Three-parameter Margules equation and the graph of experimental data are shown below.

P/kPa x1 y1 ln gamma1 x2 y2 ln gamma2 GE/RT GE/RTx1x2

29.819 0 0 #DIV/0! 1 1 2.71828183 #DIV/0! #DIV/0!
31.957 0.0455 0.1056 14.4405275 0.9545 0.8944 2.7297767 3.262616 75.123985
33.553 0.094 0.1818 10.3411056 0.906 0.8182 2.76261436 3.474993 40.803538
35.285 0.1829 0.2783 6.90888116 0.8171 0.7217 2.8438245 3.587323 24.003889
36.457 0.2909 0.3607 5.0903942 0.7091 0.6393 3.01097095 3.615875 17.529205
36.996 0.398 0.4274 4.17965159 0.602 0.5726 3.25467965 3.622818 15.12053
37.068 0.5069 0.4885 3.61827896 0.4931 0.5115 3.63092068 3.624513 14.500812
36.978 0.5458 0.5098 3.46736151 0.4542 0.4902 3.81282738 3.624272 14.619756
36.778 0.5946 0.5375 3.3096839 0.4054 0.4625 4.08406871 3.62362 15.032594
35.792 0.7206 0.6157 3.00696259 0.2794 0.3843 5.21198733 3.623047 17.995058
34.372 0.8145 0.6913 2.85827305 0.1855 0.3087 6.80900928 3.591135 23.768221
32.331 0.8972 0.7869 2.77546498 0.1028 0.2131 9.46486395 3.463135 37.548022
30.038 0.9573 0.8916 2.73777375 0.0427 0.1084 12.9007605 3.171733 77.592675
27.778 1 1 2.71828183 0 0 #DIV/0! #DIV/0! #DIV/0!
P1sat is where x1=1.000, y1=1.000