Practica 4

Sistema Mezcla Cronica Soln etanol

1 50ml 5ml

2 50ml 25ml

Sistema 1

1 6 90

VNa2S2O3 CNa2S2O3
t S1 S1 ( )2 2 3
4 =
0 0 0 3
3 15.7 0.01046667 (7 0.01)2 2 3
6 12.1 0.00806667 4 (1) =
5 3
9 9.2 0.00613333 = 0.004666667
12 7 0.00466667
(2 0.01)2 2 3
15 5.2 0.00346667 4 (2) = = 0.00133
25 3
18 4.2 0.0028
21 2.6 0.00173333
24 2.3 0.00153333
27 2 0.00133333
30 1.6 0.00106667
VNa2S2O3 CNa2S2O3
T s2 S2 S2
0 5.1 0.0034
3 2 0.00133333
6 1.2 0.0008
9 1.1 0.00073333
12 0.8 0.00053333
15 0.5 0.00033333
 t vs CNa2S2O3
0.012

0.01

0.008

0.006
t

0.004

0.002

0
0 5 10 15 20 25 30 35
CNa2S2O3

t VNa2S2O3 CNa2S2O3 -Ca delta t CA x y

-
0 0 0 0.010466667 3 0.00523333 5.25270686 #NUM!
- -
3 15.7 0.01046667 -0.0024 3 0.00926667 4.68133155 7.13089883
- -
6 12.1 0.00806667 -0.00193333 3 0.0071 4.94766049 7.34712194
- -
9 9.2 0.00613333 -0.00146667 3 0.0054 5.22135633 7.62337532
- -
12 7 0.00466667 -0.0012 3 0.00406667 5.50493162 7.82404601
- -
15 5.2 0.00346667 -0.00066667 3 0.00313333 5.76565788 8.41183268
- -
18 4.2 0.0028 -0.00106667 3 0.00226667 6.08944496 7.94182905
- -
21 2.6 0.00173333 -0.0002 3 0.00163333 6.41713236 9.61580548
- -
24 2.3 0.00153333 -0.0002 3 0.00143333 6.54775254 9.61580548
- -
27 2 0.00133333 -0.00026667 3 0.0012 6.72543372 9.32812341
-
30 1.6 0.00106667 -0.00106667 -30 0.00053333 7.53636394 #NUM!

= +1
= 0.004666 0.006133 = 0.0012
= +1
= 12 9 = 3
 + +1
=
2
0.006133 + 0.004666
= = 0.0012
2
= ( )
= (0.00406667) =-5.50493162

= ( )

0.0012
= ( ) = 7.82404601
3

sistema 1
0
-7 -6.5 -6 -5.5 -5 -4.5 -4
-2

y = 1.24x - 1.1644 -4
R = 0.8622
LNCa

-6

-8

-10

-12
LN(-CA/t)

M=n=1.24

K= 1.16=0.3134
Sistema 2

sistema 2
t VNa2S2O3 CNa2S2O3 -Ca delta t CA x y
0 5.1 0.0034 0.00068 3 0.00047333 -7.6557107 -8.39203005
3 2 0.00133333 0.000266667 3 0.00021333 -8.45265467 -9.32812341
6 1.2 0.0008 0.00016 3 0.00015333 -8.78289636 -9.83894903
9 1.1 0.00073333 0.000146667 3 0.00012667 -8.97395159 -9.92596041
12 0.8 0.00053333 0.000106667 3 8.6667E-05 -9.35344122 -10.2444141
15 0.5 0.00033333 6.66667E-05 -15 3.3333E-05 -10.3089527 #NUM!

= +1
= 0.0008 0.00133333 = 0.00016
= +1
= 12 9 = 3
+ +1
=
2
0.0008 + 0.0073333
= = 0.0007666
2
= ( )
= (0.00406667) =-5.50493162

= ( )

0.0007666
= ( ) = 9.83
3
 Sistema 2
-8
-9.5 -9.3 -9.1 -8.9 -8.7 -8.5 -8.3 -8.1 -7.9 -7.7 -7.5

-8.5

y = 1.1209x + 0.1431
R = 0.9855 -9
LnCA

Sistema 2
-9.5 2)
Linear (Sistema

-10

-10.5
Ln(-CA/t)

M=n=1.12

K= 0.1432 = 1.15