(English+Hindi)

CHEMISTRY U S

1. Among the following, correct statement

1.
is :
(1) Brownian movement is more
pronounced for smaller particles (1) UU
than for biggerparticles.
(2) Sols of metal sulphides are lyophilic.
(3) Hardy Schulze law states that bigger (2) U
the size of the ions, the greater is its
coagulating power.
(3) U- U
S
(4) One would expect charcoal to adsorb
chlorine more than hydrogen
sulphide. (4) U, U
U U
2. Excess of NaOH (aq) was added to U
100 mL of FeCl 3 (aq) resulting into
2.14 g of Fe(OH) 3 . The molarity of
FeCl3 (aq) is : 2. 100 mL FeCl3 () NaOH ()
(Given molar mass of Fe=56 g mol1 and U U 2.14 g Fe(OH)3
molar mass of Cl=35.5 g mol1) FeCl3 () U ,
(1) 0.2 M ( Fe U =56 g mol1
(2) 0.3 M Cl U =35.5 g mol1)
(3) 0.6 M (1) 0.2 M
(4) 1.8 M (2) 0.3 M
(3) 0.6 M
(4) 1.8 M

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3. Among the following, the incorrect 3.

statement is :
(1) At low pressure, real gases show
ideal behaviour. (1) U, S , U
(2) At very low temperature, real gases

show ideal behaviour. (2) U, S
(3) At very large volume, real gases U
show ideal behaviour.
(3) U, S
(4) At Boyles temperature, real gases
show ideal behaviour. U
(4) U, S U
4. For a reaction, A(g) A(l); H=3RT.
The correct statement for the reaction is :
(1) H=UO
4. A(g) A(l) H=3RT.
(2) H=U=O
(3) ?H? < ?U?
(1) H=UO
(4) ?H? > ?U? (2) H=U=O
(3) ?H? < ?U?
5. What is the standard reduction potential
(4) ?H? > ?U?
(E8) for Fe3+ Fe ?
Given that :
5. Fe3+ Fe (E8)
2+
Fe +2e Fe ; E
Fe 2+/Fe =0.47 V

?

Fe 3++e Fe 2+ ; E
Fe 3+/Fe 2+=+0.77 V
Fe 2++2e Fe ; E
Fe 2+/Fe =0.47 V
(1) 0.057 V
(2) +0.057 V
Fe 3++e Fe 2+ ; EFe

3+ 2+=+0.77 V
/Fe
(3) +0.30 V
(4) 0.30 V (1) 0.057 V
(2) +0.057 V
(3) +0.30 V
(4) 0.30 V

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6. If the shortest wavelength in Lyman series 6. U U

of hydrogen atom is A, then the longest
U A He+
wavelength in Paschen series of He+ is :
U
5A
(1) 5A
9 (1)
9
9A
(2) 9A
5 (2)
5
36A
(3) 36A
5 (3)
5
36A
(4) 36A
7 (4)
7

7. 5 g of Na2SO4 was dissolved in x g of H2O.

The change in freezing point was found 7. x 5 U U
to be 3.828C. If Na2SO4 is 81.5% ionised, U 3.828C
the value of x
Na2SO4 81.5% x
(K f for water=1.868C kg mol 1 ) is ( Kf=1.868C kg mol1)
approximately :
(U S=32 g mol1
(molar mass of S=32 g mol1 and that of Na=23 g mol1)
Na=23 g mol1)
(1) 15 g
(1) 15 g
(2) 25 g
(2) 25 g
(3) 45 g
(3) 45 g
(4) 65 g
(4) 65 g

8. Addition of sodium hydroxide solution to

8. (HA) U UU
a weak acid (HA) results in a buffer of pH 6 $U
pH 6. If ionisation constant of HA is 105, HA SU 105 , U
the ratio of salt to acid concentration in U
the buffer solution will be :
(1) 4:5
(1) 4:5
(2) 1 : 10
(2) 1 : 10
(3) 10 : 1
(3) 10 : 1
(4) 5:4
(4) 5:4

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9. The rate of a reaction A doubles on 9. A U, 300 310 K

increasing the temperature from 300 to
U 300 K
310 K. By how much, the temperature of
reaction B should be increased from 300 K U B
so that rate doubles if activation energy U B
of the reaction B is twice to that of A
reaction A.
(1) 9.84 K
(2) 4.92 K (1) 9.84 K
(3) 2.45 K (2) 4.92 K
(4) 19.67 K (3) 2.45 K
(4) 19.67 K
10. The enthalpy change on freezing of 1 mol
of water at 58C to ice at 58C is :
10. 58C U 1 58C U
(Given fus H=6 kJ mol 1 at 08C, U
Cp(H2O, l)=75.3 J mol1 K1,
Cp(H2O, s)=36.8 J mol1 K1) ( fus H=6 kJ mol1 at 08C,
(1) 5.44 kJ mol1 Cp(H2O, l)=75.3 J mol1 K1,
Cp(H2O, s)=36.8 J mol1 K1)
(2) 5.81 kJ mol1
(1) 5.44 kJ mol1
(3) 6.56 kJ mol1
(2) 5.81 kJ mol1
(4) 6.00 kJ mol1
(3) 6.56 kJ mol1
(4) 6.00 kJ mol1
11. Which of the following is paramagnetic ?
(1) NO+
(2) CO
11. ?
(1) NO+
2
(3) O2 (2) CO
(4) B2 2
(3) O2

(4) B2

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12. The pair of compounds having metals in 12. ,

their highest oxidation state is :
U S ,
(1) MnO2 and CrO2Cl2
(1) MnO2 CrO2Cl2
(2) [NiCl4]2 and [CoCl4]2
(3) [Fe(CN)6]3 and [Cu(CN)4]2
(2) [NiCl4]2 [CoCl4]2
(4) [FeCl4] and Co2O3 (3) [Fe(CN)6]3 [Cu(CN)4]2

(4) [FeCl4] Co2O3

13. sp3d2 hybridization is not displayed by :
(1) BrF5 13. mU sp3d2 U ,
(2) SF6
(1) BrF5
(3) [CrF6]3
(2) SF6
(4) PF5
(3) [CrF6]3
(4) PF5
14. Identify the pollutant gases largely
responsible for the discoloured and
lustreless nature of marble of the Taj 14. UU
Mahal. U
(1) O3 and CO2
(2) CO2 and NO2
(3) SO2 and NO2 (1) O3 CO2
(4) SO2 and O3 (2) CO2 NO2
(3) SO2 NO2
15. In which of the following reactions,
hydrogen peroxide acts as an oxidizing (4) SO2 O3
agent ?
(1) HOCl+H2O2 H3O++Cl+O2
15. U
(2) I2+H2O2+2OH 2I+2H2O+O2
UU U M U ?
(3) 2MnO
4 +3H2 O 2 2MnO 2 +3O 2 +
(1) HOCl+H2O2 H3O++Cl+O2
2H 2 O+2OH
(2) I2+H2O2+2OH 2I+2H2O+O2
(4) PbS+4H2O2 PbSO4+4H2O
(3) 2MnO
4 +3H2 O 2 2MnO 2 +3O 2 +
2H 2 O+2OH

(4) PbS+4H2O2 PbSO4+4H2O

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16. Consider the following ionization 16. A B

enthalpies of two elements A and B.
U U
Element Ionization enthalpy (kJ/mol)
(kJ/mol)
st nd rd
1 2 3
m
A 899 1757 14847
A 899 1757 14847
B 737 1450 7731
B 737 1450 7731
Which of the following statements is
correct ? ?
(1) Both A and B belong to group-1
where B comes below A. (1) A U 1 S
B
(2) Both A and B belong to group-1 B, A
where A comes below B.
(2) A U B 1 S
(3) Both A and B belong to group-2
where B comes below A. A, B

(4) Both A and B belong to group-2 (3) A U B 2 S

where A comes below B. B, A

(4) A U B 2 S
17. Consider the following standard electrode A, B
potentials (E8 in volts) in aqueous solution :

Element M 3+ / M M+ / M 17. UU
Al 1.66 + 0.55 (E8, U ) U U U
Tl +1.26 0.34
fl M 3+ / M M+ / M
Based on these data, which of the following
statements is correct ? Al 1.66 + 0.55
Tl +1.26 0.34
(1) Tl+ is more stable than Al3+
(2) Al+ is more stable than Al3+ U U,
(3) Tl+ is more stable than Al+ ?
(4) Tl3+ is more stable than Al3+ (1) Al3+ Tl+ SU
(2) Al3+ Al+ SU
(3) Al+ Tl+ SU
(4) Al3+ Tl3+ SU

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18. A metal M reacts with nitrogen gas to 18. M, U

afford M3N. M3N on heating at high
U M3N U U
temperature gives back M and on
reaction with water produces a gas B. Gas U U M3N, M
B reacts with aqueous solution of CuSO4 U B
to form a deep blue compound. M and U B, CuSO4
B respectively are :
U U U U
(1) Li and NH3 M B
(2) Ba and N2
(1) Li NH3
(3) Na and NH3
(2) Ba N2
(4) Al and N2
(3) Na NH3
19. The number of S=O and SOH bonds (4) Al N2
present in peroxodisulphuric acid and
pyrosulphuric acid respectively are :
(1) (2 and 2) and (2 and 2) 19. UUU UU
(2) (2 and 4) and (2 and 4) l S=O SOH

(3) (4 and 2) and (2 and 4)
(4) (4 and 2) and (4 and 2) (1) (2 2) (2 2)
(2) (2 4) (2 4)
20. A solution containing a group-IV cation (3) (4 2) (2 4)
gives a precipitate on passing H 2S. A
solution of this precipitate in dil.HCl (4) (4 2) (4 2)
produces a white precipitate with NaOH
solution and bluish-white precipitate with
basic potassium ferrocyanide. The cation 20. -IV l
is : , H2S U U U
(1) Co2+ HCl , NaOH
(2) Ni2+ U U
(3) Mn2+ UU -S$
(4) Zn2+ U

(1) Co2+
(2) Ni2+
(3) Mn2+
(4) Zn2+

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21. A mixture containing the following four 21. U

compounds is extracted with 1M HCl.
1M HCl c
The compound that goes to aqueous layer
is : U ,

(I) (II) (I) (II)

(III) (IV)
(1) (I) (III) (IV)

(2) (II) (1) (I)

(3) (III) (2) (II)

(4) (IV) (3) (III)

(4) (IV)

22. The reason for drug induced poisoning

is : 22. -U U U
(1) Binding reversibly at the active site
of the enzyme
(1) U
(2) Bringing conformational change in
the binding site of enzyme
(3) Binding irreversibly to the active site (2) M U
of the enzyme
(4) Binding at the allosteric sites of the (3) U
enzyme

(4) SUU U

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23. Which of the following compounds will 23. $

not undergo Friedel Crafts reaction with
U U ?
benzene ?

(1)
(1)

(2)
(2)

(3)
(3)

(4)
(4)

24. Among the following, the essential amino

acid is : 24.
(1) Alanine
(2) Valine
(1)
(3) Aspartic acid (2)
(4) Serine (3) SU
(4) U

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25. The major product expected from the 25.

following reaction is :

(1)
(1)

(2)
(2)

(3)
(3)

(4)
(4)

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26. The major product of the following 26.

reaction is :

(1) CH2=CHCH2CH=CHCH3
(1) CH2=CHCH2CH=CHCH3
(2) CH2=CHCH=CHCH2CH 3
(2) CH2=CHCH=CHCH2CH3
(3) CH3CH=C=CHCH2CH3
(3) CH3CH=C=CHCH2CH3
(4) CH3CH=CHCH=CHCH3
(4) CH3CH=CHCH=CHCH3

27. U
27. Which of the following statements is not
true about partition chromatography ? U ?
(1) Mobile phase can be a gas (1) S
(2) Stationary phase is a finely divided (2) SU S U
solid adsorbent

(3) Separation depends upon
equilibration of solute between a (3) U SU S
mobile and a stationary phase U U U
(4) Paper chromatography is an example
of partition chromatography
(4) $ , U
U
28. The IUPAC name of the following
compound is :
28. IUPAC

(1) 1, 1-Dimethyl-2-ethylcyclohexane
(2) 2-Ethyl-1,1-dimethylcyclohexane (1) 1, 1-U-2-
(3) 1-Ethyl-2,2-dimethylcyclohexane
(2) 2--1,1-U
(4) 2, 2-Dimethyl-1-ethylcyclohexane
(3) 1--2,2-U

(4) 2, 2-U-1-

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29. The major product of the following 29.

reaction is :

(1)
(1)

(2)
(2)

(3)
(3)

(4)
(4)

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30. The major product of the following 30.

reaction is :

(1)
(1)

(2)
(2)

(3)
(3)

(4)
(4)

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