w'fmd'i' ^W'fm<& Wmldrl iuka;%Kh - 2014

ridhk oHdj - I m;%h

ms<s;=re i|yd u. fmkau

m%Yak ms<s;=r m%Yak ms<s;=r
wxlh wxlh
(1) 3 (26) 2
(2) 5 (27) 5
(3) 1 (28) 4
(4) 1 (29) 2
(5) 3 (30) 3
(6) 3 (31) 5
(7) 4 (32) 3
(8) 5 (33) 2
(9) 1 (34) 5
(10) 5 (35) 2
(11) 3 (36) 3
(12) 3 (37) 5
(13) 2 (38) 1
(14) 3 (39) 1
(15) 4 (40) 2
(16) 4 (41) 2
(17) 3 (42) 5
(18) 2 (43) 1
(19) 5 (44) 4
(20) 1 (45) 5
(21) 2 (46) 3
(22) 4 (47) 4
(23) 2 (48) 1
(24) 5 (49) 4
(25) 1 (50) 2

[2 jk mssgqj n,kak
 -2-
w'fmd'i' ^W'fm<& Wmldrl iuka;%Kh - 2014
ridhk oHdj - II m;%h
ms<s;=re i|yd u. fmkau

1. (a) (i) He < O < Cl < Mg

(ii) Li
(iii) laf,daka
(iv) CH4 < CO < CO2
+
(v) NO2 < NO2 < NO3
(,l=Kq 45 = 20)

()
(+) (+)
Ob
(b) (i) Oa C N (,l=Kq 10)
Oc

(ii)
()

(+) (+)
O (+) (+)
O
O C N O C N
()
O O
(1) (2)

wfrdamK jHdma; we;s wdldrh iudk neka ia:dhs;djhka tlsfklg iudk f'
tfy;a jvd oaHq;a iDK mrudKq jk N yd O u; Ok wdfrdamk mej;Su ia:dhs;djh
wvqug fya;=f'
(,l=Kq 53 = 15)

(iii) CO/ ldnka fudfkdlaihs (,l=Kq 02)

(c)
mrudKqj uqyqlrKh mrudKqj jgd bf,lafg%dak
hq., cHd;sh

Oa SP3 p;=ia;,Sh
Na SP2 ;,Sh ;%sfldaKdldr
C SP frh
(,l=Kq 36 = 18)

(d) (i) bf,lafg%dak kHdi

Zn 4s 3d Co 4s 3d
2 10 2 7

Zn ys kHdih idfmalaIj jvd ia:dhs f' bf,lafg%dak ia:dk.;ug we;s keUqrej
wvqf'
f,dayl nkaOkfha m%n,;djh wvqf'
(,l=Kq 25 = 10)
O O
(ii) CH3 C OH ys wka;r wkql H nkaOk mj;S' CH3 C H ys ia:r oaO%ej - ia:r
oaO%ej wdlrIK n, muKla we;s w;r idfmalaIj m%n,;djfhka wvqh'
(,l=Kq 33 = 9)
(uq ,l=Kq 92)
[3 jk mssgqj n,kak
 -3-
2. (a) (i) A - Na B - Mg

(ii) C - NaOH E - MgO (,l=Kq 16)

(iii) H2 $ yhsv%cka (,l=Kq 04)

(iv) 4 Na + O2 2Na2O
2Na + jemqr O2 Na2O2

(v) Mg(s) + ;kql H2SO4 MgSO4 + H2(g)
(aq) (aq)

Mg(s) + idka 2H2SO4 MgSO4 + SO2(g) + 2H2O(l)

(aq) (aq)

(,l=Kq 04)

(vi) NaCl(aq), NaOCl(aq), H2O(l) (,l=Kq 23 = 6)

(vii) NaOH - m%n, NdIal

Mg(OH)2 - NdIal
Al (OH)3 - WNh.=Ks
H2 SiO3 - b;d n, wd,sl
H3 PO4 - n, wd,sl
H2 SO4 - m%n, wd,sl
HClO4 - b;d m%n, wd,sl (,l=Kq 23 = 6)
,l=Kq (66) + (72)

(b) (i) Co (,l=Kq 05)

(ii) Is 2s 2p 3s 3p 3d 4s (,l=Kq 10)

2 2 6 2 6 7 2


(iii) + II CoO (,l=Kq 02)

+ III Co2O3 (,l=Kq 02)

[Co(H2O)6]
2+
(iv) (,l=Kq 06)

(v) (a) Co(OH)2 / [Co(OH)2(H2O)4] - ks,a wjlafIamh (,l=Kq 05)

[Co(NH3)6] - ly Uqre djKh (,l=Kq 05)
2+


(b) [Co(H2O)6] + 2OH Co(OH)2 + 6H2O /
2+

Co(OH)2 + 6NH3 [Co(NH3)6] + 2OH (,l=Kq 05)

2+

[Co(H2O)6] + 2OH [Co(OH2) (H2O)4] + 2H2O (,l=Kq 05)
2+


(vi) jrKh ;o meye f'$ ly Uqre" ;e,s Uqre njg m;af' (,l=Kq 05)
[Co(NH3)6] ixlSrKh [Co(NH3)6] njg TlaislrKh f' (,l=Kq 05)
2+ 3+

3. (a) (i) PV = nRT u.ska
P1lA
V = lA f' P1lA = nTRT ; nT =
RT
(ii) m<uq wjia:djg P1lA = nTRT nT = P1lA / RT
fojk wjia:djg P2 lA = nTR2T nT = P2lA / 2RT

uq jdhq ujq , ixLHdj fjkia fkdjk neka "
P1lA P lA
= 2
RT 2RT
P2 = 2P1
[4 jk mssgqj n,kak
 -4-

(iii)
h Yla;shlska T1
2T
hq;a wKq Nd.h

-1
f.h / ms
^,l=Kq 4.0hs&

(b) jdIam jdIam jdIam jdIam
mSvkh mSvkh mSvkh mSvkh
PA P A
PAC
PAB PA
PB
PA
PC PC
PB
XA 0 1 1 0 XA
XB 1 0 0 1 X
c

^1& rEmh ^2& rEmh

(v) AB Y%Kh mmQrK ;;a;ajfhka iDK wm.ukhla fmkajk w;r AC Y%Kh

mmQrK ;;a;ajfhka Ok wm.ukhla fmkajhs'
^,l=Kq 6.0hs&
4. (a) (i)
CH3 CH3
CH3 C NH2 CH3 C OH
CH3 CH3
C F
(ii)
CH3 CH3 O
C2H5 C NH2 C3H5 C OH C2H5 C CH3
H H
B E Y
(iii)
CH3
CH3CH2CH2CH2NH2 CH3 CH2 NH2
C
H

(iv)
CH3 CH3 CH3 O
CH3 C CH2 NH2 CH3 C CH2 OH CH3 C C H
H H H

A D X
,l=Kq (10 4 = 40)
[5 jk mssgqj n,kak
 -5-

(b) (i) CH3 OH (,l=Kq 4 hs)

(ii)
+ OH CH3 Br CH3
OMgBr H
CH2 C CH3 C C H C C Br
CH2 C CH3 CH3
CH3 CH3
CH3

P Q R S
,l=Kq (5 4 = 20)
(iii)

m%;sl%shdj m%;sl%shd jr.h

1 O
2 E
3 AE

,l=Kq (2 3 = 6)
,l=Kq 30
(c) (i)
m<uq mshjr
CH3 CH3
8 ..
H3C C Br H3C C+ + Br
+8

CH3 CH3

CH3
H3C
: OH

H3C C OH
H3C C+
CH3
CH3

,l=Kq (7 2 = 14)

(ii) CH3 CH2 - Br m%d:l we,als,a fya,hsvhls'

+
fuh idokq ,nk ldfnd legdhkh CH3CH2 f'
th m%d:l ldfnd legdhkhla neka wia:dhs f'
C - Br nkaOkh |Su;a kshqla,sfhdahs,h jk ( OH iu. jk nkaOkh iEu;a

tljr isjk neka ;ks mshjr m%;sl%shdjls' ^10)

CH3 H

: OH OH + Br

C

H C Br 8 +
H3C ^05)
+8

H H

kuq;a (CH3)3 C+ ldfnd legdhkh ;D;shsl ldfnd legdhkhla neka th ia:dhsh'

^01)
,l=Kq 30

[6 jk mssgqj n,kak
 -6-

5. (a) (i) PV = nRT P 2.5 103m3 = 0.15mol 8.314JK1mol1 700K

PV = 3.49 105Nm2
(ii) PV = nRT 5
8.5 10 Nm 2.5 10 m = n 8.314JK1mol1 700K
2 3 3

n = 0.365 mol

(iii) 2H2(g) + X2(g) 2H2X(g)

(x 0.08) + (0.15 0.04) + (0.08) = 0.365
x = 0.255 mol

[H2X(g)] = 0.08 mol dm3

2
(iv)
2 P
[H2X(g)] H2X(g) 2.5
2
Kp = 2
[X(2g)] [H2(g)] P P [X2(g)] = 0.11 mol dm3
H2(g) X2(g)
2.5
(
0.08
)
2

(v) 2.5 [H2(g)] = 0.175 mol dm3

mol dm3 2.5
1
Kc =
( )(0.11 0.175
)
2

2.5 2.5
= 4.7 mol dm
1 3

( )

0.08 8.5 10
2

( 0.08 )
5 2
0.365 Pa
1
P
K = H2X(g) = 0.365 8.5 10 Pa
5

( 0.175 8.5 10 ) ( 0.11 8.5 10 )

p 2

=( )
5 5
0.365 0.365 P 0.175 8.5 10 5
Pa
H2(g) 0.365
= 8 10 Pa 7 1

P
X2(g) = ( 0.11 8.5 10 )
5
Pa
0.365

5a - ^,l=Kq 60hs&
+
(b) (i) Kw = [H ] [OH (aq)]

(aq)

+
(ii) log Kw = log {[H ] [OH (aq)]}

(aq)
+
log [H ] log [OH (aq)]

(aq)

pKw = pH + pOH

(iii) + -
BOH(aq) B(aq) + OH(aq)
[B ][OH (aq)]
+

Kb = (aq)
[BOH(aq)]
2
[OH (aq)]

Kb =
C
[OH ] = (KbC)1/2

(aq)

- log [OH ] = 1 log Kb 1 log C

2 2
1 K 1
pOH = 2 p b 2 log C
14 - pH = 1 pKb 1 log C
2 2
pH = 14 1 pKb + 1 log C
2 2
[7 jk mssgqj n,kak
 -7-

(iv) PH 14 + 1 log (1 10 mol dm ) + 1 log 0.1 mol dm-3

=
5 3
2 2
5
= 14 0.5
2
= 11 ^30)

(v) BCl + NaOH BOH + NaCl

NaOH + HCl NaCl + H2O
BOH + HCl BCl + H2O
,l=Kq (3 4 = 12)

(vi) (I) pH

}p hn

} Me.O

,l=Kq (2 6 = 12)
15 35 V HCl

}
(II) NaOH iu. m%;sl%shd l< 0.1 15
=
HCl ujq, 1000
= 1.5 103 mol
BOH iu. m%;sl%shd l<
HCl ujq, } =
0.1
1000
(35 15)

= 2 103 mol
X ys ;snQ NaOH ujq, = (1.5 103 + 2 103) 50
25
= 7 10 mol
3

= 2 10
3
C1 100 = 0.08 mol dm3
25

= 7 10 1000
3
C2 = 0.28 mol dm3 ,l=Kq (2 6 = 12)
25
5b - ^,l=Kq 90)

6. (a) (i) i. c,Sh djKfha imQrKfhkau whk njg >gkh mj;sk jH

ke;fyd;a
>k j wjia:df fukau c,Sh djKfha o whk mj;sk jHh
ii. tjeks ixfhda.j, ix;Dma; djK ;=< whk idkaKh b;d by< f' whk w;r
o wdlrIK n, mj;S' ^whk tlsfklska iajdh;a; fkdf'&
^,l=Kq 10)

[8 jk mssgqj n,kak
 -8-
(ii) m<uq Ag2CrO4(s) >gkh isf'
lsish wjia:djl b m%;sl%shd iS>%;djh miq m%;sl%shd iS>%;djhg iudk f'
Ag2CrO4(s)
2Ag+(aq) + CrO4 (aq) 1 2

2
t;eka isg whk idkaKhka ksh;j mj;sk w;r [Ag (aq)] [CrO4- (aq)] hk
+ 2

whksl .=;h w, WIAK;ajfha ixfhda.fha KSP g iudk f'

NH3 tl;= l, g'

2 hk iu;=,s;;djh we;s fuka
+
Ag+(aq)+2NH3(aq) [Ag(NH3)2] (aq)

djKfha Ag idkaKh wvq f' tg f,a peg,shr uQ,Oruhg wkqj by; 1

+

2
m%;sl%shdj M, foig keUqre fuka [CrO4 (aq)] jef'
,l=Kq (2 10 = 20)

2
(iii) Ag2CrO4(s) 2Ag+(aq) + CrO4(aq)
iu;=,s; 4 4
idkaKh 2 10 1 10
mol dm3
2
KSP = [Ag+(aq)]2 [CrO4(aq)]
= (2 10 mol dm3)2 (1 10 mol dm3)
4 4


= 4 10 mol3 dm9 ,l=Kq 20
12

2 1
(iv) kj [CrO4 ] = (5 105 + 100) mol dm3

= 1 mol dm3
1/
Ksp 2
[Ag +
] =
(aq) 2
[CrO4aq

( 100 mol dm )
1/
= 4 10 mol 3dm
3
2
12
9

= 2 10 mol dm3
6

wjlafIamk Ag2CrO4 ujq,

= (2 10 2 10 ) 500 mol
4 6

1000
= 1 10 mol ,l=Kq 20
4



(v) KC = [Ag(NH3)+2(aq)]
[Ag (aq)] [NH3 (aq)]
+ 2

(2 10 mol dm3)
4
1 108 mol dm3 =
(2 10 mol dm3 ) [NH3 (aq)]
6 2

[NH3](aq) = 1 10 mol dm3

3

iuia: NH3 ujq, = (1 10 ) + (2 2 10 ) mol

3 4

2
= 7 10 mol
4

,l=Kq 20

6a - ^,l=Kq 90)

[9 jk mssgqj n,kak
 -9-
(b) (i)
(I) H = (2 105 + 0) (0 + 89) KJ mol
1

= 299 KJ mol (12)

1

(II) S = (2 72 + 27) (42 2 137)JK mol

1 1

= 224 JK mol (12)

1 1

(III) G = H ST = 299 KJ mol 224 JK mol 298 K

1 1 1

= 299 KJ mol 66.752 KJmol

1 1

= (299 66.752) KJmol

1

= 232.248 KJmol (12)

1

(ii) G i|yd + w.hla ,ef' we;s m%;sl%shdj iajhxisoaO fkdf' ta wkqj X Tlaisydrlh

f,i o"Y Tlaisydrlh f,i o l%shd l< hq;=h' tk 'r' fY%afha Y by<ska o" X my<ska
o" msysgd we;' (10)

(iii) I. Anode - Y Cathode X

II. Anode Y(s) Y (aq) + 2e
2+

III. Cathode X (aq) + 2e X(s)
2+

IV. Y(s) Y (aq, 1mol dm ) X (aq, 1mol dm ) X(s) ,l=Kq 14
2+ 3 2+ 3

6b - ^,l=Kq 60)
C CH C C Na+
7' (a) (i) 2 + 2Na 2 + H2 (10)

C C Na+ O O Na+
(ii) + CH3 C H CH3 C C C
H
,l=Kq 10

(iii) O
C CH Hg2+ C CH3

;kql H2SO4
Na
C C Na+

O Na+
C C C
CH3
H2O

OH
C C C
CH3

PBr3

Br Br Br Br
Br2 / CCl4
C C C C C C ,l=Kq (5 11 = 55)
CH3 Br Br CH3
7a - ^,l=Kq 75)

[10 jk mssgqj n,kak

 - 10 -
(b) (i) a, h iy f (10)

(ii) a - w, NIau
h - w, NIau
f - kshqla,sfhdas,sl wdfoaY (15) 7b - ,l=Kq 25

(c) (i) NH2 N2Cl CN
(i) NaNO2 CUCN
(ii) ;kql HCl KCN
0 - 5 C
A
ldur dil H2SO4
WIaK;ajh

OH COOH

idka H2SO4

O
O C

B ,l=Kq (9 4 = 36)

(ii) we;s ixfhda.h c,Sh NaOH iu r;a lrkq ,ef'

O
NH2
H O
NaOH(aq) C O Na+
N C +

,efnk djKhg ;kql HCl djKhla tla lrhs'

+
NH2

NH3 Cl(aq)

+ ;kql HCl

O
C O Na+
+ ;kql HCl COOH + NaCl

,efnk iq wjlafIamh fmrd fjka lr .kq ,ef' th fnkafidhsla w,hhs' (14)

l,am ms<s;=r ( +
NH3 Cl(aq) COOH
H O ;kql HCl
N C +

,efnk iq wjlafIamh fmrd fjka lr .kq ,ef' th fnkafidhsla w,hhs'

,l=Kq 50

8' (a) (i) r;a lsf c,fha hfuka iy isis,a lsf kej; ;o ly meye;s wjlafIamhla
,efuka PbI2 mj;sk nj ;yjqre f' frdai meye;s ixfhda.h w,hl hjk neka
NdIal ixfhda.hls' idka HCl iu ks,a meyehla ,nd fokafka Co h'
2+

PbI2 yd Co(OH)2 wvx.= f'
,l=Kq (2 8) + (4 + 4)
[11 jk mssgqj n,kak
 - 11 -
2
(ii) [CoCl4]
Tetrachlorocobaltate(II) ion ,l=Kq (3 2 = 6)
8a - ^,l=Kq 30)

(b) (1) r;a lsf l meyehg yefrk iq meye;s f, wjlafIamh PbS2 O3 f'
,l=Kq (3 3 = 9)

(2) Y fmrKfha Tlaisydrlhla we;'

tu Tlaisydrlh Ca whk iu wjlafIamhla idoka bj;a f'
2+

fuu wjlafIamh CaC2O4 h hq;=h' ,l=Kq (3 3 = 9)

(3) Z fmrKfha Ca whk b;sj ;sfnk w;r kegf wjlafIamhla ,eug HCO3
2+
2
whk CO3 olajd fhdackh we;' CaCO3 wjlafIam f'
,l=Kq (3 3 = 9)

(4) NO3 fyda NO2 h yel' Z fmrKfha TlaislrKhla mej;sh fkdyels neka NO2 h
- -

fkdyel' ,l=Kq (2 4 = 8)
wekdhk y;r
2 2

C2O4 , S2O3 , HCO3 yd NO3 f'

,l=Kq (4 4 = 16)
8b - ^Wmu ,l=Kq 60)

(c) (A) Cl idkaKh fiu

AgCl ujq, = Ag+ whk ujq,
0.287g
=
143.5gmol
1

= 0.002 mol
Cl idkaKh = 0.08 mol dm (7)
3

(B) 2Fe + 3H2S 2FeS + S(4)+ 6H
3+ +

4Fes + 7O2 2Fe2O3 + 4SO2(4) (01)

S + O2 SO2
H2O + 5SO2 + 2MnO4 5S2O4 + 2Mn + 4H
2+ +
(4)

6H + 5C2O4 + 2MnO4 10CO2 + 2Mn (4)+ 8H2O

+ 2- 2+

(4)
,l=Kq (3 5 = 15)
C2O4 ujq, = 0.12 25 = 3 10 mol
2- 3

1000

b;s MnO4 ujq, = 3 10 2

= 1.2 10 mol
3 3

5
SO2 iu m%;l s% d l< MnO4 ujq, = 0.048 50 1.2 10
3
s h

1000
= 1.2 10 mol
3

Fe ujq, = Fes ujq, = SO2 ujq,

3+

= 1.2 10 mol 5 2
3

3
2 3
Fe idkaKh = 2 10 1000
3+

25

= 0.08 mol dm
3
,l=Kq (3 8 = 24)
[12 jk mssgqj n,kak
 - 12 -
(C) +
H idkaKh fiu
NaOH ujq, = (B) ys fmrKfha iuia; H ujq,
+

0.6
= 20
1000
= 12 10 mol
3

H2S f.ka ,enqKq H ujq, = 3 Fe mol

+ 3

= 3 2 10 mol
3

= 6 10 mol
3

wdrNl djKfha H ujq, = (12 10 6 10 )

+ 3 3

= 6 10 mol
3


6 10
3

wdrNl djKfha H idkaKh =

+
1000
25
= 0.24mol dm
3

,l=Kq (3 8 = 24)

9' (a) (i) (i) Ca3 (PO4)/ Ca3(PO4)2 CaX2 (5)

(ii) tys c, djH;djh wvq ksid (5)
(iii) 3Ca3(PO4)2 CaX2 + 14HNO3 3Ca(H2 PO4)2 + 7Ca(NO3)2 + 2HX (10)
(iv) c,fha fydka hjk neka myiqfjka flld,Sk fnda. i|yd o fhdod .; yel'
tu whk myiqfjka Ydl uq,a u.ska Wrd .efka' (5)
(v)
fmfrda,sh

H2(g) N2(g) Nd.sl jd;h

wdijkh
X
P = 250 atm
T = 450C
W;Afm%arl Fe

NH3(g)
Y
P = 1 - 9 atm
T = 850 - 1225C
pt/ Rd W;Afm%arl

NO(g)

oHq;a NO2(g)
fokh

c,h

wemghs

iqmr
fdiafa
w,amd,kh HNO3 (aq)

[13 jk mssgqj n,kak

 - 13 -

(I) A - H2(g)
B - N2(g)
C - NH3(g)
D - NO(g)
E - NO2(g)
F - wemghs ,l=Kq (6 4 = 24)

(II) P - Nd.sl wdijkh

Q - oHq;a fokh
R - w,amd,kh ,l=Kq (3 3 = 09)

(III) X - 250 atm, 450C, Fe - W;afm%r
a l
Y - 850C - 1225C ,1 - 9 atm, ma,ek$ frdah W;afm%r
a l ,l=Kq (6 2 = 12)
9a - ^,l=Kq 70)

(b) (i) wefkdavh - ghsfksh

lef;davh - ksl,a ,l=Kq (3 2 = 06)

Cl2(g) + 2e ^wefkdavfha&

(ii) 2Cl(aq) (4)

2H2O (l) + 2e 2OH(aq) + H (g) ^lef;davfha& (4)
2

(iii) wefkdavfha wdfrdamK bj;a u;aa lef;davfha wdfrdamK iemhSu;aa ksid$

Na wefkdavfha isg lef;dav l=rhg .uka lsu u.ska (4)
+


(iv) mg,h yryd wekdhk yqjudre fkdjk neka OH ixprKh je<elafuka Cl2 yd

.eu j<lajhs' (4)

(v) CO2 yd wfkl=;a wd,sl jdhq wjfYdaIKhg$ inka lvodis idh jr. ksmoug
c,h msh lsf ner f,day bj;a lsug" c,fha wd,sl;dj bj;a lsug
,l=Kq (4 2 = 08)
9b - ^,l=Kq 30)

(c) (i) m%NdixYaf,aIKh" ysre t<sfhka c, wKq |Sfuka ^m%Nd fokh&

,l=Kq (3 2 = 06)
+
(ii) NH4 , NO2 , NO3 ,l=Kq (3 2 = 06)

(iii) ksidf.a fi!LH msySu

YdL jrOkh wvd, u
ls .rev" f,dAyuh jHqyj,g ydks u
mdIdK rKh
foaY.=l fjkia
jeks ms<s.; yels ms<s;=re ,l=Kq (3 4 = 12)

(iv) 1. i,ashqla" khs%la jeks w, mfia we;s wefkda is,sflaguh jH hlr yka
Al whk c,hg uqod yhs' fuh u;aiHhkaf.a lru,aj, l%shdld;ajhg ndOd
3+

muqKqjhs'
2. mi yryd .,d hk w, jeis c,h fmdaIl bj;a lrk w;r Al whk ksoyia
3+

lrhs' f ksid Ydlj, Ca yd Mg jeks w;HdjYH fmdaIl fjkqjg Al whk
2+ 2+ 3+

wjfYdaIKh f' ,l=Kq (4 2 = 08)

[14 jk mssgqj n,kak

 - 14 -

(v) fidaka we,ayhsv" fmfrdlais weis,a khsf% (PAN) fmfrdlais fnkaiska khsf%
(PBN) ,l=Kq (3 2 = 06)

(vi) jk j.dj yd jk ixrlaIKh

bkaOk oykh wju lsu ,l=Kq (3 2 = 06)

(vii) wekau iqir lsu

W;afm%arl mjr;l Nd;h ,l=Kq (3 2 = 06)
9c - ^,l=Kq 50)

10' (a) n+ +
X XO2 + (5 n) 10 (4)

+
12H + 2IO3 + 10e I2 + 6H2O (5 n) (4)
+
+ n+
12(5 n) H + 2(5 n) IO3 + 10X 10 XO2 + (5 n) I2 + 6(5 n)H2O (4)

n+
IO3 : X = (10 2n) : 10
(5 n) : 5 (2)

jeh jQ X ujq, = 0.2 10

n+
= 2 10 mol (2)
3

1000

IO3
= (5 n) 1.2 10 mol
3

n+ = (4)
X 5 2 10 mol
3

5 1.2 10 = (5 n) 2 10 (2)
3 3

6.0 10 = 10 10 2 10 n
3 3 3

4 10 = 2 10 n
3 3

n = 2 (3)

10a - ^,l=Kq 25)
(b) 1. P - H2S
Q- S
R - Cr2(SO4)3
X - H2O
Y - Na2S2O3
Z - SO2 ,l=Kq (6 2 = 24)

2. (i) 3H S + 4H SO + K Cr O K2 SO4 (aq) + Cr2 (SO4)3 (aq) + 3S(s) + 7H2O(l)
2 (g) 2 4(aq) 2 2 7(aq)

(ii) H2S(g) + jemqr 2NaOH(aq) Na2 S (s) + 2H2 O(l)

(iii) 4S(s) + 6NaOH(aq) 2Na2 S (s) + Na2 S2O3(aq)+ 3H2 O

(iv) Na S O +2 HCl 2NaCl(aq)+ H2 O(l) + S(s) + SO2 (g)

2 2 3(aq)

(v) S(s)+ WKq id' 2H2SO4 (aq) 3SO2 (g) + 2H2 O(l) ,l=Kq (5 4 = 20)

[15 jk mssgqj n,kak

 - 15 -

3. SO2(g) + 2H2O(l) H2SO4 (aq) + 2H + 2e

+

X + nH
+
+ ne XHn
u,afm;s$ wjrK
jrKj;a ixfhda.h (6)

idhu 10b - ,l=Kq 50

(c) (i) I R = K [A] [B] [C] (10)

x Y Z

II 1 10 mol dm s = K (0.05mol dm ) (0.05 mol dm ) (0.05 mol dm ) (01)
3 3 1 3 x 3 Y 3 Z

3 10 mol dm s = K (0.15mol dm ) (0.05 mol dm ) (0.05 mol dm ) (02)

3 3 1 3 x 3 Y 3 Z

9 10 mol dm s = K (0.15mol dm ) (0.15 mol dm ) (0.05 mol dm ) (03)

3 3 1 3 x 3 Y 3 Z

9 10 mol dm s = K (0.15mol dm ) (0.15 mol dm ) (0.05 mol dm ) (04)

3 3 1 3 x 3 Y 3 Z

,l=Kq (5 4 = 20)
X
1 1 10 (0.05)
3

3 = X (2)
2 3 10 (0.15)
x = 1 (2)

( )
Y
3 9 10 0.15
3

3 =
(2)
2 3 10 0.05
y = 1 (2)

9 10
( )
4
3
Z
1 (2)
3 =
3 9 10 1
z = 0 (2)


III R = K [A] [B] (10)

(ii) I A jeh we;s m%udKh = 0.2 mol (2)

B iE we;s m%udKh = 0.2 mol (2)
n = 2 A ujq, 0.2 la jeh jk g B ujq, 0.2 la ksmof' (2)
tu ksid n = 2 f' (2)

n
II Kc = [P] = (0.4 ) mol dm = 1
3

[A] (0.4) mol dm3

(2) (2) (2)

III R = K [P] [B] (2)

IV Kc = [P] (2)
[A]
[P] = Kc [A] (2)
R = K K [A] [B] (2) 10c - ,l=Kq 75
c

* * *