FACULTY OF CHEMICAL ENGINEERING UNIVERSITI TEKNOLOGI MARA (UiTM) SEPARATION PROCESS (CHE 544) TEST 1 (1% HOURS) Answer All Questions QUESTION 1 (15 marks) (P01, PO6, CO1, CO2, C3) A mixture containing 50 mole percent methanol and 50 mole percent water is to be separated using continuous distillation at atmospheric pressure. The overhead product is to contain 90 mole Percent methanol and the bottom product 10 mole percent. The feed is enter at its boiling point. Calculate the following. @) The amount of overhead and bottom product. (marks) b) The number of trays required using McCabe-Thiele method at reflux ratio of 4, (6 marks) ©) The minimum number of trays. (2 marks) 4) The minimum reflux ratio, Re (2 marks) Use graph paper provided with the question paper. Please attach the graph paper together with your answer sheets, QUESTION 2 (15 marks) (P01, POS, CO1, Coz, C2, C4) @) Distillation column tray efficiency can be determined through three (3) ways, With the ald appropriate diagram, describe all the three (3) ways of determining the tray efficiency. (7 marks) b) For a distillation of a liquid feed containing 33% n-hexane, 37% n-heptane and 30% n- octane at 1.2 atm total pressure, determine the bubble point and the corresponding vapor composition at equilibrium for each component. Assume that the mixture can be approximated as an ideal mixture (following Raoult’s law), and take n-heptane as the base component. (Hint: Assumption of bubble point may start at 85°C). (8 marks)in-Pentane VAPOR PRESSURE, atm of: jbo 0.2} 0.15) 0.1 a) 60 70 80 $0 woo 80110 120 TEMPERATURE“C Vapor pressure data for light hydrocarbons systems 13044 07 0s 04 03 02 04 Equilibrium Diagram for Methanol-Water SystemQueston 1 Fz lod ty mol 2 ae : Xe > OS OS soe 0, %e %pz 0-4 Desa | > ae ue oe WW, Xw Misletoc Feed ip Wquid at dhe boils pos, g =! Cuerhaal Whe ar xe ) )) over wotena) Yalan@ - Fr porw A wo = dew O Component balance on a Exp = Dxo + WW, w= F-0 (oo (2S)= plod) + Wt) ww (0.5) = 9 (4) + (i@-D)(0-1) D= 4 0d) Wi D egwst YO Sredgb) Fur enviching aerating bine Nie Xn On \ an ” ea st od yexs%> 204 No gO Oe eae ai aa at X=0, 97 = OB %Xn4 O1¥ Fv sMoping spe@alg Whe, pie at point Y= xk = Xwr 01 wath are wterscction af Abe a WOR And eanciing yer Wag - From are Bega , Ae number af tras required ewes Simoes = 2) Raw tee Giegeam the a ee eae ee A _—— A) primum flax @HO , Rm cae Rn ee wat ae! Geo) 3c} = O-%Rm + 03 [Enon 0 uex 60 =%% so=*x ko="x vb a 60 so £0 90 so vo co zo ro 7 E | $024 | + D- pers Ey EE | &) D1 peysany i | | | Az Oe bas © Qe oe v | ee — Ay Hdd! 7 @-a tS ee ie orm 4 rn” 1 © & aub ae Bebo = | | Qe wy 00 I Ea wie3shg Jeyem-joueyjew 405 wesBeIg wntquinby zo ‘£0 vo so 90 zo 80 60 MeQueshon 2(A) Ayres of rey ehRciencies - © ove’ way K&denoy , Eo = Coraing Ane Entire tower we Eo = mumboer of idect AayS wunber of actual trys 2 6 Nvuc pee Any ob freney eficiency men atetvn = eomcene 0d the ay Ex + Yn - inal Se eames Se. 7 oF the mixed vapor leaving Sa - Yoo tayo Ynti = the average actval can contecrtion of the mixed! vapey entering © tay no ~ a a = dhe uneentyaton of the vapor Yhet eq uili briaen orth gg Gaentrettion ang Kaui leaving Mee hay - @ Poin /tocad ebkcienes Ger ee coneuns ON A specific pont oa the “hey ee Z Jo = concenacation FP vapor a ne omelet a syeoihe point in tay n ee F Ya - Saat Yann = Concewrzation of vapor ® enenng ray 9 ot mE yomt Nee = contenteavee of vapor det 2quikbaum oy Xn at Same port:point, aQustor 2) Raeti's baw : we Pip Bese camponend = W-heptone C&) D pccume Ts 89°C x % Ki P= 1-2 Om Cormgenen’ of oi xi A ps tos 395 2534 0.839 5 0:33 065 On \ O3% ic Basa cea oe Bs 1336 \ rage es Oe Bax Ye = 0-4) | 3 agec ® Pssume T= oo" Component XK % i at Hx : eee ac ae Cad 8 Ba ees 03% : : a “2 0:30 oat Pega 30 a: 1.203 Cee ES = 0183 | Bok X Pont ae® Assume Ts 44°C Congorest |< % «i di KK 8 0:33 22 (833 2-222 0-933. 6 par 20.8 0.0% \ 034 O4Bt OB 03 ce tO sl) Se EAR % = 0443 —O ave ee | Tyeig por’ = ee Po Caiubersr puedes — @ Le © ao =e Vepur compowitur © C4) __ g mor ¥S ae