BI TP

2
Bi 1: Xt phn ng oxi ho-kh: Cu ( r ) 2 Ag Cu 2 Ag (r )
a/ Hy vit cc na phn ng v cho bit phn ng no l phn ng oxi ho, phn ng no l phn
ng kh.
b/Nu s dng phn ng ny ch to mt pin in th phn ng no xy ra Anot,phn ng no xy
ra Catot, in cc no l in cc dng(+)
c/hy cho bit chiu dng in(quy c) v chiu chuyn vn ca in t trn dy dn ngoi.
d/Vit k hiu quy c ca pin
e/Tnh sut in ng E0 ca pin
Bi 2: Tnh sut in ng E0 pin to bi phn ng:
Ag Cr 2 Ag (r ) Cr 3

( )

0Ag 3
Cho bit th in cc chun: p Ag = 0,8V ; p Cr Cr 2 = -0, 41V
0

0
Bi 3 : Tnh sut in ng E ca pin to bi phn ng:
2 Fe3 Cl2 2 Fe3 2Cl -
0
( 3
) 0Cl
Cho bit: p Fe Fe 2 = 0, 77V ; p 2 2Cl - = 1,36V

Bi 4: Tnh sut in ng ca pin Daniell khi[Zn ]=0,1M v [Cu2+]=1M
2+

Bit rng E0=1,1V

Bi 5: Tnh hng s cn bng ca phn ng:
2 Fe3 Sn 4 2 Fe 2 Sn 2

(
3
) 4
(
Cho bit p Fe Fe 2 = 0, 77V ; p Sn Sn 2 = 0,15V
0 0
)
Bi 6 : bit ng vi na phn ng: 2 H 2O 2e H 2 2OH - , p 0 = -0,83V
ng vi na phn ng: O2 4 H 4e 2 H 2O, p 0 = 1, 23V
Hy tnh cc th in cc khi pH=7(dung dch nc)
Bi 7 : Tnh th in cc ca cc in cc di y 25oC:
a/ Fe / FeSO4 (5.10-3 M ), j 0 = -0, 44V
b/ Ag / AgNO3 (10-3 M ), j 0 = 0,8V
c/ Pt / Fe3 (10-3 M ), Fe 2 (10-1 M ), j 0 = 0,77V
d/ ( Pt )Cl2(5atm ) / HCl 0,5M , j = 1,36V
0

Bi 8: Cho phn ng: 2 Hg 2 Ag Hg 22 2 Ag

Xc nh chiu ca phn ng 250C trong cc trng hp sau:
2
a/ Khi nng ca cc ion Ag+ v Hg 2 ln lt bng 10-4 M v 0,1M
2
b/ Khi nng ca cc ion Ag+ v Hg 2 ln lt bng 0,1M v 10-4 M
2
Bit gi tr th kh chun ca cc cp oxi ho-kh: Hg 2 / Hg v Ag+/Ag bng 0,79V v 0,8V
Bi 9: Cho Fe3 1e Fe 2 , E 0 = 0, 771V
Ag 1e Ag , E 0 = 0, 799V
2 3
Ngi ta rp 1 pin theo s : Ag / Ag Fe / Fe / Pt .
Vi [ Fe 2 ] = [ Fe3 ] = 0,1M
a/ Khi nng Ag+ bng bao nhiu th sc in ng ca pin bng 0?
b/ Tnh hng s cn bng ca phn ng: Fe2 Ag Fe3 Ag 250C