LEMBAR PERHITUNGAN

Standarisasi Picnometer
Massa picnometer kosong = 24,991gr
Massa aquadest dan picno = 49,935 gr
Massa aquadest = 49,935 24,991 = 24,944 gr
24,944
Volume picnometer = = 0,996 /3 = 25,044

Kebutuhan NaOH 0,55 N ; V 10L

1
N NaOH = %

1
0,55 = 1 0,98
40 10

m NaOH = 224,49 gram

Kebutuhan NaOH 0,45 N ; V 10L
N1 x V1 = N2 x V2
0,55 mol/L x V1 = 0,45 mol/L x 10 L
V1 = 8,182 L ~ 8,2 L
Vaquadest = (10-8.2) L
= 1.8 L
Kebutuhan NaOH 0,55 N ; V 10L
N1 x V1 = N2 x V2
0,35 mol/L x V1 = 0,45 mol/L x 10 L
V1 =5L
Vaquadest = (10-7,55) L
= 2.45 L
Kebutuhan HCl = 0,485 N ; 500 ml
( + )
HCl =
(49,282) 20,917
=
25

= 1,1346 g/mL

V HCl = % 1000
0,4 36,5 100
= 1,1346 0,25 1000 1

= 30.84 mL
V aquades = (500 30.84) mL
= 469.16 mL

A-1
1. n CO2 Terserap
2
N CO2 terserap = N Na2CO3 =

N CO2 terserap = N CO2 terserap x Q NaOH

N HCl = 0,485 N
Q NaOH = 4,25 ml/detik = 4,25 x 10-6 m3/detik

Variabel 1 Konsentrasi NaOH 0,55 N

N CO2 terserap n CO2 terserap
T Va Vb
(mol/L) (mol/det)
1 9.6 0.2 0.0097 0.000041225

2 9.4 0.4 0.0194 0.00008245

3 9.3 0.5 0.02425 0.000103063

4 8.7 0.6 0.0291 0.000123675

5 9.1 0.8 0.0388 0.0001649

6 9.5 1 0.0485 0.000206125

7 9.1 0.7 0.03395 0.000144288

8 9 0.6 0.0291 0.000123675

9 9.7 0.4 0.0194 0.00008245

10 8.5 0.7 0.03395 0.000144288

11 9.2 0.6 0.0291 0.000123675

rata-rata 9.1909 0.5909 0.02866 0.000121801

Variabel 2 Konsentrasi NaOH 0,45 N

N CO2 terserap n CO2 terserap
T Va Vb
(mol/L) (mol/det)
1 9 0.8 0.0388 0.0001649

2 8.2 1.1 0.05335 0.000226738

3 8.4 1.3 0.06305 0.000267963

4 8.5 0.7 0.03395 0.000144288

5 8.6 0.2 0.0097 0.000041225

6 9.5 0.2 0.0097 0.000041225

7 8.4 0.5 0.02425 0.000103063

8 8.3 0.9 0.04365 0.000185513

9 8 0.4 0.0194 0.00008245

10 8.5 0.4 0.0194 0.00008245

rata-rata 8.7 0.2 0.0097 0.000041225

A-2
 Variabel 3 Konsentrasi NaOH 0,35 N
N CO2 terserap n CO2 terserap
T Va Vb
(mol/L) (mol/det)
1 7.6 0.2 0.0097 0.000041225

2 6.9 0.5 0.02425 0.000103063

3 6.2 0.4 0.0194 0.00008245

4 6.5 0.9 0.04365 0.000185513

5 6.6 0.2 0.0097 0.000041225

6 6 0.6 0.0291 0.000123675

7 6.4 0.3 0.01455 6.18375E-05

8 6.3 0.5 0.02425 0.000103063

9 6.2 0.4 0.0194 0.00008245

10 6.3 0.4 0.0194 0.00008245

rata-rata 6.4 0.6 0.0291 0.000123675

2. kGa (tetapan perpindahan massa CO2 fase gas)

=
105
= 1
( 3,14 3,32 30,3)
4

= 0,40537
2
kGa =
2
A= 4
3,32
= 4

= 0,00085487 m2
H = 30,3 cm = 0,303 m
P = 6,5 bar x 1 bar = 7.5 bar

PERHITUNGAN HARGA Kga

32
=

1 1 22
Luas kolom absorbsi (A) = 4 2 = 4 (3,3)2 = 0.00085564 2
7

Tinggi packing (Z) = 30,3 cm = 0.303 m

Fraksi ruang kosong () = 0,4054
Tekanan absolut = (6,5+1) bar = 7,5 bar

A-3
 Variabel 1 Konsentrasi NaOH 0,35 N
0.000123675
= 2
= 0.0636 3
0.00085564 0.303 0,4054 x 7,5 bar

Variabel 2 Konsentrasi NaOH 0,45 N

0.000041225
= 2
= 0.212 3
0.00085564 0.303 0,4054 x 7,5 bar

Variabel 3 Konsentrasi NaOH 0,55 N

0,000121801
= = 0.06264 3
0.00085564 0.303 1000 0,4054 x 7,5
3. kLa (tetapan perpindahan massa CO2 fase cair)
Z1 = 0,001 m

-P = Z x ( 2)

Hg = 13554 kg/m3
CO2 = 1.976 kg/m3
CO2 = 13.72 kg/ms
9.8
-P = 0.001 m x (13554 1.976)kg/3 x 1

-P = 132.8098 kg/m2
(1)2
S1 = 4
(0,021)2
= 4

= 0,000346 m2
(2)2
S2 = 4
(0,015)2
= 4

= 0,000177 m2
2 CO2 x QCO2 1,4003 CO2 1
= 4,0777 x ( ) x (CO2 x )3
CO2 x a

= 1.26 x 10-7 m2/det

6 (1)
=
6 (10,40537)
=
3,56778
=

= 1 (tetapan awal)
P
2 ( )
2
V CO2 = 1
1
2

A-4
 132.8098 /2
21( 0
1.976 /3
V CO2 = 0.000346 2
1
0.000177

V CO2 = 11.86533 m/s

Q CO2 = V CO2 x S2
Q CO2 = 11.86533 x 0,000177 = 2.100164 m3/s
1NaOH pada konsentrasi 1% (200C) = 1.0095 g/ml
NaOH pada konsentrasi 1% (400C) = 1.0033 g/ml
1 1
=
2 1 2 1
1.0095 30 20
=
1.0033 1.0095 40 20
y = 1.0064
NaOH pada konsentrasi 1% (300C) = 1.0064 g/ml
NaOH pada konsentrasi 2% (200C) = 1.0207 g/ml
NaOH pada konsentrasi 2% (400C) = 1.0139 g/ml
1 1
=
2 1 2 1
1.0095 30 20
=
1.0033 1.0095 40 20
y = 1.0173
NaOH pada konsentrasi 2% (300C) = 1.0173 g/ml
NaOH pada konsentrasi 4% (200C) = 1.0428 g/ml
NaOH pada konsentrasi 4% (400C) = 1.0352 /g/ml
1 1
=
2 1 2 1
1.0095 30 20
=
1.0033 1.0095 40 20
y = 1.039
NaOH pada konsentrasi 4% (300C) = 1.039 g/ml
m NaOH pada 0.55 N = 224,49 gram dalam 10 liter larutan
%w = 2.2449 %
m NaOH pada 0.45 N = 183.67 gram dalam 10 liter larutan
%w NaOH 0.45 N = 1.8367 %
m NaOH pada 0.35 N = 142.86 gram dalam 10 liter larutan
%w NaOH 0.35 N = 1.4286 %
Mencari NaOH 0.55 N (0.22449 %) =
1.0173 2.2449 2
=
1.039 1.0173 42

A-5
y = 1.02 gr/ml
Mencari NaOH 0.35 N (0.22449 %) =
1.0064 1.4286 1
=
1.0173 1.0064 21
y = 1.011 gr/ml
Mencari NaOH 0.45 N (0.22449 %) =
1.0064 1.8367 1
=
1.0173 1.0064 21
y = 1.015 gr/ml
NaOH pada 30o C konsentrasi 0% = 0.00080 kg/ms
NaOH pada 30o C konsentrasi 5% = 0.00103 kg/ms
NaOH pada 30o C konsentrasi 10% = 0.00143 kg/ms

Mencari viskositas NaOH 0.55 N

0.00080 2.2449 0
=
0.00103 0.00080 50
y = 0.000903 kg/ms
Mencari viskositas NaOH 0.45 N
0.00080 1.8367 0
=
0.00103 0.00080 50
y = 0.000884 kg/ms
Pada NaOH 0.35 N
0.00080 1.4286 0
=
0.00103 0.00080 50
y = 0.000866 kg/ms
Pada Konsentrasi 0.55 N
2 CO2 x QCO2 1,4003 CO2 1
= 4,0777 x ( ) x (CO2 x )3
CO2 x a

0.06264 3 2 3 bar

8,314472 x 105 x 303 K = 4,0777 x
2.1 x 109 2 /s mol.K

kg 1,4003
1.976 3 x 2.1001643 / 0.000903 kg/ms 1

( kg 3,56778 ) x( kg )3
0.000903msx 1,976 3 x 2.1 x 109 2/s

kg 1,4003
1.976 3 x 2.1001643 / 0.000903 kg/ms 1
2
= 4,0777 x ( kg 3,56778 ) x ( kg )3 x
0.000903msx 1,976 x 2.1 x 109 2 /s
3

2.1 x 109 2 /s
( 3
5 bar
)
0.06264 3 8,314472 x 10 x 303 K
mol.K

kg 1,4003
1.976 3 x 2.1001643 /
2 -4 2
= 3.2633 x 10 m /s x ( kg 3,56778 )
0.000903msx

21.4003=3.2633 x 10-4 m2/s x 22639.6158

A-6
0.5997 = 7.388
= 28.0717
3,56778
= 28.0717 = 0.1271

Untuk NaOH 0.45 N

2 CO2 x QCO2 1,4003 CO2 1
= 4,0777 x ( ) x (CO2 x )3
CO2 x a

0.212 3 2 3 bar

8,314472 x 105 x 303 K = 4,0777 x
2.1 x 109 2 /s mol.K

kg 1,4003
1.976 3 x 2.1001643 / 0.000903 kg/ms 1

( kg 3,56778 ) x( kg )3
0.000903msx 1,976 3 x 2.1 x 109 2/s

kg 1,4003
1.976 3 x 2.1001643 / 0.000903 kg/ms 1
2
= 4,0777 x ( kg 3,56778 ) x ( kg 9
)3 x
0.000903msx 1,976 3 x 2.1 x 10 2 /s

2.1 x 109 2 /s
( 3
5 bar
)
0.212 3 8,314472 x 10 x 303 K
mol.K

kg 1,4003
1.976 3 x 2.1001643 /
2 -5 2
= 9.64 x 10 m /s x ( kg 3,56778 )
0.000903msx

21.4003= 9.64x 10-5 m2/s x 22639.6158

0.5997 = 2.1825
= 3.6745
3,56778
= = 0.971
3.6745

Untuk NaOH 0.35 N

2 CO2 x QCO2 1,4003 CO2 1
= 4,0777 x ( ) x (CO2 x )3
CO2 x a

0.0636 3 2
5 3 bar
2
8,314472 x 10 x 303 K = 4,0777
mol.K
2.1 x 109
s

1,4003
kg 2.1001643 kg
1.976 3 x 0.000903 1
ms
x( kg 3,56778 ) x( kg 2
)3
0.000903 x
ms 1,976 3 x 2.1 x 109
s

kg 2.1001643
1,4003 kg
1.976 3 x 0.000903 1
2 ms
= 4.0777 x ( kg 3,56778 ) x ( kg 2
)3 x
0.000903msx 1,976 x 2.1 x 109
3 s

2.1 x 109 2 /s
( 5 3 bar
)
0.0636 3 8,314472 x 10 x 303 K
mol.K

kg 2.1001643
1,4003
1.976 3 x
2 -4
= 3.215 x 10 x ( kg 3,56778 )
0.000903msx

21.4003= 3.215 x 10-4 x 22639.6158

0.5997 = 7.2778

A-7
 = 27.3766
3,56778
= 27.3766 = 0.1303
NaOH x QNaOH 0,3 NaOH
= 0,2258 x ( ) x (NaOH x )0,5
NaOH x a

Pada Konsentrasi 0.35 N

kg 0,3
27.3766 1.011 x 103 3 x 4.25 106 3 /

2
= 0,2258 x ( kg ) x
2.1 x 109 0.000866
ms
x 0.1303
s

0.000866 kg/ms
( kg 2
)0,5
1.011 x 103 3 x 2.1 x 109
s

kLa = 1.6521 x 10-8 3
Pada Konsentrasi 0.45 N
kg 0,3
3.6745 1.015 x 103 3 x 4.25 106 3 /

2
= 0,2258 x ( kg ) x
2.1 x 109 0.000884
ms
x 0.971
s

0.000884 kg/ms
( kg 2
)0,5
1.015 x 103 3 x 2.1 x 109
s

kLa = 6.701 x 10-8 3
Pada Konsentrasi 0.55 N
kg 0,3
28.0717 1.02 x 103 3 x 4.25 106 3 /

2
= 0,2258 x ( kg ) x
2.1 x 109 0.000903
ms
x 0.1271
s

0.000903 kg/ms
( kg 2
)0,5
1.02 x 103 3 x 2.1 x 109
s

kLa = 1.634 x 10-8 3
4. k2 (tetapan reaksi CO2 dengan NaOH)

a.H . pg . D A .k 2 .[OH ] k L
2

Ra
a.H . D A .k 2 .[OH ] k L
2

1
k Ga

( )
=

H = 2.88 x 10-4 mol/ m3. Pa
= 2.1x 10-9 m2/det
Pg = 6,5 atm = 650000 Pa
N HCl = 0,485 N
Q NaOH = 4,25 x 10-6 m3/det
Pada konsentrasi 0.35 N
Ra = QNaOH .N Na2CO3 = 4,25 x 10-6 m3/det. 0.0000291 mol/m3 = 1.23675 x 10-12
(6.40,6 )0,485
= = 0.00014065 mol/m3
210

A-8
 1.23675 x 10-12 =
mol 2 2
0.1303 2.88 x 104 x 650000 2.1 x 109 2 0.00014065 mol/3 + (1.6521 x 108 3 )
3 Pa s
mol 2
0.1303 2.88 x 104 3 2.1x 109 2 0.00014065 mol/3 + (1.6521 x 108 3 )
1+ Pa

0.0636
3

k2=2315.01
Pada konsentrasi 0.45 N
Ra =QNaOH .N Na2CO3 = 4.25 x10-6 m3/s x 0.0000097 mol/m3= 4.1225x10-11 kg/s
(8.70,2 )0,485 /
= = 0.000206125 mol/m3
210
4.1225x10-11 kg/s =
mol 2 2
0.971 2.88 x 104 3 x 650000 2.1 x 109 2 0.000206125 mol/3 + (6.701 x 108 3 )
Pa s
mol 2 2
0.971 2.88 x 104 3 2.1 x 109 2 0.000206125 mol/3 + (6.701 x 108 3 )
Pa s
1+

0.212 3

k2 = 621.78
Pada konsentrasi 0.55 N
Ra = QNaOH x N Na2CO3 = 4.25 x 10-6 m3/s x 0.02866 mol/l =1.22655x10-10 mol/m3
(9.190,59 )0,485
= = 0.00020855 mol/m3
210
1.22655 x10-10 mol/m3 =
mol 2 2
0.1271 2.88 x 104 x 650000 2.1 x 109 2 0.00020855 mol/3 + (1.634 x 108 3 )
3 Pa s
=
mol 2 2
0.1271 2.88 x 104 3 2.1 x 109 2 0.00020855 mol/3 + (1.634 x 108 3 )
Pa s
1+

0.093728 3

k2 = 633.8

A-9