expectedto givea whiteprecipitatewith brominewater?

A CzHsNHz B G* t,
./--4.
c cr. cHs{fNHz

40 Whichsequencecorrectlyrepresentsthe followingcompoundsin the orderof

increasingpKa values?

cl
I
?-o'
,t:)'.).H
((
H
1",

A 12 3 B 213

c 3 21 D 2 31

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CONFIDENTIA[* 29
37 Manakah antarapolimer-polimer
berikutdihasilkan
melaluipempolimeran
kondensasi?
A Polietena B Poliamida
G Getahsintetik D Perspeks

38 Pengklorinan
metanaberlakurnelalui
satusirilangkah.
Manakah
antaraberikut
tidakbenar?
A pemulaan
Langkah adalahendotermik.
B Radikalbebasklorinterbentuk
dalamlangkahpemulaan.
C Salahsatuhasilialahetana.
D Tindakbalashanyaakanberhenti apabilasemuaatomhidrogen
dalam
molekulmetanatelahdigantikandenganatom-atomklorin.

39 Antarayangberikut,manasatukahdijangkamemberikan putih
satumendakan
denganairbromin?
A C2H5NH2 B G**,

C CH'-O D cnr-@r.ln,
yangmanakah
40 Turutan tertibpenambahan
mewakili nilaipG sebatian-sebatian
'erikut?

A 12 3 B 213

c 3 21 D 2 31

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CONFIDENTIAL* 30
Section B

Foureachquestionin this section,aneor moreof the threenumberedstatements

1 to 3
maybe conect.The responses A to D shouldbe selectedas follows:

A B c D
1 onlyis correct 1 and2 onlyare 2 and3 onlyare 1 , 2 a n d3 a r e
correct correct correct

41 An elementY produced
thefollowingmassspectrum

Percentage
abundance

14 15 mass/charge
Fromthe abovemassspectrum, it canbe concluded
that
numberof Y is 14.5.
1 the nucleon
2 the relativeatomicmassof Y is 14.2U.
3 the elementY hastwoisotopes withrelativeisotopicmassesof 14 and15.

42 A cunentof 20 A waspassedthroughaqueouscopper(ll) sulphatefor 40.6minutes

lt wasfoundthatthe massof the anodechangedby 16.85g.
usingcopperelectrodes.
Whichof thefollowingobservationsis/aretrue?
[A of Cu = 63.5;Faradayconstant= 96500C mofl]
1 by 16.85g.
Themassof the anodeincreased
2 Thecolourintensityof theelectrolyte
remainedunchanged.
3 Thecopperanodeis impure.

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CONFIDENTIAL* 31
BahagianB

Bagitiaptiap soalandalambahagianini, satuatau lebihpenyataandaipada tiga

penyataanyangbernombort hingga3 mungkinbetul.ResponsA,hinggaD hendaklah
dipilihsepeftiyang berikut:
A B c D
1 sahaja 1 dan 2 sahaja 2 dan 3 sahaja 1 , 2 d a n3
yang betul. yangbetul. yangbetul. adalahbetul.

jisimspektrum
41 SuatuunsurY menghasilkan berikut

Peratus
kelimpahan

14 15 jisim/cas
Daripada jisimspektrumdi atas,bolehdisimpulkanbahawa
1 nombornukleon Y ialah14.5.
2 jisimatomrelatifY ialah14.254.
3 unsurY mempunyai duaisotopdengan jisimisotoprelatif14dan15.

42 Arus20A dialirkan
melaluiakueuskuprum(ll)
sulfatselama40.6minitdengan
menggunakan kuprum.Didapatibahawajisimanodberubahsebanyak
elektrod-elektrod
16.85g. Manakahantarapenyataan berikutadalahbenar?
[A Cu = 63.5;PemalarFaraday = 96500C mol{]
1 Jisim anodbertambahsebanyak 16.85g.
2 Keamatan warnaelektrolit
tidakberubah.
3 Anodkuprumtidaktulen.

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CONFIDENTIAL* 32
A B c D
1 onlyis correct 1 and 2 onlyare 2 and 3 onlyare 1,2 and3 ar e
correct correct correct

43 In whichof the followingreactionsis the bondanglein the productgreaterthan in

thereactant?
I H2O(l) + H.(aq) HgO*(aq)
2 Coz(9) + oH'(aq) -> HcOi (aq)
3 CzH+(9) + H, (g)

U Thegraphbelowshowshowthepercentage of reactant
X(g)thatremained in an
mixturevarieswith1ff at pressures
equilibrium of 1 atm and2atm.(T is thetemperature
Kelvin)

E
=
L

:t
cr
o
(5
cn
x
s
1/T(K'l)

Whichof the followingcan be deducedfromthis graph?

1 The equationfor the abovereactioncouldbe X(g) T- y(g) + Z(g).

2 The forwardreactionis endothermic.

3 The equilibriumconstantKoincreasesas the pressureincreases.

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CONFIDENTIAL'T 33
A B c D
I sahaja 1 dan 2 sahaja 2 dan 3 sahaja 1,2dan3
yang betul. yangbetul. yangbetul. adalahbetul.

43 Manakahantaratindakbalasberikut,sudutikatanhasiltindakbalaslebihbesar
daripadabahantindakbalas?
1 HzO(ce) + H.(ak) -t HsO.(ak)
2 GOz(g) + OH-(ak) -> HCO' (ak)
3 CzHo(g) + Hz(g) CzHs(9)

perubahanperatusbahantindakbalasX(g)yang
44 Grafdi bawahmenunjukkan
tertinggal
dalamsuatucampurankeseimbangan mengikut1ff padatekanan
1 atm dan2 atm.(T ialahsuhudalamKelvin)

g
( Ut5
o ct)
oc
o- ( 5
6
v.=

xo
SE
.Y

1/T(K'l)

Manakahantaraberikutdapatdideduksikan
darigraf ini?

1 Persamaantindakbalasdi atasmungkinX(g) F==J YG) + Z(g).

2 Tindakbalaske hadapanadalahendotermik.

3 Pemalarkeseimbangan
Kobertambah
apabilatekananbertambah.

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CONFIDENTIAL* 34
A B c D
1 onlyis correct 1 and 2 onlyare 2 and3 onlyare 1 , 2 a n d3 a r e
correct correct correct

45 Thepartitioncoefficientof X betweenetherandwateris 8.0at roomconditions.

Giventhat100cm3of the aqueoussolutionwhichcontains5.00g of X is extractedby
using100cm3of ether.Hence,it canbe concluded that
I X is moresolublein etherthanwater.
2 the massof X extractedis 4.44g.
3 the concentration
of X remaining
in wateris 5.60gdm-t.

46 Whichof thefollowingaboutcatalystis conect?

1 lt increases
the rateconstantof a reaction.
2 lt doesnotchangechemically at the endof the reaction.
3 lt changesthe enthalpyof reaction.

47 Thee.m.fof a Daniellcellcanbe increased

by
o, 1 decreasingthe concentration
of Zn2*.
2 increasing
the concentration
of Cu2*.
3 increasing
thevolumeof theCu2*ionicsolution.

48 Ethenereactswithhydrogenhalide,HX,according
to theequation:
CH2= gg, + HX -+ CH3CH2X
In the reaction
I zrelectronsare usedto forma bondwiththe hydrogen
atomfromHX.
2 the intermediateis CHs- CHz*.
3 the reactivity
increasesin the orderHF < HBr< HCI< Hl.

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CONFIDENTIAL* 35
A B c D
1 sahaja 1 dan 2 sahaja 2 dan3 sahaja 1 , 2 d a n3
yangbetul. yang betul. yangbetul. adalahbetul.

45 PekalisekatanX di antaraeterdanair ialah8.0padakeadaanbilik.Diberibahawa

100cm3larutanakueusyangmengandungi
5.00g X diekstrakkan
dengan
menggunakan100cm3eter.Maka,bolehdisimpulkan
bahawa
1 X lebihlarutdalameterdaripadaair.
2 jisimX yangdiekstrakkanialah4.44g.
X yangtertinggaldalam
3 kepekatan air ialah5.60gdm-3.

46 Manasatudi antarayangberikutadalahbenarbagimangkin?
pemalarkadarbagisuatutindakbalas.
{ la meningkatkan
2 la tidakberubahsecarakimiapadaakhirtindakbalas.
3 la mengubah entalpibagisuatutindakbalas.

47 D.g.e.selDaniellbolehditambahkandengan
1 mengurangkan kepekatanZn2*.
2 meninggitkan
kepekatanCu2*.
3 menambahkan
isipadularutanionCu2*.

*8 Etenabertindakbalasdenganhidrogenhalida,HX,mengikutpersamaan
berikut.
CHr=CH2+ HX + CH.CH2X
Dalamtindakbalasitu,
1 elektronn digunakanuntukmembentuk
satuikatandenganhidrogendariHX.
2 perantaraannyaialahCHs- CHr*.
bertambahmengikuttertibHF < HBr< HCI< Hl.
3 kereaktifan

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CONFIDENTIAL* 36

A B c D
1 onlyis correct 1 and2 onlyare 2 and3 onlyare 1 ,2 a n d3 a r e
correct correct correct

49 Whichstatementislaretrueaboutglycine(aminoethanoic
acid)?
1 lt reactswithhydrochloric
acid.
2 lt releasescarbondioxidewithsodiumhydrogen
carbonatesolution.
easilyin organicsolvents.
3 lt dissolves

T hasthefollowingstructure:
50 Compound

is/aretrueof compound
Whichof thefollowingstatement(s) T?
1 lt formsan orangeprecipitate
with2,4-dinitrophenylhydrazine.
2 it has4 chiral carbonatoms.
3 it canreactwithethanoicacidto forman ester.

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CONFIDENTIAL* 37

A B c D
I sahaja 1 dan 2 sahaja 2 dan3 sahaja 1,2dan3
yangbetul. yangbetul. yangbetul. adalahbetul.

yangmanakahbenarmengenaiglisina(asid
49 Penyataan aminoetanoik)?
I la bertindakbalasdenganasidhidroklorik.
2 la membebaskan karbondioksidadenganlarutannatriumhidrogenkarbonat.
3 la larutdenganmudahdalampelarut-pelarut
organik.

50 SebatianT mempunyai
strukturberikut:

PenyataanyangmanakahbenarmengenaiT?
1 la membentuk jinggadengan2,4-dinitrofenilhidrazina.
mendakan
2 la mempunyai4atomkarbonkiral.
3 la bolehbertindakbalasdenganasidetanoikuntukmenghasilkan
ester.

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JABATANPELAJAMN JOHORJABATANPELAJARANJOHORJABATANPELAJARANJOHORJABATAN

JAI 96212 4RANJOHORJABA 4NroHoa pERGUBAAN STpM 2011 tN

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JABATAN PELAJARAN JOHOR

SIJIL TINGGI PERSEKOLAHAN MALAYSIA

ForExaminer's
use
Instructions to candidates: (Untukkegunaan
pemeriksa)
Answer illthe questionsin SectionA in the spacesprovided. All
working must 6e shown.For numerical answers,znil must be quoted I
whereverthey are appropriate. 2

Answer any four questionsfrom sectionB. For this section, write 3

your answerson the answersheets.Begin eachansweron afresh sheet 4
of paper and arrange your answersin numerical orfur. Tieyour answer
5
sheetsto this booklet.
6
Answersmay be written in either English or Malay.
7
A Data BooHet is provided 8
9

l0
Total
(Jumlah)

This question paper consistsof 23 printed pages.

STPM96212
*This questionpaperis CONFIDENTIA! until theexaminationis over. CONFIDENTIAL*

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CONFIDENTIAL* 2

Section A [40 marksl

Answerall the questionsin this section.

1. (a) A 20 dm3closedvesselcontaining 1.5moleH2g?s,x moleN2gas and1.2moleCO2

gas hasa totalpressureof 500 kPaat a temperature
of 298 K.
(i) Calculatethe valueof x. [3 marks]

(ii) 1.5moleof neongaswasaddedintothe 20 dm3vesset.Calculate

the
partialpressureof the hldrogengas. [1 mark]

(b) Hydrazine,NzHr is usedas fuel for rocket.

(i) Writethe electronicconfiguration
of nitrogenatom. [1 mark]

(ii) Drawthe dot-cross structurefor hydrazinemolecule. [1 mark]

is lowerthanthat of propanone
(c)The boilingpointof dimethylether(CHsOCHs)
(cH3cocH3).
(i) Givea reasonfor the differencein theirboilingpoints. [2 marks]

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CONFIDENTIAL- 3

BahagianA[40markahl

Jawab semua soalandalambahagianini.

1. (a) Sebuahbekastertutup20 dm3yangmengandungi1.5moleH2g?s,x mole N2gas

dan 1.2moleCOzgasmempunyaijumlah tekanan500kPapadasuhu298 K.
(i) Hitungkan
nilaix. [3markah]

(ii) 1.5molgas neonditambahke dalambekas20 dm3itul.Hitungkan

tekanan
separabagigashydrogenitu. t1 markahl

(b) Hydrazine,NzHr digunakansebagaibahanapiuntukroket.

(i) Tuliskonfigurasi
bagiatom nitrogen. [1 markah]

(ii) Lukisgambarrajahtitiksilanguntukmolekulhidrazina. [1 markah]

(c)Takatdidihdimetileter(CH3OCH3)
adalahlebihrendahdaripadatakatdidih
propanon(CH3COCH3).
(i) Berikansatusebabuntukperbezaan
dalamtakatdidihmereka. l2markah]

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CONFIDENTIAL*

(ii) Statethetypesof hybridisation

presentin the carbonatomsof the two
compounds
below. [2 marks]
Dimethylether:

Propanone :

2 (a)(i) Givethe definition potential.

for standardelectrode [2marks]

Thestandardreductionelectrodepotentialfor
severalhalf-cellreactionsat298K are
shownin thetablebelow.

Half-cellreactions. E0
SzOot- + 2e -+ 2SO42- +2.01
lFe(CN)el"'+ e +0.36
-[Fe(CN)5]a-
Fe"* + g Fgt* +0.77
-
12 + 2e 2l' +0.54
-

Whenan aqueoussolutionof potassium peroxodisulphate

, K2S2Osis addedto an
aqueoussolutionof potassium
iodide,Kl , a reddishbrownsolutionis obtained.

(iD Writea balancedionicequationfor the abovereaction. [2marks]

(iii) Writea celldiagramfor the abovereaction. [1mark]

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CONFIDENTIAL*

jenispenghibridan
(ii) Nyatakan yangwujuddalamatom-atom
karbonduasebatian
di bawah [2 markah]
...
D i me ti l e te r:

P r o p a n o: n.........

elektrodpiawai.
2 (aXi) Berikantakrifankeupayaan [2 markah]

elektrodpiawaibeberapa
Keupayaan tindakbalassetengahpadasuhu298K
diitunjukkan
dibawah.

Tindakbalassetengahsel. Eo
SzOs'' + 2e 2SOn'- +2.01
[Fe(CN)5]" + e -+[Fe(CN)5]* +0.36
Fe"- + g +Fg" +0.77
lz + 2e +0.54
-2 1 -

Apabilasuatularutankaliumperoxidisulfat,
KzSzOeditambahkepadasuatu
larutankaliumiodide,Kl, suatularutanperangterbentuk.

(ii) Tulissatupersamaan
ionyangseimbang
bagitindakbalasdiatas
[2 markah]

(iii) Tulisrajahselbagitindakbalasdiatas. [1 markah]

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 I

CONFIDENTIAL*

(iv) Calculate
the standardcelle.m.f., Eo en for the reactionin (b)(iii). [1mark]

(b) Thephasediagramof a substance

W is shownbelow.

Pressure
(atm)

Temperature
fc)

(i) Stateallthe changesof phasesof substance

W at the followingpointsas the
temperature
increases. [2marks]

P : . . .... Q:

R : . . . ... S:

T : . . . ...

(ii)Baseon the curveoY, comparethe densityof solidw andliquidw. [1mark]

(iii)Describethe changein meltingpointwhenpressureis increased [1mark]

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 CONFIDENTIAL- 7

piawaisele.m.f.,Eo cell bagitindak

(iv) Kirakeupayaan balasdi (bxiii)
Ilmarkah]

(b) Gambarajah
fasasuatubahanW ditunjukkan
di bawah.

Tekanan
(atm)

Suhu (oC)

(i) Nyatakan
semua perubahan
fasabahanW padatitikberikutapabilasuhu
meningkat. [2markah]

Q:

(ii) Bbrdasarkan
lengkungOY,bandingkan pepejalWdengancecairW.
ketumpatan
Ilmarkah]

(iii) Huraikanperubahan
takatdidihbahanW apabilatekananditambah. [lmarkah]

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CONFIDENTIAL-

3 A studentexamined thewaterfroma miningpoolwhichcontainslead(ll)ions.The

presence of leadionscanbe shownbythe precipitation of yellowlead(ll) iodide.The
solubility solutionof tead(ll)iodideat
of a saturated 15"Cis 0.46gdm-t.

(a) (i)Writean expression product,Kp,for lead(ll) iodideat 15oC.

for thesolubility
[1mark]

(ii) Calculatethe concentrationof lead (ll) ions in moldm'3 [2marks]

(iii)Calculate of iodideionsin moldm-3.

theconcentration [2marks]

(iv)Calculate product,K.o,for lead(ll) iodide.

the solubility Ilmarkl

(b) Stripsof copperaredroppedintoa conicalflaskcontaining

hot507onitricacidsolution.
A colourless andveryreactivegasis givenoff.Thegasthenreactswithoxygenin the air
to form a browngas.
(i) Namethecolourless gas. [1 markl

(ii) Writethe equationforthe reactionbetweencopperandnitricacid. [1 mark]

(iii)ldentifythe browngasandwritean equation

for itsformation [2marks]

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CONFIDENTIAT

3 Seorangpelajarmengujiairdaripada sebuahlombongyangmengandungi ionplumbum

(ll).Kehadiran ionplumbumbolehditunjukkandaripadamendakan yangberwarna kuning
plumbum (ll) iodida.Hasildarabketerlarutan
untuklarutantepuplumbum(ll) iodidapada
15oCadalah0.46g dm-t.

(a) (i)Tuliskanhasildarab (tl)iodidepada150C.

, Ko, bagiplumbum
keterlarutan
[lmarkah]

(ii)Kirakankepekatan
ionplumbum
(ll) dalammoldm-3. [2markah]

(iii) Kirakankepekatanion iodidadalammoldm-3. [2markah]

(iv) Kirakanhasildarabketerlarut?D,
Gp,untukfor plumbum(ll) iodide. [lmarkah]
g
(b)Suatujalurkuprumdi masukkan dalamsatukelalangkonyangmengandungi 50%
larutanasidnitrik.Suatugastanpawarnadanreaktifdibebaskan.
Gasitu bertindakbalas
denganoxygendan membentuksatugasperang.
(i) Namakangasyangtanpawarnaitu. [1 markah]

(ii) Tulissatupersamaan
untuktindakbalasantarakuprum
danasidnitrik.[lmarkah]

(iii) Kenalpasti
gas perangtersebutdantulispersamaan
pembentukannya.[2
markah]

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CONFIDENTIAL* 10

is a powerful
4. Pethidine painkilling
drug:

CHs CH.
I II
I *Nl- cr H
N:
,/\ ./\
CHZ CHZ CHZ CHZ

CH, CHz

o
co2cH2cH3 c02cH2cH3

Pethidine E

(a) The pethidinemoleculecontainstwo functionalgroups,one whichreactswith dilute

acidto givecompoundE.
hydrochloric

(i) What type of reactionis this and what type of functionalgroup does it showthe
pethidinemoleculeto have? [2marks]

(ii) Nametheotherfunctionalgroupin themolecule.Statethetypeof reaction

undergone,andgivethestructuralformulaof eachof the products,
when
pethidine
reactsunderrefluxwithaqueous sodiumhydroxide.
[3marks]

group: ......
Functional

: ......
Typeof reaction

:
Structuralformula

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CONFIDENTIAL* 11

adalahubat tahansakityangamatberkesan
4. Pethidine

CHs CHs
II I
I
*lLcrH
N:
./\ ./\
CHZ CHZ CHZ CHZ

CHz CHz

o
co2cH2cH3

Pethidine

(a) Molekulpethidinemengandungi
duakumpulanberfungsi,
salahsatudaripadanya
bertindakbalasdenganasid hidroklorikcair untukmenghasilkan
sebatianE.

(i) Apakahjenistindakbalasyangterlibatdan apakahjenis kumpulanberfungsiyang

terlibat? [2markah]

(ii) Namakankumpulanberfungsiyang satulagidalammolekultersebut. Nyatakan

jenistindakbalasyangakanditunjukkan,dan berikanformulastrukturbagisetiap
hasiltindakbalasapabilapethidine
bertindak
balasdengannatriumhidroksida
akueusdi bawahrefluks. [3markah]

Kumpulan
berfungsi
:

Jenistindakbalas:

Formula
struktur:

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 CONFIDENTIAL* 12

j reactswithaqueous
(b) 2-bromobutane hydroxideionsto givebutan-2-ol.
r (D forthisreaction.
Statethe condition [1 markl

i
[1 mark]
:l: ....
li fii) Statewhattypeof mechanism in thisreaction.
is involved
il
I

(iiD Statethe reagentsneededto convert2-bromobutane

to
CH3CH2CH(CH3)CH(OH)CH3 in twosteps. 12marksl

Step1 : ........

Step2 : ......

(iv) between2-bromobutane
Nameonereagentthatcanbe usedto differentiate
andCHgCH2CH(CH3)CH(OH)CH3 withoutheating. [1 mark]

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CONFIDENTIAL* 13

butan-2-ol.
bertindakbalasdenganion hidroksidaakueusmenghasilkan
(b)2-bromobutana
(i) Nyatakankeadaanuntuktindakbalasini. [1 markah]

jenismekanisma
Nyatakan yangterlibatdalamtindakbalasini. [lmarkah]

(iii) reagenyangdiperlukan
Nyatakan untukmenukarkan kepada
2-bromobutana
dalamdua langkah.
CH3CH2CH(CH3)CH(OH)CH3 [2 markah]

L a n g ka 1
h :......

L a n g ka 2h : ......

(iv) Namakansatu reagenyang bolehmembezakan dan

antara2-bromobutana
CHgCHzCH(CH3)CH(OH)CH3 tanpapemanasan. [1 markah]

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 I'

CONFIDENTIAL* 14

Section B [60 marks]

Answertour questionsin fhis section.

5. (a) The majorbuffersystemthat is usedto controlthepH of bloodconsistsof carbonic

acid,HzCOg and sodiumhydrogencarbonate, NaHCOe. Explainhowthe systemworksin
the pH of the blood.
controlling [4 marks]

(b) 20.0cm3of 0.20moldm-3aqueousNHgwastitratedwith0.16moldm-3aqueous

HCl.Sketcha graphof pH againstvolumeof HCI(aq)addedduringthe titrationprocess.
point.
Markandexplainthe positionof the equivalence [4 marks]

fromthe Arrhenius
(c) The activationenergy,E",of a reactioncanbe calculated
equation:
k _ 1 " -E,lRT

w h e r e k = ra te co n sta n t,ft=g d sconstant,T=tem per atur e,andA= fr equency fac tor .

Rateconstants for the decomposition acidare k = 4.75x 10{ s'1at
of acetonedicarboxylic
293K andk = 1.63x 103-s-1at 303 K.
(aq) #
CO(CH2COOH)z +2 COz(g)
CO(CHs)z(aq)
(D Calculatethe activationenergy,E" , of thisreaction. [4 marks]
(ii) Writethe rate equationfor the reaction. [1 mark]
(iiD Whatis the timetakenfor the concentration (aq)
of CO(CH2COOH)z
to changefrom2.00moldm'3to 1.00moldm-3at 303 K. [2 marks]

6. (a) Thefollowingdataarefoundof chlorine.

Enthalpychangeof atomisation, AHr = +121kJmol-1
Electronaffinity, AH2 = - 364 kJ mo'1
Enthalpychangeof hydration, AH3 = - 381 kJ mol'1
By drawingan energycycle,calculatethe enthalpychangefor the reaction,AH4.
% Clzt.g)+ water+ - Cl- (aq) AH+.
Deducethe strengthof chlorineas an oxidisingagentbasedon the AHr valueobtained.
[6 marks]

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CONFIDENTIAL* 15

BahagianB[60markahl

Jawabempat soalandalambahagianini.

5. (a) SistempenimbalutamayangdigunakanuntukmengawalpH darahterdiridaripada

asidkarbonik,HzCOs NaHCO3.
dan natriumhydrogenkarbonat, Terangkan bagaimana
sistemini berfungsidalam pH darah.
pengawalan [4 markah]

(b) 20.0cm3of 0.20moldm-3NH3akueusdititratkandengan0.16moldm-3HCIakuas.

semasaprosespentitratan.
Lakarkansatugraf pH lawanisipaduHCI(ak)ditambahkan
takatkesetaraan.
kedudukan
danterangkan
Tandakan [4 markah]

(c) Tenagapengaktifan, daripadapersamaan

E",suatutindakbalasbolehdihitungkan
Ar r h e n i u s '
k - A |-E " /RT

di manak = pemalarkadar,R = pemalargas,T = suhu,danA = faktorfrekuensi.

Pematar-pemalarkadarbagipenguraian adalahk = 4.75x 10a g1
asidasetondikarboksilik
pada293 K dan k = 1.63x 103's-1pada303K.
(ak) =-
CO(CH2COOH)z + 2 COz(g)
CO(CH3)2(ak)
(i) tenagapengaktifan,
Hitungkan E" , bagitindakbalasini. [4 markah]
(ii) Tuliskanpersamaan
kadarbagitindakbalasitu. [1 markah]
(iii) Kirakanmasayangdiambiluntukkepekatan (ak)berubah
CO(CH2COOH)z
dari2.00moldm-3ke 1.00moldm-3pada303K. [2 markah]

6. (a) Databerikutadalahdiperolehibagiklorin.
Perubahan entalpipengatoman, AHr = +121kJmol-1
Afinitielektron, AHz = - 364 kJ mo'l
Perubahan entalpipenghidratan, AH3 = - 381 kJ mol-1
Denganmelukissuatukitartenagaatauselainya, perubahan
hitungkan entalpibagitindak
balasberikut,AHn.
%C l z@)+w a ter +e +Cl- ( aq) ,AHr .
kekuatanklorinsebagaiagenpengoksidaan
Deduksikan nilaiAHayang
berdasarkan
diperoleh [6 markah]

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CONFIDENTIAT 16

(b) (i) Gasescanonlybe liquefiedby pressurealoneif theirtemperature

is belowtheir
no amountof pressurewillliquefya
T".Abovethe criticaltemperature
'criticaltemperature',
gas.
for theircriticaltemperatures.
Usethefollowingdataandsuggestan explanation
Gas formula M, T"/oc
Methane CHo 16 -82
Ammonia NHs 17 133
steam Hzo 18 374
[5 marks]
(ii) In the industrial of air,highpressureair is allowedto expandintoa
liquefaction
regionof lowpressure, whereupon itstemperature dropsby a largeamount.An idealgas
doesnotshowthisbehaviour. Givean explanation for the aboveobservation.
[4 marks]

oxidecanbe represented
7 Theformationof magnesium cycleas
witha Born-Haber
shownbelow.

Md-(sl r 0r3-{g)

t
J*
Ms(g)
In',
olsl

f*
Ms(s)
A
I
o(g)
an,

J*,
Mg(s)
A
I
ar.
* o,,o

(a) (i) Namethe enthalpychangeAHr,AHzand AHz [3marks]

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 http://edu.joshuatly.com/
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CONFIDENTIAL- 20

8s ?rl
9. (a) Explainthe term opticalisomerism,usingthe compoundCHaCH(OH)CH2CH3
example. [3 marks]

(b ) X, C8H10O , liberateswhitefumeswithphosphorous(V)chloride.X reactswithalkaline

iodineto giveyellowprecipitates.WhenX is heatedwithan excessof concentrated
sulphuric acid,compound to X. Undersuitableconditions
Y is formed.Y canbe converted ,
Y undergoespolYmerization.
Determine andwritethe
the structureof X andY. Explainhowyouderivethe structures
of the reactionsinvolved.
Equations [Tmarks]

(c) Compounds A and B aretwo isomerswithmolecularformulaCaHroO. A dissolvesin

aqueoussodiumhydroxidebut B doesnot.B givesoffwhitefumeswiththionylchlorideand
withalkalineaqueousiodinebutA doesnot.B is synthesised
formsa yellowprecipitate
whereasA is from4-ethylaniline.
startingfrombromobenzene

formulaeof A andB. [5 marks]

andwritethe structural
Explainthe aboveobservations

R andS havethefollowingstructure.
10.(a) Compounds

@"HzCHzNHz @"t2coNH2
RS
for the reac,tions,
(i) Writeequations with
if any,whenR andS reactseparately
acidundersuitableconditions.
dilutehydrochloric [2 marks]

used,and
statingthe reagentsandconditions
(ii) Describebrieflya chemicaltest,
to distinguish
observations, betweenR andS. [3 rnarks]

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 http://edu.joshuatly.com/
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(b) Statethe reagentsandconditions

for steps| , ll and lll. Drawthe structuralfonnulaeof
A andB.

g II,
CH3CH2CH2BT
$ CH*CHaCHaCOTH

III

Bf CHsCHzCTCO2CI
Qlo*
[5marksl

(c) Describethe schemeof reactions(in

notmorethan3 steps),slatingthe reagentsand
conditions,
forthesynthesis starting
rrom@Lr. .
@cooc2H'
"
[Smarks]

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 http://edu.joshuatly.com/
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JABATAN PELAJARAN JOHOR

SIJIL TINGGI PERSEKOLAHAN MALAYSIA

STPM 96211 http://edu.joshuatly.com/

CONT'IDENTI.A,L*
 ANSWERFOR CHEMISTRYPAPER1 (TRIAL EXAM}
2011

1 D 11 D 21 c 31 B 41 G
2 A 12 D 22 D 32 A 42 c
3 D 13 B 23 B 33 B 43 A
4 A 14 D 24 A 34 c 44 B
5 A 15 c 25 D 35 c 45 D
6 B 16 c 26 B 36 A 46 B
7 c 17 A 27 D 37 B 47 B
8 c 18 B 28 B 38 D 48 D
9 A 19 G 29 B 39 D 49 B
10 B 20 B 30 c 40 c 50 B

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Question Details Mark Awarded
1(a)(i) PV = nRT 1
= (1.5+ x + 1,2)x 8.31x 29g
500x 103x20.0x 10-3 1
X =1.3 1
Or
..
x= 500x 103x20.0 x 10-3- 2.7
8.31x 298
1 .3

1(a)(ii) 1 .5
x500=l88k P a
1 .5+ I .3 +1 .2

1(bxi) N: 1s22s22p3

1(bxiD xx +*
** ot
Ho*lx IJ*
HH

1(c)(i) Relativemolecularmass of propanoneis higher,therefore

strongerVan der Waals forces of attractionsexist between
moleculescomparedto the ether.

1(c)(ii) Ether: sp3

Propanone:spt,sp'

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Question Details Mark Awarded
2(a) (i) The standard electrode potentialis the potential difference
between the standard hydrogen electrode and other
electrode systems with the concentration of 1.0 M at t
atm / under standard conditions

2(a) (ii) SrOu t- 2e --> 2SOot-

2l ---+ la+2e

Sror'- 2r 2SOot-

2(a) (iii) Pt(s)/l-(aq),lz(aq) SrOu o (aq) , SOa2- (aq) / pt(s)

2(a) (iv) E@.ur = +2-A1 V -(+0.54V )= + 1 . 4 7 Y

2 (b) (i) P solid Q: solid &liquid R: liquid

S liquid& gas T: Gas 4-5 correct:2m
2-3 correct:1m

2 (b) (ii) Densityof solid W is lower than liquidW.

2 (b) (iiD The meltingpoint decreasewith increasein pressure

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 3 (a) (i) K.p= [ pb'z.]lll

3 (a) (ii) R.M.Mof Pbl2= 461,

concentrationof Pbl2in water =0.46 g dm-.
The concentrationof the lead ion = 0.46t461
= 9.978X 104 moldm-3
=10.0X 10-4mol dm-3

3 (a) (iii) The concentrationof the iodide ion = 2 X I pbr.J

= 2 X 9 . 9 7 8 X 1 0 -4

. , . , , :.. = 1 . 9 9 6 X1 0 3 mo ld m-3
= 2.e X 10 3 mol dm-3

3 (a) (iii) K"p= [Pbr.][r],

=[9.978X 104]l 1.996X 10-.12
= 3.975X 10-emol3dm-e
= 4.0 X 10-emol tdm-9,

3 (b) (i) Nitrogenmonoxidegas, NO

3 (b) (ii) 3Cu1"y+ 8HNO31"qy
-'3Cu(NO3)21"01
+ 2NO (e) + 4HzOo)

3 (b) (iii) Browngas : nitrogendioxide,NO2

2NQnl + Oe{s)e 2NO4e1
Colourless Brown

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 Question Details Mark Awarded

aa(i') Acid-base reaction

Aminefunctionalgroup

('i) Functionafgroup : Ester

I

Typeof reaction : hydrolysis

StructuralFormula:

CHr
I
I
N:

CHz CHz
II I
I I
C\
C
rts,
COO- Na* c2H5oH

4(b) (i) Reflux

(iD Nucleophilic
substitution

(iiD Step1 - magnesium

anddryether

Step2 - CH3CHO
followedby diluteacid

(iv) Sodium/ PCls/ SOCI2

/ PCl3

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Question Details Mark Awarded
5(a) H2CO3(aq) <-----+ HCO3 (aq) + H*(aq)

In the presenceof acid,

HCO3-(aq) + H"(aq) r------->HzCOg(aq)

Carbonicacid being unstable,decomposeto CO2and H2O

In the presenceof alkali,
llzcor(aa) + oH-(aq) r--> HCo:-(ad + Hro(l)
5(b)
Shape-1m

Equivalencepoint Label- 1m

End point<7 -1m

i 1,0 ll :'s !r j5 ;hl ,i5

-t0
ltrlurn* of fi{} rnl$c.ljern'

Hydrolysisof NHa*ions in water,thus is acidic

NHo* + 11rg <-> NH, + 1-1rg* pH<7

5(c) (i)
fsk=rgA-
E rl)
#r*f, I

E- 9: =!:-(f -1] unsubstituted

k2 2.303R\72 \ )

Substituting kr = 1.63x 10-3, T1= 303 substituted

kz=4.75x 10-a,T2= 2g3
E"= 9 .1 0x 1 0 4J o r 9 1 .0kJ
(ii) Rate = k[CO(CHTCOOH)r] 1
0.693
(iii) llme = ___;
1.63x10-' 1
= 425s 1

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 Details

%.ch(o)--ll3l-+ct1g1 4 correct:2m

lr 3 correct:1 m

^rLI l-ta+
JI
Cr(aq)( -38r cr(g)

AHa= +121+(- 364) +1-381)

= 121-364-381
= 424 kJ

AHavery exothermic,

Criticaltemperature of CH+ < NHe < HzO

6(bxi)
- CHohas weak Van der Waals forces of attractionbetween
molecules,

- NH. and steam has strong H-bonding

- H-bondingin water is strongerthan in ammonia

- the strongerthe intermolecularforcesof attraction, the more

gnergyis requiredto overcomethem,thusthe criticaltemperature

-Energyis requiredto overcomethe intermolecularforces of

attraction.

- energy is drawn from the surroundings,temperaturedrop

-ideal gas has negligibreintermolecularforces of attraction

- expansionof idealgas does not requireenergyto overcomethe

intermolecularforces of attraction

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 Question Details Mark Awarded

7(a)(i) AHt = Atomisationenthalpyof magnesium

I
LHz = First ionisationenergyof magnesium
I
AH7= Latticeenergyof magnesiumoxide
I

(ii) AH r =A Hr +A Hz +A Hs +A Hq + A Hs + A Ho + A Hz
I
= +150+(+736)+1+ 1450)+(+950) +(-3389)
I
= - 603 kJ/mof
I

The chargeof Mg 2*ion and Ba 2*ion are the same but the size of the
Mg '* ion is smallercomparedto the Ba 2*ion I

Latticeenergy= QrQ. I
(iii) r* *[-

So, Latticeenergyof MgO > BaO

b(D - CFCs can cause depletionof ozonelayer

- becausethey are unreactive

fnitiationstep: CCI2F,2> . CCIFz + o Cl

Propagationstep : o Cl + O. -+ ClOo + Oz
ClOo +O -> oCl+Oz

Net reaction : 2Qt -----+ 3O2

(ii) Hydrofluorocarbon,
HFC

will not releasedamagingchlorinefree radicalsinto the atmosphere

OR
C-H bondswill br-eakdownbeforethey reachstratosphere

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Question Details Mark Awarded

8(aXi) With cold NaOH(aq)

-Chlorine undegoes disproportionation'reaction in cold I
NaOH(aq)to form NaCland NaClO.
0 -1 +1 I
Cl2 + 2NaOH > N*l +NaClO +HzO
I
-Chlorineoxidisedto NaCIOand reducedto NaCl.TheNaCl
and NaCIOproducedare sodiumsalts and have no chlorine
smell.

With hot NaOH(aq)

-Chlorineundegoesdisproportionation
reactionin hot I
NaOH(aq)to form NaCland NaClOs.
0 -1 +5
3Cl2 + 6NaOH ) SNaCl +NaClOs +3HzO I

Chlorineoxidisedto NaClOsand reducedto NaCl.TheNaCl I

and NaClO. producedare sodiumsalts and have no
chlorinesmell. (max5m)

8(a)(ii) - Fluorine is highly electronegativeelement.HFhas the

highest b.p becausehydrogenbondingexist betweenHF
molecules.
I

- Hydrogenbondingdoes not existin HCl,HBrand Hl

becauseCl, Br and I atoms are not highly
electronegative.

- b.p increases from HGlto Hl becausethe molecularsize

increasesfrom HCI to Hl. I

-The largerthe molecularsize, the stronger the Van der I

Waals forces of attraction between the molecules and
the higher the b.p.

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Question Details Mark Awarded

e(a) Opticalisomerism occursin compounds withthe same

structuralformulabut differin theireffecton plan+polarised
light.

- Opticdisomerscontaina chiralcarbon,

- Are nonsuperimposable or minorimagesto oneanother,

- Rotatethe planeof plane'polarised
lightin opposite
directionbutto the samedegree.
Eg
oH 1
I
cH. - c'- cH2cH3
I (max 3 marks)
H

(b)
Since X giveswhite fumeswith.fQlq,{ is an alcohol. I

X gives a give yellowprecipitateswith alkalineiodine shows I

that X has structure. CH3CH(OH)R

CHsCH(OH)CoH,L
HenceX is 1-phenvlethanol.
Equations:
+ PCls ->
CH3CH(OH)CoHs CH3CH(CI)CoHs+
x HCI + POCIr
White fumes

+ 4Iz + 6Na OH- ----+ CHI3 +

CH3CH(OH)CoHs
yellow precipitate
X

+5NaI+5HzO
CoHsCOO-Na

ExcessH2SO4
CH3CH(OH)CeHs CHz= CH (C6Hs) +
X Y HzO

X undergodehydrationto form Y, phenylethgne,

I
CHe:CHCoHr
(7)
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( c) - A and B are aromaticcompounds,highlyunsaturated
-A isaphenol
1
- B contains-OH group and the structure
OH
I 1
cH3-c-
I
H

- 4-ethylanilinereactswith nitrousacid to produceA

- bromobenzenereacts with Mg/dry ether to produce a
Grignardreagent.The Grignardreagent then reactswith
ethanaltoproducea 20alcohol,B
OH
I
CHCH:
A: B:

cH2cH3

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Question Details Mark
Awarded
,r;<\
10(a)(i) + Hcl H2CH2NH3*Cl- 1
\!2/"t2cH2NH2

+ Hct+Hzo + NH4cr 1
@"n2coNHz
-@cH2cooH
(ii) Reagentsused - sodiumhydroxide l 1
Conditions- reflux f
Observations-
R - no visible reaction 1
S - gas with a characteristicsmell,NH. , given off .
1

10(b)
Step l- KCN / ethanol,reflux 1
Step ll- HCl, reflux 1
Steplll - PClsor SOCIz 1
A: CH3CHzCH2CN 1
B:
o-c-cH2cH2cH3 1
10(c)

@*. ooH
1
I
lCzHsOH /
lConc H2SO4
,
lreflux
I
7 .1 t
\!,lcooc2Hs
Step1 - oxidationof methylbenzene 'l

Reagent- KMnOrandH2SOa 1
Condition
-reflux

Slep2 -esterification 1
Reagent- ethanolanda concentratedH2SO4 1
condition
- reflux

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